Objetivo

Elaborar un diagrama de Chaudron que representa la relación del porcentaje de CO

contra la temperatura durante las reacciones de reducción del hierro. Para realizarlo
se necesitaran los siguientes datos: G, Kp, %CO los cuales serán obtenidos de
tablas y calculados con las fórmulas correspondientes.
TERMODINAMICA DE LA REDUCCION DE LOS OXIDOS DE FIERRO
De acuerdo al diagrama Fe-O, la reducción de los óxidos de Fe se divide en 2 etapas
marcadas por la temperatura de estabilidad de la wüstita.
Caso I
Reducción de los óxidos de Fe a T ≤ 570°C

(1)
Caso II
Reducción de los óxidos de Fe a T ≥ 570°C (tiene una mayor complejidad para el
agente reductor)

(2)

(3)

(4)

DATOS TERMODINAMICOS DE LAS REACCIONES

Energía libre para la reacción 4

Energía libre para la reacción 3

Energía libre para la reacción 2

Energía libre para la reacción 1

FÓRMULAS EMPLEADAS

Una vez que se tienen los datos necesarios se procede a calcular Kp y %CO para
un rango de temperatura de 100°C a 1200°C para posteriormente tabular y graficar.
Se calcularon primeramente los G para cada temperatura y reacción:
1. 𝐹𝑒𝑂 + 𝐶𝑂 4. 3𝐹𝑒2𝑂3 +
→ 𝐹𝑒 + 𝐶𝑂2 2. 𝐹𝑒3𝑂4 + 3. 1/4 𝐹𝑒3𝑂4 𝐶𝑂 →
𝐶𝑂 → 3𝐹𝑒𝑂 + 𝐶𝑂 → 3 4 2𝐹𝑒3𝑂4 +
+ 𝐶𝑂2 𝐹𝑒 + 𝐶𝑂2 𝐶𝑂2
T ∆𝐺 T ∆𝐺 T ∆𝐺 T ∆𝐺
100 -3677 100 6205 100 -1206.5 100 -9167
110 -3625.7 110 6113.5 110 -1190.9 110 -9295.7
120 -3574.4 120 6022 120 -1175.3 120 -9424.4
130 -3523.1 130 5930.5 130 -1159.7 130 -9553.1
140 -3471.8 140 5839 140 -1144.1 140 -9681.8
150 -3420.5 150 5747.5 150 -1128.5 150 -9810.5
160 -3369.2 160 5656 160 -1112.9 160 -9939.2
170 -3317.9 170 5564.5 170 -1097.3 170 -10067.9
180 -3266.6 180 5473 180 -1081.7 180 -10196.6
190 -3215.3 190 5381.5 190 -1066.1 190 -10325.3
200 -3164 200 5290 200 -1050.5 200 -10454
210 -3112.7 210 5198.5 210 -1034.9 210 -10582.7
220 -3061.4 220 5107 220 -1019.3 220 -10711.4
230 -3010.1 230 5015.5 230 -1003.7 230 -10840.1
240 -2958.8 240 4924 240 -988.1 240 -10968.8
250 -2907.5 250 4832.5 250 -972.5 250 -11097.5
260 -2856.2 260 4741 260 -956.9 260 -11226.2
270 -2804.9 270 4649.5 270 -941.3 270 -11354.9
280 -2753.6 280 4558 280 -925.7 280 -11483.6
290 -2702.3 290 4466.5 290 -910.1 290 -11612.3
300 -2651 300 4375 300 -894.5 300 -11741
310 -2599.7 310 4283.5 310 -878.9 310 -11869.7
320 -2548.4 320 4192 320 -863.3 320 -11998.4
330 -2497.1 330 4100.5 330 -847.7 330 -12127.1
340 -2445.8 340 4009 340 -832.1 340 -12255.8
350 -2394.5 350 3917.5 350 -816.5 350 -12384.5
360 -2343.2 360 3826 360 -800.9 360 -12513.2
370 -2291.9 370 3734.5 370 -785.3 370 -12641.9
380 -2240.6 380 3643 380 -769.7 380 -12770.6
390 -2189.3 390 3551.5 390 -754.1 390 -12899.3
400 -2138 400 3460 400 -738.5 400 -13028
410 -2086.7 410 3368.5 410 -722.9 410 -13156.7
420 -2035.4 420 3277 420 -707.3 420 -13285.4
430 -1984.1 430 3185.5 430 -691.7 430 -13414.1
440 -1932.8 440 3094 440 -676.1 440 -13542.8
450 -1881.5 450 3002.5 450 -660.5 450 -13671.5
460 -1830.2 460 2911 460 -644.9 460 -13800.2
470 -1778.9 470 2819.5 470 -629.3 470 -13928.9
480 -1727.6 480 2728 480 -613.7 480 -14057.6
490 -1676.3 490 2636.5 490 -598.1 490 -14186.3
500 -1625 500 2545 500 -582.5 500 -14315
510 -1573.7 510 2453.5 510 -566.9 510 -14443.7
