PHY./INO.

CHEMISTRY

TARGET : JEE (Main + Advanced) 2016

Course : VIJETA (JP) Date : 25-05-2015 NO. 14

TEST IN FORMATI ON

DATE : 07.06.2015 CUMULATIVE TEST (CT) - 1 (ADVANCED)

Syllabus : Solution & Colligative Properties, Solid State, Coordination Compounds (up to VBT),
Thermodynamics, Ionic equilibrium, s-Block Element (All ChemInfos and Handouts till date)

This DPP is to be discussed in the week (25-05-2015 to 30-05-2015)

DPP No. # 14 (JEE-ADVANCED)
Total Marks : 63 Max. Time : 40 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.5 (3 marks, 2 min.) [15, 10]
Multiple choice objective ('–1' negative marking) Q.6 to Q.7 (4 marks, 2 min.) [08, 04]
Subjective Questions ('–1' negative marking) Q.8 to Q.11 (4 marks 3 min.) [16, 12]
Match the Following (no negative marking) Q.12 (8 marks, 6 min.) [08, 06]
ChemINFO : 4 Questions ('–1' negative marking) Q.13 to Q.16 (4 marks, 2 min.) [16, 08]

1. When the complex K6 [(CN)5 Co–O–O–Co(CN)5] is oxidised by bromine into

K5[(CN)5 Co–O–O–Co(CN)5]. Then which of the following statements will be true about this change:
(In both complex Co have t2g6, eg0,0 configuration) :
tc ladqy K6 [(CN)5 Co–O–O–Co(CN)5] czksehu }kjk K5[(CN)5 Co–O–O–Co(CN)5] esa vkWDlhd`r gksrk gS] rks bl
ifjorZu ds lanHkZ esa fuEu esa ls dkSulk dFku lgh gS &
(nksuksa ladqyksa esa Co dk foU;kl t2g6, eg0,0 gS) :
(A) Co() is oxidised in Co() (B) The O–O bond length will increase
(C*) The O–O bond length will decrease (D) ‘A’ & ‘B’ both are correct
(A) Co(), Co() esa vkWDlhd`r gksrk gSA (B) O–O ca/k yEckbZ esa o`f) gksxhA
(C*) O–O ca/k yEckbZ esa deh gksxhA (D) ‘A’ o ‘B’ nksuks lgh gSaA
Sol. (C) In the first complex, ligand is O22– which is oxidised into O 21– hence, O – O bond length decreases.
(C) izFke ladqy esa O22– fyxs.M gSa] tks O21– esa vkWDlhd`r gksrk gSa] bl izdkj O – O cU/k yEckbZ de gksxhA

2. 120 g Mg was burnt in air to give a mixture of MgO and Mg3N2. The mixture is now dissolved in HCl to form
MgCl2 and NH4Cl, if 107 grams NH4Cl is produced. Then, the moles of MgCl2 formed is :
(A) 3 moles (B) 6 moles (C*) 5 moles (D) 10 moles
120 g Mg ok;q esa tydj MgO rFkk Mg3N2 dk ,d feJ.k nsrh gSA tc feJ.k dks HCl esa ?kksyk tkrk gS] rks MgCl2 rFkk
NH4Cl mRikfnr gksrs gSaA ;fn 107 xzke NH4Cl curk gS rks MgCl2 ds fdrus eksy cusxas %
(ijek.oh; Hkkj Mg = 24, N = 14, Cl = 35.5)
(A) 3 eksy (B) 6 eksy (C*) 5 eksy (D) 10 eksy
1
Sol. Mg + O  MgO , 3Mg + N2  Mg3 N2
2 2
(5  a )
a a (5 – a)
3

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 1
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
 MgO + 2HCl  MgCl2 + H2O Mg3 N2 + 8HCl  2NH4Cl + 3MgCl2

5a 2 (5  a )
a a (5 – a)
3 3
 Total moles of MgCl2 = a + (5 – a) = 5 moles
Alternatively :
Apply POAC on Mg
Mg  MgCl2
5 moles x moles
1×5=x×1  x = 5 moles
1
g y- Mg + O  MgO , 3Mg + N2  Mg3 N2
2 2
(5  a )
a a (5 – a)
3
MgO + 2HCl  MgCl2 + H2O Mg3 N2 + 8HCl  2NH4Cl + 3MgCl2

5a 2 (5  a )
a a (5 – a)
3 3
 MgCl2 ds dqy eksy = a + (5 – a) = 5 eksy
Alternatively :
Mg ij POAC yxkus ij
Mg  MgCl2
5 eksy x eksy
1×5=x×1  x=5 eksyA

