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A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part has only one section: Section-A.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
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Useful Data
PHYSICS
Atomic masses: H=1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16,
F=19, Na=23, Mg=24, Al = 27, Si=28, P=31, S=32,
Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,
Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108,
Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.
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Physics PART – I
SECTION – A
(Only One Option Correct Type)
This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
3
1. A conical flask of mass 10 kg and base area 10 cm2 is floating in
liquid of specific gravity 1.2 as shown in the figure. The force that
2
liquid exerts on curved surface of conical flask is (g = 10 m/s ) 10cm
(A) 20 N in downward direction
(B) 40 N in downward direction
(C) 20 N in upward direction
(D) 40 N in upwards direction
0oC
K
temperature in 0C of the junction EF of the two slabs is:
(A) 20 B F D
(B) 50
(C) 60
(D) 80
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5. A lift moves upward with an acceleration of 1.2 ms-2. A nail falls from the ceiling of the lift 3 m
above the floor of the lift. When velocity of lift was 2.4 m/s upward, distance of its fall with
reference to the shaft of the lift is
(A) 0.75 m (B) 0.5 m
(C) 0.9 m (D) 1.5 m
7 A rail track is banked for speed v by making the height of the outer rail h higher than that of the
inner rail. The distance between the rails is d. the radius of curvature of the track is r, then (d<< r)
h v2 h v2
(A) (B) tan sin1
d rg d rg
h v2 h v2
(C) tan1 (D)
d rg r dg
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13. Find the distance moved by wedge when the block just reaches m
ground in figure.
Mhcot Mh tan h
(A) (B) M
Mm Mm
Mh tan mhcot
(C) (D)
Mm Mm
14 Find the height at which the weight will be same as at the same depth from the surface of the
earth.
R
(A) (B) 5 R R
2
5 R R 3 R R
(C) (D)
2 2
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15. A steel plate has face area 4 cm 2 and thickness 0.5 cm is fixed rigidly at the lower surface. A
tangential force of 10 N is applied on the upper surface. Find the lateral displacement of the
upper surface with respect to the lower surface. Rigidity modulus of steel = 8.4 × 1010 Nm-2
(A) 1.5 m (B) 1.5 A0
(C) 1.5 nm (D) 1.5 pm
16. An aluminum hunk is covered with gold shell to form an ingot. The ingot weighs 45 N in air and
39 N is water. Find the weight of the gold in the shell. Au/ w 19.3, A / w 2.7 .
(A) 12 N (B) 11.5 N
(C) 33.5 N (D) 36 N
18. Drops of liquid of density d are floating half immersed in a liquid of density . If the surface
tension of liquid is T then the radius of the drop is
3T 6T
(A) (B)
g 3d g 2d
3T 3T
(C) (D)
g 2d g 4d 3
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19. Two solid cylinders connected with a short light rod about common
x
axis have radius R and total mass M rest on a horizontal table top k
connected to a spring of spring constant k as shown. The cylinders
are pulled to the left by x and released. There is sufficient friction for
the cylinders to roll. Find time period of oscillation.
M M
(A) 2 (B) 2
k 2k
3M M
(C) 2 (D) 2
2k 3k
900 2 0
1 60
21. The ends of a stretched string of length L are fixed at x = 0 and x = L. In one experiment, the
x
displacement of the wire is y1 A sin cos t and energy E1 and in another experiment, its
L
2x
displacement is y 2 A sin sin 2t and energy E2 then
L
(A) E2 = E1 (B) E2 = 2E1
(C) E2 = 4E1 (D) E2 = 16E1
40m
22. Two loudspeakers L1 and L2 driven by a common oscillator and L1
D
amplifier are arranged as shown. the frequency of the oscillator is 9m
gradually increased from zero and the detector at D records a series of
L2
maxima and minima. If the speed of sound is 330 ms-1, the frequency
at which the first maximum is observed as
(A) 165 Hz (B) 330 Hz
(C) 495 Hz (D) 660 Hz
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23. When two tuning forks A and B are sounded together, x beats s-1 are heard. Frequency of A is n.
