Held on

12th January
2nd SHIFT

Date: 26-03-19
Time: 03:00 Hrs Max. Marks: 360
1. Let S and Sc be the foci of an ellipse and B be (a) {1, –1} (b) {3, –3}
any one of the extremities of its minor axis. (c) { 3 } (d) { 3 , − 3 }
If 'ScBS is a right angled triangle with right
angle at B and area ('ScBS) = 8 sq. units, then 7. The tangent to the curve y = x2 – 5x + 5,
the length of a latus rectum of the ellipse is parallel to the line 2y = 4x + 1, also passes
(a) 2 (b) 4 (c) 4 2 (d) 2 2 through the point
⎛1 7⎞
(a) ⎛⎜ , ⎞⎟
7 1
2. The expression ~(~p o q) is logically (b) ⎜ , ⎟
⎝2 4⎠ ⎝4 2⎠
equivalent to
(a) p š q (b) ~p š q ⎛ 1 ⎞ ⎛1 ⎞
(c) ⎜ − , 7 ⎟ (d) ⎜ , − 7 ⎟
(c) ~p š ~q (d) p š ~q ⎝ 8 ⎠ ⎝8 ⎠
3. If the sum of the first 15 terms of the series 8. The total number of irrational terms in the
3
⎛3⎞ ⎛ 1⎞ ⎛ 1⎞
3 3
3 ⎛ 3⎞
3 binomial expansion of (71/5 – 31/10)60 is
⎜⎝ 4 ⎟⎠ + ⎜⎝1 2 ⎟⎠ + ⎜⎝ 2 4 ⎟⎠ + 3 + ⎜⎝ 3 4 ⎟⎠ + ..... (a) 55 (b) 54 (c) 48 (d) 49