3. If the number of molecules of SO2 (atomic weight = 64) effusing through an orifice of unit area of cross-section
in unit time at 0°C and 1 atm pressure is n. The number of He molecules (atomic weight = 4) effusing under
similar conditions at 273°C and 0.25 atm is
0ºC vkSj 1 atm nkc ij ;fn ,d NksVs fNnz ds vuqizLFk dkV ds izfr bdkbZ {ks=kQy ls izfr bdkbZ le; esa fNnz ls fulfjr
(effused) gq, SO2 ds (ijek.kq Hkkj = 64) eksyksa dh la[;k n gSA leku ifjfLFkfr;ks 273°C vkSj 0.25 atm ij fulfjr He
(ijek.kq Hkkj = 4) ds v.kqvksa dh la[;k gksxhA
n n
(A*) (B) n 2 (C) 2n (D)
2 2

PSO2
Sol. Rate of effusion of SO2 
T1  MSO2

1
 n (1)
273  64
Similarily, rate of effusion of He through same orifice be x molecule per unit time.
PHe
So, x
T2  MHe

1/ 4
 n (2)
273  2  4
Now (2) ÷ (1)
x 1 273  64 x 1 n
= × =  x=
n 4 273  2  4 1 n 2 2

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 2
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
4. The pH of 1.0 M NaHSO 4 solution will be (given that K1 and K2 for H2SO4 equal to  and 10–2 respectively)
(A*) nearly 1.0 (B) between 2 and 3 (C) between 1.2 and 1.8 (D) between 3 and 4
1.0 M NaHSO4 foy;u dh pH D;k gksxh \ (fn;k gS fd H2SO4 ds fy, K1 and K2 dk eku Øe'k%  o 10–2 gS)
(A*) yxHkx 1.0 (B) 2 o 3 ds e/; (C) 1.2 o 1.8 ds e/; (D) 3 o 4 ds e/;
– + 2–
Sol. HSO4 H + SO 4

2C 2 1
10–2 = =
1  1 
  = 9.5 × 10–2
 H+ = 9.5 × 10–2 and pH = 1.02.

5. The coordination number of a central metal atom of a complex is :

,d ladqy ds dsUnzh; /kkrq ijek.kq dh leUo; la[;k (coordination number) fuEu ds }kjk fu/kkZfjr dh tkrh gSA
(A) The number of only anionic ligands bonded to the metal ion.
/kkrq vk;u ls caf/kr dsoy] _.kvk;fud fyxs.Mksa dh la[;k }kjk
(B) The number of ligands around a metal ion bonded by  bonds.
/kkrq vk;u ds pkjksa vksj  ca/kksa ls caf/kr fyxs.Mksa dh la[;k }kjk .
(C) The number of ligands around a metal ion bonded by  and  bonds both.
/kkrq vk;u ds pkjksa vksj  rFkk  ca/kksa ls caf/kr fyxs.Mksa dh la[;k }kjk
(D*) The number of  bonds between ligands & central metal atom.
dsUnzh; /kkrq ijek.kq rFkk fyxs.M ds e/;ca/kksa dh la[;k }kjk
Sol. By defination. ifjHkk"kk lsA

6.* Which of the following statement(s) is/are true

fuEufyf[kr esa ls dkSulk@dkSuls dFku lR; gS@gSa \
(A*) Chelation effect is maximum for five and six membered rings.
oy;dj.k izHkko (Chelation effect) ik¡p rFkk N% lnL; oy; ds fy, vf/kdre gksrk gSA
(B*) Chelating ligands are at least bidentate ligand.
oy;dkjd fyxs.M (Chelating ligands) de ls de f}nUrqd fyxs.M gksrs gSa
(C*) As the number of rings in a complex increase stability of complex (Chelate) also increases.
ladqy esa oy;ksa dh la[;k esa o`f) ds lkFk ladqy (fdysV) (Chelate) ds LFkkf;Ro esa Hkh o`f) gksrh gSA
(D) Azide ion (N3–) has two N as donor atoms and behaves as a chelating ligand.
,tkbM vk;u (N3–) nkrk ijek.kqvksa ds :i esa nks N ijek.kq j[krk gS rFkk ,d oy;dkjd fyxs.M ds leku O;ogkj djrk
gSA
Sol. Azide ion (N3–) does not act as bidenate ligand because it is linear and it is not possible to donate both the
electrons simultaneously to same metal ion/atom.
,tkbM vk;u (N3–) f}nUrqd fyxs.M ds leku O;ogkj ugha djrk gS D;ksfd ;g js[kh; vk;u gSA blfy, ,d gh lkFk nksuksa
,dy bysDVªkWu ;qXeksa ds }kjk cU/k dk fuekZ.k lEHko ugha gSaA

7. It is an experiment fact that :

DMG + Ni()salt + NH4OH  Red ppt.

