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Read the following Instructions very carefully before you proceed.

1. The question paper consists of 3 Subjects (Subject I : Chemistry, Subject II : Physics,
Subject III : Mathematics). Each Subject has 2 sections (Section I and Section II)
2. Section I contains 2 types of questions [Type 1 & Type 2]
Type 1 contains 5 Single Correct Answer Type Questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONLY ONE CHOICE is correct.
 Marking scheme [3 Marks for Correct answer & –1 NEGATIVE MARKING for wrong answer]
Type 2 contains 8 Multiple Correct Answer Type Questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE OR MORE CHOICES may be correct.
 Marking scheme [4 Marks for All Correct answers, +1 for Partially correct answer and
–2 NEGATIVE MARKING for wrong answer]
3. Section II contains 5 Single Integer Value Type Questions. The answer to each of the questions is a
single-digit integer, ranging from 0 to 9 (both inclusive).
 Marking scheme [3 Marks for Correct answer & NO NEGATIVE MARKING for wrong answer]
4. For answering a question, an ANSWER SHEET (OMR SHEET) is provided separately. Please fill your
Test Code, Roll No. and Group properly in the space given in the ANSWER SHEET.
5. No one will be permitted to leave the test room before the end of the test, i.e. 01.00 PM.

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SUBJECT - I (CHEMISTRY) 62 MARKS

SECTION - I [TYPE-1]
SINGLE CORRECT ANSWER TYPE
This section contains 5 Single Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONLY ONE Choice is Correct:

1. Which of the following represents qualitative sketch of probability (P) of finding electron versus
distance from nucleus (r) for 2s-orbital of hydrogen atom?

2. 1 mole of an ideal gas is expanded reversibly and isothermally at temperature 300 K to double its
volume. Calculate G during this process.
(Take 2.303  R  log 2  5.76 )
(A) 1728 J (B) 0 (C) 1728J (D) 750 J

2 2 3 
Among  Ni  CN 4  ,  Ni  H 2 O 6  ,  CrCl6 
3
3. , Co  NH 3 6  , KO 2 and N O , the total number of
paramagnetic species is : [Atomic Number Ni  28, Co  27, Cr  24]
(A) 2 (B) 3 (C) 4 (D) 5

4. The increasing order of first ionization enthalpy of the following Group 14 elements is:
(A) Pb  Sn  Ge  Si  C (B) Sn  Pb  Ge  Si  C
(C) C  Si  Ge  Sn  Pb (D) C  Si  Ge  Pb  Sn

5. Which of the following polymers is formed by only one type of monomeric units?
(A) Bakelite (B) Terylene (C) Teflon (D) PHBV

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SECTION - I [TYPE-2]
MULTIPLE CORRECT ANSWER TYPE
This section contains 8 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONE or MORE Choices may be Correct:

6. The product(s) of the following reaction sequence is(are) :

(i) Fuming H2SO4

 
(ii) NaOH (aq.)
(iii) Br2 / H 2 O (excess)
(iv) NaNO 2 / HCl  0  5C 
(v) H3 PO 2

7. The correct statement(s) about the following reaction sequence is (are):

(A) W gives dark violet coloration with 1% aqueous FeCl3 solution

(B) X gives effervescence of a colorless, odorless gas with aq. NaHCO3
(C) Z is used as anti-inflammatory drug
(D) Z can give X on acidic hydrolysis

8. For the molecule of diborane  B2 H 6  , which of the following statement(s) is(are) correct?
(A) Hybridisation of both boron atoms is sp3
(B) All bond angles around each boron atom are identical
(C) All B  H bond lengths are equal
(D) The maximum number of atoms that can lie in same plane is 6

9. Which of the following statement(s) is/are correct? When a mixture of NaCl and K 2 Cr2 O7 is gently
heated with conc. H 2SO4 ?
(A) Deep red vapours are evolved
(B) The vapours when passed into NaOH solution gives yellow solution of Na 2 CrO 4
(C) Chlorine gas is evolved
(D) Chromyl chloride is formed

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27 29
10. 13 Al is a stable isotope than 13 Al . The latter is expected to disintegrate by:
(A)   emission (B)   emission
(C) positron emission (D) proton emission

11. Positive Tollen’s test is observed for:

O
||
(A) H  C  OH (B)

(C) (D)

12. The molecule having linear shape is(are):


(A) BeCl2 (B) XeF2 (C) I3 (D)  I  CN 2 

13. Rate of chemical reaction depends on:

(A) The number of collisions between molecules
(B) The force of collisions between molecules
(C) The orientation of collisions between molecules
(D) The spontaneity of the reaction

SECTION - II
SINGLE INTEGER VALUE CORRECT TYPE
This section contains 5 single Integer Value Correct type Questions. Each question has an integer answer
between 0 and 9. Fill the answer bubbles in the OMR Sheet APPROPRIATELY and CAREFULLY.
1. In the following monobromination reaction, the number of possible products (including
stereoisomers) are ______.

