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Lime ABS
RTD MIBC RTD/MIBC
Rougher
Scavenger 1A
Scavenger 1B Scavenger 2
pH = 8.4
Grinding
Circuit
Final Tail
Final
Concentrate
the majority of copper losses occur in the coarse (+106 μm) and 100
ultra-fine (-CS5) size classes with 75 and 12 per cent of the 90
copper present in the final tailings stream being accounted for by
80
these respective size classes. This is illustrated in Figure 2.
70
Copper
Recovery (%)
35 60
Sulphur
50
30 Iron
40 SiO2
Copper Distribution (%)
25 30
20
20
Feed
10
Tailing
15 0
-CS5
+106 μm
+150 μm
+212 μm
+300 μm
+425 μm
+38 μm
+53 μm
+75 μm
CS5
CS4
CS3
CS2
CS1
10
5 Size Fraction
0
FIG 3 - Recovery as a function of size.
+5 μm
μm
+1 μm
+ 1 μm
+2 μ m
+3 μm
+4 m
μm
μ
8
3
5
06
50
12
00
25
+3
+7
Size Fraction
40
particle recovery loss in order to develop strategies for improving +CS5 50-80 80-100
100%
30-50
copper recovery. 0-10
10-30
Degree of Liberation (%)
Copper in the flotation feed occurs almost completely as
chalcopyrite and is very well liberated, even at the relatively
coarse P80 utilised, (with only 5.6 per cent of the chalcopyrite FIG 4 - Chalcopyrite distribution in the Osborne flotation feed
being less than 50 per cent liberated). This is illustrated in Figure 4 (+CS5).
which shows the chalcopyrite liberation distribution in the +CS5
fractions of the flotation feed. Liberation was found to be poorer which showed a significant proportion of chalcopyrite that was
as particle size increased but it was only the +300 μm material less than 50 per cent liberated. This may be seen in Figure 5.
16
90
80 14
70 12
60
10
50 Wt% in each Size
8 Wt% in Tailing
Class
40
6
30
4
20
+300 +300 2
+150 10 +150
+106 0
+106 0
Size Size
+53 +53
100% 100%
+CS5 80-100 +CS5 50-80 80-100
50-80 30-50
30-50
0-10 10-30 10-30
0-10
Degree of Liberation (%) Degree of Liberation (%)
FIG 5 - Proportion of chalcopyrite in each liberation class in each FIG 7 - Proportion of chalcopyrite in each liberation class in each
size class of the Osborne flotation feed (+CS5). size class of the Osborne final tailings (+CS5).
Degree of particle liberation does have a significant impact on in the final tailings is fast-floating, 62 per cent is slow-floating
the recovery achieved, particularly for the coarser particle sizes. and 36 per cent is non-floating). This implies that coarse
This may be seen in Figure 6. Recovery of all liberation classes liberated copper is floating slowly in the circuit when it should
is much lower than expected though and based on previous be floating rapidly and be recovered after a very short residence
MMPT experience, chalcopyrite particles more than 50 per cent time – an indication that insufficient collection (or copper
liberated would be expected to float very quickly and exhibit depression) is occurring in this circuit. It was speculated by
MMPT that the formation of iron-hydroxide coatings on copper
very high recovery in the circuit in all size classes.
mineral surfaces would be consistent with all the observed
findings and is therefore considered as one of two major
100
mechanisms responsible for copper losses in this circuit (the
90 second mechanism is believed to be poor cell recovery as a result
80
of low air rates in the 8 m3 cells and poor recovery across the
froth phase in the 16 m3 cells). Opportunities for improving the
Chalcopyrite Recovery (%)
70
recovery of copper are discussed in more detail throughout the
+300
60
+150
later sections of this paper.
50 +106
40
+53 Gangue recovery mechanisms
+CS5
30 Gangue recovery results in a lower concentrate grade. The
20
amount of gangue recovered to concentrate also often limits
copper recovery in that additional recovery of copper results in
10
an unacceptable concentrate grade because of the corresponding
0 increased gangue recovery. It is therefore important to
0-10 10-30 30-50 50-80 80-100 100%
understand the mechanisms of gangue recovery to assist with
Degree of Liberation
developing strategies to prevent it from being recovered.
