JP XII Physical&Inorganic Chemistry (5) - Prev Class XI Chaps + Solution & Colligative Properties +solid State PDF

PHY./INO.
CHEMISTRY
TARGET : JEE (Main + Advanced) 2017

Course : VIJETA (JP) Date : 27-04-2015 NO. 07 & 08
TEST IN FORMATI ON
DATE : 17.05.2015 PART TEST (PT) - 01 (ADVANCED)
Syllabus : Solution & Colligative Properties, Solid State, Thermodynamics, Ionic equilibrium, s-Block
Element. (All ChemInfos and Handouts till date)
This DPP is to be discussed in the week (27-04-2015 to 02-05-2015)

DPP No. # 07 (JEE-MAIN)
Total Marks : 60 Max. Time : 40 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.20 (3 marks, 2 min.) [60, 40]
1. Consider the reaction

CaCO3(s) CaO(s) + CO2(g)
in a closed container at equilibrium. What would be the effect of addition of CaCO 3 on the equilibrium
concentration of CO2 ?
lkE; ij ,d can fudk; es fuEu vfHkfØ;k dk voyksdu dhft,
CaCO3(s) CaO(s) + CO2(g)
CO2 dh lkE; lkUnzrk ij CaCO3 dks feykus dk D;k izHkko gksxk \
(A) Increases (B) Unpredictable (C) Decreases (D*) Remains unaffected
(A) o`f) gksxh (B) dgk ugha tk ldrk gS (C) de gksxh (D*) vizHkkfor jgsxh
2. A complex organic compound contains 21 atoms of carbon per molecule. The percentage of carbon in the
compound is 70%. If 36 gram of the substance is dissolved in 100 mL of water then the molarity of the
solution will be–
,d dkcZfud ladqy ;kSfxd dkcZu ds 21 ijek.kq izfreksy j[krk gSA ;kSfxd esa dkcZu dk 70% mifLFkr gSA ;fn 36 xzke
inkFkZ (substance) dks 100 mL ikuh es feyk;k tk;s rc foy;u dh eksyjrk gksxh–
(A*) 1 (B) 0.1 (C) 1.43 (D) 0.143
Sol. One mole of compound contains 12 × 21 = 252 g carbon
,d eksy ;kSfxd 12 × 21 = 252 g dkcZu gS
100
Molar weight = 252 × = 360
70
100
 eksyj Hkkj = 252 × = 360
70
36 1000
Molarity =  =1
360 100
36 1000
 eksyjrk =  =1
360 100
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3. In the reaction CS2 () + 3O2 (g)  CO2 (g) + 2SO2 (g) H = 265 kcal
The enthalpies of formation of CO 2 and SO2 are both negative and are in the ratio 4 : 3. The enthalpy of
formation of CS2 is +26kcal/mol. Calculate the enthalpy of formation of SO 2.
CS2 () + 3O2 (g)  CO2 (g) + 2SO2 (g) H = 265 kcal
mijksDr vfHkfØ;k esa] CO2 rFkk SO2 nksuksa ds laHkou dh ,UFksYih _.kkRed gS rFkk 4 : 3 ds vuqikr esa gSA CS2 ds laHkou
dh ,UFksYih +26kcal/mol gSA SO2 ds laHkou dh ,UFksYih dh x.kuk dhft;s \
(A) – 90 kcal/mol (B) – 52 kcal/mol (C) – 78 kcal/mol (D*) – 71.7 kcal/mol
Sol. Cs2 () + 3O2 (g) Co2 (g) + 2So2 + 2so2 H =
Let Hf (CO2 , g) = 4 x
and Hf (SO2 , g) = 3x
Hreaction = Hf (CO2 ,g) = 2 Hf (SO2 .g) – Hf (CS2 )
– 265 = 4 x + 6x –26
x = –23.9
Hf (SO2,g) = 3x = 71.7 kcal / mol.
4. For the reaction at 25°C, X2O4()  2XO2(g)

