Name : …….……………………………………...…….… Index number : ……………..

Class : …………………..

CONFIDENTIAL
Chemistry
Paper 3
September
2007
1½ jam
SPM TRIAL EXAMINATION 2007
MAKTAB RENDAH SAINS MARA

CHEMISTRY
Paper 3
One hour and thirty minutes

For Examiner’s Use

DO NOT OPEN THIS QUESTION BOOKLET
UNTIL BEING TOLD TO DO SO
Full Obtained
Question
Mark Mark
1. Write your name, index number and class
in the space provided.
1 33
2. This question booklet is bilingual.
2 17
3. The question is in English followed by the
Malay version.
Total 50
4. Candidate is required to read the
instruction on page 2.

This question booklet contains 13 printed pages.

[See Next Page
INFORMATION FOR
4541/3 © 2007 Hak CANDIDATES
Cipta MARA CONFIDENTIAL
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INFORMATION FOR CANDIDATES [MAKLUMAT UNTUK CALON]

1. This question paper consists of two questions. Answer all questions.

[Kertas soalan ini mengandungi dua soalan. Jawab semua soalan]

2. Write your answers for Question 1 in the spaces provided in the question paper.
[Tuliskan jawapan bagi Soalan 1 dalam ruang yang disediakan dalam kertas soalan]

3. Write your answers for Question 2 on the lined pages at the end of the question
paper in detail.
[Tuliskan jawapan bagi Soalan 2 pada halaman bergaris di bahagian akhir kertas
soalan ini dengan terperinci]

4. Show your working, it may help you to get marks.

[Tunjukkan cara mengira kerana ia boleh membantu anda mendapatkan markah]

5. If you wish to cancel any answer, neatly cross out the answer.
[Sekiranya anda hendak membatalkan sesuatu jawapan, buat garisan di atas
jawapan itu.]

6. The diagrams in the questions are not drawn to scale unless stated.
[Rajah yang terdapat dalam soalan tidak dilukis mengikut skala kecuali dinyatakan
sebaliknya.]

7. Marks allocated for each question or part of the question are shown in brackets.
[Markah yang diperuntukkan bagi setiap soalan atau ceraian soalan ditunjukkan
dalam kurungan.]

8. The time suggested to complete Question 1 is 45 minutes and Question 2 is 45

minutes.
[Masa yang dicadangkan untuk menjawab Soalan 1 ialah 45 minit dan Soalan 2
ialah 45 minit.]

9. You may use a non-programmable scientific calculator.

[Anda dibenarkan menggunakan kalkulator saintifik yang tidak diprogramkan.]

10. Hand in all your answer sheets at the end of the examination.
[Serahkan semua kertas jawapan anda di akhir peperiksaan.]

Marks awarded [Pemberian markah]

Score
Description [Penerangan]
[Skor]
Excellent : The best response
3
[Cemerlang] : [Respons yang paling baik]
Satisfactory : An average response
2
[Memuaskan] : [Respons yang sederhana]
Weak : An inaccurate response
1
[Lemah] : [Respons yang kurang tepat]
No response or wrong response
0
[Tiada respons atau respons yang salah]

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1 An experiment is carried out to determine the end point of a neutralisation process. For
50.00 cm3 of aqueous potassium hydroxide 0.1 mol dm-3 is titrated against Examiner’s
Use
hydrochloric acid with an unknown concentration using phenolphthalein as an [Untuk
indicator. Kegunaan
The titration is repeated twice. Diagram 1.1 shows the results of the experiment. Pemeriksa]

[Satu eksperimen telah dijalankan untuk menentukan takat akhir bagi proses peneutralan. 50.00 cm3
larutan kalium hidroksida 0.1 mol dm-3 dititratkan dengan asid hidroklorik yang kepekatannya tidak
diketahui dengan menggunakan penunjuk fenolftalein.
Pentitratan diulang sebanyak dua kali. Rajah 1.1 menunjukkan keputusan eksperimen.]

