Δ𝐻 𝑠𝑢𝑏 = Δ𝐻 𝑓𝑢𝑠 + Δ𝐻 𝑣𝑎𝑝

𝑑𝐿𝑛𝑃𝑣𝑎𝑝 Δ𝐻 𝑣𝑎𝑝
=− 𝑬𝒄𝒖𝒂𝒄𝒊ó𝒏 𝒅𝒆 𝑪𝒍𝒂𝒖𝒔𝒊𝒖𝒔 − 𝑪𝒍𝒂𝒑𝒆𝒚𝒓𝒐𝒏
1 𝑅
𝑑 (𝑇)
𝑃𝐵
𝑍 = 1 + 𝑅𝑇 𝑬𝒄𝒖𝒂𝒄𝒊ó𝒏 𝒗𝒊𝒓𝒊𝒂𝒍 𝒕𝒓𝒖𝒏𝒄𝒂𝒅𝒂 Z=PV/RT
𝑃𝐵
𝐵̂ = 𝐵° + 𝑤𝐵1 𝑪𝒐𝒓𝒓𝒆𝒍𝒂𝒄𝒊ó𝒏 𝒅𝒆 𝑷𝒊𝒕𝒛𝒆𝒓 𝒅𝒐𝒏𝒅𝒆: 𝐵̂ = 𝑅𝑐𝑇
𝑐

0.422 0.172
𝐶𝑜𝑟𝑟𝑒𝑙𝑎𝑐𝑖ó𝑛 𝑑𝑒 𝑉𝑎𝑛 𝑁𝑒𝑠𝑠 𝑦 𝐴𝑏𝑏𝑜𝑡𝑒 𝐵° = 0.083 − 𝐵1 = 0.139 −
𝑇𝑟 1.6 𝑇𝑟 4.2
Para la ecuación de Van der Waals:
𝑅𝑇 𝑎 𝑎
𝑰) 𝑃 = − 2 𝑰𝑰) (𝑃 + )(𝑉 − 𝑏) = 𝑅𝑇
𝑉−𝑏 𝑉 𝑉2
𝑅𝑇 2 𝑎 𝑎𝑏
𝑰𝑰𝑰) 𝑉 3 − (𝑏 + )𝑉 + − =0
𝑃 𝑃 𝑃
𝑏𝑃 𝑎𝑃 𝑎𝑏𝑃2
𝑰𝑽) 𝑍 3 − ( + 1) 𝑍 2 + [ ] 𝑍 − =0
𝑅𝑇 (𝑅𝑇)2 (𝑅𝑇)3
𝑎 𝑏 𝑏 2𝑎 𝑏
𝐼𝑛 𝜑 = 𝑍 − 1 − − 𝐼𝑛 [𝑍 (1 − )] ó 𝐼𝑛 𝜑 = − − 𝐼𝑛 [𝑍 (1 − )]
𝑅𝑇𝑉 𝑉 𝑉 − 𝑏 𝑅𝑇𝑉 𝑉
Para Redlich-Kwong
𝑅𝑇 𝑎 𝑎
𝑃= − (𝑃 + ) (𝑉 − 𝑏) = 𝑅
𝑉 − 𝑏 √𝑇 𝑉(𝑉 + 𝑏) √𝑇 𝑉(𝑉 + 𝑏)
𝑍 3 − 𝑍 2 + (𝐴 − 𝐵 − 𝐵 2 )𝑍 − 𝐴𝐵 = 0
2
𝑅 2 𝑇𝑐 2.5 𝑚3 𝑅 𝑇𝑐 𝑚3
𝑎 = 0.427480 [=] ( ) 𝐾 0.5 𝑏𝑎𝑟 𝑏 = 0.086646 ( ) [=]
𝑃𝑐 𝑘𝑚𝑜𝑙 𝑃𝑐 𝑘𝑚𝑜𝑙
𝑎𝑃 𝑏𝑃
𝐴= 𝐵=
𝑅 2 𝑇 2.5 𝑅𝑇
𝑎
− 𝑏𝑅𝑇 − 𝑃𝑏 2
𝑅𝑇 𝑎𝑏
𝑉 3 − ( ) 𝑉 2 + (√𝑇 )𝑉 + =0
𝑃 𝑃 𝑃√𝑇

