Solution JEE Main 2019 Mock Test 5

IT2019JEE Main 2019 Mock Test-(100374.
1)-PCM20
FIITJEE - JEE (Main)

PHYSICS, CHEMISTRY & MATHEMATICS
JEE Main 2019 Mock Tests (Code-100374.1)
HINTS AND SOLUTIONS
PHYSICS (PART-I)
1. Number density = 5  1028 atoms/m3

22 3
= 5  10 atoms/cm
Since, 1 atom of indium is doped in 5  107 Silicon atoms, so total number of indium atoms doped per
cm3 will be
5  1022
n  1015 atoms cm 3 .
5  107
2. Due to inertial
 dv 
3. P  B  
 V 
 y 
P  B  
 x 
 y 
P  P  
 x 
P u
  
P c
4. Q = 10(1)40 = 400 cal

400
Amount of ice melted =  5g
800
 amount of water = 10 + 5 = 15 gm
5. Work done = change in gravitational PE of COM.

N
37
37
N
6.
mg
7. Output equation y = A  B  A.B
9. Range of frequency is 2 to 10 MHz.
V L
10. Veq  V02   0 
 2 
Req   L 2  R2
11. x = 3 sin 100 t + 8 cos2 50 t
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IT2019JEE Main 2019 Mock Test-(100374.1)-PCM21
 1  cos2??/ 50t 
 3 sin100t  8  
 2 
X = 5 sin (100t) + 4
12. Rate of heat emitted = eAT4(body)

Rate of heat absorbed = eAT4(surrounding) e A  eB eA eB
A T B
T T
P
14. 100   3  0 1 2  0  2  3  0  3  4  0  1
P
 3  4  9  4  2%
2
15. f  a2  Z  b  .
 (D)
16. 2mg sin30 – T = 2m(a)

T
T = ma
mg 600
 a  g/3&T 
3 T
300
 Net force =
   
Result of these forces  T ˆj  T cos600 ˆj  T sin 60  ˆi  
3 ˆ 3 ˆ
 T i  Tj
2 2
mg

6

 3iˆ  3ˆj 
As net force in pulley = 0,
mg
force by clamp 
6

3iˆ  3 ˆj 
17. When u decreases v increases. For plane mirror u decreases.
 the image in plane mirror moves towards the left.
18. After collision,

the rod starts rotating about its centre of mass.
Now the torque of mg about the centre of mass = 0, hence  is constant.
M
G
GM 2GM
19.  4 
2R 5R 5R
2
GMem GMem GMem
20. E    
12R 4R 6R
A(t=4sec)
21.  
v 2  u2  2gh  02  402  2 10 h 
UA=0
 h  80m
where h is maximum height reached by ball A
v = u – gt  t = 4 sec, u A (T=t+t)
u B
80 h =80 m
t'   2 sec
uA  uB
u' A  gt '  20m / s
u'B  40  2  10  20m / s B 40m/sec = uB
Thus the speed of each ball gets interchanged (for equal mass & elastic collision)
m
22. T1  T2  m2r1 T2
T1 T2
T2  m 2  r1  r2 
 T1  m 2  2r1  r2 
Thus T1  T2
23. N/N0 = et
24. J1 x 0.1 = 5 x I 0.5 5 mA

J1 = 50 mA
I = 50 + 5 = 55 mA 5 mA
0.1 0.2 0.3
J1 I
I
S B C D
1
1
26. qEy  mv 2
2
Magnetic force will not do any work.
3 2
27. = B
4
d 3 2 dB
=  
dt 4 dt
 32
i= 
R 4R
28. Effective length = (r2 + r1)
29. 2.4 km downstream from the point directly opposite to 0
2
30. sin C 
3
At face AC, i is 60º
i  C
CHEMISTRY (SECTION-II)
1. C
Van der Waal’s force
Natural rubber is a pure hydrocarbons therefore the only force of attraction between the adjacent
chain is van der Waals’ force
2. A
Calculate mole fraction ( XO2 ) :
Mass of 1 L of solution = 1000 g
 1000 g [d = 1 g ml–1]
1000g
nH2O   55.55
18 gmol1
nO2 nO2 1.25  10 3
nO2   
nO2  nH2O nH2O 55.55
 2.25  105
Calculation of partial pressure : Applying Henry’s law
pO2  KH  xO2
= 25  103 bar  (2.25  10–5) = 0.5625 bar
3. B
6 Cr–O bonds are equivalent
O O 2–
O Cr O Cr O
1.62A 1.77A
O O
4. A
CH3 C C CH3 H2
CH3 CH3
Lindlar 's
C C
catalyst
H H
Br2 / CCl4
Racemic mixture of dibromides
5. B
Anisole (C6H5OCH3) is activated ring for SEAr reaction
6. B
NH3 0 NH3 0
O 2N NH3 O 2N NO 2
(I) Cr 3  Cr 3 
O 2N NH3 O 2N NH3
NO 2 NH3
Facial (or cis) Optically inactive Meridional (trans) Optically inactive
 Two stereoisomers
Mirror
OX 3 3
OX
(II) OX Fe3  Fe OX
OX OX
d-form -form
 Two stereoisomers
7. C
k1 2  103
kc    100
kb 20
1 1
kc    0.1
kc 100
8. B
Mac Arthur-Forest method
9. D
Based on theory
10. D
CH3 CH2Br CH2COOH
CCl Mg (i) CO
 NBS 