The major gangue minerals present are pyrite (five per cent of
FIG 6 - Chalcopyrite recovery as a function of particle size and the feed), iron oxide species (45 per cent of the feed) and quartz
degree of liberation. (21.5 per cent of the feed). The predominant gangue component
reporting to the concentrate is pyrite which exhibits a 12 per cent
Mineralogical analysis of the final flotation tailings revealed recovery in the circuit (and makes up approximately 14 per cent of
that a significant proportion of liberated, coarse chalcopyrite the final concentrate). Pyrite is recovered across all size classes
particles are present in this stream. This is shown in Figures 7, 8 (Figure 10) and is largely liberated (Figure 11). This suggests that
and 9. So although liberation does have an impact on a certain fraction of pyrite in the system is floatable and is being
chalcopyrite and therefore copper recovery in the circuit, poor recovered by true flotation rather than by entrainment or as
liberation is not the primary reason for the presence of significant composites with chalcopyrite.
quantities of coarse copper bearing particles in the final tailings. Since pyrite is the major diluent in the final concentrate and is
This result must therefore be due to either insufficient residence recovered by true flotation, the overall concentrate copper grade
time in the circuit, poor recovery of coarse particles or (and therefore recovery) is largely related to the pH and reagent
insufficient collector on the chalcopyrite surfaces. Insufficient scheme in use and its effect on pyrite floatability. Too much
collector on surfaces could be a consequence of lower than collector (or too low a pH) can potentially result in excessive
required collector addition or the inability of the collector to coat pyrite recovery and a low concentrate grade whereas too little
the surfaces because of the presence of other hydrophilic collector, too high a pH or too much pyrite depressant can
coatings on the chalcopyrite surfaces. decrease chalcopyrite recovery rates. It should be noted that the
A batch flotation test conducted on the final tailings material Osborne circuit is set up to preferentially float copper at the front
suggests that there is a significant quantity of floatable copper of the circuit and then encourage some pyrite recovery at the
being lost to the tailings (a copper recovery of approximately back end of the circuit. Some pyrite recovery is desirable since
60 per cent was achieved during this test). This copper does float the gold is recovered together with copper to the final concen-
slowly though (with the floatability component model which was trate and gold recovery is believed to be linked somewhat to
fitted to the survey data showing that two per cent of the copper pyrite recovery.
20
35
18
30
16
Mineral Recovery (%)
14 25
12
20
Wt% of Final
10 Concentrate
15
8
10
6
4 +300 5
+150
2 +106 0
Size
+53
0 100%
+CS5 50-80 80-100
+300 μm +150 μm +106 μm +53 μm +CS5 30-50
10-30
0-10
Size Fraction (μm) Degree of Liberation (%)
Pyrite depression is currently achieved by adding ammonium these variables in the cells in the Osborne circuit. These
bi-sulfate and lime to the rod mill feed to achieve a pH of 8.5. It measurements were analysed to determine the reason for the
is a possibility that iron hydroxide coatings are forming on observed low cell recoveries.
chalcopyrite surfaces under thesec onditions and contributing Bubble surface area flux (Sb) is defined as the bubble surface
towards the poor recovery of coarse, liberated chalcopyrite in the area rising up through the cross-sectional area of the cell per unit
circuit. Further studies investigating a reduction in the use of time and is proportional to the superficial gas rate (Jg) and
these pyrite depressants to determine if an increase in copper inversely proportional to the bubble size. The higher the gas rate
recovery could be achieved were recommended. and the smaller the bubble size, the faster the kinetics achieved in
Non-sulfide gangue minerals do not usually float naturally and the pulp zone of a flotation cell. The superficial gas rate was
only report to the final concentrate via entrainment or when in measured to increase down the bank with a resulting increase in
composites with floatable minerals. They thus usually exhibit low bubble surface area flux (Figure 13). The bubble surface area flux
overall recoveries but show increased recovery in both the fine was found to be very low in the rougher cells (20 - 25 m2/sec/m2
size classes (due to entrainment) and the coarse size fractions compared with 55 - 60 m2/sec/m2 in the pyrite roughers and
where liberation is incomplete. scavengers) and is therefore contributing to the lower than
One of the significant non-sulfide gangue species present in expected recoveries achieved by these cells.
the Osborne feed is quartz (which comprises about 25 per cent of
the feed). Silica assays were therefore used as an indicator for the
recovery of non-sulfide gangue. Figure 12 shows the distribution 70.0 2.0
of silica in the final concentrate. A high proportion is silica in 1.8
60.0 Sb
this stream is ultra-fine (45 per cent -CS5) which would be
Sb (m /sec/m )
2
1.2
way of minimising entrainment recovery to the final concentrate. 40.0
There is also a small but significant proportion of silica in the 1.0
2
30.0
coarse size fractions, supposedly reporting due to an association 0.8
with the floating chalcopyrite particles. 20.0 0.6
0.4
10.0
50 0.2
45 0.0 0.0
40
Silica distribution (%)
35
30
25
5
Two causes for this low bubble surface area flux in the rougher
cells were identified, firstly the superficial gas rate to these cells
0
is low and secondly the bubbles in these cells are relatively large
μm
μm
μm
μm
μm
μm
μm
+4 m
when compared with other cells in the circuit. This may be seen
μ
8
06
50
25
12
00
+3
+5
+7
+1
+2
+3
Size Fraction superficial gas rate for all the measured cells in the circuit. The
rougher cells have the lowest superficial gas rates and also the
largest bubbles. Normally as the superficial gas rate is increased
FIG 12 - Silica distribution in the Osborne final flotation the bubbles become larger (Gorain et al, 1997) but in this case
concentrate. the trend is reversed. It is also known that an increase in frother
Reducing the recovery of non-sulfide gangue to the final
concentrate could therefore be achieved by reducing the 1.80
Copper recovery was found to decrease down the circuit with 0.60
recoveries in the order of 20 per cent off the first two rougher
0.40 Roughers
cells and three to five per cent off the final cells in the pyrite
scavenger bank. It is the opinion of MMPT that a copper 0.20 Other cells
recovery of 20 per cent off the first flotation cell in a circuit is
0.00
very low and that this figure should more typically be in the
0.00 0.20 0.40 0.60 0.80 1.00 1.20
order of 50 per cent.