Which of the following is/are true about this red ppt :
;g ,d izk;ksfxd rF; gS fd &
DMG + Ni() yo.k + NH4OH  yky vo{ksi
bl yky vo{ksi ds lanHkZ esa fuEu esa ls dkSuls dFku lR; gS@gSa &
(A*) It is a non–ionic complex (B*) It involves intra molecular H–bonding
(C) Ni() is sp3 hybridised (D*) It is a diamagnetic complex
(A*) ;g ,d vu&vk;fud ladqy gSA (B*) blesa var% vkf.od H–ca/ku lfEefyr gSA
3
(C) Ni() sp
ladfjr gSA (D*) ;g ,d izfrpqEcdh; ladqy gSA
Sol. The complex is ladqy gS

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 3
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
8. Write IUPAC names of the following
fuEu ds fy, IUPAC uke fyf[k,&
(a) [Co(NH3)6][CuCl5] (b) [V(H2O)6]Cl3 (c) (NH4)3[Co(C2O4)3]

(d) Cl4 (e) (f) Na2[SiF6]

(g) K2 [CrO4] (h) [(NH3)5Cr – OH – Cr(NH3)5]Cl5 (i) [Fe(en)3] [Fe(CO)4]

(j) [TiCl4(Et2O)2] (k) Mn2(CO)10 (l) [VO(acac)2] (m) Fe4 [Fe(CN)6]3
Ans. (a) Hexaamminecobalt(III) pentachloridocuprate(II)
(b) Hexaaquavanadium(III) chloride
(c) Ammonium tri(oxalato)cobaltate(III)
(d) Tetraamminecobalt(III)-di- -hydroxidobis(ethylenediamine)cobalt(III) chloride
(e) Bis (ethylenediamine) cobalt (III)--imido--hydroxidobis(ethylenediamine) cobalt (IV) ion
(f) Sodium hexafluoridosilicate(IV)
(g) Potassium tetraoxidochromate(VI)
(h) -hydroxidobis-(pentaamminechromium(III)) chloride
(i) Tris(ethylene diamine) iron (III) tetracarbonyl iron (–III) (metal in this complex can also be iron (II))
(j) Tetrachloridobis(diethylether)titanium(IV)
(k) Decacarbonyldimanganese(0)
(l) Bis(acetylacetonato)oxidovanadium(IV)
(m) Iron (III) hexacyanido-C-ferrate(II) (also called Prussian blue)

9. Write the structural formula corresponding to each of the following IUPAC names :
(a) hexaamminechromium (III) tetrachloridocuprate (II) (b) diamminedichloridoplatinum (II)
(c) tetracarbonyl nickel(0)
(d) tetraammineplatinum(II) amminetrichloridoplatinate (II) (e) sodium dithiosulphatoargentate(I)
(f) potassium tetracyanido-C-nickelate(0) (g) bis( 5  cyclopentadienyl)iron (II)
(h) tetrathiocyanato-N-zincate (II) ion (i) potassium tetraoxidomanganate(VII)
(j) potassium trioxalatoaluminate (III)
(k) tetrapyridineplatinum (II) tetrachloridoplatinate (II)
fuEu IUPAC uke ds laxr izR;sd ds lajpuk lw=k dks fyf[k,&
(a) gSDlk,EehuØksfe;e(III) VsVªkDyksjkbMksD;wizsV(II) (b) Mkb,EehuMkbDyksjkbMksIysfVue(II)
(c) VsVªkdkcksfZ uyfudy(0) (d) VsVªk,EehuIysfVue(II) ,EehuVªkbDyksjkbMksIysfVusV(II)
(e) lksfM;e MkbFkk;kslYQsVksvtsZUVsV (I) (f) iksVSf'k;eVsVªklk;ukbMks-C-fudysV(0)
(g) fcl~(5 –lkbDyksisUVkMkbbukby) vk;ju(II) (h) VsVkª Fkk;kslk;usVks-N-ftUdsV(II) vk;u
(i) iksVSf'k;eVsVªkvkWDlkbMkseSaxusV(VII) (j) iksVSf'k;eVªkbvkWDlsysVks,Y;qfeusV (III)
(k) VsVªkfijhMhuIysfVue(II) VsVªkDyksjkbMksIysfVusV(II)
Ans. (a) [CrIII(NH3)6]2[CuIICl4]3 (b) [PtIICl2(NH3)2] (c) [Ni0(CO)4]
II II
(d) [Pt (NH3)4][Pt Cl3NH3]2 I
(e) Na3[Ag (S2O3)2] (f) K4[Ni0(CN)4]
5
(g) Fe[ – C5H5]2
5 means that all the five carbon atoms of cyclopentadienyl anion are coordinated to the metal ion