is equal to 225 k, then k is equal to 9. If a straight line passing through the point
(a) 27 (b) 9 (c) 108 (d) 54 P(–3, 4) is such that its intercepted portion
between the coordinate axes is bisected at P,
4. If sin4 α + 4 cos4 β + 2 = 4 2 sinD cosE; D, E then its equation is
[0, S], then cos(D + E) – cos(D – E) is equal (a) 4x + 3y = 0 (b) 4x – 3y + 24 = 0
to (c) 3x – 4y + 25 = 0 (d) x – y + 7 = 0
(a) –1 (b) 0 (c) 2 (d) − 2
5. In a game, a man wins Rs. 100 if he gets 5 or 10. lim π − 2 sin−1 x
is equal to
6 on a throw of a fair die and lose Rs. 50 for x →1− 1− x
getting any other number on the die. If he 1 π (d) 2
decides to throw the die either till he gets a
(a) π (b) (c)
2π 2 π
five or a six or to a maximum of three throws,
then his expected gain/loss (in rupees) is 11. If nC4, nC5 and nC6 are in A.P., then n can be
400 400 (a) 12 (b) 14 (c) 9 (d) 11
(a) loss (b) gain
9 3 12. Let f be a differentiable function such that
400 f(1) = 2 and f c(x) = f(x) for all x  R. If
(c) 0 (d) loss h(x) = f(f(x)), then hc(1) is equal to
3
(a) 2e2 (b) 4e (c) 2e (d) 4e2
6. Let S be the set of all real values of O such that
a plane passing through the points (–O2, 1, 1), 13. The set of all values of O for which the system
(1, –O2, 1) and (1, 1, –O2) also passes through of linear equations
the point (–1, –1, 1). Then S is equal to x – 2y – 2z = Ox
 x + 2y + z = Oy e⎧
⎛ e ⎞ ⎫⎪
2x x
–x – y = Oz ⎪⎛ x ⎞
19. The integral ∫ ⎨ ⎜ ⎟ − ⎜ ⎟ ⎬ loge xdx is
has a non-trivial solution equal to ⎪⎝ e ⎠
1⎩
⎝x⎠ ⎪
⎭
(a) is an empty set
1 1 1 1 1
(b) contains exactly two elements (a) −e− (b) − + −
2 e 2 2 e 2e2
(c) is a singleton
(d) contains more than two elements 3 1 3 1 1
(c) −e− (d) − −
14. The number of integral values of m for which 2 2e 2 2 e 2e2
the quadratic expression, (1 + 2m)x2 – 2(1 + 20. If a curve passes through the point (1, –2)
3m)x + 4(1 + m), x  R, is always positive is and has slope of the tangent at any point
(a) 8 (b) 7 (c) 3 (d) 6 x2 − 2 y
(x, y) on it as , then the curve also
15. The mean and the variance of five observations x
are 4 and 5.20, respectively. If three of the passes through the point
observations are 3, 4 and 4; then the absolute (a) (− 2 , 1) (b) (–1, 2)
value of the difference of the other two
(c) ( 3 , 0) (d) (3, 0)
observations is
(a) 3 (b) 1 (c) 7 (d) 5 21. There are m men and two women participating
G G G in a chess tournament. Each participant plays
16. Let a , b and c be three unit vectors, out of
G G two games with every other participant. If the
which vectors b and c are non-parallel. number of games played by the men between
G
If D and E are the angles which vector a themselves exceeds the number of games
G G
makes with vectors b and c respectively and played between the men and the women by
G G G 1G 84, then the value of m is
a × (b × c ) = b , then |D – E| is equal to (a) 11 (b) 9 (c) 12 (d) 7
2
(a) 45° (b) 60° (c) 90° (d) 30° 22. If the angle of elevation of a cloud from a point
3
17. If the function f given by f(x) = x – 3(a – 2) P which is 25 m above a lake be 30° and the
x2 + 3ax + 7, for some a  R is increasing in angle of depression of reflection of the cloud
(0, 1] and decreasing in [1, 5), then a root of in the lake from P be 60°, then the height of
f (x ) − 14 the cloud (in metres) from the surface of the
the equation, = 0 (x z 1) is lake is
(x − 1)2 (a) 50 (b) 45 (c) 60 (d) 42
(a) 7 (b) –7 (c) 5 (d) 6
⎛ n n n 1⎞
3x13 + 2 x11 23. lim ⎜ 2 2 + 2 2 + 2 2 + .... + ⎟
⎝
n→∞ n + 1 n +2 n +3 5n⎠
18. The integral ∫ (2x 4 + 3x2 + 1)4 dx is equal to is equal to
(where C is a constant of integration) π
(a) tan–1(2) (b)
x4 2
(a) +C π
6(2 x 4 + 3x2 + 1)3 (c) tan–1(3) (d)
4
x4 24. If a circle of radius R passes through the origin
(b) +C
(2 x 4 + 3x2 + 1)3 O and intersects the coordinate axes at A and
B, then the locus of the foot of perpendicular
x12 from O on AB is
(c) +C
6(2 x 4 + 3x2 + 1)3 (a) (x2 + y2)3 = 4R2x2y2
(b) (x2 + y2)2 = 4Rx2y2
x12 (c) (x2 + y2)(x + y) = R2xy
(d) +C
(2 x 4 + 3x2 + 1)3 (d) (x2 + y2)2 = 4R2x2y2
25. If an angle between the line, 28. Let z1 and z2 be two complex numbers
x + 1 y − 2 z − 3 and the plane, x – 2y – satisfying |z1| = 9 and |z2 – 3 – 4i| = 4. Then
= =
2 1 −2 the minimum value of |z1 – z2| is
⎛2 2 ⎞ (a) 2 (b) 2 (c) 0 (d) 1
kz = 3 is cos−1 ⎜ ⎟ , then a value of k is
⎝ 3 ⎠ ⎡ 1 sin θ 1 ⎤
⎢
29. If A = ⎢ − sin θ ⎥
5 (b) 3 (c) 3 (d) − 5 1 sin θ⎥ ; then for all
(a) −
3 5 5 3 ⎢⎣ −1 − sin θ 1 ⎥⎦
26. The equation of a tangent to the parabola, ⎛ 3π 5π ⎞
x2 = 8y, which makes an angle T with the θ ∈⎜ , , det(A) lies in the interval
⎝ 4 4 ⎟⎠
positive direction of x-axis is
(a) x = ycotT – 2tanT (b) y = xtanT – 2cotT ⎛3 ⎤ ⎡5 ⎞
(a) ⎜ , 3⎥ (b) ⎢ , 4 ⎟
(c) x = ycotT + 2tanT (d) y = xtanT + 2cotT ⎝2 ⎦ ⎣2 ⎠
27. In a class of 60 students, 40 opted for NCC, ⎛ 5⎤ ⎛ 3⎤
(c) ⎜1, ⎥ (d) ⎜ 0, ⎥
30 opted for NSS and 20 opted for both NCC ⎝ 2⎦ ⎝ 2⎦
and NSS. If one of these students is selected at
30. Let Z be the set of integers.
random, then the probability that the student 2
selected has opted neither for NCC nor for If A = {x ∈ Z : 2( x +2)( x −5x +6) = 1} and
NSS is B = {x  Z : –3 < 2x – 1< 9}, then the number
1 5 1 2 of subsets of the set A × B is
(a) (b) (c) (d)
6 6 3 3 (a) 218 (b) 212 (c) 215 (d) 210
 CHEMISTRY

