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Plasma Technologies
Table of Contents
Abstract: ........................................................................................................................................................ 3
1. Introduction:.............................................................................................................................................. 3
2. Research Problem: .................................................................................................................................... 5
2.1. Aims and Objectives: ......................................................................................................................... 5
2.2. Expected Outcome: ............................................................................................................................ 5
3. Rationale for Investigation:....................................................................................................................... 6
4. Literature Review: .................................................................................................................................... 6
4.1. Cellulose: ........................................................................................................................................... 6
4.1.1. Cellulose and its Derivatives: ..................................................................................................... 6
4.2. Cellulose Applications: ...................................................................................................................... 8
4.2.1. Application in Pharmaceutical Industry: ..................................................................................... 8
4.2.2. Application in extended release (ER) solid dosage forms: ......................................................... 8
4.2.3. Application in Automotive Industry: .......................................................................................... 9
4.3. Plasma Technology: ......................................................................................................................... 12
4.3.1. Effect of Plasma Technology: ................................................................................................... 15
5. Research Methodology: .......................................................................................................................... 15
6. Discussion: .............................................................................................................................................. 18
7. Conclusion: ............................................................................................................................................. 20
References:.................................................................................................................................................. 22
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Abstract:
The fundamental aim of this project was to carry out research on plasma technology in
cellulose applications. In the view of the fact that cellulose has been widely used as a main
source of paper, textile, bio medical instruments etc, at present there is a need to find utilisation
of plasma technology in cellulose applications. This project also indicates its potential
applications in different sectors. Mostly, the project was more aimed at how to improve the
effectiveness and efficiency of cellulose and why cellulose filters are a promising alternative to
existing filters. The effects of plasma technology on cellulose filters are also discussed.
Discussion regarding the topic of project with the supervisor and compilation of the research
materials by means of the resource areas were selected. The steps of completion of the project
involve the review of the literatures, arrangement s of the researched content and completion of
project.
Keywords:
Engine Filters.
1. Introduction:
Automotive giants including their respective suppliers are stressing on the use of filters
based on cellulose for several reasons which depends on economic, regulatory, product-specific
purposes and organization strategy-related. In spite of being the most plentiful natural polymer
found on the planet, only in recent times has it received considerable attention in the processing
of cellulose into several kinds of nano & micro structures. The utilisation of materials based on
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from nature and it contains many benefits for the betterment of environment, like dropping the
rate of Carbon Dioxide emissions into air throughout their succession of manufacturing,
dispensation and utilisation. The adoption of materials based on cellulose by automotive industry
has been increasing since past few years and approval of materials based on cellulose in the car
making industry is chiefly driven by policies, economic, company policy-related and product-
polymer which can be mostly found in green plants. Every year, thousands of tons of cellulose
are produced by green plants as it is not possible for gasoline to make polymers. The
products from cellulose can be made in different forms, like fibres, vela, sheet and powder.
Together they compose cellulose an essential substance for prospective applications in a number
In recent times, studies have been carried out for advancement of cellulose with the basic
aim of changing its characteristics in an advantageous way. Amongst all the advancement
approaches is the exposure of cellulose to plasma treatment (Lindner, Massner, Gartner, & Koch,
2014). The utilisation of plasma treatment for alteration of outside properties of artificial textiles
and polymers has been done in recent times (Lindner, Massner, Gartner, & Koch, 2014). The
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physical and chemical properties of the surface of a polymer, like colouring ability, chemical
lubricity are modified by the procedures (Lindner, Massner, Gartner, & Koch, 2014). The chains
of polymer are moderately decomposed throughout the plasma treatment and forms novel
functional groups. Functional groups can perform as centres of reaction for ensuing substance
2. Research Problem:
This study is focused on problems related to the current types of filters and plasma
technologies on cellulose applications. The basic aim is to explore the effects of plasma
treatment on the surface properties of cellulose and to discover the different approaches to
improve the effectiveness and efficiency of cellulose applications by using plasma technology in
different industries which includes textile, and paper, medical and automobile.