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 4
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
 (h) [ZnII(NCS)4]2– (i) K[MnVIIO4] (j) K3[AllII(C2O4)3] (k) [PtII(Py) 4][PtIICl4].

CH2OH
10. To 100g of water some ethylene glycol ( | ) was added and the solution was cooled to 100C when 20g
CH2OH

of ice was separated. What was the amount of ethylene glycol added to water? What will be its boiling point?
(Kf for water is 1.86 and Kb is 0.513).
CH2OH
ty ds 100g esa dqN ,fFkyhu XykbdkWy ( | ) dks feyk;k x;k rFkk foy;u dks 100C rd B.Mk dj fn;k x;k rks
CH2OH

20g cQZ i`Fkd gks tkrh gSA ty esa ,fFkyhu XykbdkWy dh D;k ek=kk feyk;h xbZ Fkh rFkk bldk DoFkukad D;k gksxk \
(ty ds fy, Kf = 1.86 rFkk Kb = 0.513).
Sol. Tf = Kf m
W / 62
10  80  62
10 = 1.86 × 80  W= = 26.67 gm
1000 1.86  1000

10
Tb = 0.513 × = 2.76ºC
1.86
Tb = 100 + Tb = 100 + 2.76 = 102.76ºC

11. A horizontal piston-cylinder arrangement is placed in a constant T bath. The piston slides in the cylinder with
negligible friction, and an external force holds it in place against an initial gas pressure of 14 bar. The initial
gas volume is 0.03 m 3.
(a) The external force on the piston is reudced gradually, allowing the gas to expand until its volume doubles.
Calculate the work done by the gas in moving the external force.
(b) How much work would be done if the same expansion is carried out by removing a part of the external
force suddenly. Also calculate efficiency of this process as compared with the reversible process.
,d {ksfrt fiLVu ;qDr flys.Mj O;oLFkk dks ,d fu;r rki LFkk;h ik=k esa j[kk tkrk gSA fiLVu] flys.Mj es a ux.; ?k"kZ.k
ds lkFk xfreku jgrk gS rFkk 14 bar ds xSl ds nkc ds fo:) ,d ckÐ; cy jksds (holds) jgrk gSA xSl dk izkjfEHkd
vk;ru 0.03 m 3 gSA
(a) fiLVu ij ckÐ; cy /khjs&/khjs de fd;k tkrk gS rFkk xSl dks bldk vk;ru nqxquk gksus rd izlkfjr gksus fn;k tkrk
gSA xfreku ckÐ; cy esa xSl }kjk fd;s x;s dk;Z dh x.kuk fdft;sA \
(b) ;fn leku izlkj] ckÐ; cy ds ,d Hkkx dks vpkud ls de djds] fd;k tk, rc fdruk dk;Z fd;k tk,xk\ mRØe.kh;
izØe dh rqyuk esa bl izØe dh n{krk dh x.kuk Hkh dhft, \
V2
Sol. (a) W = – nRT ln V
1

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 5
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
 V2 0.06
W = – P1V1 ln V = – 14 × 0.03 ln bar m 3
1 0.03
= – 14 × 0.693 × 0.03 = – 0.29 bar m3 Ans.
(b) P1V1 = P2V2
P1V1 14  0.03
 P2 = V = = 7 bar
2 0.06
 W = – Pext (V2 – V1) = – 7 (0.06 – 0.03) = – 7 × 0.03 = – 0.21 bar m 3.
0.21
Efficiency = = 72% Ans.
0.29

12. Match the column :

feyku dhft,&
Column () Column ()
dkWye () dkWye ()
(A) O2, O2+, O2– (p) Diamagnetic izfrpqEcdh;

(B) O22–, C2 ,C22– (q) Same bond order leku ca/k Øe

(C) N2 ,CO, NO+ (r) Paramagnetic vuqpqEcdh;