Now when one prong of for B is loaded with a little wax, the number of beats per second
decreases. The frequency of fork B is
(A) n + x (B) n – x
2
(C) n – x (D) n – 2x
24. In an experimental determination of the velocity of sound using a Kundt’s tube, standing waves
are set up in the metallic rod as well as in the rigid tube containing air, both the waves have the
same
(A) amplitude (B) frequency
(C) wavelength (D) particle velocity
(D) 843.5 Hz
26. A cylinder has an alloy piston at a temperature of 200C. There is all round clearance of 0.5 mm
between piston and cylinder wall when the internal diameter of the cylinder is exactly 10 cm. The
temperature at which it will exactly fit into the cylinder is
(A) 220oC (B) 250oC
o
(C) 270 C (D) 290oC
Given: expansion coefficient of alloy is 1.6 × 10-5/oC and expansion coefficient of cylinder is 1.2 ×
10-5/oC.
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27. Calculate the change in entropy of n moles of a perfect gas when its temperature changes from
T1 to T2 while its volume change from V1 to V2.
T T V
(A) nCv loge 2 (B) nCv loge 2 nRloge 2
T1 T1 V1
V2 T2 V
(C) nRloge (D) nCv loge nRloge 2
V1 T1 V1
28. A student measured the length of a pendulum 1.351 m and time for 30 vibrations is 2 minutes 10
sec using his wrist watch. Find the percent error in g committed.
(A) 1.72% (B) 1.813%
(C) 1.61% (D) 1.513%
29. A ball of mass m and density is immersed in a liquid of density 3 at a depth h and released.
To what height will the ball jump up above the surface of liquid? (neglect the resistance of water
and air).
(A) h (B) h/2
(C) 2h (D) 3h
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Chemistry PART – II
SECTION – A
(Only One Option Correct Type)
This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
− +
31. The common features among the species CN , CO and NO are
(A) bond order and nucleophilicity
(B) bond order and electrophilicity
(C) bond order and isoelectronic structure
(D) electrophilicity and isoelectronic structure.
32. Cs+ ion imparts violet colour to the flame. This is due to the fact that the emitted radiation has
(A) high energy (B) low energy
(C) longer wavelength (D) lower wave number
CH3
|
34. D2
CH3 CH CH CH2 The final product will be
Ni
(A) optically active with one chiral centre
(B) optically inactive due to internal compensation
(C) optically inactive due to external compensation
(D) optically inactive due to absence of chiral centre
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Me C C Me
(I) (II)
O O
O O
Me C CH2 C Me Ph C CH2 C Me
(III) (IV)
O O O O
(A) II III IV I (B) I IV III II
(C) I III IV II (D) IV III I II
36. What mole percentage of CO2 in air is just sufficient to prevent loss in weight when CaCO3 is
o
heated at 100 C?
CaCO3 (s) CaO (s) + CO2 (g)
Kp = 0.0095 atm at 100oC
(A) 2.9% (B) 0.05%
(C) 0.71% (D) 0.95%
37. The decomposition of Cl2O7 at 400 K in the gas phase to Cl2 and O2 is a first order reaction. After
100 seconds at 400 K, the pressure of Cl2O7 falls from 0.06 atm to 0.03 atm. The rate constant of
the reaction is
(A) 6.932 10 3 s (B) 6.932 102 Ms1
(C) 6.932 103 L mol1s1 (D) 6.932 103 s1
38. 0.3 g of an oxalate salt is dissolved in 100 mL of water. The whole solution required 90 mL of
0.05 N KMnO4 solution for complete oxidation. Percentage of oxalate ion by weight present in the
sample used for the experiment is
(A) 100% (B) 55%
(C) 33% (D) 66%
39. Ratio of radii of second orbit of protium (H), deuterium (D) and tritium (T) is
(A) 1 : 2 : 3 (B) 12 : 22 : 32
1 1 1
(C) : : (D) 1 : 1 : 1
1 2 3
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44. In the reaction A + B C + 2D, two moles of A and two moles of B are mixed in a volume of
one litre. If 1.2 moles of C is formed at equilibrium, the value of equilibrium constant is
(A) 1.69 (B) 1.08
(C) 10.8 (D) 16.9
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46. The solubilities of carbonates decrease downward in magnesium group due to a decrease in
(A) hydration energies of cations (B) inter-ionic attraction
(C) entropy of solution formation (D) lattice energies of the solids
47. 0.02 M aqueous solution of NH4Cl undergoes hydrolysis. As a result of it, the solution develops
acidity.