This study is aimed to provide useful information to understand the effects of different
plasma treatments on cellulose surface. The results are based on experiments. The comparison
and evaluation of the potential of cellulose filters with existing filters is also done. In this paper,
Finding a suitability of the different plasma technologies for different kinds of cellulose
applications, then find out the appropriate method to use cellulose for the manufacturing in
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This investigation can help in reducing the vehicles emission, enhance power rating, and
keep engines sustainable. The studies provide useful information to understand the plasma
reaction on amorphous and crystalline regions of cellulose surfaces and allow predicting effects
of the plasma treatment on physical and chemical properties of much more complex cellulose
4. Literature Review:
4.1. Cellulose:
The organic compound which is found in abundance and typically produced by green
plants is known as cellulose. It is the most systematic constituent in plant tissues and cells.
Cellulose is known as a natural stretched polymer chain that has an important character in human
food-cycle ultimately. Cellulose can be utilized in several areas like animal foods, paper and
wood, clothes plus fibres, pharmaceutical & cosmetic industries as an excipient. Cellulose
consists of partially man-made derivatives which are widely utilized in cosmetic &
pharmaceutical productions. Cellulose esters & cellulose ethers are basically the two key types of
Currently cellulose-based filters are very popular and in great demand in automotive
industry and turning out to be increasingly significant in this automotive field due to
manufacturing of the new technology cars which are light weight and exploring new ways to
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The first derivative is known as cellulose esters which are usually the type of polymer
that does not dissolve in water plus they have high-quality characteristics of film-forming. They
are extensively used in medication controlled discharge preparations like enteric coated and
osmotic systems of drug delivery. Cellulose esters are frequently utilized with cellulose ethers
classified into inorganic and organic sets. For pharmaceutical industries organic cellulose esters
The second type is called cellulose ethers these compounds have high molecular weight
anhydroglucose components of cellulose with alkyl groups (Sinha & Panigrahi, 2009). The
significant commercial properties of these polymers are known by their chemical structure,
molecular weights and sharing of the alkyl groups, amount of replacement and molar
replacement (where relevant). These characteristics usually involve oxidation, hydrolysis, and
solubility and viscosity in solution. Viscosity of cellulose ether solutions is directly related with
their molecular weights. Some of the extensively used cellulose ethers are: Sodium
cellulose (HPMC), Hydroxypropyl cellulose (HPC), Ethyl cellulose (EC) and Methyl cellulose
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Mucoadhesives and Bioadhesives are polymer films containing drug with capability of
sticking to organic membranes following mixing with mucus compounds or moisture. In mid-
1980s, Bioadhesives were introduced as a novel scheme in medicine deliverance and these days.
Bioadhesives are acknowledged as hopeful policies to extend the residence period and to
Forms of solid dosages like microcapsules, granules, spherules, pills, pellets and tablets
are frequently layered for several reasons like protecting responsive drugs from moisture, air and
every unsuitable condition of the environment, safety in opposition to enzymatic or acidic drugs
degradation, odour or flavour induction or creating time or site precise discharge qualities in
pharmaceutical industry to produce several customised discharge systems of drug delivery like
constant delivery, extended drug delivery, delayed drug delivery, instant drug delivery, pulsatile
drug delivery or one-by-one drug delivery prescribed amount (Kolarova, Vosmanska, Rimpelova
& Svorcik, 2013). Together, ester and ether cellulose derivatives are commonly utilized in solid
pharmaceuticals for coating purposes. Ethers are usually hydrophilic & alter to water gel when it
is exposed to water. Though, several cellulose ethers for instance, ethyl-cellulose are unsolvable
in H2O but most of the cellulose ethers like methyl, Hydroxypropylmethyl and Hydroxypropyl
are the types of cellulose which are water soluble (Kolarova et al., 2013).
Extended release (ER) medicines consign to pharmaceutical dosage forms which permits
double or more than double decrease in regularity of the medicine supervision in contrast to
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usual forms of dosage. These conceptions could be prepared as matrix or coated form. Coated
extended release conceptions are usually created with water unsolvable polymer layer coating
which includes or excludes ability of gel formation. The prevailing method of releasing drugs in
coated emergency release is dispersion while in matrix form of extended releases; matrix erosion
is the key method of releasing the drug (Jafari, Asadollahi & Farzaneh, 2012). Ethyl cellulose is
generally the most utilized cellulose-based polymer amongst these customized release forms of
dosage. Ethyl cellulose is totally unsolvable in propylene glycol, glycerine and water, and
dissolves in several untreated solvents like methyl acetate, chloroform, toluene, methanol and
ethanol. Fluid scatterings of ethyl cellulose, for example, Surelease (Colorcon) or Aqua coat
(FMC Biopolymer) or its natural arrangements can be utilized for covering of augmented
discharge details. After ingestion of these plans, an insoluble gooey gel is conforming to the
tablet which doesn't permit to medication to openly discharge from measurement structure. Drug
particles ought to go over this hindrance by dissemination component to enter the mass
disintegration medium and in this manner the discharge length is broadened significantly more
than the same uncoated ordinary definition. Bigger strong pharmaceuticals like tablets can be
covered with pivoting skillet coaters though the littler sorts as granules, beads or pills are coated
with air-suspension coater or fluid asset bed tools (Jafari, Asadollahi & Farzaneh, 2012).