Recovery from a flotation cell has been shown to be a function Superficial Gas Rate (cm/s)
0.12
0.10
recoveries. Making the changes suggested should therefore
increase the recovery achieved by these cells but will, in all like-
0.08
lihood, be accompanied by a decrease in concentrate grade. The
0.06
use of a cleaning stage would therefore be beneficial since it
0.04 would allow the rougher and scavenger cells to be operated in
0.02 order to maximise recovery while the cleaner circuit could be
0.00 operated to achieve an acceptable concentrate grade. The effect
Roughers Scavenger Scavenger Scavenger Pyrite Pyrite of this scenario will be investigated using simulation techniques
1A 1B 2 Rougher Scavenger in the subsequent section.
FIG 15 - Fitted cell scale-up numbers for the Osborne flotation SIMULATION OF ALTERNATIVE STRATEGIES
circuit. FOR FLOTATION CIRCUIT IMPROVEMENT
In the previous section, an analysis of the current circuit
Froth recovery is a function of the bubble stability and the time conditions highlighted a number of strategies that should be
bubbles remain in the froth. This is in turn a function of froth trialled in the circuit with the objective of improving metallurg-
depth, froth transportation distance and froth mobility. During the ical performance. Where possible, simulations were performed
surveys, bubble stability was assessed in the cells by measuring using the models developed as part of the project to predict the
dynamic froth stability (Barbian, Ventura-Medina and Cilliers, improvement in circuit performance that would result.
2003). The time particles spent in the froth phase was character-
ised using paper tracers and a knowledge of the froth depth and Increasing residence time
gas rate.
Batch testing of the pyrite scavenger tailing stream indicated that
Dynamic froth stability was found to decrease down the bank there was a significant quantity of copper (more than 60 per cent)
as is shown in Figure 16. The total froth residence time was that was still floatable and was not being recovered in the circuit.
observed to be significantly longer in the 16 m3 cells than the 8 m3 Simulations were performed using the circuit model to determine
cells at the head of the circuit. These cells had a significantly if an increase in the capacity of the circuit would result in an
larger surface area and exhibited significant froth dead zones. increase in recovery. In these simulations, new scavenger cells
The presence of these dead zones is detrimental to recovery in were added to the end of the circuit with cell recovery rates equal
that particles reporting to these zones must eventually drop back to that measured in the last pyrite scavenger cell. The results
into the pulp phase, resulting in a decrease in the overall from these simulations are summarised in Figure 17 which shows
recovery achieved by the cell. It was therefore concluded that the that copper recovery increases are possible in the circuit but only
lower cell recovery rates observed in the cells at the end of the with a significant increase in the installed capacity. Doubling the
bank in Figure 15 is a consequence of lower froth recovery circuit capacity is only expected to increase copper recovery by
caused by poorer froth stability and longer froth residence times. 2.8 per cent.
In order to overcome this froth recovery problem in the 16 m3 The small recovery increase with an increase in capacity is a
cells it was recommended that either froth crowders be installed function of two effects. Although there is a significant quantity
70 (% Cu) (%)
60.6
100
60.4
95 240tph
Current grind 60.2
Net Revenue (A$/t)
Cu Recovery (%)
90 60.0 265tph
P80 = 254 μm
59.8 290tph
85 P80 = 209 μm
P80 = 169 μm 59.6 Baseline
80 P80 = 127 μm 59.4
P80 = 101 μm 59.2
75
P80 = 80 μm
59.0
70
58.8
20 22 24 26 28 30 32
4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00
Final Concentrate Cu Grade (%) kWh/t
FIG 19 - Copper recovery versus concentrate grade predicted in FIG 20 - Specific net revenue versus specific energy consumption
200 Monte Carlo simulations performed at different grind sizes. in the Osborne concentrator.
should give increased net revenue since all of these scenarios combined grinding/flotation model simulations allows for the
have positive slopes over the range of energy inputs evaluated. optimisation of the total process rather than the traditional
The need to maximise energy input during grinding becomes individual process evaluation.