H = 2.1 Kcal and S = 20 cal K–1. The reaction would be :
(A*) spontaneous (B) non-spontaneous (C) at equilibrium (D) unpredictable
25°C ij vfHkfØ;k X2O4()  2XO2(g) ds fy, H = 2.1 Kcal rFkk S = 20 cal K–1 gSA vfHkfØ;k %
(A*) Lor% gksxh (B) vLor% gksxh (C) lkE; ij gksxh (D) ds fy, dgk ugha tk ldrk gS
Sol. G = H – TS
= 2.1 × 103 – 20 × 298 < 0.
5. A 10% w/w solution of cane sugar has undergone partial inversion according to the reaction
Sucrose + water  glucose + fructose
The boiling point of the solution is 100.7°C.
What fraction of sugar has inverted ?
(Kb (H2O) = 1.8 K.kg/mol)
xUuk 'kdZjk ds ,d 10% w/w foy;u dk fuEu vfHkfØ;k ds vuqlkj vkaf'kd izkrhiu gksrk gSA
lqØksl + ty  Xywdksl + ÝDVksl
foy;u dk DoFkukad 100.7°C gSA
'kdZjk ds izfriu dk fHkUu fdruk gksrk gS \
(Kb (H2O) = 1.8 K.kg/mol)
(A) 0.5 (B*) 0.2 (C) 0.3 (D) 0.4
Sol. Let degree of dissociation of sucrose be .
 Sucrose + water  glucose + fructose
i = 1 + (2 – 1)= 1 + 
10  1000
 Tb = iKbm  0.7 = (1 + ) × 1.8 ×
342  90
0.7  342  9
 1+= = 1.2
1.8  1000
  = 0.2
Sol. ekuk lqØksl ds fo;kstu ds fo;kstu dh ek=kk  gSA
 lqØksl + ty  Xywdksl + ÝDVksl
i = 1 + (2 – 1)= 1 + 
10  1000
 Tb = iKbm  0.7 = (1 + ) × 1.8 ×
342  90
0.7  342  9
 1+= = 1.2
1.8  1000
  = 0.2
PAGE NO.- 2
6. The species C2
Lih'kht C2 j[krk gSA
(A) Has one  bond and one  bond (B*) Has both  bond
(C) Has both  bonds (D) Does not exist
(A) ,d  ca/k rFkk ,d  ca/k (B*) nksuksa  ca/k
(C) nksuksa  ca/k (D) vfLrRo ugha j[krk gSA
Sol. Double bond in C2 has both  bonds between the two C-atoms because 4 electron are present in  molecular
orbitals
C2 esa nks dkcZu ijek.kqvksa ds e/; nks ca/k gksrs gSa rFkk nksuksa gh  ca/k D;ksfd 4 bysDVªkWu  vkf.od d{kdks esa mifLFkr gksrs gSa
7. An acid solution of pH = 6 is diluted 1000 times, the pH of the final solution becomes.
pH = 6 ds ,d vEy foy;u dks 1000 xquk ruq fd;k x;kA rc ifj.kkeh foy;u dk pH D;k gks tkrk gSA
(A*) 6.99 (B) 6 (C) 3 (D) 9
Sol. pH = 6 means [H+] = 10–6 M. After dilution [H+] 10–6/1000 = 10–9 M
pH = 6 dk vFkZ [H+] = 10–6 M. ruqdj.k ds i'pkr~ [H+] 10–6/1000 = 10–9 M
 [H+] from H2O cannot be neglected
vr% H2O ls izkIr [H+] vk;uksa dks ux.; ugha fd;k tk ldrkA
Total dqy [H+] = 10–9 + 10–7 = 10–7 (10–2 + 1) = 10–7 (1.01)
or ;k pH = –log 1.01 x 10–7 = 7 – 0.0043 = 6.9957
8. Which of the following has highest electron affinity ?

fuEu esa ls fdldh bySDVªkWu ca/kqrk vf/kdre gS \
(A*) Li+ (B) Na+ (C) F– (D) Cl–
Sol. Addition of an electron to F– and Cl– ions will involve replusions therefore their EA is almost zero. On the other
hand, addition of an electron to Na+ and Li+ will involve attraction. Since Li+ is much smaller than Na+ ion,
therefore, EA of Li+ is higher than that of Na+.
F– rFkk Cl– vk;u esa ,d bysDVªkWu ds ;ksx ls izfrd"kZ.k gksrk gS bl izdkj budh EA yxHkx 'kwU; gks tkrh gSA nwljh vkSj
Na+ rFkk Li+ esa
,d bysDVªkWu dk ;ksx ls vkd"kZ.k gksrk gSA ;)fi Li+ , Na+ vk;u fd rqyuk esa vf/kd NksVk gS bl izdkj
Li+ fd EA Na+ fd rqyuk esa vf/kd gSA
9. A pre-weighed vessel was filled with oxygen at NTP and weighed. It was then evacuated, filled with SO3 at the
same temperature and pressure and again weighed. The weight of oxygen will be–
(A) Same as that of SO3 (B) 4 times that of SO3
(C) 2.5 times that of SO 3 (D) 0.25 times that of SO3
igys ,d [kkyh ik=k dk Hkkj eki dj NTP ij mls vkDlhtu ls Hkjdj Hkkj ekirs gSA vc bl ik=k dks fuokZfrr djds mlh
leku rki vkSj nkc ij SO3 ls Hkjdj nksckjk Hkkj ekirs gSA vkDlhtu dk Hkkj gksxk
(A) SO3 ds leku (B*) SO3 dk 4 xquk
(C) SO3 dk 2.5 xquk (D) SO3 dk 0.25 xquk
Sol. Since T & P are same & vessel is also same so at constant P, V, & T no of males in both the cases will be
same
tc dh rki vkSj nkc leku vkSj ik=k Hkh leku gS blfy, fu;r P, V, & T ij eksyks dh la[;k Hkh leku gksxh
WSO3 WO 2
=
80 32
2
WO2 = WSO 3
5
= 0.4 WSO3
10. Which will give maximum [H+] ion concentration by dissolving equal moles in water
fuEu es ls fdldks ikuh es ?kksyus ij [H+] vk;u dh lkUnzrk vf/kdre gksxhA ;fn lcds eksy cjkcj gks&
(A*) LiOH (B) NaOH (C) KOH (D) RbOH
PAGE NO.- 3

