LAMPIRAN

Lampiran 1. Pembuatan Larutan

1. Larutan NaCl 3% 250 mL
𝑚𝑎𝑠𝑠𝑎 𝑧𝑡
% = 𝑉 𝑝𝑒𝑙𝑎𝑟𝑢𝑡 × 100%
𝑚𝑎𝑠𝑠𝑎 𝑧𝑡
3% = × 100%
250 𝑚𝐿

Massa = 7.5 gram

2. Larutan NaCl 6% 250 mL

𝑚𝑎𝑠𝑠𝑎 𝑧𝑡
% = 𝑉 𝑝𝑒𝑙𝑎𝑟𝑢𝑡 × 100%
𝑚𝑎𝑠𝑠𝑎 𝑧𝑡
6% = × 100%
250 𝑚𝐿

Massa = 15 gram

3. Larutan NaCl 9% 250 mL

𝑚𝑎𝑠𝑠𝑎 𝑧𝑡
% = 𝑉 𝑝𝑒𝑙𝑎𝑟𝑢𝑡 × 100%
𝑚𝑎𝑠𝑠𝑎 𝑧𝑡
9% = × 100%
250 𝑚𝐿

Massa = 22.5 gram

4. Larutan NaCl 12% 250 mL

𝑚𝑎𝑠𝑠𝑎 𝑧𝑡
% = 𝑉 𝑝𝑒𝑙𝑎𝑟𝑢𝑡 × 100%
𝑚𝑎𝑠𝑠𝑎 𝑧𝑡
12% = × 100%
250 𝑚𝐿

Massa = 30 gram

5. Larutan NaCl 15% 250 mL

𝑚𝑎𝑠𝑠𝑎 𝑧𝑡
% = 𝑉 𝑝𝑒𝑙𝑎𝑟𝑢𝑡 × 100%
𝑚𝑎𝑠𝑠𝑎 𝑧𝑡
15% = × 100%
250 𝑚𝐿

Massa = 37.5 gram

6. Larutan NaCl 18% 250 mL

𝑚𝑎𝑠𝑠𝑎 𝑧𝑡
% = 𝑉 𝑝𝑒𝑙𝑎𝑟𝑢𝑡 × 100%
 𝑚𝑎𝑠𝑠𝑎 𝑧𝑡
18% = × 100%
250 𝑚𝐿

Massa = 45 gram
Lampiran 2. Menentukan volume piknometer
(𝑤 𝑝𝑖𝑘𝑛𝑜+𝑎𝑘𝑢𝑎𝑑𝑒𝑠)− (𝑤 𝑝𝑖𝑘𝑛𝑜 𝑘𝑜𝑠𝑜𝑛𝑔)
V pikno = 𝜌 𝑎𝑖𝑟
46.0066 𝑔𝑟𝑎𝑚−20.2205 𝑔𝑟𝑎𝑚𝑚
1. V pikno = 𝑔 = 25.876 cm3
0.9965
𝑐𝑚3