520 -1522.4 520 2362 520 -551.3 520 -14572.4
530 -1471.1 530 2270.5 530 -535.7 530 -14701.1
540 -1419.8 540 2179 540 -520.1 540 -14829.8
550 -1368.5 550 2087.5 550 -504.5 550 -14958.5
560 -1317.2 560 1996 560 -488.9 560 -15087.2
570 -1265.9 570 1904.5 570 -473.3 570 -15215.9
580 -1214.6 580 1813 580 -457.7 580 -15344.6
590 -1163.3 590 1721.5 590 -442.1 590 -15473.3
600 -1112 600 1630 600 -426.5 600 -15602
610 -1060.7 610 1538.5 610 -410.9 610 -15730.7
620 -1009.4 620 1447 620 -395.3 620 -15859.4
630 -958.1 630 1355.5 630 -379.7 630 -15988.1
640 -906.8 640 1264 640 -364.1 640 -16116.8
650 -855.5 650 1172.5 650 -348.5 650 -16245.5
660 -804.2 660 1081 660 -332.9 660 -16374.2
670 -752.9 670 989.5 670 -317.3 670 -16502.9
680 -701.6 680 898 680 -301.7 680 -16631.6
690 -650.3 690 806.5 690 -286.1 690 -16760.3
700 -599 700 715 700 -270.5 700 -16889
710 -547.7 710 623.5 710 -254.9 710 -17017.7
720 -496.4 720 532 720 -239.3 720 -17146.4
730 -445.1 730 440.5 730 -223.7 730 -17275.1
740 -393.8 740 349 740 -208.1 740 -17403.8
750 -342.5 750 257.5 750 -192.5 750 -17532.5
760 -291.2 760 166 760 -176.9 760 -17661.2
770 -239.9 770 74.5 770 -161.3 770 -17789.9
780 -188.6 780 -17 780 -145.7 780 -17918.6
790 -137.3 790 -108.5 790 -130.1 790 -18047.3
800 -86 800 -200 800 -114.5 800 -18176
810 -34.7 810 -291.5 810 -98.9 810 -18304.7
820 16.6 820 -383 820 -83.3 820 -18433.4
830 67.9 830 -474.5 830 -67.7 830 -18562.1
840 119.2 840 -566 840 -52.1 840 -18690.8
850 170.5 850 -657.5 850 -36.5 850 -18819.5
860 221.8 860 -749 860 -20.9 860 -18948.2
870 273.1 870 -840.5 870 -5.3 870 -19076.9
880 324.4 880 -932 880 10.3 880 -19205.6
890 375.7 890 -1023.5 890 25.9 890 -19334.3
900 427 900 -1115 900 41.5 900 -19463
910 478.3 910 -1206.5 910 57.1 910 -19591.7
920 529.6 920 -1298 920 72.7 920 -19720.4
930 580.9 930 -1389.5 930 88.3 930 -19849.1
940 632.2 940 -1481 940 103.9 940 -19977.8
950 683.5 950 -1572.5 950 119.5 950 -20106.5
960 734.8 960 -1664 960 135.1 960 -20235.2
970 786.1 970 -1755.5 970 150.7 970 -20363.9
980 837.4 980 -1847 980 166.3 980 -20492.6
990 888.7 990 -1938.5 990 181.9 990 -20621.3
1000 940 1000 -2030 1000 197.5 1000 -20750
1010 991.3 1010 -2121.5 1010 213.1 1010 -20878.7
1020 1042.6 1020 -2213 1020 228.7 1020 -21007.4
1030 1093.9 1030 -2304.5 1030 244.3 1030 -21136.1
1040 1145.2 1040 -2396 1040 259.9 1040 -21264.8
1050 1196.5 1050 -2487.5 1050 275.5 1050 -21393.5
1060 1247.8 1060 -2579 1060 291.1 1060 -21522.2
1070 1299.1 1070 -2670.5 1070 306.7 1070 -21650.9
1080 1350.4 1080 -2762 1080 322.3 1080 -21779.6
1090 1401.7 1090 -2853.5 1090 337.9 1090 -21908.3
1100 1453 1100 -2945 1100 353.5 1100 -22037
1110 1504.3 1110 -3036.5 1110 369.1 1110 -22165.7
1120 1555.6 1120 -3128 1120 384.7 1120 -22294.4
1130 1606.9 1130 -3219.5 1130 400.3 1130 -22423.1
1140 1658.2 1140 -3311 1140 415.9 1140 -22551.8
1150 1709.5 1150 -3402.5 1150 431.5 1150 -22680.5
1160 1760.8 1160 -3494 1160 447.1 1160 -22809.2
1170 1812.1 1170 -3585.5 1170 462.7 1170 -22937.9
1180 1863.4 1180 -3677 1180 478.3 1180 -23066.6
1190 1914.7 1190 -3768.5 1190 493.9 1190 -23195.3
1200 1966 1200 -3860 1200 509.5 1200 -23324
Posteriormente sacamos los valores de Kp