61. Which of the following V, T plots represents the behavior of one mole of an ideal gas
at one atmosphere?
V  L
V  L 28.6L
38.8L
373K
373K
22.4L 20.4L
273K 273K

T K  T K
1) 2)
V  L V  L
30.6L 14.2L
373K 373K
22.4L 22.4L
273K 273K

T K  T K 
3) 4)
62. Potassium crystallizesin a bcc lattice. What is the number of unit cells in 3.9gm of K
atomic weight of K=39
NA NA NA
1) 2) 3) 4) N A
20 10 5
63. There are no S–S bond in

(1) S2O42– (2) S2O52– (3) S2O32– (4) S2O72–

64. Which set of quantum number is correct for 19th electron of K  z  19  .

1 1 1 1
1) 2,1,1,  2) 3, 2, 2,  3) 4, 0,0,  4) 4,1,0, 
2 2 2 2

65. Calculate G 0  KJ / mol  at 1270 C for a reaction with K eq  105

1) –38.294 2) –16.628 3) –9.16 4) None

66. 0.2 molal acid HX is 20% ionised in solution k f  1.86K molality 1 .The freezing

point of the solution is

1) 0.900 C 2) 0.450 C 3) 0.310 C 4) 0.530 C
67. Select the rate law that corresponds to the data shown for the reaction A  B  C
Exp [A] [B] [C]
1 0.012 0.035 0.10
2 0.024 0.070 0.80
3 0.024 0.035 0.10
4 0.012 0.070 0.80

1) Rate  k  B 3 2) Rate  k  B 4

1 3
3) Rate  k  A  B  4) Rate  k  A2  B 2

68. How many liters of water must be added to 1 liter of an aqueous solution of HCl with
a P H of 1 to create an aqueous solution with P H of 2
1) 0.9L 2) 2.0 L 3) 9.0 L 4) 0.1 L

69. Conductivity of a saturated solution of Cu2  Fe  CN 6  is 6.4  106  1cm 1 solubility


 
product of Cu2  Fe  CN 6  is given m k4  Fe  CN 6   720 s cm 2 mol 1

 m  CuSO4   260 s cm 2 mol 1

 m  K 2 SO4   300 s cm 2 mol 1

1) 2  1015 2) 4  1015 3) 2  1012 4) 4  1012

70. Surface tension of lyophilic solution is

1) lower than water 2) More than water
3) equal to water 4) None
71. In which of the following equilibrium change in volume of the system does not alter
the number of moles
 1) N 2 g   O2 g   2 NO ( g ) 2) PCl5 g   PCl3 g   Cl2 g 

3) N 2 g   3H 2( g )  2 NH 3 g  4) SO2Cl2 g   SO2  g   Cl2  g 

72. Consider the following compounds

(i) SO2 (ii) H 2O2 (iii) O3
among these compounds those which can acts as bleaching agents would include

1) (i) and (ii) 2) (ii) and (iii) 3) (i) and (iii) 4) (i) , (ii) and (iii)

73. The true statement acids of phosphorus H 3 PO2 , H 3 PO3 and H 3 PO4 is
1) The order of their acidity is H 3 PO4  H 3PO3  H 3PO2
2) All of them are reducing in nature
3) All of them are tribasic acids
4) The geometry of phosphorus is tetrahedral in all the three
74.
 