4
  2
  
Et O 2 (ii) H3 O
C(CH3)3
11. A
(KE)1 T1 300
K.E  T   
(KE)2 T2 350
300
 (KE)2  (KE)1
350
% change in K.E.
(KE)2  (KE)1 350  300
  100   100
(KE)1 300
= 16.67%
12. C
SOCl2 KCN SnCl2 HCl
OH     CN   CHO
Stephan ' s
reaction
13. C
i 1

n 1
i 1
 0.9  ; i  1.9
2 1
  iCRT  1.9  0.002  0.0821 300
= 0.094 bar
14. D
Number of moles of Mg
12  10 3
  0.5  103
24
Number of Mg atoms
= 0.5  10–3  6  1023 = 3  1020 atoms
In HCP unit cell z = 6 and number of tetrahedral
void = 12 and number of octahedral void = 6
Total void = 18
Total number of voids
3  1020
  18  9  1020
6
15. C
A(  ) (1 atm, 400K)  A(g) (1 atm, 400K)
During boiling, G = 0, V > 0
 w < 0, q > 0, H > 0, S > 0
16. B
Mannose is a monosaccharides, a C–2 epimer of glucose
17. B

NH3  H  NH4
sp3 sp3


2NH3   
 NH2  NH4
sp3 sp3 sp3
H3BO3  OH  [B(OH)4 ]

sp3


H2O  H 
 H3 O

sp3 sp3
18. D
  1.5 and T1V1 1  T2 V2 1
 1
V  4
T2  T1  1   20  8K
 V2  25
19. A
Phenol is also called carbolic acid. Benzoic acid is more acidic than phenol. So the acid reacts with
NaHCO3 to give CO2(g), while phenol does not react.
20. A
Bond order : O2  2, O22  3
O2  2.5, O22  1
21. C
5 m mol HCl would required 10 m mol (40 ml) NH3 solution. M mol of NH4+ formed = 10 in 50 ml
10 K 10 14
[NH4 ]   0.2M, Kh  w 
50 Kb 2  105
 5  1010
[H ]  KhC  5  1010  0.2  105 , pH  5
22. A
dRT 64  .0821 300
M   6.4
P 246.3  1
nHe  4  nCH4  16
6.4 
nHe  nCH4
nHe 4

nCH4 1
23. A
C 195  0.05
k   9.75  103 Scm1
1000 1000
1 A
Also, G   k  
R 
1.5cm2
 9.75  103 S cm1 
0.50cm
 29.25  103 ohm1
V
Also, V  IR  I   5  29.25  103
R
 0.146  0.15 A
24. A
Mg2 C3  H2 O  CH3 C  CH


C C C : Two  and two  bonds.
, 
25. D
26. A
G  TSouniv  400  56
Also G  H  TSo
H  G
 S 
T
4.0  104  400  56

  44
400
27. B
MgCO3 < CaCO3 < SrCO3 < BaCO3
Thermal stability increases down the group
28. A
h2 1
From relationship between wavelength and potential difference, eV  
2m  2
h2
or 2  [V  potential difference]
2meV
h 1 1
or    or 
2me V V
150  108
or  
V
or   0.154 nm  154  10 12 m
150  10 8 150  108
or V  2
  63.5
 154  10 12
29. A
O
30. A
Ammoniacal AgNO3
MATHEMATICS (PART-III)
4
1. 1  1
3  2cos x
Also 3 + 2 cos x > 0  x  R
1  
So, 3 + 2cos x  4  cos x   2n   x  2n  , n  I.
2 3 3
 x 1  x 2   x 1  x 2 
 x  x    ...        ... 
log3  log  1    log3  log  1   
3 23    3 23  2
 3  3     =
2. lim = lim
x 0 x x 0 x 3
3. lim
x 
 
x 2  x  1  ax  b  0 , x = –y as x  –, y  
1/2
  1 1  
= lim
y 
 
y 2  y  1  ay  b  0 = lim  y  1   2 
y   y y 
 ay  b   0

  
  1  1 1     1  1 
= lim  y 1    2   ...  ay  b   0 = lim  y 1  a     b    ...  0
y 
  2  y y    y 
 2  2y 
1 1
 1 + a = 0  a = –1 and –b=0b=
2 2
x/2
4. y = 1 – 2 y-axis  x = 0  y = 0
dy 1 dy 1
 2x/2 log2    log2
dx 2 dx P 2
2
y= x  2x – y log 2 = 0
log2
 1  1
tan   log 
x x
5. f(x) = lim e
x 
 1
 1  1
tan   log 
tan  
x x  log x  x  = 0.
But lim e = lim
x  x  x 1
x
So, f(x) = e0 = 1
f  x dx 3 3
Hence,  dx =    t 8/3  t 2/3  c
3
sin11 x cos x 3
sin11 x cos x 8 2
3  1  4 tan2 x 
g(x) =   c
8  tan2 x 3 tan2 x 
  15
g   
4 8
2 1 2 2
 For 0  x  1 , 0  x  1 and
6.  [x 2 ] dx   [x 2 ] dx   [x 2
] dx  
2
0 0 1  For 1  x  2, 1  x  2 
2 1 2
  [x 2 ] dx   0.dx   1.dx
0 0 1
7. y = loge x
loge x x  0 y
 y = logex
log ( x) x  0
Now, y  loge x   e
loge x x  1
(0, 1)
 loge x x  1
O x
For y  loge | x | , we have (1, 0) (0, 0) (1, 0)
loge x x  1  x  1

 loge x  1 x  1 (0, 1)
log x x  1
y  loge | x |   e
loge ( x) x  1
 loge (x)  x 1

 loge ( x)  1 x  0
0
0
Hence required area is equal to 4  ey dy  4 e y   
 
 4 e0  e   4 sq. units

dy  y(x  y)
8. 
dx x2
Putting y = vx since this is homogeneous differential equation
xdv vx(x  vx) dv dv  dx
 v  2
  v(1  v)  x  2v  v 2  
dx x dx v(v  2) x
dv dx
On integrating, we get     a , where a is any arbitrary
v(v  2) x
1 1 1  dx 1  v 
   dv     a  ln    ln x  a
2  v v  2  x 2  v  2 
y a
 ln  ln   , where b is again any arbitrary constant
y  2x x
 x2y = c (y + 2x)
9. We have, (1  2x + 3x2  4x3 +  to )n = [(1 + x)2]n = (1 + x)2n

(2n)!
 Coefficient of xn = 2nCn =
(n!)2
10. u + t = 15 … (1)
and x + y + z = 5 ... (2)
Now number of non-negative integral solutions of (1) = 2+151C15 = 16C15
and number of non-negative integral solutions of (2) = 3+51C5 = 7C5
16 7
 Total number of ways = C15  C5 = 336
11. log0.3 z  1  log0.3 z  i  z  1  z  i  (z  1) (z  1)  (z  i) (z  i)

 zz  z  z  1  zz  iz  iz  1  (1  i)z  (1  i)z  0  (z  z)  i(z  z)  0
zz zz
   0 xy>0
 2   2i 
12. We have product of the roots 2e4 ln k  1  31 given  e4 ln k  16

e
   16  k 4  16  k 4  16  0
ln k 4
 
 k 2  4  k  2 k  2   0 k  2, 2
As k > 0, we get k = 2. Sum of the roots  5k  10
13. Let the sum of n terms exceeds 1000. Then


1 1  3n  > 1000, or ,
3n  1
> 1000
1 3 2
or, 3n > 2001, but 36 = 729 and 37 = 2187
 n > 6, but n is a positive integer
 n = 7, 8, 9, …
 The minimum number of terms = 7
14. Applying R2  R2 – R3
a2 b2 c2
=4 a b c
2 2 2
 a  1 b  1  c  1
Applying R3  R3 – R1
a2 b2 c2
=4 a b c
1  2a 1  2b 1  2c
Applying R3  R3 + 2R2
a2 b2 c 2
 = 4 a b c = 4(a – b)(b – c)(c – a) = 0
1 1 1
if a – b = 0 or b – c = 0 or c – a = 0
 a = b or b = c or c = a
 ABC is an isosceles triangle
15. All the elements below the main diagonal have to be necessarily zero. Thus minimum number of zero
n  n  1
elements is = 1 + 2 + 3 +  + (n – 1) =
2
16. Total number of ways = 25 = 32

Favourable number of ways = coefficient of x 12 in x10 (1 + x)5 = 10
10 5
Hence, the required probability = =
32 16
17. Circumcentre, centroid and orthocentre of a triangle lies on a line, so that the orthocentre of the
  a  12  a  12 
triangle lies on the line joining the circumcentre (0, 0) and the centroid  , 
 2 2 
 
2 2
 a  1  a  1 2 2
 y x  (a  1) x  (a + 1) y = 0
2 2
18. The centre of the circle x2 + y2 – 2x – 4y + 1 = 0 is (1, 2) and the radius = 12  22  1  2

Since the tangents drawn to the circle are perpendicular these ordinate from some point on the circle
2
(x – 1)2 + (y – 2)2 = 2 2  
2 2
or, x + y – 2x – 4y – 3 = 0
Let (h, k) be a point as it so that
h2 + k2 – 2h – 4k – 3 = 0 …(1) y = 2x +c
Now the chord of contact of (h, k) w.r.t. the first circle
i.e. hx + ky – (x + h) – 2(y + k) + 1 = 0
or, (h – 1)x + (k – 2)y – (h + 2k – 1) = 0
Comparing with y = 2x + c
h  1 k  2   h  2k  1 4
or, 2x – y + c = 0, we have   
2 1 c c
8 c8 4 2c  4
h–1= h= and k – 2 = k=
c c c c
2 2
 c  8   2c  4  c 8  2c  4 
Putting in (1), we get      2   4 3  0
 c   c   c   c 
or, c2 – 16c + 64 + 4c2 + 16c + 16 – 2c2 + 16c – 8c2 – 16c – 3c2 = 0
or, –8c2 + 80 = 0  c2 = 10  |c| = 10
1
19. Any tangent to the parabola y2 = 4x is y  mx 
m
It is a tangent to the circle (x  3)2 + y2 = 9 if the length of the perpendicular from the centre (3, 0)
upon (1) is equal to radius of the circle i.e., 3
1
3m   0
m 1 1
  3  9m2  2  6  9(1  m2 )  m2 
1 m 2 m 3
1  1 2
 m but m > 0, as the point  2 ,  is above the x-axis.
3 m m
 The required line is 3y  x  3
20. Let the tangent be bx cos  + ay sin   ab = 0 so that A  (a sec , 0), B  (0, b cosec ),
and AB2 = a2 sec2  + b2 cosec2  = a2 (1 + tan2 ) + b2 (1 + cot2 )
= a2 + b2 + a2 tan2  + b2 cot2  = a2 + b2 + 2ab + (a tan   b cot )2  (a + b)2
= AB/min = (a + b)
AB is clearly the diameter of circumcircle of triangle OAB. Thus minimum area of triangle
 2
OAB =  a  b 
4
21. Let the common tangent be

2
y = mx + … (1)
m
Putting for y from (1) in xy = 1, we get
 2
x  mx    1 … (2)
 m 
If (1) is tangent, discriminant of (2) should be zero  m = 1
 The common tangent is y = x + 2
   2   1  2 
sin  1  sin  2 
22.
  2
tan 1
  2
.tan 1 =
 2   
2 2    2   1  2 
cos  1  cos  2 
 2   
1 
sin2  sin2 2
= 2 2  1  cos 1  1  cos 2  = cos 2  cos 1  cos 2  2cos 2   1
  1  cos 1  1  cos 2  cos 1  cos 2 2cos 2  cos 2 3
cos 2 1  sin2 2
2 2
3 2 2 2 3
23. The given equation becomes 3sin  – 4sin  = 4sin  (sin  – sin ) = 4sin  sin  – 4sin 
2 2 3
 3sin  = 4sin  . sin   sin  =  sin   0
4
3  
 sin  =    sin   = n  (n  I)
2 3 3
2m 2m
24. tan1  tan1 = tan–1(m2 + m + 1) – tan–1 (m2 – m +1)
42
m m 2 2
2
1 m  m  1 m  m  1  
So that
n
2m
 tan1 m4  m2  2   tan1 3  tan1 1   tan1 7  tan1 3   ...  tan1 n2  n  1  tan1 n2  n  1
m 1
n2  n
= tan–1(n2 + n + 1) – tan–1 1 = tan1
n2  n  2
25. Let the sides of the triangle be 7, 7 – d, 7 – 2d