1. 𝐹𝑒𝑂 + 𝐶𝑂 2. 𝐹𝑒3𝑂4 + 3. 1/4

→ 𝐹𝑒 + 𝐶𝑂2 𝐶𝑂 → 𝐹𝑒3𝑂4 + 𝐶𝑂 4. 3𝐹𝑒2𝑂3 +
3𝐹𝑒𝑂 + → 3 4 𝐹𝑒 + 𝐶𝑂 → 2𝐹𝑒3𝑂4
𝐶𝑂2 𝐶𝑂2 + 𝐶𝑂2
T Kp T Kp T Kp T Kp
100 1.09E+08 100 2.74E-14 100 433.5329 100 1.08673E+20
110 16002865 110 7.12E-13 110 232.432 110 2.9538E+18
120 3238994 120 1.08E-11 120 138.2582 120 1.46419E+17
130 838222.1 130 1.07E-10 130 89.08285 130 1.15225E+16
140 263131.3 140 7.66E-10 140 61.11789 140 1.30383E+15
150 96400.09 150 4.22E-09 150 44.09196 150 1.97275E+14
160 40040.02 160 1.88E-08 160 33.13421 160 3.77955E+13
170 18441.8 170 7.01E-08 170 25.75086 170 8.795E+12
180 9258.109 180 2.26E-07 180 20.58125 180 2.40651E+12
190 4997.406 190 6.45E-07 190 16.8421 190 7.54721E+11
200 2869.093 200 1.66E-06 200 14.06138 200 2.65794E+11
210 1736.589 210 3.89E-06 210 11.94328 210 1.03388E+11
220 1100.201 220 8.44E-06 220 10.29592 220 43820289036
230 725.2439 230 1.71E-05 230 8.991072 230 20012286809
240 494.9694 240 3.28E-05 240 7.940766 240 9756253487
250 348.2932 250 5.96E-05 250 7.083196 250 5037679387
260 251.7983 260 0.000103 260 6.374029 260 2736900055
270 186.4649 270 0.000172 270 5.780862 270 1555660689
280 141.0781 280 0.000277 280 5.279602 280 920651769.4
290 108.8119 290 0.00043 290 4.852063 290 564920839.2
300 85.39097 300 0.000649 300 4.484321 300 358113191.3
310 68.06736 310 0.000955 310 4.165579 310 233789565.8
320 55.03264 320 0.00137 320 3.887365 320 156748946.1
330 45.07097 330 0.001924 330 3.642962 330 107672944.3
340 37.34865 340 0.002647 340 3.42699 340 75614058.83
350 31.28361 350 0.003578 350 3.2351 350 54183888.89
360 26.46271 360 0.004755 360 3.063747 360 39552913.63
370 22.58815 370 0.006222 370 2.910018 370 29368078.33
380 19.44221 380 0.008028 380 2.771501 380 22150217.61
390 16.86362 390 0.010224 390 2.646188 390 16949714.58
400 14.73145 400 0.012864 400 2.532393 400 13144908.34
410 12.95401 410 0.016006 410 2.428693 410 10321393.5
420 11.46098 420 0.019708 420 2.333882 420 8198228.623
430 10.19796 430 0.024034 430 2.246929 430 6581937.122
440 9.122404 440 0.029045 440 2.166953 440 5337307.991
450 8.200811 450 0.034807 450 2.093192 450 4368543.283
460 7.406538 460 0.041385 460 2.024989 460 3606890.89
470 6.718253 470 0.048846 470 1.961772 470 3002409.649
480 6.118746 480 0.057254 480 1.903041 480 2518408.541
490 5.594037 490 0.066676 490 1.848361 490 2127641.692
500 5.132699 500 0.077177 500 1.797346 500 1809672.171
510 4.725329 510 0.088821 510 1.749658 510 1549023.945
520 4.36415 520 0.101671 520 1.704999 520 1333871.873
530 4.042689 530 0.115788 530 1.663101 530 1155103.278
540 3.755535 540 0.131231 540 1.623728 540 1005638.946
550 3.498137 550 0.148059 550 1.586669 550 879937.1833
560 3.266653 560 0.166326 560 1.551735 560 773628.2885
570 3.057824 570 0.186086 570 1.518756 570 683242.8496
580 2.868873 580 0.20739 580 1.48758 580 606008.1202
590 2.697424 590 0.230284 590 1.458068 590 539694.2362
600 2.541436 600 0.254814 600 1.430097 600 482497.2086
610 2.39915 610 0.281024 610 1.403553 610 432949.2681
620 2.269043 620 0.308952 620 1.378335 620 389849.7032
630 2.149793 630 0.338635 630 1.354349 630 352211.161
640 2.04025 640 0.370108 640 1.331511 640 319217.6973
650 1.939407 650 0.403401 650 1.309743 650 290191.8093