2. 2 molal aqueous sugar solution is heated to 105.2°C. If the fraction of water (by mass) present in the
solution that will vapourise out at this temperature is X. Then what is the value 10 X ? (Take K b of
H 2O  0.52C kg mol1 ).

3. 
The number of stereoisomers possible for the complex Co  gly 3  , gly  NH 2 CH 2 COO  is______. 
4. The number of moles of oxalate ions C 2O 24    that can be oxidized by two moles of KMnO 4 in
acidic medium are ______.

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5. A vessel of volume 5 liters contains 1.40 grams of dinitrogen at a temperature 1800 K. The pressure
of gas in atm (approximated to nearest integer) if 30% of its molecules are dissociated into atoms
is ______.

SUBJECT - II (PHYSICS) 62 MARKS

SECTION - I [TYPE-1]
SINGLE CORRECT ANSWER TYPE
This section contains 5 Single Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONLY ONE Choice is Correct:

1. The cross-section of a prism is shown in the figure. One of

its reflecting surface AC is given by y  x 2 . A ray of light
travelling parallel to x-axis is incident normally on the face
AB. The minimum distance of the incident ray from the point
A to get refracted ray from surface AC is:
2  1 2  1
(A) (B)
2 4
2  1
(C) (D) None of these
8

2. A parallel beam of uniform monochromatic light of wavelength 546 nm has an intensity of

200 W/m 2 . The number of photons in 1 mm3 of this radiation is:
(A) 183 (B) 1831 (C) 18311 (D) 183117

3. Water of volume 2 litre in a container is heated with a coil of 1 kW at 27ºC. The lid of the container is
open and energy dissipates at rate of 160 J/s. In how much time temperature will rise from 27ºC to
77ºC? [Given specific heat of water is 4.2 kJ/kg]
(A) 8 min 20 s (B) 6 min 2 s (C) 7 min (D) 14 min

4. A conductor of rectangular cross-section has dimension

(a  2a  4a) as shown. Resistance across AB, CD and
EF are RAB , RCD , REF respectively. Then:
(A) RAB : RCD  2 :1
(B) RAB : REF  8 :1
(C) RCD : REF  1: 4
(D) None of them are correct

5. When force F acts on side of hexagonal body for what

range of coefficient of friction body will topple?
(A)   0.29 (B)   0.29
(C)   0.21 (D)   0.21

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SECTION - I [TYPE-2]
MULTIPLE CORRECT ANSWER TYPE
This section contains 8 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONE or MORE Choices may be Correct:

6. A rod of mass M is hinged at A on a smooth horizontal surface and can rotate about A without
friction. A particle of mass m moving on the horizontal plane strikes the rod and comes to rest just
after collision.

(A) Impulsive hinge reaction at A may be in forward direction during collision

(B) Impulsive hinge reaction at A may be in backward direction during collision
(C) Hinge reaction can not be zero during collision
(D) Angular momentum of system about A will remain conserved

7. A ray of light is incident grazingly on face AB of a right angled prism as shown. It emerges out of
face AC, as shown, e = Angle of emergence. Refractive indices of different media have been shown in
the diagram. Choose the correct alternatives.

(A) 12  sin 2 e   22

(B)  22  sin 2 e  12

(C) 12  cos 2 e   22

(D) If the ray just fails to emerge out of the face AC of the prism, for  2  3 , angle of refraction
2
at face AB is sin 1
3

8. A ball is projected with initial speed V at distance

20 cm from pole of a concave mirror. Speed of image
cannot be:
(A) Greater than V
(B) Less than V
(C) Equal to V
(D) Zero

9. Ionization energy of a hydrogen-like ion A is greater than that of another hydrogen-like ion B. Let r,
u, E and L represent the radius of the orbit, speed of the electron, energy of the atom and orbital
angular momentum of the electron respectively. In ground state choose the incorrect option.
(A) rA  rB (B) u A  uB (C) E A  EB (D) LA  LB

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10. Let 0 be the absolute permittivity,  r be the relative permittivity, 0 and  r be the absolute and
relative permeability respectively. If M represents mass, L represents length, T represents time and I
represents current, then:
(A) [0 ]  [ M 1L3T 2 ] (B) [(00 ) 2 ]  [ M 0 L4T 4 ]
(C) [r  r ]  [ M 0 L2T 2 ] (D) [r ]  [ r ]