(𝑉𝑖 − 𝑏𝑖 )𝑃 𝑎𝑖 𝑏𝑖
𝐼𝑛 𝜑 = 𝑍1 − 1 − 𝑙𝑛 ( )− 1.5
𝐼𝑛 (1 + ) 𝑃𝑎𝑟𝑎 𝑒𝑠𝑝𝑒𝑐𝑖𝑒𝑠 𝑝𝑢𝑟𝑎𝑠
𝑅𝑇 𝑏𝑖 𝑅𝑇 𝑢𝑖

𝑏1 (𝑉 − 𝑏)𝑃 𝑎𝑖 𝑎𝑏1 𝑏
𝐼𝑛𝜑1 = (𝑍 − 1) − 𝐼𝑛 ( )− [ − 2(𝑦1 𝑎1 + 𝑦2 𝑎1,2 )] 𝐼𝑛 (1 + )
𝑏 𝑅𝑇 𝑏𝑖 𝑅𝑇 1.5 𝑏 𝑉
Ecuación de Soave
𝑎𝛼
(𝑃 + ) (𝑉 − 𝑏) = 𝑅𝑇
𝑉(𝑉 + 𝑏)
1 2
𝛼 = [1 + 𝑚(𝑤) (1 − 𝑇𝑟 2 )]

𝑚(𝑤) = 0.48508 + 1.55171𝑤 − 0.15613𝑤 2

𝑅𝑇 𝑎 𝛼 − 𝑏𝑅𝑇 − 𝑝𝑏 2 𝑎 𝛼𝑏
𝑉3 − 𝑉2 ( ) + ( )𝑉 − =0
𝑃 𝑃 𝑃

𝑍 3 − 𝑍 2 + (𝐴 − 𝐵 − 𝐵 2 )𝑍 − 𝐴𝐵 = 0
𝑏 𝑎𝛼 𝑏
𝐼𝑛 𝜑 = 𝑍 − 1 − 𝐼𝑛 [𝑍 (1 − )] − 𝐼𝑛 (1 + )
𝑉 𝑏𝑅𝑇 𝑉
Ecuación de Peng-Robinson
𝑎𝛼
(𝑃 + ) (𝑉 − 𝑏) = 𝑅𝑇
𝑉(𝑉 + 𝑏) + 𝑏(𝑉 − 𝑏)
𝑅 2 𝑇𝑐 2 𝑅𝑇𝑐
𝑎 = 0.45724 ( ) 𝑏 = 0.0778 ( )
𝑃𝑐 𝑃𝑐
1 2
𝛼 = [1 + 𝑚(𝑤) (1 − 𝑇𝑟 2 )]

𝑚(𝑤) = 0.37464 + 1.54226𝑤 − 0.26992𝑤 2

𝑍 3 − 𝑍 2 (1 − 𝐵) + (𝐴 − 3𝐵 2 − 2𝐵)𝑍 − (𝐴𝐵 − 𝐵 2 − 𝐵 3 ) = 0
𝛼 𝑃𝑟 𝑃𝑟
𝐴 = 0.45724 𝐵 = 0.07780
𝑇𝑟 2 𝑇𝑟
(𝑉𝑖 − 𝑏𝑖 )𝑃 (𝑎 𝛼)𝑖 𝑉𝑖 + (1 + √2 )𝑏𝑖
𝐼𝑛 𝜑𝑖 = 𝑍𝑖 − 1 − 𝐼𝑛 ( )− 𝐼𝑛 [ ]
𝑅𝑇 𝑏𝑖 2√2 𝑅𝑇 𝑉𝑖 + (1 − √2 )𝑏𝑖

Propiedades Molares Parciales

𝜕𝑛𝑉 𝑚3
̅̅̅
𝑀𝑖 = [ ] [=] ̅̅̅̅ + 𝑥2𝑉2
𝑉 = 𝑥1𝑉1 ̅̅̅̅
𝜕𝑛𝑖 𝑇,𝑃,𝑛𝑗 𝑘𝑚𝑜𝑙

Tangente
𝑑𝑀
̅̅̅̅ = 𝑀 + 𝑋2 (
𝑀1 ̅̅̅̅ = 𝑀 − 𝑋1(𝑑𝑀/𝑑𝑥2)
) 𝑜 𝑀2
𝑑𝑥1

𝐺𝑖𝑏𝑏𝑠 − 𝐷𝑢ℎ𝑒𝑚 ∑ 𝑥𝑖𝑑𝑀𝑖 = 0 ∴ 𝑥1𝑑𝑀1 + 𝑥2𝑑𝑀2 = 0