Manufacturers of filters used in vehicles persist with their attempts to create medium that
is going to fulfil the needs of car engines in present era. The customers of vehicle filters continue
to insist items that are going to offer protection to their vehicle engines throughout intervals in
maintenance which are increasing day by day. This is significant to recognise that filter medium
distinctions could be of high value from one to another filter. A cartridge or spin-on filter might
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be of the similar diameter & length as a different vehicle filter; however this does not signify that
the engine filter is going to give the same performance and guard the engine as the cellulose-
Cellulose-based mixture and cellulose itself have demonstrated in past few years that it is
the top media worth for majority of air, fuel and lube filter applications. Innovative equipment
has now permitted the production of filter media based on cellulose that offers the finest blend of
Speed experiments have revealed that cellulose-based media oil filters have shown extra
capability and integrity of media after 25,000 kilometres in standard applications. By means of
media filters based on cellulose, managers of maintenance could attain their objectives of lengthy
intervals in maintenance at the least expense with no effect on the life of engine (Vander,
Glass-based filters were made to be used in pneumatic systems since it has small flow
limitation at high-level filtration performances. The properties of small flow limitation are useful
in pneumatic systems where oil, when cold is being pushed all the way through the medium &
filtration in the normal range of 2-4 micron that is needed. Filters based on glass medium have a
downside concerning aptitude. Normally, glass-based media contains the similar size of the pore
& similar diameter of the fibre throughout the whole piece. However, the media could be
modified to be extremely proficient, except after that it is so stiff that this media has extremely
small capacity or life. The filters based on glass-media could be made to be extra open, except
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then lost of efficiency occurs. One thing is to be remembered that the properties of little flow
limitations of media based on glass aren’t much significant in oil filtration of engine lube. The
oil in the engine has a propensity to heat up quickly, thus resistance to the flow is not a big issue
In majority of air, oil and fuel filter functions, cellulose-based filters are a superior
selection as compared to other types of filters. Once more, the basic reason is the life or capacity
of the filter (Sun et al., 2011). Filters based on cellulose are made with different size of fibres.
On filter’s top-most layers, the fibres are gathered, relatively than packed down together. When
contaminants or fuel is conceded all the way through the filter, numerous bits are collected on
the downy fibres on the outside and do not go beyond into the piece. The process is known as
"adsorption" since the bits stick to the fluffy fibres. When the technique of separation is applied
by the filters, additional little flecks could be removed before these particles enter the tiny spaces
in the pores on the panel surface of the filter. This process avoids tiny particles from clogging the
One more benefit of using cellulose-based filters is that the material of the filter will
characteristically be wider. The more width means the extra period the tiny particles will use
roving throughout the filter. Every occasion the liquid alters the route around a strand, the
momentum of the particles lets them roving in the similar route they were going and the particles
are focused on the fibres of the cellulose-based filters. The process of separating the particles is
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applied by the media, the further separation of particles is done with no clogging the tiny spaces
Other type of filters does remove a number of particles by means of impingement and
adsorption; however the levelled and even fibres cannot seize the particles at one place and then
the particles are cleaned with the liquid travelling throughout the filters. Typical filters mostly
utilize the technique of particle separation known as "direct interference." Mostly people think
this is how the filtration is done in vehicles. Direct interference is basically particles separation
by running the solution throughout tight spaces between the pores that are too small to grasp the
particles. Nevertheless, when containments clog all the pores, the filter is clogged and the life of
the filter is almost finished. Since filters based on cellulose are better at impingement and
adsorption, cellulose filters could get rid of additional impurities than other type of filters
without clogging the spaces between the pores (Gupta et al., 2007).