Titration Set 1 2 3
[Set Titratan]

Initial Burette
Reading
[Bacaan Awal
Buret]

………………cm3 ………………cm3 ………………cm3

Final Burette
Reading
[Bacaan akhir
buret]

………………cm3 ………………cm3 ………………cm3

DIAGRAM 1.1
[RAJAH 1.1]

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For
Examiner’s
Use
[Untuk
Kegunaan
(a) State two observations that you could obtain during the experiment.
[Nyatakan dua pemerhatian yang boleh diperoleh semasa eksperimen]
Pemeriksa]

1(a) 1. ………………………………………………………………………….

2. ………………………………………………………………………….
[3 marks]

(b) Record the burette readings in the spaces provided in Diagram 1.1.
[Catatkan bacaan buret pada ruang yang disediakan dalam Rajah 1.1]
1(b)

[3 marks]

(c) Construct a table and record the initial burette readings, final burette readings and
volume of hydrochloric acid needed for each titration set.
[Bina sebuah jadual dan rekodkan bacaan awal buret, bacaan akhir buret dan isipadu asid hidrokorik
yang diperlukan bagi setiap set pentitratan]

1(c)

[3 marks]

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For
(d) (i) What is the average volume of hydrochloric acid used in the experiment? Examiner’s
[Berapakah purata isipadu asid hidroklorik yang digunakan dalam eksperimen ini?] Use
[Untuk
Kegunaan
Pemeriksa]

(ii) The chemical equation for the reaction is :

[Persamaan kimia bagi tindak balas ini ialah:]

KOH + HCl → KCl + H2O

Determine the concentration of hydrochloric acid used.

[Tentukan kepekatan asid hidroklorik yang digunakan.]

1(d)

[3 marks]

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For
Examiner’s
Use (e) The experiment is repeated using sulphuric acid to replace hydrochloric acid.
[Untuk It was found that the volume of sulphuric acid required is half the volume of
Kegunaan
Pemeriksa]
hydrochloric acid used.
State the inference of this observation.
[Eksperimen ini diulang dengan menggunakan asid sulfurik untuk menggantikan asid hidroklorik.
Didapati isipadu asid sulfurik yang diperlukan adalah separuh daripada isipadu asid hidroklorik yang
digunakan.
Nyatakan inferens bagi pemerhatian ini]

……………………………………………………………………………………….
1(e)
………………………………………………………………………………………..

[3 marks]

(f) Potassium chloride which is produced in this experiment is an example of a soluble

salt.
Classify the following substances into soluble and insoluble salt.
[Garam yang terhasil dalam eksperimen ini ialah kalium klorida, sejenis garam terlarutkan. Kelaskan
bahan – bahan berikut kepada garam terlarutkan dan garam tak terlarutkan.]

Substances
[Bahan – bahan]

Sodium sulphate Lead(II) iodide Barium sulphate

[Natrium sulfat] [Plumbum(II) iodide] [Barium sulfat]

Magnesium nitrate Zinc carbonate Silver chloride

[Magnesium nitrat] [Zink karbonat] [Argentum klorida]

1(f)

[3 marks]

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For
(g) Diagram 1.2 shows three test tubes containing potassium hydroxide solution with Examiner’s
different concentrations and pH values. Use
[Rajah 1.2 menunjukkan tiga tabung uji yang mengandungi larutan kalium hidroksida pada kepekatan [Untuk
dan nilai pH yang berbeza.] Kegunaan
Pemeriksa]

Test tube
1 2 3
[Tabung uji]

Concentration
[Kepekatan]

0.1 mol dm-3 0.01mol dm-3 0.001 mol dm-3

potassium hydroxide potassium hydroxide potassium hydroxide
[kalium hidroksida] [kalium hidroksida] [kalium hidroksida]

pH value
13 12 11
[Nilai pH]

DIAGRAM 1.2
[RAJAH 1.2]

Based on Diagram 1.2,

[Berdasarkan Rajah 1.2,]

(i) Give the operational definition for the pH value of an alkali.