Ans. (A) LiOH is least basic  [OH ]  min imum
 [H ]  max imum
 [OH ] 
(A) LiOH lcls de {kkjh; gSA
 [H ] 
11. A chloride dissolves appreciably in cold water. When placed on a platinum wire in Bunsen flame, no distinctive
colour is noticed. The cation is–
,d DyksjkbM B.Ms ikuh es ?kqy tkrk gSA tc bls IysVhue ¼platinum½ ds rkj ij j[kdj cqUlsu Tokyk esa xeZ djrs gS rks
dksbZ jax izkIr ugh gskrk gSA og /kuk;u gS&
(A) Ca2+ (B*) Mg2+ (C) Ba2+ (D) Pb2+
Ans. (B) PbCl2 is insoluble in cold water.
Ca2+ & Ba2+ give bricke red & apple green colours respectively to the Bunsen flame
(B) PbCl2 B.Ms ikuh esa vfoys; gSA
Ca2+ & Ba2+ cqUlsu Tokyk ds lkFk Øe'k% bZaV tSlk yky vkSj lsc tSlk gjk (bricke red & apple green colours ) jax nsrk gSA
12. The solvent which is better to be used during ebullioscopic, measurement has–
DoFkkukadekih (ebullioscopic) vuqekiu ds nkSjku dkSuls foyk;d dk mi;ksx djuk vPNk gS
(A*) High Kb (B) Low Kb (C) Kb = Kf (D) Kf < Kb
Ans. (A) Higher the value of Kb , more will be Tb . Hence, it can be measured more accurately
(A) Kb dk eku T;knk gksxk rc Tb dk eku Hkh T;knk gksxk blfy, ;g vf/kd lgh ekik tk ldrk gSA
13. Standard molar enthalpy of formation of CO 2 is equal to -

(A) zero
(B) the standard molar enthalpy of combustion of gaseous carbon
(C) the sum of standard molar enthalpies of CO & O 2
(D*) the standard molar enthalpy of combustion of C(s)
CO2 dh ekud eksyj ,UFkSYih fdlds cjkcj gS -
(A) 'kwU;
(B) xSlh; dkcZu ds ngu dh ekud eksyj ,UFkSYih ds cjkcj gS
(C) CO vkSj & O2 dh ekud eksyj ,UFkSYih ds ;ksx ds cjkcj gS
(D*) C(s) ds ngu dh ekud eksyj ,UFksYih ds cjkcj gS
Ans. (D)
14. The most unsymmetrical crystal system is:

(A) Cubic (B) Hexagonal (C*) Triclinic (D) Orthorhombic
fuEufyf[kr esa ls lokZf/kd vlefer fØLVy fudk; gS &
(A) ?kuh; (Cubic) (B) "kVdks.kh; (Hexagonal) (C*) f=kurk{k (Triclinic) (D) fo"keyEck{k (Orthorhombic)
Sol. For triclinic a  b  c &       90°
15. The number of crystal systems known are :

dqy fdrus izdkj ds fØLVyh; fudk; Kkr gS %
(A*) 7 (B) 8 (C) 6 (D) 4
16. Tetragonal crystal system has the following unit cell dimensions:
(A) a = b = c and  =  =  = 90° (B*) a = b  c and  =  =  = 90°
(C) a  b  c and  =  =  = 90° (D) a = b  c and  =  = 90°,  = 120°
f}leyEck{k (tetragonal) fØLVy fudk;] fuEufyf[kr esa ls dkSulh bdkbZ dks"Bhdk foek;sa j[krk gSA
(A) a = b = c rFkk  =  =  = 90° (B*) a = b  c rFkk  =  =  = 90°
(C) a  b  c rFkk  =  =  = 90° (D) a = b  c rFkk  =  = 90°,  = 120°
Sol. a  b  c &  =  =  = 90° the crystal system is orthorhombic
PAGE NO.- 4
17. Which has no axis of rotation of symmetry ?
(A) Hexagonal (B) Orthorhombic (C) Cubic (D*) Triclinic
fuEu esa ls fdlesas leku :i ls ?kw.kZu dk dksbZ v{k ugha gS ?
(A) "kV~dks.kh; (B) fo"keyEck{k (C) ?kuh; (D*) f=kurk{k
Sol. In triclinic unit sell.
f=kurk{k ,dd dksf"Vdk esa
a b c
    