Usually, plasma is basically a gas in an ionized state that counted as the 4th form of
matter. Universe is made up of 99 percent plasma. Plasma is electrically impartial when observed
through a microscope. Though plasma has free charge carriers and is electrically conductive. To
generate plasma, enough energy must be applied to a gas. This energy is usually provided by an
electric source, which can be direct current (DC), radio frequency (RF), low frequency (LF) or
Numerous researches are carried out annually on technology of plasma treatment, enlightening
the huge opportunities provided by this fairly novel technology. In pharmaceuticals, plasma
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technology could be utilized for management of wound, treatment of tumour, surgery equipment,
process (that is, embedding of the novel useful groups on the surface being treated), technology
of plasma treatment in addition is being used to advance the properties of surface of the polymer
by application of plasmas containing reactive gases (such as water, ammonia, nitrogen and
oxygen) to surface of the polymer (Inbakumar et al., 2009). The plasma technology is
adhesion cleaning and promotion to semiconductors production. The reactions of plasma could
also be utilized for nuclear and plastic waste removal and carburizing or nitrating of steels
Plasma with low pressure could produce in discharging process of electrical gases. The
chemical process of the plasma occurs in non-balanced states (Shahidi et al., 2013). The groups
which are included in reactions of plasma, like ions and electrons, metaestable particles, free
radicals and atoms in excited states, could interrelate chemically and physically with hard
exteriors. Reactivity of the surface, water repellence, wettability and release of soil from fibres
used in textiles could be enhanced by utilizing technology of plasma treatment (Jun, Fengcai &
Bingqiang, 2008).
Plasma technology will not just eliminate impurities on the surface, break down chains of
polymer and bring in useful surface grouping, but in addition transform the cellulose nano-
topography (Jun, Fengcai & Bingqiang, 2008). Rooted on images from scanning electron
microscopy, Inbakumar et al. (2009) demonstrated that, following the treatment with plasma, the
cellulose-based fibre’s surface appears to develop into rougher surface with a considerable
quantity of minute cracks & grooves. Rooted on these scanning electron microscopy photos, they
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found that the application of plasma technology scratches the surface of fabrics of cotton (Wei et
al., 2007).
In the field of textile, critical examination work has been going ahead since the mid-
1990s in numerous research facilities over the world managing treatments of plasma with low-
with respect to the upgrades in different useful properties in plasma-treated materials. A range of
industrial low-pressure plasma equipment, mainly in model variety, has been intended for in-
line/batch textiles processing for more than a decade. Treatments with plasma are very famous in
the industry of textiles due to their many benefits as compared to usual damp processing methods
(Jun, Fengcai & Bingqiang, 2008). The treatment with plasma doesn’t change the mass
characteristics. Treatments with plasma technology demonstrate different benefits, since they are
amongst the ground-breaking methods to improve the wet processing of textile starting from pre-
treatments to concluding. Plasma is known to be distinctively useful tool for surface engineering
due to:
Their supreme thermal, physical, and chemical variety, allow the customization of
research.
Environment friendly and dry characteristics of plasma (Jun, Fengcai & Bingqiang,
2008).
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Due to the treatment of plasma technology, four chief impacts on the surfaces are usually
seen. Each of the effect is forever there to some extent; however one might be preferred over the
other effects, which depends upon the chemistry of the gas and substrate, the parameters of
operation and design of the reactor. The four key impacts are cleaning of the surface, etching or
ablation, chemical bonding close to surface molecules and alteration of chemical structure of the
Activation of plasma comprises the addition of novel operational groups on top of the
plasma-treated surface. Surface properties then rely upon the characteristics of the
chemical groups.
Grafting assisted by plasma is a process containing only two steps in which the activation
instance. The monomers after that go through a usual polymerization of free radical on
and the polymerization happens in the plasma itself (Calvimontes et al., 2011).
5. Research Methodology:
functioning environment of the vehicle, space availability, properties of filters media, and
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technology used in production. The process of the design comprises analysis of empirical and
theoretical forms demonstrating performance of filter media and flow of aerosol in housings of
the filter and by means of elements of the filter. Careful selection of filter media relies on these
models and basic tests conducted in the laboratory. The design of filter element is assessed in
immense detail by means of numerous field and laboratory tests (Lindner et al., 2014).
