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eactron
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Ug Which letter represents the enthalpy change of the forward direction?
ooA"
ND MARK for TITUE or "B" for FALSE : Theforu,ard. reactionis an example of an enclothermic
reaction.
L-, -t:, The rate of formation of oxygen in the reaction 2NzOs(g) + 4NO2(g) + Oz(g) is2.2-B (mol 02) L-
's-'. What is the rate of decomposition of NzOs?
A. 0.57 (mol N2O5) L-rs-r
B. 9.12 (mol NzOs) L-rs'r
C. 2.28 (mo1N2O5) L-rs-l
D. 1.14 (molNzOs) L-rs-
E. 4.56 (molNzOs) L'rs-r
t"-'
\ , ,"0, t H:etdGq) -b* -y$dq) + cl-(aq) FASr
lo,on-frc1 + rlpkre) --5* H2o(l) + Io-(aq) slow
\
L,' Which of the lollowing expresses the rate law for the given mechanism?
rate: ft[OH-][HIO]
B. rate : flOH-lllllHClOl
C. :
rate rtoHl tll tHClOl{Cll
D. rate : f[I'][I{2O][ClO:],
E. rate : rU-ltHClOl [Clol [oHl'z
\--
LrrN Which of the following represents an intermediate in the rnechanism?
\-A.I clo-
B. oH-
C. CI'
D. I'izO
E. None of the above
V
7'/^
(ts,\ Which of the following represents a catalyst in the mechanism?
f\. clo-
B. HIO
C. cl-
D. HzO
E. There is no catalyst in the mechanism.
(-
L- ZO. Consider the Haber Process for the synthesis of ammonia gas, an exothermic reaction. Which
factor will)Olinerease the concentration of ammonia?
A. increasing the concentration of Nz
B. increasing the concentration of I{z
C. decreasing the temperature
D. increasing the pressure of the system
E. increasing the volume of the system
For Qtrestions 21 - 24, trse the follor,ving answer choices:
A. r\oidic becarrse it is strong acid.
a_
e :e . A 1.25 M solution of the weak acid HA is 9.2Yo dissociated. What is the pH of the solution?
A. 0.64 B. 0,94 c. 1.13 ' D. 2.16 E. 3.39
D-rr.For the reaction 99g) + 3Hz,G) -- gzOig) + Cff+(e), K. :0_03! : 189 at 1000 K. If a vessel is filled
with these gases zuch thafthe-initial concentrations afe 1CO1 M, [Hz] :9.045 M, [HzO] :
i0.020\( and [CH+] :0 010 M,. in which direction will the reacfion occur and wh]?-
3
E. lll:3:H:iJ::::*Ii,1l,"J',f*,1,::";I:t:u',
L. rre reasrron
The at equurD,ur,
is ar
reaction rs equilibrium because K.: Q.. ffi ,,:u-
i* i:U
u""ourr::::_-_****:.*;
G,= * k.=
e < v _>,1:ior{t,d.li
r8c'1
n
e_ze,DeterminethepHofa0.253MsoIutiono@H4CD?Ku:l'2x10..Vml.|l
A. 2l ri. +.e \c e.n @- y-= v..,.
Wa.5 o Y- b
E, ], Consider thc dimerization reaction: 2A -+ Az
rate = k[Al'
When the initial concentration of A is 2.0 M, it requires 30 min for 60Yo of A to react. Calculate
the rate constant.
A. l.1x lo-3M'ls-l J- r re (Eo)
7,0
B. 3.2 x l}-a M-rs-r
C. 5.0 x M-ls-l
10-a U * Pf,r-r)
D. 4.2 x l}'a M-ls-l
E. None of the above ,O7= v-V Q]= = \t =
\qipri
t4
L 30. A first-order reaction has a half-life of 231 S. The time required for 600/o reaction is:
A. 153 s. B. 73.9 s. C. 170 s. D. 133 s. E. 305 s.
, For Questions 31 -33, consider a solution of 0.10 M arsenic acid (I{3AsOa), where I(u1 :6.0 x 10-3, Kur:
' 1.0 * l0-7, and K* : 3.0 x i0-12.
'z ,{L
ft-O Determine the plI of this solution.
A. t.7 B. 4.0 c. 6.3 D. 1.0 8.3.2
r-\ z._
U
^ (8)What is the concentration of [HzAsO,{-]?
H2I\sOu a------- f++ H2 A='Ou
c.. v. x\
+
r,y)r
-A. 1.0 x 10-7 M
B. 6.0 x 10-3 M \ . \0tv\
+x
c '/-
+y
c. 0.022M C -/ kq't ('o'(\0+
D. 0.077 M t
E. 6.0 x i0-ro M /= jldql,ottL
t93t 97F l?,\= I'Ll
n {ll)O"termine
U i^\ the concentration of .?H =
[AsO4-3].
A. x 10-7
- 1-
10-'M
1.0 H,-A sOu =-- H. + HAdO;'-
-v/ B.
C.
1.4 x 10-17 M
3.0 x 10-12 M
\ . o? tL18 .o7h1e
-l-\
o
+y
D. 3.0 x 10-re M C -/
kr= 1.0 x\(r'1
E. 6.0 x 10-ro M E ,021179'Y , ozlb=ttl) )
(h
!/ 34. lf
increasing the concentration of A in a chemical reaction causes no increase in the rate of the
,.u"tior, then we can say that:
A. Aisacatalyst.
B. the reaction rate is zero-order in [A].
C. the reaction rate is first-order in ln [A].
D. the reaction rate is second-order in 1/[A].
E. A is not involved in the reaction.
35. (10 points) Cations of transition metals do not exist as isolated species in aqueous solution. Instead they are "complexed"
by anions or neutral molecules which covalently bond to the metal cation. One such complex ion equilibrium is
--]
[Co(H2O)6]2*(aq)+ 4 Cl-(aq) [CoC!]2-(aq) + 6 HrO(D
(pinksolution) il-i - -, (bluesolution)
In other words, a solution of [Co(Urb)u]2'(aq; lives a pink solution, while a solution of tcoclal'z,(afl gives a blue solution. An
equilibriurn mixture of both complex ions gives a violet solution.
(a) A few drops of 1 M aqueous sodium chloride solution is added to a sample of the qarne equilibrium mixture at room
ternperature? There is a color change observed. Does the color become more pink ol'more bluE?-Explain
Cl {era clro ps CT IMNA( \ r.r) ri\ Cort\C {\-c \ ( n r \ ra, i Fo fufn bliUg-
'.}o '\[,no i
becour,, crddi,'3 Yan ( tr rtr\ !ie\o t.rr \\ 5\ r\( { l'3-
€qltit\rDr\ttv\r tO b\ure tr\6\ Q- o( { I'rt pr odUct.
(b) A few drops of I M aqueous silver nitrate are added to the equilibrium mixture. A white precipitate of silver chloride is
forrned. Does the solution become more pink or more blue? Explain.
oC.
B) (3 pts) If Kc: 5.6 x !02 at 1000 what are the equilibrium concentrations at this temperature?
= 4mo ,qB J
,,(,
il
1
= -
*L"
-l -
"
,- I
I in no particular order: