LP-Flash.

xsl
This spreadsheet performs flash calculations at low pressures and temperatures.
(pressure < 1,000 psia, temperature < 200 oF)

Instructions:
1) Update input data in blue;
2) Run Macro Solution;
3) Enter a value for z-factor in the "Flash Calculation" section;
4) View results.

Input Data:
Pressure: 600 psia
Temperature: 200 o
F
Specific gravity of stock tank oil: 0.90 water = 1
Specific gravity of solution gas: 0.70 air = 1
Gas solubility (Rs): 3000 scf/STB

Composition

Compound Mole Fraction (zi)

C1 0.6599
C2 0.0869
C3 0.0591
i-C4 0.0239
n-C4 0.0278
i-C5 0.0157
n-C5 0.0112
C6 0.0181
C7+ 0.0601
N2 0.0194
CO2 0.0121
H2S 0.0058
1.0000

Property Table:

a= 0.9474
c= 0.876
n= 9.76

Compound b (oR) TB (oR) F ki

C1 300 94 2.7369439072 3.688176
C2 1145 303 2.0440294029 0.91163
C3 1799 416 1.598761655 0.371333
i-C4 2037 471 1.238477128 0.179537
 n-C4 2153 491 1.1228075048 0.142177
i-C5 2368 542 0.7811249022 0.07137
n-C5 2480 557 0.6948479408 0.05997
C6 2738 610 0.3400397417 0.029317
C7+ 3770 793 -0.9558241536 0.002148
N2 470 109 3.5998053934 21.02221
CO2 652 194 2.3729459544 1.769903
H2S 1136 331 1.710812048 0.4655

Flash Calculation:

nv = 0.7627

Compound zi ki zi(ki-1)/[nv(ki-1)+1]
C1 0.6599 3.6882 0.5816
C2 0.0869 0.9116 -0.0082
C3 0.0591 0.3713 -0.0714
i-C4 0.0239 0.1795 -0.0524
n-C4 0.0278 0.1422 -0.0690
i-C5 0.0157 0.0714 -0.0500
n-C5 0.0112 0.0600 -0.0372
C6 0.0181 0.0293 -0.0677
C7+ 0.0601 0.0021 -0.2510
N2 0.0194 21.0222 0.0239
CO2 0.0121 1.7699 0.0059
H2S 0.0058 0.4655 -0.0052
-0.0007

nL = 0.2373

Compound xi yi xiMWi yiMWi

C1 0.2163 0.7979 3.4701 12.7984
C2 0.0932 0.0849 2.8019 2.5543
C3 0.1135 0.0422 5.0072 1.8593
i-C4 0.0639 0.0115 3.7118 0.6664
n-C4 0.0804 0.0114 4.6733 0.6644
i-C5 0.0538 0.0038 3.8828 0.2771
n-C5 0.0396 0.0024 2.8550 0.1712
C6 0.0697 0.0020 6.0073 0.1761
C7+ 0.2515 0.0005 28.7322 0.0617
N2 0.0012 0.0251 0.0334 0.7023
CO2 0.0076 0.0135 0.3355 0.5938
 H2S 0.0098 0.0046 0.3337 0.1553

Apparent molecular weight of liquid phase: 61.84

Apparent molecular weight of vapor phase: 20.68
Specific gravity of liquid phase: 0.50
Specific gravity of vapor phase: 0.71
Input vapor phase z-factor: 0.958
Density of liquid phase: 31.50
Density of vapor phase: 1.83
Volume of liquid phase: 0.08
Volume of vapor phase: 277.34
GOR (check with the input solution gas ratio): 3343
 MWi ziMWi pci (psia) zipci (psia) Tci, (oR) ziTci (oR)

16.04 10.58 673 444.11 344 227.01

30.07 2.61 709 61.61 550 47.80
44.10 2.61 618 36.52 666 39.36
58.12 1.39 530 12.67 733 17.52
58.12 1.62 551 15.32 766 21.29
72.15 1.13 482 7.57 830 13.03
72.15 0.81 485 5.43 847 9.49
86.18 1.56 434 7.86 915 16.56
114.23 6.87 361 21.70 1024 61.54
28.02 0.54 227 4.40 492 9.54
44.01 0.53 1073 12.98 548 6.63
34.08 0.20 672 3.90 1306 7.57
MWa = 30.45 ppc = 634 Tpc = 477
water =1
air = 1

lbm/ft3
lbm/ft3
bbl
scf
scf/bbl