41.8695 𝑔𝑟𝑎𝑚−16.6085 𝑔𝑟𝑎𝑚𝑚

2. V pikno = 𝑔 = 25.349 cm3
0.9965
𝑐𝑚3

46.2744 𝑔𝑟𝑎𝑚−20.8855 𝑔𝑟𝑎𝑚𝑚

3. V pikno = 𝑔 = 25.478 cm3
0.9965
𝑐𝑚3

45.9968 𝑔𝑟𝑎𝑚−20.2200 𝑔𝑟𝑎𝑚𝑚

4. V pikno = 𝑔 = 25.867 cm3
0.9965
𝑐𝑚3

46.2927 𝑔𝑟𝑎𝑚−17.2718 𝑔𝑟𝑎𝑚𝑚

5. V pikno = 𝑔 = 25.108 cm3
0.9965
𝑐𝑚3

42.1003 𝑔𝑟𝑎𝑚−16.6519 𝑔𝑟𝑎𝑚𝑚

6. V pikno = 𝑔 = 25.537 cm3
0.9965
𝑐𝑚3

46.7268 𝑔𝑟𝑎𝑚−20.3242 𝑔𝑟𝑎𝑚𝑚

7. V pikno = 𝑔 = 25.495 cm3
0.9965
𝑐𝑚3

Lampiran 3. Massa jenis larutan

(𝑤 𝑝𝑖𝑘𝑛𝑜+𝑙𝑎𝑟𝑢𝑡𝑎𝑛)−(𝑤 𝑝𝑖𝑘𝑛𝑜 𝑘𝑜𝑠𝑜𝑛𝑔)
𝜌= 𝑉𝑜𝑙𝑢𝑚𝑒 𝑝𝑖𝑘𝑛𝑜𝑚𝑒𝑡𝑒𝑟

1. 46.5121 𝑔𝑟𝑎𝑚 −20.2205 𝑔𝑟𝑎𝑚

𝜌= = 1.01604 g/cm3
25.876 𝑐𝑚3
2. 42.8434 𝑔𝑟𝑎𝑚 −16.6085 𝑔𝑟𝑎𝑚
𝜌= = 1.0349 g/cm3
25.3497 𝑐𝑚3
3. 47.8219 𝑔𝑟𝑎𝑚 −20.8855 𝑔𝑟𝑎𝑚
𝜌= = 1.0572 g/cm3
25.4781 𝑐𝑚3
4. 48.0462 𝑔𝑟𝑎𝑚 −20.2200 𝑔𝑟𝑎𝑚
𝜌= = 1.0757 g/cm3
25.8673 𝑐𝑚3
5. 49.3244 𝑔𝑟𝑎𝑚 −20.3242 𝑔𝑟𝑎𝑚
𝜌= = 1.0945 g/cm3
26.4953 𝑐𝑚3
6. 44.9137 𝑔𝑟𝑎𝑚 −17.2718 𝑔𝑟𝑎𝑚
𝜌= = 1.1008 g/cm3
25.1088 𝑐𝑚3
7. 42.7869 𝑔𝑟𝑎𝑚 −16.6519 𝑔𝑟𝑎𝑚
𝜌= = 1.0234 g/cm3
25.1088 𝑐𝑚3

Lampiran 4. Massa larutan

Massa = 𝜌larutan × volume larutan
1. Massa = 1.01604 g/cm3 × 250 cm3 = 254.01 gram
2. Massa = 1.0349 g/cm3× 250 cm3 = 258.725 gram
3. Massa = 1.0572 g/cm3× 250 cm3 = 264.3 gram
4. Massa = 1.0757 g/cm3× 250 cm3 = 268.925 gram
5. Massa = 1.0945 g/cm3× 250 cm3 = 273.625 gram
6. Massa = 1.1008 g/cm3× 250 cm3 = 275.2 gram
7. Massa = 1.0234 g/cm3× 250 cm3 = 255.85 gram

Lampiran 5. Massa pelarut

Massa pelarut = massa larutan – massa penimbangan (%)
1. Massa pelarut = 254.1 gram – 7.5014 gram = 246.5086 gram
2. Massa pelarut = 258.725 gram – 15.0004 gram = 243.7246 gram
3. Massa pelarut = 264.3 gram – 22.5004 gram = 241.7996 gram
4. Massa pelarut = 268.925 gram – 30.0008 gram = 238.9242 gram
5. Massa pelarut = 273.625 gram – 37.5004 gram = 236.1246 gram
6. Massa pelarut = 275.2 gram – 45.0011 gram = 230.1989 gram

Lampiran 6. Molalitas
𝑚𝑎𝑠𝑠𝑎 1000
m= × 𝑚𝑎𝑠𝑠𝑎 𝑝𝑒𝑙𝑎𝑟𝑢𝑡
𝑀𝑟
7.5014 𝑔𝑟 1000
1. m= 𝑔 × 246.5086 𝑔𝑟𝑎𝑚 = 0.5207 m
58.44
𝑚𝑜𝑙

15.0004 𝑔𝑟 1000
2. m= 𝑔 × 243.7246 𝑔𝑟𝑎𝑚 = 1.0532 m
58.44
𝑚𝑜𝑙

22.5004 𝑔𝑟 1000
3. m= 𝑔 × 241.7996 𝑔𝑟𝑎𝑚 = 1.5922 m
58.44
𝑚𝑜𝑙

30.0008 𝑔𝑟 1000
4. m= 𝑔 × 238.9242 𝑔𝑟𝑎𝑚 = 2.1488 m
58.44
𝑚𝑜𝑙

37.5004 𝑔𝑟 1000
5. m= 𝑔 × 236.1246 𝑔𝑟𝑎𝑚 = 2.7176 m
58.44
𝑚𝑜𝑙

45.0011 𝑔𝑟 1000
6. m= 𝑔 × 230.1989 𝑔𝑟𝑎𝑚 = 3.3449 m
58.44
𝑚𝑜𝑙

Lampiran 7. ∆Tf teoritis

∆Tf = Kf × m × i
1. ∆Tf = 1.86℃m-1 × 0.5207 m × 2 = 1.9370℃
2. ∆Tf = 1.86℃m-1 × 1.0532 m × 2 = 3.9179℃
3. ∆Tf = 1.86℃m-1 × 1.5922 m × 2 = 5.9229℃
4. ∆Tf = 1.86℃m-1 × 2.1488 m × 2 = 7.9935℃
5. ∆Tf = 1.86℃m-1 × 2.7176 m × 2 = 10.1095℃
6. ∆Tf = 1.86℃m-1 × 3.3449 m × 2 = 12.4430℃