H3N NH3
Z Y

COOH
X
Correct order of acidic strength is :
(A) x > y > z (B) z > y > x (C) y > z > x (D) x > z > y

75. Which of the following molecule / species has minimum number of lone pair’s on its
central atom?
1) BrF3 2) BrF4 3) XeF5 4) I3
76. Which of the following hydride is polymeric in nature.
1) CaH 2 2) NaH 3) LiH 4) BeH 2
77.  Cr  H 2O   Cl3 has a magnetic moment of 3.87 BM .The correct distribution of 3d
 6

electrons in chromium of the complex is

1) 3d 1xy ,3d 1yz ,3d 12 2) 3d 1xy ,3d1yz ,3d 1zx
z

3) 3d 1 2 ,3d12 ,3d1xy 4) 3d 1xy ,3d 1 2 ,3d1yz

 x  y2  z  x  y2 
78. If excess of AgNO3 solution is added to 100ml of 0.024M solution of dichlorobis
(ethylenediamine) cobalt (III) chloride how many moles of AgCl be precipitated

1) 0.0012 2) 0.0016 3) 0.0024 4) 0.0048

79. Calgon used as a water softener is

1) Na2  Na4  PO3 6  2) Na4  Na4  PO4 6 

3) Na4  Na2  PO3 6  4) Na2  Na4  PO4 5 

80. Chemical composition of ‘slag’ formed during the smelting process in the extraction
of copper is
1) Cu2O  FeS 2) FeSiO3 3) CuFeS2 4) Cu2 S  FeO
81. Which of the following is a secondary pollutant
1) NO 2) SO2 3) CO 4) PAN
82. Which among the given molecule exhibit tautomerism?
O O

O
Ph
Ph
I II III

1) Only III 2) Both I and III

3) Both I and II 4)Both II and III
83. The synthesis of alkyl fluorides is best accomplished by
1) Finkelsteinreaction 2) Swarts reaction
3) Free radical fluorination 4) Sandmayer’s reaction

1) B H ,THF
2 6

X
2) H 2O / OH
H 2O2
84. .
What is X
CH 3
OH

1) 2) OH

OH

3) OH 4) None
85. What is the Z in the following reaction?
PCl alc.KOH
3  X  Y 
2 4 (i ) conc.H SO
Z  Z
(ii ) H 2Oboil

1) CH 2  CH  CH 2  OH 2) CH3  CH  OH   CH3
3) (CH3CH 2 )2 CHOH 4) CH 3CH  CH 2

1) CrO Cl / CS
2 2 2  A  B OH 
86. C6 H 5  CH 3 
 H3O

The conversion of A to B is called as

1) Cannizaro reaction 2) Aldol Condensation
3) Clemmenson reduction 4) Etard reaction

87. Which of the following order is true regarding basic nature of NH 2 group?
1) o-Toluidine>Aniline>o-Nitroaniline
2) o- Toluidine < Aniline > o-Nitroaniline
3) o-Toluidine < Aniline < o-Nitroaniline
4) o-Toluidine > Aniline < o-Nitroaniline
88. Which of the following pairs are incorrectly matched?
1. Sucrose- Monosacharide 2. Fructose – Aldose sugar
3. Glucose – Mutarotation 4. Sucrose – Reducing sugar
1) 2,3 and 4 2) 1,2 and 3 3)1, 2 and 4 4) 2 and 4 only
89. The catalyst used for olefin polymerization is
1) Ziegler - Natta catalyst 2) Wilkinson Catalyst
3) Raney Ni 4) Merrifield resin
90. Dettol consists of
1) Cresol + ethanol
2) Xylenol + terpeneol
3) Chloro xylenol + terpeneol
4) None
61. In the figure M1 and M2 are two fixed mirrors shown. If the object ' O ' moves towards the plane
mirror, then the image I (which is formed after two successive reflections from M1 & M2
respectively) will move

(a) always towards right (b) always towards left

(c) depends on position of O (d) cannot be determined
62. A sphere of radius R is having charge Q uniformly distributed over it. The energy density of the
electric field in the air, at a distance r (r > R) is given by (in J/m3) :