 
11. A waveform: y1 = A sin  2 x  4t   is superposed with a second waveform, to produce a standing
 3
wave with a node at x = 0. The equation of the second waveform can be:
 5   
(A) y2  A sin  2 x  4t   (B) y2  A sin  2 x  4t  
 3   3
   
(C) y2  A sin  2 x  4t   (D) y2  A sin  2 x  4t  
 3  3

12. Current passing through a coil varies with time t as i = 2t2. At 1 second total flux passing through the
coil is 10 weber. Then:
(A) self-inductance of the coil is 10 H
(B) self-inductance of the coil is 5 H
(C) induced emf across the coil at 1 second is 20 V
(D) induced emf across the coil at 1 second is 10 V

13. Pick the correct statements(s):

(A) The rms translational speed for all ideal-gas molecules at the same temperature is not the
same but it depends on the mass.
(B) Each particle in a gas has average translational kinetic energy and the equation
1 2 3
mvrms  kT establishes the relationship between the translational kinetic energy of a
2 2
particle and temperature of an ideal gas.
(C) Temperature of an ideal gas is doubled from 100°C to 200°C. The average kinetic energy of
each particle is also doubled.
(D) It is possible for both the pressure and volume of a monoatomic ideal gas to change
simultaneously without causing the internal energy of the gas to change.

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SECTION - II
SINGLE INTEGER VALUE CORRECT TYPE
This section contains 5 single Integer Value Correct type Questions. Each question has an integer answer
between 0 and 9. Fill the answer bubbles in the OMR Sheet APPROPRIATELY and CAREFULLY.
1. A long coaxial cable consists of two thin walled, conducting cylinders with inner radius 2cm and
outer radius 8cm. The inner cylinder carries a steady current 1 A, and the outer cylinder provides the
return path for that current. The current produces a magnetic field between the two cylinders.
The energy stored in the magnetic field for length 1 m of the cable is 20x nJ. The value of x is
__________. (Use ln 2 = 0.7)

2. A monoatomic gas initially in state A(P0, V0) is taken through a

cyclic process ABCA as shown in the figure. The pressure of point B
is twice of that of A. The curve BC is a rectangular hyperbola. If the
net work done by the gas is xP0V0, then find the value of x.

3. The ratio between total acceleration of the electron in singly ionized helium atom and hydrogen atom
when both in ground state is __________.

4. A viscous fluid fills the clearance between a shaft and a sleeve. When a force of 800 N is applied to
the shaft, parallel to the sleeve, the shaft attains a speed of 2 cm/s. If a force of 2.4 kN is applied
instead, the shaft would move with a speed k cm/s, the value of k is __________.

5. Consider the nuclear reaction X 200  A110  B80 . If the binding energy per nucleon for
X, A and B are 7.4 MeV, 8.2 MeV and 8.1 MeV respectively, then the energy released in the reaction
is 10k MeV, the value of k is __________.

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SUBJECT - III (MATHEMATICS) 62 MARKS

SECTION - I [TYPE-1]
SINGLE CORRECT ANSWER TYPE
This section contains 5 Single Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONLY ONE Choice is Correct:
 
1. Let      . Let 1 and 1 are the roots of the equation x 2  4 x cosec   4  0 and  2 and 2
3 6
are the roots of the equation x 2  4 x cot   4  0 . If 1  1 and  2  2 , then 1  2 equals.
(A) 4  cosec   cot   (B) 4cosec  (C) 4cot  (D) 0

2. There are 5 male and 5 female tennis players. A team of 4 players is to be selected from these players
including a captain (from these 4 players) for the devis cup tournament. If the team has to include at
least one girl, then number of ways of selecting team is:
(A) 820 (B) 210 (C) 800 (D) 200

 
3. Let S   x   ,   ; x  0,   . The sum of all distinct solution of the equation
 2
sec x  cosec x  2  tan x  cot x   0 in the set S is equal to:
5  
(A)  (B)  (C) 0 (D)
6 2 2

4. A sport company has only two plants s1 and s2 . Plant s1 produces 30% and plant s2 produces 70% of
the total sports product. 10% of the products produced in this company turn out to the defectives. It is
known that P (products turn out to be defective given that it produced in plant s1 ) = 8 P (products turn
out to be defective given that it is produced in plant s2 ). Where P(E) denotes the probability of an
event E. A product produced in the factory is randomly selected and it does not turn out to be
defective. Then the probability that it is produced in plant s2 is:
70 72 78 81
(A) (B) (C) (D)
93 93 93 93
1
5. The least value of   R  for which 4x 4   2 for all x  0 , is:
x2
1 2 4 8
(A) (B) (C) (D)
27 27 27 27