660 1.846383 660 0.438543 660 1.288975 660 264568.3813
670 1.760401 670 0.475559 670 1.269141 670 241873.982
680 1.680779 680 0.514472 680 1.250183 680 221710.3263
690 1.606913 690 0.555302 690 1.232045 690 203741.0002
700 1.538267 700 0.598065 700 1.214677 700 187680.7506
710 1.474365 710 0.642777 710 1.198034 710 173286.8073
720 1.414785 720 0.68945 720 1.182071 720 160351.8173
730 1.359147 730 0.738092 730 1.166749 730 148698.0694
740 1.307114 740 0.788712 740 1.152033 740 138172.753
750 1.258383 750 0.841314 750 1.137887 750 128644.0495
760 1.212679 760 0.895901 760 1.12428 760 119997.8996
770 1.16976 770 0.952473 770 1.111183 770 112135.318
780 1.129402 780 1.011029 780 1.098569 780 104970.1555
790 1.091407 790 1.071565 790 1.086412 790 98427.2273
800 1.055592 800 1.134076 800 1.074688 800 92440.74283
810 1.021794 810 1.198554 810 1.063376 810 86952.98326
820 0.989864 820 1.26499 820 1.052454 820 81913.18516
830 0.959665 830 1.333375 830 1.041904 830 77276.5947
840 0.931074 840 1.403696 840 1.031707 840 73003.66413
850 0.903978 850 1.47594 850 1.021846 850 69059.36731
860 0.878274 860 1.550092 860 1.012306 860 65412.61485
870 0.853866 870 1.626135 870 1.003071 870 62035.75319
880 0.830669 880 1.704054 880 0.994127 880 58904.13435
890 0.808602 890 1.783829 890 0.985461 890 55995.7455
900 0.787593 900 1.86544 900 0.977061 900 53290.88925
910 0.767573 910 1.948869 910 0.968915 910 50771.90705
920 0.748481 920 2.034093 920 0.961011 920 48422.93934
930 0.73026 930 2.121091 930 0.95334 930 46229.71709
940 0.712855 940 2.20984 940 0.945891 940 44179.38025
950 0.696219 950 2.300316 950 0.938656 950 42260.31927
960 0.680306 960 2.392495 960 0.931625 960 40462.0365
970 0.665074 970 2.486354 970 0.92479 970 38775.02472
980 0.650483 980 2.581866 980 0.918143 980 37190.66052
990 0.636497 990 2.679006 990 0.911677 990 35701.11039
1000 0.623083 1000 2.777748 1000 0.905384 1000 34299.2481
1010 0.610209 1010 2.878067 1010 0.899258 1010 32978.5816
1020 0.597846 1020 2.979934 1020 0.893292 1020 31733.18848
1030 0.585966 1030 3.083324 1030 0.887481 1030 30557.65871
1040 0.574544 1040 3.18821 1040 0.881818 1040 29447.04386
1050 0.563555 1050 3.294563 1050 0.876298 1050 28396.81192
1060 0.552979 1060 3.402357 1060 0.870916 1060 27402.80712
1070 0.542793 1070 3.511564 1070 0.865667 1070 26461.21408
1080 0.532978 1080 3.622157 1080 0.860545 1080 25568.52575
1090 0.523516 1090 3.734107 1090 0.855547 1090 24721.51482
1100 0.514389 1100 3.847388 1100 0.850668 1100 23917.20801
1110 0.505582 1110 3.961971 1110 0.845904 1110 23152.86312
1120 0.497078 1120 4.077829 1120 0.841251 1120 22425.9483
1130 0.488865 1130 4.194935 1130 0.836706 1130 21734.1235
1140 0.480927 1140 4.31326 1140 0.832264 1140 21075.22371
1150 0.473254 1150 4.432778 1150 0.827922 1150 20447.24387
1160 0.465832 1160 4.553462 1160 0.823677 1160 19848.32523
1170 0.45865 1170 4.675284 1170 0.819526 1170 19276.743
1180 0.451698 1180 4.798217 1180 0.815466 1180 18730.89527
1190 0.444965 1190 4.922236 1190 0.811494 1190 18209.29282
1200 0.438443 1200 5.047312 1200 0.807606 1200 17710.55
Por ultimo con los valores obtenidos de Kp calculamos el %CO