Q2 Q2 Q2 Q2
(a) (b) (c) (d)
32  0 R 2 r 2
2
32 2 0 r 4 32 2  0R 4 16 2  0r 4
63. A uniform wire of resistance R is stretched uniformly n times & then cut to form five identical wires.
These wires are arranged as shown in the figure. The effective resistance between A & B will be:

nR R n 2R n 2R
(a) (b) (c) (d)
5 5n 2 5 2
64. The switch is closed at t = 0. Initially charge on capacitor is zero. The time after which charge on

 1
capacitor is CE  1  
 e

(a) RC (2) 2RC (c) 4RC (d) None of these

65. A sphere and a cube of same material and same total surface area are placed in same evacuated
space after they are heated to same temperature. The ratio of their initial rate of cooling in space is:
 1
(a) 1 (b)  (c) (d)
6 6

66. A charged particle of specific charge (charge/mass)  is projected from origin with a velocity u

 
v 0 iˆ  ˆj in a uniform and constant magnetic field B  B0 iˆ . The position co-ordinates of the particle


at time t  B  are
0

 v0 2v0  v0   v0   2v0 v 0    v0  2v0 

(a)  2B  , B , B   (b)   2  ,0,0  (c)  0, ,  (d)  B  ,0, B  
 0 0 0   B   B0  2B 0   0 0 
67. The frequency of oscillation of current in the inductor is :

1 1
(a) (b)
3 LC 6 LC

1 1
(c) (d)
LC 2  LC
68. A vertical rod of length l is moved with constant velocity v towards East. The earth's magnetic field
is B and the angle of dip is  . The induced e.m.f. in the rod is :
(a) Blv cot  (b) Blv sin  (c) Blv tan  (d) Blv cos 
69. In the figure shown in a YDSE, a parallel beam of light is incident on the slits from a medium of
refractive index n1. The wavelength of light in this medium is 1 .A transparent slab of thickness 't’
and refractive index n3 is put infront of one slit. The medium between the screen and the plane of
the slits is n2. The phase difference between the light waves reaching point ' O’ ' (symmetrical,
relative to the slits) is:

2 2
(a) (n 3  n 2 )t (b) (n 3  n 2 )t
n 1 1 1

2 n 1  n 3  2 n 1
(c)   1  t (d) (n 3  n 2 )t
n2 1  n 2  1

70. All electrons ejected from a surface by incident light of wavelength 200 nm can be stopped before
travelling 1 m in the direction of uniform electric field of 4 N/C. The work function of the surface is:
(a) 4 eV (b) 6.2 eV (c) 2 eV (d) 2.2 eV
71. The activity of a sample of radioactive material is A1 at time t1 and A2 at time t2(t2 > t1) Its mean life
is T.

A1  A2
(a) A 1 t 1  A 2 t 2 (b)  constant (c) A 2  A1e(t1 t2 /T) (d) A 2  A 1e(t1 /Tt 2 )
t2  t1
72. The current flowing through battery in the given circuit is [diodes are ideal].

(a) 1.2 A (b) 2A (c) 3A (d) 0.5 A

73. In an electromagnetic wave, the electric field oscillates sinusoidally with amplitude 48 Vm-1,
the RMS value of oscillating magnetic field will be nearly equal to :
(a) 1.6  10 8 T (b) 10  10 9 T (c) 144  10 8 T (d) 11.3  10 8 T
74. The maximum peak to peak voltage of an AM wave is 12 mV and the minimum peak to
peak voltage is 4 mV. The modulation factor is
(a) 10% (b) 20% (c) 25% (d) 50 %
75. A closed organ pipe oscillating in its first overtone is in unison with a tuning fork of frequency 330
Hz. If P0 is the maximum value of pressure amplitude, what is pressure amplitude at the middle
of the organ pipe ? (speed of sound in air is 330 m/sec)

P0 P0 P0 P0

(a) (b) (c) (d)
2 2 4 3
76. Length of a string tied to two rigid supports is 40 cm. Maximum length (wavelength in cm)
of a stationary wave produced on it, is -
(a) 20 (b) `80 (c) 40 (d) 120
77. Which of the following dimensional formula is incorrect.
(a) [permittivity of the free space × electric field] = [M oL2 T1A 1 ]

(b) [electrical conductivity] = [M 1L3 T 3A 1 ]

 Elctric filed  o 1 1
(c) [viscous force] = [M 1L1T 2 ] 
(d)   [M L T ]
 Magnetic field 
78. RMS speed of a monoatomic gas is increased by 2 times. If the process is done adiabatically
then the ratio of initial volume to final volume will be
2 3
(a) 4 (b) 43 (c) 22 (d) 8
79. Which of the following will have maximum total kinetic energy at temperature 300 K.