NH4 H2O NH4 OH H
–5
The basicity constant Kb for NH4OH is 1.85 × 10 and the ionic product of water
K w 1 10 14 and 298 K. [pKb = 4.73]
For the reaction NH4 H2O NH4 OH H . The hydrolytic constant of NH
4 ion is
(A) 5.4 1010 (B) 4.5 1010
(C) 1.85 10 9 (D) 1.85 109
48. In solid state each ammonia molecule has 6 other ammonia molecules as nearest neighbours.
∆H of sublimation of NH3 molecule at melting point is 30.2 kJ/mole and in absence of H−bonding
the ∆ H sublimation is 14.4 kJ/mole. The strength of H − bond in solid state is
(A) 166.8 kJ/mol (B) 55.6 kJ/mol
(C) 27.8 kJ/mol (D) 13.9 kJ/mol
49. If 2 moles of ideal gas at 27° C is subjected to expand reversibly ten times of its initial volume, the
change in entropy of expansion of the gas is
(A) 19.59 JK–1 mol–1 (B) 38.29 JK–1 mol–1
–1 –1
(C) 9.79 JK mol (D) 29.38 JK–1 mol–1
Br
O
(A) 4-Aectamide-6-bromohexen-3-one
(B) 4-Bromomethyl-1-ethylamino-1-oxohept-4-en-3-one
(C) N-Ethyl-2-(2-bromoethyl)-3-keto-4-pentenamide
(D) 4-Bromoethyl-3-keto-5-ethylamidopentene
51. 1 g mixture of Co58 and Co59 has the activity of 2.2 × 1012 dis sec–1 . Half-life of Co58 is 71.3 days.
The percent by mass of Co58 in mixture is
(A) 18.8% (B) 0.39%
(C) 0.188% (D) 3.99%
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52. A sample of radioactive substance shows an intensity of 4.6 millicurie at a time and an intensity of
3.24 millicurie 600 seconds later. The half-life of radioactive material is (log 1.42 = 0.1522)
(A) 593.6 sec (B) 1186.5 sec
(C) 59.36 sec (D) 118.65 sec
Br CH2 H
Br
H CH3
(C) C C C (D)
Cl CH3
56. From the graph given below, select the option which correctly matches the orbitals for which the
radial probability distribution is given:
B
A
2
4r
2 C
(r)
(r)
(A) A - 3p, B - 3d, C - 3s (B) A - 3s, B - 3d, C - 4p
(C) A - 4p, B - 3d, C - 5f (D) A - 3p, B - 4d, C - 4p
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58. Name the indicator and the colour change at end point during the volumetric estimation of sodium
hydroxide using standard oxalic acid (NaOH(aq) in the conical flask).
(A) Methyl orange, yellow to pink
(B) Methyl orange, pink to yellow
(C) Phenolphthalein, disappearance of pink colour
(D) Phenolphthalein, appearance of pink colour
CH3
14 1. Hg OCOCH ,H O
59. H3C 3 2
2. NaBH / OH
2
P. P is
4
H
H3C CH3
14
(A) C CH2 CH3 (B) H3C CH2 CH2
14
H3C
OH H OH
CH3
CH3
HO CH CH3 14
(C) (D) H3C CH CH3
H CH3
14 H OH
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x y
p q
62. If z x iy and z1/3 p iq, then is equal to:
p2 q2
(A) 1 (B) – 1
(C) 2 (D) – 2
x 8 x 8
63.
The number of real root of 7 4 3
74 3 14 is
(A) 0 (B) 2
(C) 4 (D) None of these
64. If the roots of the equation x 2 2ax a2 a 3 0 are real and less than 3, then
(A) a < 2 (B) 2 a 3
(C) 3 a 4 (D) a > 4
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3x
65. The roots of the equation, 2x 2.3 x 1 9 are given by
2
(A) 1 log2 3,2 (B) log2 ,1
3
log3
(C) 2, 2 (D) 2,1
log2
m
66. If the 4th term in the expansion of px x 1 is 2.5 for all x R, then
5 1
(A) p ,m 3 (B) p ,m 6
2 2
1
(C) p ,m 6 (D) None of these
2
6
67. Let n N and n
2 1 . Then the greatest value of n is
2
68. If 15
Cr 15 Cr 1 15
C15 r 15C16 r 16
C13 , then the value of r is
(A) 2 (B) 3
(C) 4 (D) None of these
69. If p, q, r are in A.P., a is G.M between p and q and b is G.M. between q and r, then a2, q2, b2 are
in
(A) A. P. (B) G.P.
