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The initial stages In physical refining, the free fatty In chemical refining, caustic soda
Once the initial stages of pre-treatment, acids in the oil are removed using is used to neutralize the free fatty
pressing and extraction are complete, single-stage distillation during the acids in the oil, in a chemical
the process of refining the raw material deodorization process. Physical reaction. This more traditional kind
begins. This normally consists of refining normally has the following of refining normally has the following
four stages – or five, if the feed general characteristics: characteristics:
contains waxes: • can only be used with certain, • can be used with a wider variety
• degumming limited types of crude oils – of crude oils, including soybean,
• neutralization for example palm oil, but not sunflower seed and rapeseed oil
• bleaching cottonseed oil or fish oil • results in a product that is more
• dewaxing/winterization • depends on efficient degumming chemically stable and therefore has
(only for oils containing waxes) prior to refining a longer shelf life
• deodorization. • is largely effluent-free, providing • results in the production of
a better environmental profile soapstock that needs expensive
Physical or chemical? • avoids producing soapstock subsequent treatment and disposal,
Two basic types of refining are normally requiring subsequent treatment, and thus involves relatively high
used to process fats and oils – physical and thus involves relatively low production costs.
and chemical. Each approach has its production costs.
own specific advantages, and the use Based on both operating costs and
of one or the other depends heavily on environmental priorities, a gradual
the quality and the type of oil involved. transition is currently taking place from
chemical refining to physical refining,
as and when technology permits.
Engineering services
We also provide a wide range of
supplementary engineering services
that can help you make sure your new
installation comes on line as quickly
and efficiently as possible – with
considerable savings. This includes
ensuring full compliance with the
relevant national and international
Mixers
Adding the correct types of reagents in the right quantities is important,
but correct mixing is crucial for the efficiency of the subsequent refining
processes.
Alfa Laval has long-term practical experience in dealing with a wide range
of mixing requirements, from the gentle “hydration” mixing in the degumming
process to the high-intensity mixing required in the Alfa Laval Multi Mix
process.
Alfa Laval plate heat exchangers have the added advantage that completely
standard units are normally fully capable of handling all requirements within
the fats and oils industry.
Gums drying
Convap Convap
Lecithin – valuable by-product The lecithin is then separated from Flexible operation
When gums are removed from edible the vapours in a large cyclone, To reach the desired capacity, Convap
oils (such as soybean, rapeseed under vacuum, before being sent and Contherm units are often installed
or sunflower seed oil) during the to Contherm heat exchanger(s) for with 2 or 4 units in parallel.
degumming stage, they are in the cooling with water.
form of wet gums with a moisture Any reductions in throughput, whether
content of 40–50%. Quality benefits temporary or not, mean the extra units
The Convap evaporator and the can be turned off, thereby reducing
When dried, these gums become Contherm cooler are both scraped- operating costs while maintaining
liquid lecithin, which can provide an surface heat exchangers that are stable product quality.
important source of additional revenue. specially designed for concentrating
and cooling viscous, heat-sensitive
Drying the gums products such as lecithin.
These wet gums are homogenized and
then fed to Convap evaporator units. As the lecithin only remains within the
Here the moisture is evaporated using Convap evaporator for a very short
steam injected into the Convap jacket. time, it undergoes a very brief period
of heat treatment, thus helping
maintain product quality.
The Alfa Laval advantage
In contrast to thin-film evaporators, the Using Alfa Laval equipment and
heat transfer surface of a Convap unit technologies enables you to:
is scraped thoroughly to prevent the • ensure uniform heat distribution
product sticking and causing burn-on. • reduce thermal impact on
oil products
The unique construction of these • increase operating flexibility
Alfa Laval scraped-surface exchangers • make operation and
makes sure the product is uniformly maintenance easier.
distributed within the evaporator and
the cooler, resulting in a product yield
of consistently high quality.
Biological catalysts The PLC enzyme reacts with PC and Keeping options open
Any gums present in the oil can also phosphatidylethanolamine (PE), forming Alfa Laval provides an optimized
be removed by using enzymes. diacylglycerols and a water-soluble degumming solution that focuses on
Enzymes are biological catalysts that phosphate-bearing ester fragment, increasing the oil yield and reducing
react specifically with target substrates, thus reducing the final emulsion. This utilities consumption.
with the added advantage that they results in cleaner separation during
yield few by-products. centrifugation, and also reduces The Alfa Laval enzymatic water
losses of the neutral oil. In addition, degumming process has the added
Phospholipase is the enzyme the diacylglycerols produced by advantage that it can always be
that reacts specifically with the PLC degumming provide a bonus oil switched back to the traditional water
phospholipids in oil. It converts gums yield that is retained throughout the degumming process if changing
into distinct fractions that are soluble refining process. market conditions make lecithin
in oil and water, respectively. The production a more commercially
phospholipases most commonly used Since PE is a non-hydratable gum, the attractive option.
in oil degumming are phospholipase oil usually has a lower gum content
A (PLA) and phospholipase C (PLC). after PLC degumming compared with
the water degumming process. This
Enzymatic water degumming means less material that requires
Phospholipids are emulsifiers that removal in subsequent processes.
cause losses of oil during the
traditional water degumming process.