1 1 1 3
(a) 1 kg, H2 (b) 1 kg , He (c) kg H2  kg He (d) kg H2  kg He
2 2 2 4
80. Figure shows three temperature scales with the freezing and boiling point of water indicated.
A change of 25 R°, 25 S° and 25 U° is denoted by x1, x2, x3 respectively. Which of the following is
correct :
(a) x 1  x 2  x 3

(b) x 2  x 1  x 3

(c) x3  x2  x1

(d) x 2  x 3  x 1

81. Two water Pipes P and Q having diameters 2  10-2 m and 4  10 2 m respectively, are joined in
series with the main supply line of water. The rate of flow of water in P is :
(a) 4 times that of Q (b) 2 times that of Q
(c) 1/2 times of Q (d) 1/4 times that of Q
82. A particle at the end of a spring executes simple harmonic motion with a period t1, while
the corresponding period for another spring is t2. If the period of oscillation with the two
springs in series is T, then :
(a) T  t 1  t 2 (b) T 2  t 21  t 22 (c) T 1  t 11  t 21 (d) T 2  t 1 2  t 2 2
83. A hollow smooth uniform sphere A of mass ‘m’ rolls without sliding on a smooth horizontal sur-
face. It collides elastically and head on with another stationary smooth solid sphere B of the same
mass m and same radius. The ratio of kinetic energy of ‘B’ to that of ‘A’ just after the collision is :

(a) 5 : 2 (b) 1:1 (c) 2:3 (d) 3 : 2

84. A uniform rod is kept at smooth horizontal surface, a constant force is applied on the rod
in horizontal direction at end ‘A’. Find the ratio of energy stored per unit volume at end A
to the energy stored per unit volume in the middle of rod.

(a) 2 (b) 4 (c) 6 (d) 8

85. A particle of mass m0, travelling at speed v0, strikes a stationary particle of mass 2m0. As a result, the
v0
particle of mass m0 is deflected through 45º and has a final speed of . Then the speed of the
2
particle of mass 2m0 after this collision is :

v0 v0 v0
(a) (b) (c) 2v0 (d)
2 2 2 2
86. The maximum velocity (in ms–1) with which a car driver can traverse a flat curve of radius 150 m
and cofficient of friction 0.6 to avoid skidding is :
(a) 60 (b) 30 (c) 15 (d) 25
87. The blocks A and B shown in the figure have masses MA = 5 kg and MB = 4 kg. The system is
released from rest. The speed of B after A has travelled a distance 1 m along the incline is

3 3 g g
(a) g (b) g (c) (d)
2 4 2 3 2
88. A block slides down an inclined plane of slope angle  with constant velocity. If it is then projected
up the same plane with an initial sped v0, the distance in which it will come to rest is:

v 20 v20 v02 v02

(a) (b) (c) (d)
g tan  4g sin  2g 2g sin
89. A man is moving with 10 m/s towards west on a horizontal ground. He observed that the rainfall
is falling vertically down wards. Now he increases his speed to 15 m/s and find that now the
rainfall is falling at an angle of 45° towards him. The speed of the rain with respect to ground is :

(a) 10 5 m / s (b) 10 m/s (c) 5 5 m /s (d) None of these

90. A projectile is fired with velocity v0 from horizontal surface making an angle  with vertical. If the
wind imparts constant horizontal acceleration ‘a’ to the left as shown in the figure, then the angle
‘  ’ at which projectile must be fired so that it returns to the point of projection is. (Assume ‘g’ to be
uniform)

1  a   2a 2  a 1  g 
(a)   tan  2g  (b)   tan 1  2  (c)   tan 1   (d)   tan  
   g  g a