(C) H. P. (D) None of these
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74. The length of the normal chord to the parabola y2 = 4x which subtends a right angle at the vertex
is
(A) 6 3 (B) 3 3
(C) 2 (D) 1
75. If two tangents to the parabola y2 =4ax make angles 1 and 2 with x-axis where
tan2 1 tan2 2 c, then the locus of the third point of the intersection is given by
(A) y 2 ax 2cx 2 (B) y 2 2ax cx 2
(C) y 2 2ax cx 2 (D) y 2 ax cx 2
16
76. If the tangent at the point 4cos , sin to the ellipse 16x 2 11y 2 256 is also a tangent to
11
2 2
the circle x y 2x 15, then the value of is
(A) (B)
2 4
(C) (D)
3 6
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78. The equation cosp 1 x 2 cosp x sinp 0, where x is a variable, has real roots. Then the
interval of p may be any of the following
(A) 0,2 (B) ,0
(C) , (D) 0,
2 2
79. A ladder rests against a wall at an angle to the horizontal. Its foot is pulled away from the wall
through a distance ‘a’ so that it slides a distance ‘b’ down the wall making an angle with the
horizontal. Then, which of the following is true?
(A) a b tan (B) b a tan
2 2
(C) a b sin (D) b a sin
2 2
81. If and , then tan equals
2
(A) 2 tan tan (B) tan tan
(C) tan 2tan (D) 2 tan tan
82. If (p, 0) is a point on a diameter of the circle x 2 y 2 4 then the quadratic equation
t 2 4t p2 0 in the variable ‘t’ has
(A) exactly one root in (- 3 , -2) (B) exactly one root in (2, 5)
(C) distinct roots greater than 2 (D) roots are not of opposite sign
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15
83. If r , r 0,1,2,3,........15 are the 16 roots of unity, then the value of | z 1 r z 2 |2 is equal to
r 0
(A) 15 | z1 |2 | z 2 |2 (B) | z1 |2 | z2 |2
(C) 16 | z1 |2 | z 2 |2 (D) | z1 |2 | z2 |2
84. If 1, 2 , 3 ........., n are the nth roots of unity, then value of
n
C1 1 nC2 2 n C3 3 ..... n Cn n is equal to
n n
(A) 1 1 1 (B) 1 2 1
1
(C)
2
n
1 2 1
(D) 2 1 2 1
n
85. The sum of least positive value and greatest negative value of x which are satisfying the equation
3
sin x cos2x is
4 2
(A) (B)
4 4
(C) (D)
3 6
86. A tangent is drawn from the point (4,0) to the circle x 2 y 2 8 touching it at a point A in the first
quadrant. The coordinates of another point B on the circle such that the chord AB is of the length
4 is
(A) 2,2 (B) 2, 2
(C) 1, 7
(D) 2 2,0
87. Two circles with radii 2 cm and 1 cm meet at a point A, whose centres lie on x-axis. The
distance between their centres is 2 cm. the chord AC of the larger circle cuts the smaller circle at
a point B and is bisected by that point. The length of chord AC is
5 7
(A) cm (B) cm
2 2
3 5
(C) cm (D) cm
2 2
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89. Two triangles ABC and DEF are formed by three tangents and the corresponding three normals
to a parabola y 2 4ax respectively. The orthocenter of ABC has coordinates (–5, 4). Then,
distance of orthocenter of DEF from axis of parabola is
(A) 5 units (B) 2 units
(C) 4 units (D) Cannot be determined
90. If the equation z3 3 i z 2 3z m i 0, where m R has at least one real root, then m
can have the value equal to
(A) 1 (B) 2
(C) 3 (D) 4
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