Phosphatidylcholine (PC) is the most
hydratable phospholipid and has the
highest emulsification strength.
Molinos Río de la Plata, Argentina’s leading soybean and sunflower seed processor,
selected Alfa Laval to convert its San Lorenzo facility to the Purifine PLC degumming
process. “Due to this innovative step, we’ve seen a significant increase in oil yields
and processing margins, enabling our facility to exploit its potential even better,” said
Luis Palacios, Molinos’ Industrial Manager.
Crude oil/
water Steam Water Steam
degummed
oil
Gums
Enzymatic deep degumming If a PLA enzyme is used, the enzyme That is why the Alfa Laval enzymatic
Enzymatic deep degumming has converts both hydratable and non- deep degumming process provides the
also been developed for the physical hydratable gums into lyso-gums and versatility that enables you to carry out:
refining of seed oils. To remove the free fatty acids. The lyso-gums are • enzymatic deep degumming
gums to a level low enough to allow more hydrophilic, which makes them • special degumming
further processing, the crude oil has easier to remove from the oil during • neutralization
to be pre-treated with a small amount centrifugation. using the same equipment.
of acid. The pH is then adjusted with
diluted lye before an appropriate Alfa Laval provides enzymatic deep The process is well suited for refining
enzyme is added. degumming solutions that employ edible oil as well as pre-treating other
either PLC or PLA enzymes, oils as part of biodiesel production.
For deep degumming of high- depending on the oil treated.
phosphorus crude oils, a PLC enzyme
is used. PC and PE are converted Versatile process
into diacylyglycerols and water soluble Depending on the oil type and oil
phosphate esters, which are separated quality, enzymatic deep degumming
from the oil during centrifugation, along is not always the most effective
with un-reacted gums. processing option.
Combi Mix
When the company ran into quality problems with its existing degumming process, it
turned to Alfa Laval for assistance. The outcome was the installation of an Alfa Laval
special degumming process line that helped the plant produce oil of a better quality,
while also enabling it to reduce losses.
“Alfa Laval is not only a supplier to us but also a partner, guide and friend,” says
Valeriy Fedorenkov, technical director.
Long Mix
Neutralization using caustic soda Neutralization of fats and oils using The other main refining method is
The impurities you most often have caustic soda refining is normally known as the Multi Mix process. This
to deal with in conjunction with fats carried out continuously using features a short contact time, which
and oils are the free fatty acids. These disc stack centrifuges. enables you to refine virtually any
normally stem from lower-quality raw oil, using either one or two washing
materials and/or inappropriate storage. Once neutralization is complete, the stages. However, if you intend to
The greater the free fatty acid content, oil is washed. The wash water is then process cottonseed oil or crude fats
the more challenging the purification removed using disc stack centrifuges, and oils of low quality, a second lye
process and the stronger the caustic and the oil is dried in a vacuum dryer. treatment – commonly known as
soda concentration needed to re-refining – will be necessary.
neutralize and remove it. Two different approaches
Alfa Laval gives you the option of two
Neutralization using caustic soda is different basic ways of neutralizing
widely recognized as an effective fats and oils.
way to purify crude oils, and has the
advantage that the soapstock formed The so-called Long Mix process is
by this process also encapsulates best suited for refining crude soybean
many other impurities. These include or rapeseed oil. It features extended
sugars, pigments and trace metals. contact time in special retention
mixers. Disc stack centrifuges are
used to separate the soapstock
and wash water from the refined oil,
in one single washing stage.
Multi Mix
“It’s not an exaggeration to say this is the most sophisticated edible oil refinery in the
country,” says David Devico, managing director. “We are at least 10 years ahead of
our Moroccan competitors.”
Miscella refining
Less space, less time If you process crude oils that have a
To provide customers with a better high gum content, Alfa Laval can also
alternative, Alfa Laval has developed a provide you with a special processing
continuous processing system that is solution for the soapstocks that result
much faster and takes up substantially from this.
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