The role of air induction method of the vehicle’s engine is augmented due to latest engine
exhaust impurities and regulations of Carbon Dioxide emissions. Life time of the vehicle engine,
emissions from the engine and consumption of the fuel depends upon the air induction system
presentation and its design. Offering advanced solutions for these needs underlines trends in the
innovation of vehicle filters. These push the need for small, more compressed and well-
structured vehicle filter medium with improved permeability. The capability could be completely
2014).
A cellulose-based filter contains fibres of large diameter. Conversely, other type of filters
contains thin fibres. Additionally, other types of filters are not as much of responsive to water as
compared to cellulose-based filters, which happens to bulge and hamper the flow. Thus, other
types of filters are going to have lesser constraints as compared to cellulose-based filters of the
similar rating of efficiency. Since the vehicle filters are fully contaminated, an additional benefit
of the other types of filters enlarged area of the flow. Impurities that clog the fifty percent surface
are of the cellulose-based filter are only going to clog 20 percent of the surface area of other
types of filters. The outcome observed is a lot lesser restriction in the other filters when
compared with filters based on cellulose for the similar point of loading (Lindner et al., 2014).
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Synthetic media has the ability to load impurities through filter media’s depth. Impurities
have a propensity to load on the surface of cellulose-based media. This is an additional method
by which usual filter technologies enlarge capacity of the filter. The selection amid synthetic and
cellulose is equilibrium amid capacity & efficiency. It is also equilibrium amid performance &
The improvement in present filters as compared to filters which existed in the past is
basically the media of the filter itself. Incorporations of early designs were metal screens, wire
meshes, steel wool and supplementary to stop the impurity particles from inflowing into the
system. The subsequent monotony of the filter media was present in the shape of mass fibre or a
variety of wicker fabrics, such as linen. When non-reusable filters turned well-liked in the 1970s,
paper and cellulose were utilized to reduce costs of production (Lindner et al., 2014).
Traditional surface type cellulose and surface type synthetic filter media that pre-
dominate the engine air induction system market can provide improved dirt competence and
improved gravimetric effectiveness when a dirt coat is created on the filter media, for which
some time is needed (Hegemann, Brunner & Oehr, 2013). The fractional efficiency & initial
efficiency for tiny dirt particles of conventional media of filters is a lot less in several other
applications. Regardless of this actuality, the media which is typically used is still cellulose-
based, since it his less costly and holds the capability of pleating into a closely filled block of
The market of vehicle filters is focused on the following requirements of performance for
air induction systems of vehicle engines: little restriction in the flow, high capacity of holding
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dust (service-free and long life designs is the key aim in several applications), top fractional &
gravimetric competence, compact and small components, incorporated silencing and air intake
method, everlasting systems of air intake including no Carbon Dioxide emissions, special
designs, volumetrically competent filters to robust into space that is available (Nithya et al.,
2011).
The significance of the air induction method of the vehicles engines has lately amplified
due to the state vehicle exhaust particulate and CO2 emission policies. Impurities present in the
system of air intake might considerably add to the entire emissions from engine which includes
emissions from crankcase considering the filters having low effectiveness. In accordance to the
previous research 40 percent of impurities which enters into the system of vehicle air intake and
inflowing into the engine goes through the exhaust. For reduction of the impurities concentration
posterior of the filter, extremely proficient filters are required. Improved competence could be
attained by making use of nano-fibre filter media & appropriate design of engine air intake
6. Discussion:
The treatment of plasma could have extreme effects over the characteristics of the
materials of filter. Various treatments of the gas plasma have diverse changes on filter surfaces.
The treatments of plasma offer great possibility for functionalisation and modification for the
materials of the filter. Usually, the technology of plasma is slow but it is stable in the industrial
revolution (Jafari, Asadollahi & Farzaneh, 2012). The treatment of plasma in textiles could not
substitute all the wet procedures nevertheless it could be a practical prior treatment, which could
offer number of economical and environmental benefits. Hence, the industry of automobile
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should be considerate for the concept of heavy investments at an initial state in the equipment as
they could be profitable in respect to environmental savings provided the sale income of great
The width of the fibre is hypothetical and to be changed beneath the treatment of plasma
specifically due to the ablation of the material. The treatment of plasma leads to an important
reduction of the width, which would surprisingly most evident for the smallest sample exposition
to discharge plasma. However, the results are comparable by means of percentage for the plasma
of untreated and treated samples. The width was further reduced after immersion of the examples
by putting into PBS for the increased periods of time. This effect would also been observed on
the fibres of pristine cellulose, but it looks to be more prominent on different samples treated
well in the discharge of plasma. The results of the treatment of plasma, especially on the
samples, with samples preserved in plasma for around 400 seconds, might be because of the
simpler liberation and dissolution and of the degraded products (Lindner et al., 2014).