1. 𝐹𝑒𝑂 + 𝐶𝑂 → 𝐹𝑒 + 𝐶𝑂2 3. 1/4 𝐹𝑒3𝑂4 +

2. 𝐹𝑒3𝑂4 + 𝐶𝑂 𝐶𝑂 → 3 4 𝐹𝑒 + 4. 3𝐹𝑒2𝑂3 + 𝐶𝑂 →
→ 3𝐹𝑒𝑂 + 𝐶𝑂2 𝐶𝑂2 2𝐹𝑒3𝑂4 + 𝐶𝑂2
%CO %CO %CO %CO
9.18876E-07 100 0.230132 9.2019E-19
6.24888E-06 100 0.42839 3.38547E-17
3.08738E-05 100 0.718091 6.82972E-16
0.0001193 100 1.110089 8.67863E-15
0.000380037 100 1.609842 7.6697E-14
0.001037333 100 2.21769 5.06907E-13
0.002497439 100 2.929613 2.64582E-12
0.005422172 99.99999 3.738198 1.13701E-11
0.010800176 99.99998 4.633651 4.1554E-11
0.02000638 99.99994 5.604722 1.32499E-10
0.034842071 99.99983 6.639496 3.76231E-10
0.057550994 99.99961 7.726017 9.67229E-10
0.090809923 99.99916 8.852757 2.28205E-09
0.137694796 99.99829 10.00894 4.99693E-09
0.201625353 99.99672 11.18472 1.02498E-08
0.286292394 99.99404 12.37134 1.98504E-08
0.395572272 99.98966 13.56111 3.65377E-08
0.533433287 99.98278 14.74739 6.42814E-08
0.703838411 99.97234 15.92458 1.08619E-07
0.910648333 99.957 17.08799 1.77016E-07
1.157528341 99.9351 18.2338 2.79241E-07
1.447861987 99.90462 19.35892 4.27735E-07
1.784673973 99.86318 20.46092 6.37963E-07
2.170564156 99.808 21.53797 9.28738E-07
2.607654061 99.73595 22.58871 1.32251E-06
3.097546778 99.64351 23.61219 1.84557E-06
3.641300676 99.5268 24.60783 2.52826E-06
4.239416846 99.38163 25.57533 3.40506E-06
4.891839832 99.20356 26.51464 4.51463E-06
5.59797076 98.98792 27.4259 5.8998E-06
6.356691706 98.72991 28.30942 7.60751E-06
7.166399835 98.42463 29.16563 9.68861E-06
8.025049669 98.06726 29.99507 1.21978E-05
8.930201741 97.65305 30.79833 1.51931E-05
9.879075821 97.17749 31.57609 1.8736E-05
10.86860694 96.63638 32.32906 2.28909E-05
11.89550258 96.02595 33.05797 2.77247E-05
12.95629936 95.34292 33.76357 3.33066E-05
14.04741813 94.58465 34.44663 3.97076E-05
15.16521601 93.74916 35.10791 4.70004E-05
16.30603475 92.83523 35.74817 5.52586E-05
17.46624458 91.84244 36.36815 6.45567E-05
18.64228307 90.7712 36.9686 7.49697E-05
19.83068891 89.62277 37.55021 8.65723E-05
21.02813032 88.39924 38.11371 9.94392E-05
22.23142836 87.10352 38.65976 0.000113644
23.43757519 85.73929 39.18902 0.000129261
24.64374775 84.31089 39.70213 0.000146361
25.8473171 82.82331 40.19972 0.000165014
27.04585389 81.28206 40.68236 0.00018529
28.23713051 79.69307 41.15063 0.000207255
29.4191202 78.06257 41.60508 0.000230973
30.58999375 76.39701 42.04623 0.000256508
31.74811408 74.70296 42.47459 0.00028392
32.89202922 72.98695 42.89065 0.000313265
34.02046397 71.25547 43.29486 0.000344598