Lampiran 8. ∆Tf percobaan

∆Tf = Tf pelarut – Tf larutan
1. ∆Tf = 0℃ – 11℃ = -11℃
2. ∆Tf = 0℃ – 11℃ = -11℃
3. ∆Tf = 0℃ – 4℃ = -4℃
4. ∆Tf = 0℃ – 8℃ = -8℃
5. ∆Tf = 0℃ – 6℃ = -6℃
6. ∆Tf = 0℃ – 2℃ = -2℃

Lampiran 9. Menghitung nilai x

𝜌𝑙𝑎𝑟𝑢𝑡𝑎𝑛 𝑚𝑎𝑠𝑠𝑎 𝑝𝑒𝑙𝑎𝑟𝑢𝑡
x = 𝜌𝑝𝑒𝑙𝑎𝑟𝑢𝑡 × 𝑚𝑎𝑠𝑠𝑎 𝑙𝑎𝑟𝑢𝑡𝑎𝑛 × ∆Tf percobaan
𝑔
1.01604 246.5086 𝑔𝑟𝑎𝑚
𝑚𝑙
1. x= 𝑔 × × (-11℃) = -10.88℃
0.9965 254.1 𝑔𝑟𝑎𝑚
𝑚𝑙
𝑔
1.0349 243.7246 𝑔𝑟𝑎𝑚
𝑚𝑙
2. x= 𝑔 × × (-11℃) = -10.76℃
0.9965 258.725 𝑔𝑟𝑎𝑚
𝑚𝑙
𝑔
1.0572 241.7996 𝑔𝑟𝑎𝑚
𝑚𝑙
3. x= 𝑔 × × (-4℃) = -3.88℃
0.9965 264.3 𝑔𝑟𝑎𝑚
𝑚𝑙
𝑔
1.0757 238.9242 𝑔𝑟𝑎𝑚
𝑚𝑙
4. x= 𝑔 × × (-8℃) = -7.9℃
0.9965 268.925 𝑔𝑟𝑎𝑚
𝑚𝑙
𝑔
1.0945 236.1246 𝑔𝑟𝑎𝑚
𝑚𝑙
5. x= 𝑔 × × (-6℃) = -5.687℃
0.9965 273.625 𝑔𝑟𝑎𝑚
𝑚𝑙
𝑔
1.1008 230.1989 𝑔𝑟𝑎𝑚
𝑚𝑙
6. x= 𝑔 × × (-2℃) = -1.848℃
0.9965 275.2 𝑔𝑟𝑎𝑚
𝑚𝑙

Lampiran 10. Menghitung nilai ln ∆𝑽

𝜌𝑙𝑎𝑟𝑢𝑡𝑎𝑛 𝑚𝑎𝑠𝑠𝑎 𝑝𝑒𝑙𝑎𝑟𝑢𝑡
ln∆V = m × × 𝑚𝑎𝑠𝑠𝑎 𝑙𝑎𝑟𝑢𝑡𝑎𝑛 × ∆Tf percobaan
𝜌𝑝𝑒𝑙𝑎𝑟𝑢𝑡

atau
ln∆V = m × x
1. ln∆V = 0.5207 m × -10.88℃ = -5.665 m℃
2. ln∆V = 1.0532 m × --10.76℃= -11.322 m℃
3. ln∆V = 1.5922 m × -3.88℃= -6.177 m℃
4. ln∆V = 2.1488 m × -7.9℃ = -16.7975 m℃
5. ln∆V = 2.7176 m × -5.687℃= -15.944 m℃
6. ln∆V = 3.3449 m × -1.848℃= -6.1813 m℃

Lampiran 11. Penurunan Titik Beku

1. Minuman Isotonik

2. Larutan NaCl

Lampiran 12. Fenomena Tekanan Osmosis

Lampiran 13. Hubungan Perubahan Volume Spuit Terhadap Perbahan Titik Didih