more pronounced at higher plant throughputs and has a weaker In the case study presented, chalcopyrite recovery in the
influence on net revenue as the throughput is decreased (since circuit was strongly influenced by its degree of liberation and
coarse or slow/poorly floating particles present under these its particle size – the coarser and less liberated the chalcopyrite,
conditions have more residence time in the flotation circuit). the lower its recovery in the flotation circuit. There were
The data in Figure 20 does not give an indication of the total significant amounts of well liberated chalcopyrite lost to the
amount of revenue generated by the concentrator on a time basis. final tailing. It is believed that these coarse copper losses were
If the same data is expressed with revenue per time (rather than due to insufficient collector coating of coarse chalcopyrite
per tonne), the results presented in Figure 21 are obtained. This surfaces (possibly due to the presence of iron hydroxide
suggests that even though it may be more efficient to operate at coatings) and poor recovery across the froth phase in the larger
lower throughputs and higher energy inputs, more revenue per flotation cells installed at the back end of the circuit.
hour can be generated by operating at a higher throughput despite
the negative impact that this has on recovery in the flotation circuit Liberated pyrite was the predominant mineral contaminating
(due to both decreased residence time and a coarser particle size) the final concentrate and is recovered by true flotation rather than
for the range of values evaluated. This data also confirms that it is by entrainment.
best to try and maximise power draw from the Osborne grinding Modelling and simulation of the circuit indicates that copper
circuit, particularly at higher plant throughputs. Any attempts to recovery can be increased (through finer grinding, increasing cell
reduce power consumption, (in the new reduced power cost recovery rates by increasing air rates, reducing bubble size,
scenario that Osborne finds itself in after conversion of the on-site improving froth stability or using froth crowders to improve froth
power station to gas fuel), are therefore more now likely to incur mobility). It may also be possible to increase copper recovery
slightly greater revenue losses than savings. rates by reducing the amount of pyrite depressant added to the
circuit. Almost all of these strategies would result in lower
18000
concentrate grades if adopted in isolation. It was therefore
concluded that the use of a cleaner stage of flotation would be
17000
very beneficial. Simulations indicated that the use of cleaning
Net Revenue (A$/hour)
16000
would enable both grade and recovery improvements in the
circuit.
15000 The main driver for concentrator revenue at Osborne is
240 t/h throughput and for the range of values evaluated, decreases in
14000 265 t/h plant efficiency are compensated for by increased throughput in
290 t/h
all cases.
13000
Baseline
12000
REFERENCES
4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 Barbian, N, Ventura-Medina, E and Cilliers, J J, 2003. Dynamic froth
kWh/t stability in froth flotation, Minerals Engineering, 16(11):1111-1116.
Bazin, C, Grant, R, Cooper, M and Tessier, R, 1994. A method to predict
FIG 21 - Net revenue versus specific energy consumption in the metallurgical performances as a function of fineness of grind,
Osborne concentrator. Minerals Engineering, 7(10):1243-1251.
Gorain, B K, Burgess, F, Franzidis, J P and Manlapig, E V, 1997. Bubble
surface area flux: A new criterion for flotation scale-up, in
An alternative way of looking at this information is to say that Proceedings AusIMM Sixth Mill Operators’ Conference, pp 141-148
it will be possible to reduce specific power consumption and (The Australasian Institute of Mining and Metallurgy: Melbourne).
maintain concentrate revenue by increasing the feed rate to the Grau, R A and Heiskanen, K, 2005. Bubble size distribution in laboratory
concentrator slightly (although this will actually move the plant scale flotation cells, Minerals Engineering, 18(12):1164-1172.
to a less efficient operating condition). Runge, K C, Dunglison, M E, Manlapig, E V and Franzidis, J P, 2001.
Floatability component modelling – A powerful tool for flotation
CONCLUSIONS circuit diagnosis, in Proceedings Fourth International Symposium on
Fundamentals of Minerals Processing, pp 93-107 (The Canadian
This paper has demonstrated that the use of traditional size by Institute of Mining, Metallurgy and Petroleum: Montreal).
size and mineralogical analysis in combination with cell Runge, K C, McMaster, J K, Ijsselstijn, M and Vien, A, 2007.
characterisation measurement and modelling analysis can Establishing the relationship between grind size and flotation
provide valuable insight and strategies for circuit improvement recovery using modelling techniques, in Proceedings Flotation 2007
which would often otherwise be overlooked. Performing Minerals Engineering Conference, Cape Town.