Since the given angle is the greatest (being obtuse), angle of the triangle, it is opposite to the greatest
2
side of the triangle and we have, 72 = (7 – d)2 + (7 – 2d)2 – 2(7 – d)(7 – 2d) cos
3
 1
 72 = 2  72 – 42d + 5d2 – 2(72 – 21d + 2d2)     d2 – 9d + 14 = 0
 2
 (d – 7)(d – 2) = 0  d = 2 (d = 7 is not possible)
Therefore the sides of the triangle are 7 cm, 5 cm, 3 cm
1 2 15 3
Area of the triangle  =  5  3  sin = cm2
2 3 4
753 7 3
Radius of the circumcircle R = = cm

4 15 3 / 4  3
                       
26. (a  b)  c  a  (b  c) if c  (a  b)  a  (b  c)   [(c  b)a  (c  a)b]  (a  c)b  (a  b)c
                       
 (c  a)b  (c  b)a  (a  c)b  (a  b)c  (c  b)a  (a  b)c  b  (a  c)  0 or (a  c)  b  0
       
i.e., either a  c = 0 or b  0 . But b  0  a  c = 0  a and c are collinear
 x  2y  2z  9 4x  3y  12z  13
27. 
1 4  4 16  9  144
AC AC AB 1 B
28. Let APC = . Then tan     
AP nAB 2n  AB 2n
AB AB 1
In APB, tan( + ) =  
AP nAB n
Now,  = ( + )  
1 1 C

tan(  )  tan  n
tan    n 2n  2
1  tan(  )tan  1 1 2n  1 
1 
n 2n 
P A
29. The mean of the series: p, p + d, p + 2d, …, p + 2nd is

1 1  2n  1
p  p  p  d  p  2d    p  2nd =  p  p  2nd = p + nd
2n  1 2n  1  2 
1 2n
 Mean deviation from mean =  p  rd   p  nd 
2n  1 r  0
1 2n 1 n  n  1
=  r n d = 2d 1  2    n  = d
2n  1 r  0 2n  1 2n  1
30. Shown in the table

p q pq ~p (p  q)  ~ p
T T T F F
T F F F T
F T F T F
F F F T F
Hence the statement neither tautology nor contradiction

Solution JEE Main 2019 Mock Test 5

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Solution JEE Main 2019 Mock Test 5

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IT2019JEE Main 2019 Mock Test-(100374.

FIITJEE - JEE (Main)

1. Number density = 5  1028 atoms/m3

4. Q = 10(1)40 = 400 cal

5. Work done = change in gravitational PE of COM.

7. Output equation y = A  B  A.B

9. Range of frequency is 2 to 10 MHz.

12. Rate of heat emitted = eAT4(body)

16. 2mg sin30 – T = 2m(a)

18. After collision,

23. N/N0 = et

24. J1 x 0.1 = 5 x I 0.5 5 mA

29. 2.4 km downstream from the point directly opposite to 0

H3BO3  OH  [B(OH)4 ]

4.0  104  400  56

9. We have, (1  2x + 3x2  4x3 +  to )n = [(1 + x)2]n = (1 + x)2n

11. log0.3 z  1  log0.3 z  i  z  1  z  i  (z  1) (z  1)  (z  i) (z  i)

12. We have product of the roots 2e4 ln k  1  31 given  e4 ln k  16

13. Let the sum of n terms exceeds 1000. Then

16. Total number of ways = 25 = 32

18. The centre of the circle x2 + y2 – 2x – 4y + 1 = 0 is (1, 2) and the radius = 12  22  1  2

21. Let the common tangent be

25. Let the sides of the triangle be 7, 7 – d, 7 – 2d

29. The mean of the series: p, p + d, p + 2d, …, p + 2nd is

30. Shown in the table

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