[Berikan definisi secara operasi bagi nilai pH untuk suatu alkali]

………………………………………………………………………………………. 1(g)(i)

……………………………………………………………………………………….
[3 marks]

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For
Examiner’s
Use
[Untuk
Kegunaan (ii) Predict the pH value if the concentration of potassium hydroxide solution is
Pemeriksa] 0.0001 mol dm-3.
[Ramalkan nilai pH bagi larutan kalium hidroksida yang berkepekatan 0.0001 mol dm-3.]
1(g)(ii) ………………………………………………………………………………............

………………………………………………………………………………………
[3 marks]

(iii) As the concentration of the potassium hydroxide solution changes, the pH value
also changes. Explain why.
[Apabila kepekatan larutan kalium hidroksida berubah, didapati nilai pH juga berubah.
Terangkan mengapa.]
1(g)(iii)
………………………………………………………………………………............

………………………………………………………………………………………
[3 marks]

(iv) State the variable involved in this experiment.

[Nyatakan pembolehubah yang terlibat dalam eksperimen ini.]

Manipulated variable: ……………………………………………………………….

[Pembolehubah yang dimanipulasikan]

Responding variable: ……………………………………………………………….

1(g)(iv) [Pembolehubah yang bergerakbalas]

Controlled variable: ………………………………………………………………...

[Pembolehubah yang dimalarkan]

[3 marks]
(v) State the hypothesis for this experiment.
[Nyatakan hipotesis bagi eksperimen ini.]

………………………………………………………………………………............
1(g)(v)
………………………………………………………………………………………
[3 marks]

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2 Equal volume of water is heated in two different kettles by a scout during camping.
Kettle 1 is heated by using alcohol X while kettle 2 is heated by using alcohol Y as
shown in Diagram 2. The size and type of both kettles are the same.
[Semasa perkhemahan, seorang pengakap telah memanaskan air yang mempunyai isipadu yang
sama dalam dua cerek berlainan Cerek 1 dipanaskan dengan alkohol X manakala cerek 2
dipanaskan dengan alkohol Y seperti ditunjukkan dalam Rajah 2. Saiz dan jenis kedua –dua cerek
adalah sama.]

Kettle 1 Kettle 2
[Cerek 1] [Cerek 2]

DIAGRAM 2
RAJAH 2

It was discovered that the mass of alcohol X needed to boil the water is more
compared to alcohol Y.
[Didapati jisim alkohol X yang diperlukan untuk mendidihkan air lebih besar berbanding alkohol Y.]

Plan a laboratory experiment to compare the heat of combustion between alcohol X

and Y based on the above situation.
[Berdasarkan kepada situasi di atas, rancangkan satu eksperimen makmal untuk membandingkan
haba pembakaran antara alkohol X dan Y.]

Your planning should include the following aspects:

[Perancangan anda haruslah mengandungi aspek berikut :]

(a) Problem statement [Pernyataan masalah]

(b) All the variables [Semua pembolehubah]
(c) Statement of hypothesis [Pernyataan hipotesis]
(d) List of substances and apparatus [Senarai bahan dan alat radas]
(e) Procedure of the experiment [Prosedur eksperimen]
(f ) Tabulation of data [Penjadualan data]

[17 marks]

END OF QUESTION PAPER

[KERTAS SOALAN TAMAT]

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For SPACE FOR YOUR ANSWERS / RUANG JAWAPAN

Examiner’s
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SPACE FOR YOUR ANSWERS / RUANG JAWAPAN For

Examiner’s
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SPACE FOR YOUR ANSWERS / RUANG JAWAPAN

For
Examiner’s __________________________________________________________________________
Use
[Untuk __________________________________________________________________________
Kegunaan __________________________________________________________________________
Pemeriksa]
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SPACE FOR YOUR ANSWERS / RUANG JAWAPAN For

Examiner’s
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[Untuk
__________________________________________________________________________ Kegunaan
Pemeriksa]
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