35.13231064 69.51478 43.68769 0.000377973
36.22661911 67.77092 44.06954 0.000413437
37.30258651 66.02961 44.44084 0.000451037
38.35954671 64.29621 44.80197 0.000490817
39.39695979 62.57567 45.15331 0.000532817
40.41440172 60.87253 45.49521 0.000577075
41.41155423 59.19087 45.82803 0.000623625
42.38819507 57.53434 46.15208 0.000672499
43.34418876 55.90614 46.46769 0.000723726
44.2794777 54.30903 46.77516 0.000777333
45.19407393 52.74536 47.07477 0.000833341
46.0880513 51.21709 47.3668 0.000891772
46.96153829 49.72578 47.65152 0.000952643
47.81471125 48.27268 47.92917 0.001015969
48.64778829 46.8587 48.20001 0.001081762
49.46102357 45.48445 48.46426 0.001150034
50.25470216 44.1503 48.72215 0.00122079
51.02913532 42.85637 48.9739 0.001294036
51.78465626 41.60259 49.21969 0.001369775
52.52161625 40.3887 49.45974 0.001448009
53.24038122 39.21427 49.69424 0.001528734
53.94132858 38.07877 49.92335 0.001611948
54.62484453 36.98151 50.14726 0.001697645
55.29132153 35.92175 50.36614 0.001785818
55.94115616 34.89865 50.58013 0.001876458
56.57474717 33.91131 50.78941 0.001969554
57.1924938 32.95878 50.9941 0.002065094
57.7947943 32.04008 51.19437 0.002163064
58.38204464 31.1542 51.39033 0.002263448
58.95463738 30.30013 51.58213 0.00236623
59.51296076 29.47683 51.76988 0.002471391
60.05739783 28.68326 51.95372 0.002578913
60.5883258 27.91841 52.13375 0.002688775
61.10611543 27.18126 52.3101 0.002800955
61.6111306 26.47079 52.48286 0.002915431
62.10372787 25.78604 52.65214 0.003032179
62.58425621 25.12604 52.81804 0.003151176
63.05305677 24.48985 52.98066 0.003272395
63.51046266 23.87655 53.1401 0.003395811
63.95679886 23.28526 53.29643 0.003521398
64.39238217 22.7151 53.44975 0.003649128
64.81752113 22.16526 53.60014 0.003778973
65.23251604 21.63492 53.74769 0.003910906
65.63765902 21.12331 53.89246 0.004044896
66.03323405 20.62967 54.03454 0.004180915
66.41951705 20.15328 54.17399 0.004318934
66.79677601 19.69346 54.31089 0.004458921
67.16527109 19.24952 54.4453 0.004600848
67.52525476 18.82084 54.57729 0.004744683
67.87697196 18.40679 54.70692 0.004890396
68.22066023 18.00679 54.83426 0.005037955
68.5565499 17.62026 54.95936 0.005187329
68.88486423 17.24668 55.08227 0.005338488
69.2058196 16.88552 55.20306 0.0054914
69.51962571 16.53627 55.32178 0.005646033
Finalmente, sacados todos estos valores proseguimos a realizar las graficas de las
distintas reacciones:

80 1. 𝐹𝑒𝑂 + 𝐶𝑂 → 𝐹𝑒 + 𝐶𝑂2
70

Fe
60

50
%CO

40 1. 𝐹𝑒𝑂 + 𝐶𝑂 →
𝐹𝑒 + 𝐶𝑂2
30

20

10

0
0 20 40 60
FeO 80 100 120
T(k)

2. 𝐹𝑒3𝑂4 + 𝐶𝑂 → 3𝐹𝑒𝑂 + 𝐶𝑂2

120

100

80

FeO
% CO

60
2. 𝐹𝑒3𝑂4 + 𝐶𝑂 →

𝐹𝑒3𝑂4
3𝐹𝑒𝑂 + 𝐶𝑂2
40

20

0
0 200 400 600 800 1000 1200 1400

T(k)
 60 3. 1/4 𝐹𝑒3𝑂4 + 𝐶𝑂 → 3 4 𝐹𝑒 + 𝐶𝑂2
50

40
Fe
%CO

30
3. 1/4 𝐹𝑒3𝑂4 +

20 𝐹𝑒3𝑂4 𝐶𝑂 → 3 4 𝐹𝑒 +
𝐶𝑂2

10

0
0 200 400 600 T(k) 800 1000 1200 1400

4. 3𝐹𝑒2𝑂3 + 𝐶𝑂 → 2𝐹𝑒3𝑂4 + 𝐶𝑂2

0.006

0.005

0.004
𝐹𝑒3𝑂4
%CO

0.003
4. 3𝐹𝑒2𝑂3 +
0.002 𝐶𝑂 → 2𝐹𝑒3𝑂4
+ 𝐶𝑂2
0.001

0
𝐹𝑒2𝑂3
0 200 400 600 800 1000 1200 1400
-0.001

T(k)
Por ultimo juntando todas las graficas y eliminando las líneas sobrantes obtenemos
la grafica de Chaudron

Chart Title
80

70

60

Fe
FeO
50
%CO

40

30

20

10
𝐹𝑒3𝑂4 1. 𝐹𝑒𝑂 + 𝐶𝑂 → 𝐹𝑒 +
𝐶𝑂2

2. 𝐹𝑒3𝑂4 + 𝐶𝑂 →
3𝐹𝑒𝑂 + 𝐶𝑂2
0
0 200 400 600 800 1000 1200 3. 1/4 𝐹𝑒3𝑂4 + 𝐶𝑂
1400
→ 3 4 𝐹𝑒 + 𝐶𝑂2
-10

T(k) 4. 3𝐹𝑒2𝑂3 + 𝐶𝑂 →
2𝐹𝑒3𝑂4 + 𝐶𝑂2

CONCLUSIÓN
El Diagrama de Chaudron muestra la concentración o %CO necesario para la
reducción u oxidación de las especies oxidadas del hierro en función de la
temperatura, dentro del alto horno. A demás de que es empleado para encontrar el
punto triple donde se encuentran en equilibrio el 𝐹𝑒3𝑂4, 𝐹𝑒𝑂 y 𝐹𝑒, es decir el punto
donde coexisten las tres fases, este fenómeno ocurre entre los 792 y 793 K (519°C)