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  • Complex Ions: (Cu (H2O) 6) 2+ Cobalt Ions Splitting of Ligands Then Electron Promotion Causes Colour Changes

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    Omar Hashem
    15 Ansichten1 Seite
    The document discusses coordination complexes of cobalt and copper ions. Cobalt ions form an octahedral complex with 6 ligands at 90 degree angles, which causes the complex to be pink. Copper ions form a blue octahedral complex with 6 water ligands, [Cu(H2O)6]2+, but forms a pale blue precipitate of Cu(OH)2 when reacted with excess NH3. Copper also forms a lime green tetrahedral complex with 4 chloride ligands at 109.5 degrees, [CuCl4]2-.

    Originalbeschreibung:

    Unit 5 chem

    Originaltitel

    Complex Ions

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    The document discusses coordination complexes of cobalt and copper ions. Cobalt ions form an octahedral complex with 6 ligands at 90 degree angles, which causes the complex to be pink. Copper ions form a blue octahedral complex with 6 water ligands, [Cu(H2O)6]2+, but forms a pale blue precipitate of Cu(OH)2 when reacted with excess NH3. Copper also forms a lime green tetrahedral complex with 4 chloride ligands at 109.5 degrees, [CuCl4]2-.

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    15 Ansichten1 Seite

    Complex Ions: (Cu (H2O) 6) 2+ Cobalt Ions Splitting of Ligands Then Electron Promotion Causes Colour Changes

    Hochgeladen von

    Omar Hashem
    The document discusses coordination complexes of cobalt and copper ions. Cobalt ions form an octahedral complex with 6 ligands at 90 degree angles, which causes the complex to be pink. Copper ions form a blue octahedral complex with 6 water ligands, [Cu(H2O)6]2+, but forms a pale blue precipitate of Cu(OH)2 when reacted with excess NH3. Copper also forms a lime green tetrahedral complex with 4 chloride ligands at 109.5 degrees, [CuCl4]2-.

    Copyright:

    © All Rights Reserved
    Als PDF, TXT herunterladen oder online auf Scribd lesen
    Markieren Sie unangemessene Inhalte
    von 1

    Octahedral Coordination

    with 90° Number 6

    Coordination Octahedral
    Number 6 with 90°
    splitting of 5 different
    Cobalt Ions
    ligands then degenerate
    electron d-orbitals [Cu(H2O)6]2+ Blue
    promotion Pink Blue with HCl
    causes colour
    changes Ligands
    Complex Ions Copper Ions
    Pale Blue
    Precipitate

    Coordination ([CuCl4]2-) dropwise


    number 4 HCl-(aq) [Cu(H2O)6]2+ Cu(OH)2(s)
    + 6(H2O)(l) NH3(aq)

    Tetrahedral Excess
    with 109.5° Lime Green NH3(aq)
    Solution

    [Cu(NH3)4(H2O)2]2+(aq) Deep Blue


    solution

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