Water absorption ability is very significant for the application of bandages based on
cellulose materials in medical. Moreover, the water sorption ability is very limited. An
unstructured pattern of the fibres of cellulose comprises free groups of hydroxyl that attract the
molecules of water leading to formulate the bonds of hydrogen. Fibre of cellulose never
dissolves in water, only fibres swell. The material constitutes of moisture which exists in the
bounded and absorbed form. Water confined by the bonds of hydrogen needs a high temperature
to dry, hence could not be get rid by drying at the temperatures in the laboratory. Generally, the
textile form of cotton is not said to be a very good hydrophilic material. Plasma exposure’s
increasing time affects the water absorption ability speedily (Gupta et al., 2007).
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In this study the variety of applications has been vehicle filters. Although being more
inadequate in the quantity of operational groups which could be inter-linked and the restricted
solidity over period of time, treatments with plasma still heads in advancement of cell capability,
differentiation, adhesion, and proliferation also improved adsorption & chemical bonding of
capable of doing everything, whereas having admission to a broader range of operational groups
and advancements in biomedical engineering helps in extra steady surfaces. The integration of
species having little molecular mass inside the coatings needs to be avoided by any means as
they could posses a harmful influence on the cells capability (Coseri et al., 2013).
These days, the systems with low pressure are definitely the commonly utilized systems
of treatment, as all the approaches at the back of the procedure are well recognized and several
systems are available commercially. Since past few years, the major concern has been the
systems of atmospheric pressure as they cost a lot less and could be further introduced and linked
in manufacturing systems of textile and it is believed that distinctive pressure systems like the
plasma jets are going to turn into the most significantly utilized systems (Shi et al., 2013).
7. Conclusion:
The research gives significant information regarding better perceptive and forecasting the
impact of plasma technology on chemical & physical characteristics of a lot more multifaceted
cellulose-based structures and systems like cotton fabrics & fibre. Technology of plasma
treatment might have deep impacts on the characteristics of cellulose-based filter. Diverse
treatments with gas plasma show diverse impacts on the filters surfaces. Treatments with plasma
give huge possibility for the functionalisation and modification of cellulose-based filters.
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The technology of plasma treatment is slow, but solid in the revolution of this industry.
Treatment of plasma for textiles can’t substitute every wet procedure, but plasma technology
could be a feasible preliminary treatment, which could offer numerous economical &
environmental advantages. Thus, vehicle filter industry must reflect on the idea of more
beginning investments in tools that is going to profit regarding savings related to the
environment & the revenue of the sale of top value added products.
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Coseri, S., Biliuta, G., Simionescu, B. C., Stana-Kleinschek, K., Ribitsch, V., & Harabagiu, V.
Gupta, P., Tenhundfeld, G., Daigle, E. O., & Ryabkov, D. (2007). Electrolytic plasma
201(21), 8746-8760.
Hegemann, D., Brunner, H., & Oehr, C. (2013). Plasma treatment of polymers for surface and
Inbakumar, S., Morent, R., De Geyter, N., Desmet, T., Anukaliani, A., Dubruel, P., & Leys, C.
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Jafari, R., Asadollahi, S., & Farzaneh, M. (2012). Applications of plasma technology in
33(1), 177-200.
Jun, W., Fengcai, Z., & Bingqiang, C. (2008). The Solubility of natural cellulose after DBD
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Karahan, H. A., & Ozdogan, E. (2008). Improvements of surface functionality of cotton fibres by
Kolarova, K., Vosmanska, V., Rimpelova, S., & Svorcik, V. (2013). Effect of plasma treatment
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Sun, S., Sun, J., Yao, L., & Qiu, Y. (2011). Wettability and sizing property improvement of raw
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Vander Wielen, L. C., Ostenson, M., Gatenholm, P., & Ragauskas, A. J. (2006). Surface
Wei, Q., Wang, Y., Yang, Q., & Yu, L. (2007). Functionalization of textile materials by plasma
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