ORGANIC CHEMISTRY

TARGET : JEE (Main + Advanced) 2016

Course : VIJAY (JR) NO. 35

This DPP is to be discussed in the week (15-02-2016 to 20-02-2016)

1. Course of the week as per plan :
2. Course covered till previous week :
3. Target of the current week :
4. DPP Syllabus :
DPP No. # 35 (JEE-MAIN)
Total Marks : 60 Max. Time : 40 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.20 (3 marks, 2 min.) [60, 40]

Answer Key
1. (C) 2. (B) 3. (A) 4. (D) 5. (B) 6. (C) 7. (D)
8. (B) 9. (C) 10. (D) 11. (A) 12. (D) 13. (D) 14. (A)
15. (A) 16. (D) 17. (B) 18. (D) 19. (D) 20. (A)

1. Which of the following is a D-aldose fuEu esa ls D-,sYMksl dkSulk gksxkA

(A) (B) (C*) (D)

Sol.(C) has correct Fischer projection formula

2. The two forms of D-Glucopyranose obtained from solution of D-Glucose are known as
(A) Epimers (B*) Anomers (C) Enantiomers (D) Geometrical Isomers
D-Xywdksl ds foy;u ls izkIr D-Xywdkslik;jsukst ds nks :i dgykrs gSa %
(A) ,ihej (B*) ,uksej (C) izfrfcEc:ih (D) T;kfefr; leko;oh
Sol. -D-Glucopyranose and -D-Glucopyranose are anomers.
gy . -D-Xywdksik;jsuksl vkSj -D-Xywdksik;jsuksl ,uksej gSaA

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 +

3. Which of the following is a C-4 epimer of D-glucose.

fuEu esa ls dkSulk D-Xywdksl dk C-4 ,ihej gS %

(A*) (B) (C) (D)

Sol.(A)

4. D-Glucose and D-Mannose are

(A) Anomers (B) Enantiomers (C) Geometrical Isomers (D*) Epimers
D-Xywdksl vkSj D-eSukst gSA
(A) ,uksej (B) izfrfcEc:ih (C) T;kfefr leko;oh (D*) ,ihej

5. In which of the following pairs, both the compounds give positive test with Tollen’s reagent?
(A) Glucose and sucrose (B*) Glucose and fructose
(C) Fructose and sucrose (D) Acetophenone and hexanal
fuEu esa ls dkSu ls ;qXeksa esa] nksuksa ;kSfxd VkWysu vfHkdeZd ds lkFk /kukRed ijh{k.k nsrs gSaA
(A) Xyqdkst rFkk lqØksl (B*) Xyqdksl rFkk QDVªksl
(C) ÝDVksl rFkk lqØksl (D) ,slhVksQhuksu rFkk gSDlsusy
Sol. Aldehydes and -hydroxy ketones give positive Tollen's test. Glucose has an aldehyde group and fructose is
an -hydroxy ketones.
Sol. ,fYMgkbM vkSj -gkbMªkWDlh dhVksu ldkjkRed VkWysu ijh{k.k nsrs gSa Xywdksl ,fYMgkbM lewg j[krk gS tcfd ÝDVksl
-gkbMªkWDlh dhVksu gSA
6. Which of the following is a reducing sugar fuEu eas ls dkSu vipf;r 'kdZjk gS \

(A) (B)

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 (C*) (D)

Sol.

It has a cyclic hemiacetal structure in one ring which opens in aqueous solution to aldehydic acyclic form
and reduces Tollen's reagent and Fehling solution.

7. Compound P & Q may be grouped as

vfHkfØ;k esa mRikn P vkSj Q gS \

H SO
2 
4
 +
KCN

(A) Diastereomers foofjeleko;oh (B) Epimers ,ihej

(C) Anomers ,uksej (D*) Both (A) and (B) are correct A vkSj B nksuksa lgh gS

8. The open chain structure of the following compound is

fn;s x;s ;kSfxd dh [kqyh J`a[kyk lajpuk gSA

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 (A) (B*) (C) (D)

Sol.(B)

9. Glucose and fructose form :

(A) same acid on oxidation (B) same alcohol on reduction
(C*) same osazone (D) different osazone .
Xyqdkst o ÝDVkst cukrs gSa %
(A) vkWDlhdj.k ij leku vEy (B) vip;u ij leku ,YdksgkWy
(C*) leku vkslktksu (D) fHkUu vkslktksu

10. Which of the following is not a tautomer of Fructose fuEu esa ls dkSu ÝDVkst dk pyko;oh ugha gSA

CH2OH
|
CO
| (Fructose) (ÝDVksl)
(CHOH)3
|
CH2OH

CH2OH
CH  OH |
|| C  OH
C  OH ||
(A) | (B) C  OH (C) (D*)
(CHOH)3 |
| (CHOH)2
CH2OH |
CH2OH

Sol. Its molecular formula is C6H10O5. Fructose has molecular formula C6H12O6. So it is not tautomer of Fructose.

11. Glucose on reduction with NaBH4 gives ?

(A*) Sorbitol (B) Fructose (C) Saccharic acid (D) Gluconic acid
Xywdksl NaBH4 ds }kjk vipf;r gksdj nsrk gS ?
(A*) lfcZVkWy (B) ÝDVksl (C) lsdfs jdvEy (D) Xywdksfud vEy

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 2H 2H
Sol. 
  