18. Three elements P, Q and R crystallize in a cubic solid lattice. The P atoms occupy the corners,
Q atoms the cube centres and R atoms the edges. The formula of the compound is:
rhu rRo P, Q rFkk R ?kuh; Bksl tkyd ds :i esa fØLVyhd`r gksrh gSA P ijek.kq dksuksa ij] Q ijek.kq ?ku ds dsUnz ij
rFkk R ijek.kq fdukjksa ij mifLFkr gSA ;kSfxd dk lw=k D;k gS &
(A) PQR (B) PQR2 (C*) PQR3 (D) PQ3R.
1 1
Sol. P=8 = 1 ; Q = 1 = 1 ; R = 12  = 3 ; formula = PQR 3
8 4
19. A compound alloy of gold and copper crystallises in a cubic lattice in which the gold atoms occupy the lattice
points at the corner of a cube and the copper atoms occupy the centres of each of the cube faces. Hence
compound alloy has formula :
xksYM rFkk dkWij ds feJ/kkrq ;kSfxd ?kuh; tkyd ds :i esa fØLVyhd`r gksrh gSA ftlesa xksYM ijek.kq ?ku ds tkyd fcUnq]
dksuksa ij rFkk dkWij ijek.kq ?ku ds izR;sd Qyd dsUnz ij fLFkr gksrs gSA blizdkj feJ/kkrq ;kSfxd dk lw=k gS &
(A) AuCu (B) Au3Cu (C) Au2Cu (D*) AuCu3
1 1
Sol. Au = 8  =1 Cu = 6  = 3 formula AuCu3
8 2
20. Column A describe nature of bonding and Column B the solid having that type of bonding :
Correct matching of A and B is in alternate :

dkWye A cU/k dh izd`fr rFkk dkWye B Bksl esa cU/k ds izdkj dks crkrk gSA
A rFkk B dk lgh feyku fuEu fodYi esa gSA

