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CHAPTER 5:
TRANSITION METAL
CONTENTS
They are called transition metals because they transition between the highly
reactive s block metals and the much less reactive metals of group 12 and the p
ELECTRON CONFIGURATION OF
ATOMS & IONS
3d orbital are filled after the 4s orbital is fully occupied by electrons.
Ti = 22
↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↑
1s 2s 2p 3s 3p 4s 3d
Fe = 26
↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↑ ↑ ↑
1s 2s 2p 3s 3p 4s 3d
4s orbital which will fill first, followed by all the 3d orbitals.
the 4s orbital behaves as the outermost, highest energy orbital.
ELECTRON CONFIGURATION OF
ATOMS & IONS
Ti22 : 1s2 2s2 2p6 3s2 3p6 4s2 3d2 By applying Afbau principle
Ti22 : 1s2 2s2 2p6 3s2 3p6 3d2 4s2 Due to energy level after repulsion
ELECTRON CONFIGURATION OF
ATOMS & IONS
When transition metals form simple ions, the electrons are removed from
the orbital of the highest energy first.
The electrons from 4s orbital are removed first before the electrons in 3d
orbitals.
Chromium & Copper are the two transition element that show
irregularities in electronic configuration.
↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↑ ↑ ↑ ↑ ↑
1s 2s 2p 3s 3p 4s 3d
↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓ ↑ ↓
1s 2s 2p 3s 3p 4s 3d
b) Mn4+
c) Fe2+
d) Fe3+
e) Co2+
TREND ACROSS THE PERIOD OF
PERIODIC TABLE
ATOMIC SIZE
ATOMIC SIZE
Across the period, atomic size decreasing so electrons are more closely
attracted to the nucleus, thus the electron is more difficult to be removed.
TREND DOWN THE GROUP OF
PERIODIC TABLE
IONIZATION ENERGY
As the element going down the group, there are just small increasing in size
and the nuclear charge increase. Atom with higher nuclear charge held
electrons closely to the nucleus. Therefore, ionization energy increase.
Crossing the period, atomic size decrease. The smaller the atomic size,
the higher the ability to attract bonding to itself.
TREND DOWN THE GROUP OF
PERIODIC TABLE
ELECTRONEGATIVITY
- Down the group, atomic mass increase. The heavier elements often have
high EN values.
SPECIAL CHARACTERISTIC OF
TRANSITION ELEMENT
UNIQUENESS
Colors can vary depending on the charge, number & groups of atom
attach to the metal ion (ligands).
When ligands are present, some d orbitals become higher / lower energy
than before.
A complex ion has a transition metal ion at its centre with a number of
ligands surrounding it.
Ligands have active lone pairs of electrons which used to form co-
ordinate bonds with the metal ion.
Other metals also form complex ions - it isn't something that only
transition metals do. However, transition metal form a very wide range
of complex ions.
CATALYTIC PROPERTIES
Hydrogenation (Reduction)
Ni
CH2=CH2(g) + H2(g) → CH3-CH3(g)
Fe
N2(g) + 3H2(g) → 2NH3(g)
EXTRACTION OF IRON
Magnetite (Fe3O4)
STEP 1 : CONCENTRATION
STEP 2 : CALCINATION
STEP 3 : SMELTING
Coke burns in air to form carbon dioxide & a lot of heat is produced (about 1875
K).
C + O2 → CO2 + Heat
This CO2 further racts with more coke and is reduced to CO.
C + CO2 → 2CO
EXTRACTION OF IRON
FUNCTION OF LIMESTONE
This CaO reacts with silica (sand) present in the ore to form slag
(CaSiO3)
CaO + SiO2→ CaSiO3
COMMERCIAL FORM OF IRON
1) Cast Iron
Contain 2-5% carbon along with traces of other impurities.
2) Wrought iron
The purest form of iron and contain carbon to the extent of 0.25%.
3) Steel
Contains 0.5 to 1.5% carbon along with variying amount of other elements.
TRY THIS
3) What 3 major types of iron. How do they differ from each other?