Beruflich Dokumente
Kultur Dokumente
Carolina Garcia
1 Matrix Formation 2
2 Annealing process 4
3 Cleaning up 5
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Chapter 1
Matrix Formation
(a) Preparation of Ozone In lab the ozone if made from Oxygen (O2 )
and an electric discharge at the boiling point of Liquid Nitrogen
(N2 ) i.e. at a temperatur of 77K, the procedure is:
• open the sample container
• Be sure that you have enough N2 and prepare it the two
cylinders
• Put the electric discard wire inside the sample tube and one
cylinder under the sample tube.
• Be sure the black stuff is close enough to the cylinder1 and
under the cylinder border
• Fill that cylinder with N2 up its border
• Slowly open the Oxygen valvule until the desire inches (The
usual amount is 3 main lines)
• to start the Ozone creation turn on the voltage source
• The main gauge should decrease (lineally) as the Ozone is
produced.
(b) Preparation of 1,3 cyclohexadiene
• If it is the first time
• Use one of the cylinders
• Let the liquid sample to warm i.e. expand the molecules so
gas is produced
3. Measure the diseare amount of sample by open the can, open the
sample valvule and watching the gauge of the line to the desider value.
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The end of the black stuff brings the electric discharge
2
4. Turn on the Cryostatic system!! not necessary and this point it could
be before.
5. Fill the rest of the Can with Ar. Open slowly the Ar valvule until 30
inches in the line gauge, close the Ar.
7. Open the vacuum to clear the line remove the extra particles of Ar
9. At 21K and after the Background collection is finished, start the de-
position. For both lines:
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Chapter 2
Annealing process
Remember that you can not close the program Spectrum One during
the running of ab experiment
14. When the matrix has th e lower temperature and it is steady it takes
time to solidify the matrix, take spectra
15. If the matrix did not evaporate you can rise the temperature again,
hence repeat procedure from step 12
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Chapter 3
Cleaning up
20. When the temperature reader is steady at room temperature the cell
holder is ready to open
23. Open the Ar valvule, this allow to move the spectrometer from the
cell holder
26. Use hexanol1 to clean the windows of the cell holder and the support
windows
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29. Open the initial vacuum
32. Let the system overnight to clean everything. And you can start again
from 1