I II III IV I II III IV
(A) P Q R S (B*) Q S P R
(C) Q P R S (D) S P Q R
PAGE NO.- 5
DPP No. # 08 (JEE-ADVANCED)
Total Marks : 77 Max. Time : 45 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.7 (3 marks, 2 min.) [21, 14]
Multiple choice objective ('–1' negative marking) Q.08 to Q.11 (4 marks, 2 min.) [16, 08]
Integer type Questions ('–1' negative marking) Q.12 to Q.14 (4 marks 3 min.) [12, 09]
Match the Following (no negative marking) Q.15 (8 marks, 6 min.) [08, 06]
ChemINFO : 4 Questions ('–1' negative marking) Q.16 to Q.20 (4 marks, 2 min.) [20, 08]
1. In a face centred cubic arrangement of A and B atoms whose A atoms are at the corner of the unit cell and B
atoms at the face centres. One of the A atom Is missing from one corner in unit cell. The simplest formula of
the compound is
A rFkk B ijek.kqvksa dh Qyd dsUnzh; ?kuh; O;oLFkk esa] A ijek.kq bdkbZ dks"Bhdk ds dksuksa ij rFkk B ijek.kq Qyd ds dsUnz
ij mifLFkr gSA bdkbZ dks"Bhdk ds ,d dksus ls ,d A ijek.kq vuqifLFkr gS rc] ;kSfxd dk ljyre lw=k gS&
(A) A7B3 (B) AB3 (C*) A7B24 (D) A2B3
1 7 1
Sol. A=7 = ; B=6 =3
8 8 2
Formula = A 7 / 8 B3 or A7B24
2. A compound is formed by elements A and B. This crystallises in the cubic structure where the A atoms are
at the corners of the cube and B atoms are at the body centres. The simplest formula of the compound is :
,d ;kSfxd dks A rFkk B rRoksa }kjk cuk;k tkrk gSA ;g ?kuh; lajpuk esa fØLVyhd`r gksrh gS tgk¡ A ijek.kq ?ku ds dksuks
ij rFkk B ijek.kq dk; dsUnz ij mifLFkr gSA ;kSfxd dk ljyre lw=k fuEu gS :
(A) A8B4 (B) AB6 (C*) AB (D) A6B
1
Sol. In simple cubic contribution of one corner =
8
total corner = 8
1
effective no. of atom per unit cell = ×8=1
8
No. of bondy center in simple cubic = 1
No. of atom in body center = 1
AB
1
Sol. ,d dksus ds fy, ljy ?kuh; ;ksxnku = 8
dqy dksus = 8
1
izfr ,dd dksf"Vdk ds fy, izHkkoh la[;k = ×8=1
8
ljy ?kuh; esa dk; dsUnzdksa dh la[;k = 1
dk; dsUnz esa ijek.kq dh la[;k = 1
3. Let the solubilities of AgCl in H2O, 0.01 M CaCl2, 0.01 M NaCl & 0.05 M AgNO3 be S1, S2, S3 & S4
respectively what is the correct relationship between these quantities . Neglect any complexation.
ekuk AgCl dh foys;rk H2O, 0.01 M CaCl2, 0.01 M NaCl ,oe~ 0.05 M AgNO3 esa Øe'k% S1, S2, S3 , S4 gSa] rks bu
ek=kkvksa esa lgh laca/k D;k gSA fdlh Hkh rjg dh tfVyrk dks ux.; ekfu;s
(A) S1 > S2 > S3 > S4 (B) S1 > S2 = S3 > S4 (C*) S1 > S3 > S2 > S4 (D) S4 > S2 > S3 > S1
PAGE NO.- 6
4. Two mole of an ideal gas is heated at constant pressure of one atomosphere from 27ºC to 127ºC. If Cv,m = (20
+ 10–2 T) JK–1 mol–1, then q and U for the process are respectively :
,d vkn'kZ xSl ds nks eksy ,d ok;qe.My ds fLFkj nkc ij 27ºC ls 127ºC rd xeZ fd;s tkrs gSaA ;fn Cv,m=
(20+10–2 T) JK–1 mol–1 gS] rc vfHkfØ;k ds fy;s q vkSj U Øe'k% gS %
(A*) 6362.8 J, 4700 J (B) 3037.2 J, 4700 J (C) 7062.8, 5400 J (D) 3181.4 J, 2350 J
Sol. (A) w = – nR T = –2 × 8.314 × 100 = –1662.8 J
400 400
 10 2 
 (20 + 10–2 T) dT = 220  100  400 2 – 300 2
U = n 
300
C V, m dT = 2 ×
300  2
 = 4700 J

4700 = q – 1662.8
 q = 6362.8 J.
5. For a reversible adiabatic process with Ti > Tƒ on an ideal gas, which of the following statement is INCORRECT:
PiVi Pƒ Vƒ
(A) Work is done by the gas. (B) T = Tƒ
i
(C*) H = 0 (D) W = nCVT

,d vkn'kZ xSl ij Ti > Tƒ okys ,d mÙØe.kh; :)ks"e çØe ds fy,] fuEu esa ls dkSulk dFku vlR; gS\
PiVi Pƒ Vƒ
(A) xSl }kjk dk;Z fd;k x;k gSA (B) T = Tƒ
i
(C*) H = 0 (D) W = nCVT

Sol. Reversible adiabatic process. So P iVi = PƒVƒ
Pi Vi Pƒ Vƒ
Ti = Tƒ (Valid for all processes on an ideal gas)
Ti > Tƒ. So internal energy of the gas decreases during the process. Also the process is adiabatic.
So q = 0. Therefore, from first law, work is done by the gas.
Also the process is adiabatic. So q = 0. Therefore, from first law, W = E = nCVT.
mRØe.kh; :)ks"e izØe] vr% PiVi = PƒVƒ
Pi Vi Pƒ Vƒ
Ti = Tƒ (vkn'kZ xSl ds fy, lHkh izØeksa ij ykxw)
Ti > Tƒ. vr% izØe ds nkSjku xSl dh vkUrfjd ÅtkZ ?kVrh gSA ;|fi izØe :)ks"e gSA vr% q = 0 blfy, izFke fu;e
ds vuqlkj] xSl }kjk dk;Z fd;k x;k gSA
;|fi izØe :)ks"e gSA blfy, q = 0, izFke fu;e ds vuqlkj] W = E = nCVT.
6. Which of the following are isostructural ?