 
Na – Hg / H2O Na – Hg / H2O

12. Which of the following will form same product (osazone) on reaction with PhNHNH 2 (excess).
fuEu esa ls dkSuls PhNHNH2 ¼vkf/kD;½ ds lkFk fØ;k djds leku mRikn ¼vkslktksu½ cuk;sxsaA

(A) X, Y (B) X, Z (C) Z, W (D*) X, Z, W

Sol.(D) Osazone formation involves following reaction :

CH2OH CHO CH  N  NHPh

| | |
CO or CHOH C  N.NHPh
| | |
R R R

13. When D-Glucose is placed in basic aqueous solution an equilibrium mixture of three compounds is obtained.
Which of the following will not be present in equilibrium mixture.
{kkjh; tyh; foy;u esa tc D-Xywdksl dks j[kk tkrk gS rks rhu ;kSfxdks dk lkE;koLFkk feJ.k izkIr gksrk gSA fuEu esa ls
dkSulk mRikn lkE; feJ.k esa mifLFkr ugha gksxkA

(A) (B) (C) (D*)

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Sol.(D)

14. How many moles of acetic anhydride (Ac2O) is needed to react completely with tataric acid, ribose and
glucose respectively.
VkVZfjd vEy] jkbckst vkSj Xywdkst ds lkFk vfHkfØ;k djus ds fy, ,slhfVd ,ugkbMªkbM ds Øe'k% fdrus eks y dh
vko';drk gksrh gSA

(A*) 2,4,5 (B) 2,3,4 (C) 4,5,6 (D) 4,5,5

Sol. Depends upon number of –OH group
–OH dh la[;k ij fuHkZj djrs gSaA

15. The following poly-saccharide has

fuEu ikWyh&lSdsjkbM j[krk gS %

(A*) Glucose monomer and - glycosidic linkage (B) Fructose monomer and - glycosidic linkage
(C) Glucose monomer and - glycosidic linkage (D) Fructose monomer and - glycosidic linkage
(A*) Xywdksl eksuksej rFkk -XykbdksflfMd ca/ku (B) ÝDVksl eksuksej rFkk -XykbdksflfMd ca/ku
(C) Xywdksl eksuksej rFkk -XykbdksflfMd ca/ku (D) ÝDVksl eksuksej rFkk -XykbdksflfMd ca/ku

16. Monomer of celluose is

lsywykst dk ,dyd gSA
(A) Fructose (B) Maltose (C) Sucrose (D*) Glucose
(A) ÝDVksl (B) ekYVksl (C) lqØksl (D*) Xywdksl
Sol. Celluose is the polymer of glucose

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 lsyqykst] Xyqdksl dk cgqyd gSA

17. The true/false statements about the following compounds are :

S1 : This carbohydrate polymer is composed of -D (+) glucose.

S2 : It has -(1,4) glycosidic linkage
S3 : It is a non-reducing carbohydrate
fuEu ;kSfxd ds fy;s lR;@vlR; dFku gksaxsA

S1 : ;s dkcksZgkbMªsV cgqyd -D (+) Xywdksl ls cuk gSA

S2 : blesa -(1,4) XykbdksflfMd ca/ku gSA
S3 : ;s vuvipk;d dkcksZgkbMªsV gSA

(A) T T T (B*) T F T (C) T F F (D) F F T

18. The following compound on hydrolysis will give

fn;k x;k ;kSfxd ty vi?kVu ds nkSjku nsxkA

(A) A pair of anomers (B) A pair of enantiomeris

(C) A pair of epimers (D*) A pair of molecules having common tautomer
(A) ,uksej ;qXe (B) izfrfcEc ;qXe
(C) ,ihej ;qXe (D*) v.kq ;qXe tks fd leku pyko;ork j[krk gS

19. Which of the following is nonreducing sugar ?

(A) Glyceraldehyde (B) Glucose
(C) Fructose (D*) Sucrose
fuEu eas ls dkSu vuvipf;r 'kdZjk gS \
(A) fXyljsfYMgkbM (B) Xyqdkst
(C) ÝDVkst (D*) lqØkst
Ans. Sucrose is not a reducing sugar, e.g., it will not reduce Fehling’s solution ; it does not form an oxime or an
osazone, and does not undergo mutarotation. This indicates that neither the aldehyde group of glucose nor
the ketonic group of fructose is free in sucrose.

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20.

The above process in which  and  form remain in equilibrium with acyclic form and a change in optical
rotation is observed which is called as -
(A*) Mutarotation (B) Epimerisation (C) Condensation (D) Inversion
mi;qZDr izfØ;k ftlesa  vkSj  :i vpfØ; :i ds lkFk lkE; voLFkk esa jgrs gSa vkSj izdkf'kd ?kw.kZu esa ifjorZu ns[kk tkrk
gSA bls dgrs gS &
(A*) E;wVkjksVs'ku (B) ,ihejhdj.k (C) la?kuu (D) izrhiu
Ans. The above phenomenon is called as mutarotation.
mi;qZDr ?kVuk dks E;wVkjksVs'ku dgrs gSA

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