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SECTION - I [TYPE-2]
MULTIPLE CORRECT ANSWER TYPE
This section contains 8 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONE or MORE Choices may be Correct:

6. Consider a pyramid OPQRS located in the first octant  x  0, y  0, z  0  with O origin and OP and
OR along the x-axis and y-axis respectively. The base OPQR of the pyramid is square with OP = 2.
The point S is directly above the mid-point T of diagonal OQ such that TS = 2, then:
 1 
(A) The acute angle between RS and PQ is cos 1  
 6
(B) The equation of the plane containing O, R, S is 2 x  z  0
4
(C) The length of perpendicular from P on the plane containing O, R, S is
5
(D) The perpendicular distance from O to the straight line containing PQ is 4

f  x
7. Let f :  0,    1  R be a differentiable function such that f '  x   1  for all x  domain of
x 1
1
the function and f  2   , then:
2
1 1 1 1
(A) lim f '    (B) lim x f   
x 0  x 2 x 0  x 2
(C) lim x 2 f '  x   1 (D) f  x   2 for all x   0, 2 
x 0

8. In a triangle ABC, let a, b, c be the lengths of sides opposite to the angles A,B,C respectively and
s a s b s c 7
2s  a  b  c . If   . The area of incircle of the ABC is , then:
3 5 7 25
3 7 16
(A) Area of ABC is (B) the radius of circum circle of ABC is
5 5 7
A B C 7  A B 3
(C) sin sin sin  (D) sin 2  
2 2 2 64  2  5
9. 
A curve of the differential equation x 2  xy  6 x  3 y  9
dy
dx

 y 2  0 passes through the point (1, 1)

then the solution curve:

(A) Intersects y  x  3 exactly at one point (B) Intersects y  x  3 exactly at two points
Intersect y   x  3 Does not intersect y   x  3
2 2
(C) (D)

10. Let f : R  R, g : R  R and h : R  R be differentiable function such that f  x   x3  3x 2  4

 
g  f  x    x and h g  g  x    x for all x  R :
1 2
(A) g ' 4  (B) h  0   116 (C) h '  2   44928 (D) g ' 4 
9 3

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11. Let C1 : x 2  y 2  4 with center at O intersect the parabola x 2  3 y at the point P in the first quadrant.
Let the tangent to the circle C1 at P touches other two circles C2 and C3 at R2 and R3 , respectively
suppose C2 and C3 have equal radii 1 unit and centers Q2 and Q3 respectively such that Q2 and Q3
lie on Y-axis then:
(A) Q2Q3  4 (B) R2 R3  2 3
(C) area of OR2 R3 is 2 3 (D) area of the PQ2Q3 is 6

12. Let R S be the diameter of the circle x 2  y 2  2 , where S is the point  

2,0 . Let P be a variable
point (Other than R and S) on the circle and tangents to the circle at S and P meet at the point Q. The
normal to the circle at P intersects a line drawn through Q parallel to RS at point E. Then the locus of
E passes through the points:
 1   1   1   1 
(A)  ,1 (B)  ,0  (C)  ,0  (D)  ,0 
2 2   2  2 3   3 

13. If for a square matrixes,  aij  of even order aij  i 2  j 2 , then :

(A) A is skew-symmetric (B) A is a perfect square

(C) A is symmetric and A  0 (D) A is neither symmetric nor skew symmetric

SECTION - II
SINGLE INTEGER VALUE CORRECT TYPE
This section contains 5 single Integer Value Correct type Questions. Each question has an integer answer
between 0 and 9. Fill the answer bubbles in the OMR Sheet APPROPRIATELY and CAREFULLY.

1. If the value of  lying between 0 to and satisfying.
2
1  sin 2  cos 2  4sin 4
n
The equation sin 
2
1  cos 2
4sin 4  0 is given by , where HCF  n, k   1 , then the
k
sin 2  cos 2  1  4sin 4
k
value of is given by _________.
12
1 
2. Let x be the solution set of the equation A x  I ; where A   32 2  and I is the corresponding unit
 n
  cos x   sin x 

matrix and x  N , then find the minimum value of  R   , n  I  .
2 
x
t6
3. The total number of distinct x   0,1 for which  1  t 6 dt  3x  1 is _________.
0

x 2 tan  k2 x 
4. Let k1 , k2  R be such that lim  1 . Then  k1  k2  equals _________. (where [ . ]
k1 x  tan x
x 0

represents greatest integer function)

  x  x  a x
4 45
5. If 1  x  x 2  ........  x9 2
 x3  .....  x9  r
r

r 1
and the value of a2  a6  a10  ........  a42 is  , then sum of all digits of  is_________.

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