fuEu esa ls dkSulh Lih'kht lelajpukRed gS \
NO3–, CO32–, ClO3– , SO3, XeO3
(I) (II) (III) (IV) (V)
(A*) (I) and (IV) (B) (II) and (V) (C) (III) and (IV) (D) (IV) and (V)
(A*) (I) rFkk (IV) (B) (II) rFkk (V) (C) (III) rFkk (IV) (D) (IV) rFkk (V)
Sol. (I) (II) (III)
PAGE NO.- 7
(IV) (V)
7. For a real gas with very large value of molar volume, which of the following equation can most suitably be
applied:
vR;f/kd eksyj vk;ru okyh ,d okLrfod xSl ds fy, fuEu esa ls dkSulh lehdj.k lokZf/kd mi;qDr :i ls iz;q Dr dh tk
ldrh gS %
a Pb a
(A) Z = 1 – V RT (B*) PVm = RT (C) Z = 1 + (D) PVm – RT = V
m RT m
Sol. For very large value of molar volume (Vm)

a
Vm and b can be neglected, so gas behaves as Ideal
 PVm = RT
vR;f/kd eksyj vk;ru (Vm) ds fy,
a
Vm rFkk b dks ux.; ekuk tk ldrk gS vr% xSl vkn'kZ O;ogkj djrh gSA
 PVm = RT
8.* When the gas is an ideal one and process is isothermal, then the correct relation is/are :
;fn ,d xSl] ,d vkn'kZ xSl gS rFkk izØe lerkih; gS] rc lgh lEcU/k gS@gSa :
(A*) P1V1 = P2V2 (B*) E = 0 (C) W = 0 (D*) H = 0
Sol. The value of work done will not be zero.
fd;s x;s dk;Z dk eku 'kwU; ugha gksxkA
9*. Critical temperature for a particular gas is – 177°C then for which of the following case value of compressibility
factor of the gas may be more than unity.
,d fuf'pr xSl ds fy, ØkfUrd rkieku – 177°C gS rks fuEu esa ls fdl xSl ds fy, lEihMh;rk xq.kkad(z) dk eku bdkbZ
ls vf/kd gksrk gSA
(A) at 0°C and 0.01 atm (B*) at 0°C and 2000 atm
(C*) at 60°C and 0.01 atm (D*) at 60°C and 10 atm
10*. Solubility of AgCN will be greater in which of the following solutions as compared to distilled water?
vklqr ty dh rqyuk esa AgCN dh foys;rk fuEu esa ls fdl foy;u esa vf/kd gksxh \
(A) 0.5 M AgNO3 (B*) 0.5 M HNO3
(C*) 5 M KCN (D) All of above mijksDr lHkh
Sol. (A) Common ion effect.
In (B) and (C), solubility equilirbium of AgCN will be pushed forward due to reaction of H+ with CN– (in B) and
complexation of Ag+ with CN– (in C) respectively.
gy % (A) levk;u izHkko (B) o (C) esa]
(B) esa CN– ds
lkFk H+ dh vfHkfØ;k ds dkj.k AgCN ds foys;rk lkE; dks vxz fn'kk esa ys tkrs gS (C) esa] CN– ds lkFk
+
Ag ds ladqy ds dkj.k AgCN ds foys;rk lkE; dks vxz fn'kk esa ys tkrs gSA
11*. Select incorrect statement :
(A) Na+ and K+ ions are responsible for maintaining isotonic property of inside and outside of the cell of
organism.
(B) Aquatic species are more comfortable in lake present at sea level in compare to lake present at high
altitude.
(C*) Solubility of N2 decrease in presence of He when oxygen cylinder is utilised by Scuba divers.
(D*) The KH value of CO 2 is higher than KH of N2.
PAGE NO.- 8
xyr dFku@dFkuksa dk p;u dhft;sA
(A) Na+ rFkk K+ vk;u] tSo dksf’kdk dh vkUrfjd rFkk ckg~; leijkljh xq.k ds fy, mÙkjnk;h gksrs gSA
(B) tyh; iztkrh;kW leqnzh LRkj ij mifLFkr >hy esa mPp LFkyksa ij mifLFkr >hy dh rqyuk esa vf/kd lgt eglw l djrs
gSA
(C*) leqnzh xksrk[kksjksa }kjk iz;qDr fd;s tkus okys vkWDlhtu flys.Mj esa He dh mifLFkr esa N2 dh foys;rk ?kVrh gSA
(D*) CO2 dk KH eku] N2 lsa vf/kd gksrk gSA
12. How many B—O—B bond are present in the structure of borax ?
cksjsDl dh lajpuk esa fdrus B—O—B ca/k mifLFkr gS \
Ans. 5
13. Certain amount of a gas confined in a piston-filled cylinder is heated from 27ºC to 127ºC keeping its pressure
constant and the gas expanded against a constant pressure doing 4.157 kJ of work on surroundings. Find
the number of moles of gas present in the cylinder ?
,d xSl dh fuf'pr ek=kk dks] ,d fiLVu ;qDr flys.Mj esa j[kk tkrk gS] bl Hkjs gq;s flys.Mj dks bldk nkc fu;r j[krs
gq, 27ºC ls 127ºC rd xeZ fd;k tkrk gS rFkk xSl fu;r nkc ds fo:) izlkfjr gksdj] ifjos'k ij 4.157 kJ dk dk;Z
djrh gS flys.Mj esa] mifLFkr xSl ds eksyksa dh la[;k Kkr dhft;s \
Ans. 5
Sol. W = – PV
4.157  103
W = – nRT or n= =5
8.314  100
14. How many of the following orbitals have x–y plane as nodal pane ?
fuEu esa ls fdrus d{kd uksMy ry ds :i esa x–y ry j[krs gS\
(a) 3s (b) 2pz (c) 3px (d) 3 dx 2 – y 2 (e) 4dxy (f) 3dxz (g) 4p y
(h) 5pz (i) 3dyz (j) 4 dz2

Ans. 4
Sol. (b), (f), (h), (i)
15. 1.22 g of a monobasic acid is dissolved in 100 g of benzene. Boiling point of solution increases by 0.13ºC
with respect to pure benzene. Find the molecular mass of acid in benzene solvent (in u). Report your answer
after dividing it by 100 and (Round it off to nearest integer).
1.22 g ,dy {kkjh; vEy 100 g csUthu esa ?kksyk tkrk gS rc bl foy;u dk DoFkukad ‘kq) csUthu ls 0.13ºC c<+ tkrk gSA
csUthu foyk;d esa vEy dk vkf.od nzO;eku (u esa) Kkr fdft,A vkidk mÙkj 100 ls Hkkx nsdj nhft;sA (fudVorhZ iw.kkZd
es)a
Ans. 2
Sol. Tb = Kb × m
1.22 / M
0.13 = 2.6 ×
0.1
 M = 244 u
 Reported answer (iz'ukuqlkj mÙkj) = 2
PAGE NO.- 9
16. Column-I and Column-II contains four entries each. Entries of Column-I are to be matched with some
entries of Column-II. One or more than one entries of Column-I may have the matching with the same
entries of Column-II.
Column-I Column-II
(Bravais Lattice(s)) [Crystal system]
(A) Primitive, face centered, body centered, end centered (p) Cubic
(B) Primitive, face centered, body centered (q) Orthorhombic
(C) Primitive, body centered (r) Hexagonal
(D) Primitive only (s) Tetragonal
LrEHk -I rFkk LrEHk-II izR;sd pkj izfof"V;k¡ j[krs gSA LrEHk-I dh izfof"V;ksa dks LrEHk-II dh dqN izfof"V;ksa ds lkFk lqesfyr fd;k
tkrk gSA LrEHk-I dh ,d ;k ,d ls vfèkd izfof"V;k¡ LrEHk-II dh leku izfof"V;ksa ds lkFk lqesfyr gksrh gSA
LrEHk -I LrEHk -II
(czsfol tkyd) ( fØLVy fudk; )
(A) izhehVho] Qyd dsfUær] dk; dsfUær] vUr% dsfUær (p) ?kuh;
(B) izhehVho] Qyd dsfUær] dk; dsfUær (q) fo"ke yEck{k
(C) izhehVho] dk; dsfUær (r) "kV~dks.kh;
(D) dsoy izhehVho (s) prq"dks.kh;
Ans. (A) - (q) ; (B) - (p) ; (C) - (s) ; (D) - (r)
PAGE NO.- 10
ChemINFO-1.5 Solid State
Daily Self-Study Dosage for mastering Chemistry Crystal Systems
There is an unlimited number of possible lattices because there is no restriction on the length of lattice translation
vector or on the angle  between them. on the basis of geometrical consideration theoritically there can be 32
different combinations of symmetry of crystal.
On other hand bravais show there is only seven types of crystal system.
(a) Cubic (b) Tetragonal (c) Orthorhombic (d) Rhombohedral (e) Hexagonal (f) Monoclinic (g) Triclinic
Seven Crystal system
Crystal Axial Axial angles Examples Type of Unit cells

System distances
Cubic a=b=c α = β = γ = 90° Cu, ZnS, KCl S,BCC,FCC
Tetragonal a=bc α = β = γ = 90° Sn(white tin), SnO2,TiO2 S,BC
Orthorhombic a  b  c α = β = γ = 90° Rhombic sulphur, CaCO3 S,BCC,FCC,ECC
Monoclinic abc α = γ = 90°;β  90° Monoclinic sulphur, PbCrO2 S,BCC
Hexagonal a=bc α = β = 90°;γ = 120° Graphite, ZnO S
Rhombohedral a = b = c α = β = γ  90° CaCO3(Calcite), HgS(Cinnabar) S
Triclinic abc α β γ  90° K2Cr2O7, CuSO4.5H2O S
Cubic ; Tetragonal ; Orthorhombic ; Monoclinic ;
Hexagonal ; Rhombohedral ; Triclinic
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
17. The lattice parameters of a given crystals are a = 8.42 Å, b = 8.42 Å and c = 9.80 Å. There coordinate axes
are mutually perpendicular to each other. The crystal is
(A*) Tetragonal (B) Ortho rhombic (C) Monoclinic (D) Trigonal
18. The crystal dimensions a = b  c ;  =  = 900  = 1200 represents

(A) Tetragonal (B*) Hexagonal system
(C) Monoclinic (D) Orthorhombic system
19. Which of the following unit cells has least symmetry ?

(A) Tetragonal (B) Monoclinic (C*) Triclinic (D) Cubic
20. Among the unit cells given below, which has highest symmetry ?
(A) Hexagonal (B) Orthorhombic (C*) Cubic (D) Monoclinic
PAGE NO.- 11
ChemINFO-1.5 Solid State
Daily Self-Study Dosage for mastering Chemistry Crystal Systems
;gk¡ vla[; la[;k esa lEHko tkyd gksrs gS D;ksafd ;gk¡ muds chp fdlh çdkj ds tkyd :ikUrj.k dh yEckbZ vFkok dks.k ij
çfrcU/k ugha gSA T;kferh; voyksdu ds vk/kkj ij lS)kfUrd :i ls ;gk¡ fØLVy dh leferrk ds 32 fofHkUu la;kstu gks ldrs gSA
nwljh vksj czsfol fØLVy ra=k ds dsoy lkr çdkj n'kkZrk gSA
(a) ?kuh; (b) f}leyack{k (c) fo"keyack{k (d) f=klerk{k (e) "kV~dks.kh; (f) ,durk{k (g) f=kurk{k
lkr fØLVy ra=k
?kuh; ; f}leyack{k ; fo"keyack{k ; ,durk{k ;
"kV~dks.kh; ra=k ; f=klerk{k ; f=kurk{k
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
17. ,d fn, x, fØLVy ds fy, tkyd çkpky a = 8.42 Å, b = 8.42 Å and c = 9.80 Å gSA muds funsZ'kh; v{k ,d nwljs
ds vU;ksU; :i ls yEcor gSaA fØLVy fuEu gSA
(A*) f}leyack{k (B) fo"keyack{k (C) ,durk{k (D) f=kdks.kh;
18. fØLVy foek a = b  c ;  =  = 900  = 1200 çnf'kZr djrh gSA

(A) f}leyack{k (B*) "kV~dks.kh; ra=k (C) ,durk{k (D) fo"keyack{k
19. fuEu esa ls fdl ,dd dksf"Bdk ds fy, lcls de leferrk gS \

(A) f}leyack{k (B) ,durk{k (C*) f=kurk{k (D) ?kuh;
20. fups fn;s x;s ,dd dksf"Bdkvksa esa ls fdlesa lokZf/kd leferrk gS \
(A) "kV~dks.kh; (B) fo"keyEck{k (C*) ?kuh; (D) ,durk{k
PAGE NO.- 12

JP XII Physical&Inorganic Chemistry (5) - Prev Class XI Chaps + Solution & Colligative Properties +solid State PDF

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PHY./INO.

TARGET : JEE (Main + Advanced) 2017

This DPP is to be discussed in the week (27-04-2015 to 02-05-2015)

1. Consider the reaction

4. For the reaction at 25°C, X2O4()  2XO2(g)

8. Which of the following has highest electron affinity ?

13. Standard molar enthalpy of formation of CO 2 is equal to -

14. The most unsymmetrical crystal system is:

15. The number of crystal systems known are :

Correct matching of A and B is in alternate :

A rFkk B dk lgh feyku fuEu fodYi esa gSA

(C*) H = 0 (D) W = nCVT

(C*) H = 0 (D) W = nCVT

6. Which of the following are isostructural ?

Sol. (I) (II) (III)

Sol. For very large value of molar volume (Vm)

(h) 5pz (i) 3dyz (j) 4 dz2

Crystal Axial Axial angles Examples Type of Unit cells

Cubic ; Tetragonal ; Orthorhombic ; Monoclinic ;

Hexagonal ; Rhombohedral ; Triclinic

18. The crystal dimensions a = b  c ;  =  = 900  = 1200 represents

19. Which of the following unit cells has least symmetry ?

?kuh; ; f}leyack{k ; fo"keyack{k ; ,durk{k ;

"kV~dks.kh; ra=k ; f=klerk{k ; f=kurk{k

18. fØLVy foek a = b  c ;  =  = 900  = 1200 çnf'kZr djrh gSA

19. fuEu esa ls fdl ,dd dksf"Bdk ds fy, lcls de leferrk gS \

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