(D) He2, Be2, B22+ (s) Isoelectronic lebysDVªksfud

Ans. [A – r] ; [B – p] ; [C – p,q,s] ; [D – q,p].
Sol. Z  7 1s , 1s* ,2s ,2s* , 2px = 2py , 2pz , *2px = *2py , *2pz
O2  No. of unpaired electron = 2 B.O. = 2
O2+  No. of unpaired electron = 1, B.O. = 2.5
O2–  No. of unpaired electron =1, B.O. = 1.5
O22–  No. of unpaired electron = O = B.O. = 
C2  No. of unpaired electron = O = B.O. = 2
C22–  No. of unpaired electron = O = B.O. = 3
N2 , CO , NO+ = No. of unpaired e– = O.B.O. = 3
He2 , Be2 B22– All have same bond order equal to zero.
He2, Be2 B22– lHkh leku ca/k Øe 'kwU; j[krs gSA

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 6
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
 ChemINFO-1.10 COORDINATION COMPOUNDS
Daily Self-Study Dosage for mastering Chemistry Coordination Compounds in Qualitative Analysis
Coordination compounds find use in many qualitative chemical analysis. The familiar colour reactions given by
metal ions with a number of ligands, as a result of formation of coordination entities, form the basis for their
detection and estimation by classical methods of analysis. Some important examples are:
Formula : IUPAC Name and Colour : Remark & Common Name
(a) [Cu(NH3)4]SO4 Tetraamminecopper(II) sulphate: deep blue: obtained when CuSO4 is
treated with excess of NH3
(b) Co(gly)3 tris(glycinato)cobalt(III): Purple didentate ligand of anion of
amino acid glycine
(c) [Fe(H2O)5(SCN)]2+ Pentaaquathiocyanato–S–iron(III): Red: formed in detection of Fe3+ ion
(d) K2[HgI4] Potassium tetraiodidomercurate(II):Faint Yellow CrystalsAlkaline solution of
this complex is called
Nessler’s Reagent, used in
detection of NH3
(e) Co[Hg(SCN)4]: Cobalt(II) tetrathiocyanato–S–mercurate(II): deep blue: crystalline p recipitate
obtained in qualitative
detection of Hg2+
(f) Fe4[Fe(CN)6]3 Iron(III) hexacyanidoferrate(II): Prussian blue: Ferriferrocyanide obtained in
detection of Fe2+
(g) K3[Co(NO2)6] Potassium hexanitrito–N–cobaltate(III): yellow: precipitate ob tain ed in
detection of Co2+
(Fischer salt)
(h) [Ni(dmg)2] Bis(dimethylglyoximato)nickel(II): Rosy red: precipitate obtained in
detection of Ni2+ ions
(i) K2[PtCl6] Potassium hexachloridoplatinate(IV): Yellow: precipitate obtained in
detection of K+ ions
(j) Na2[Fe(CN)5NO+] Sodium pentacyanidonitrosoniumferrate(II): Red Sodium nitroprusside used
in detection of S2– ions or
sulphur
(k) [Fe(H2O)5(NO+)]SO4 Pentaaquanitrosoniumiron(I) sulphate: Brown ring obtained in detection of Fe2+
ion
(l) [Cu(CN)4]3– Tetracyanidocuperate(I): Colourless: stable soluble complex
obtained in detection of Cu2+
on adding excess of KCN
solution
(m) (NH4)2[PtCl6] Ammonium hexachloridoplatinate(IV): yellow: one of the only few compounds
of NH4+ ion which precipitates

Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.

13. What is the oxidation state of Fe in the brown ring complex?

(A) 0 (B*) 1 (C) 2 (D) 3

14. Select the correct option for the rosy red complex obtained in the detection of Ni 2+.
(A) Coordination number of Ni is 4 (B) The complex is square planar
(C) Chelating ligand is present in the complex (D*) All of the above are correct

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 7
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
15. Which of the following complexes is not blue?
(A) Co[Hg(SCN)4] (B) Fe4[Fe(CN)6]3 (C) [Cu(NH3)4]SO4 (D*) [Fe(H2O)5(SCN)]2+

16*. Which of the following precipitates are yellow?

(A*) K3[Co(NO2)6 (B) [Fe(H2O)5(NO+)]SO4
(C*) (NH4)2[PtCl6] (D*) K2[PtCl6]

ChemINFO-1.10 COORDINATION COMPOUNDS

Daily Self-Study Dosage for mastering Chemistry xq.kkRed fo'ys"k.k esa milgla;kstu ;kSfxd
milgla;kstu ;kSfxdksa dk mi;ksx cgqr ls xq.kkRed jklk;fud fo'ys"k.k esa fd;k tkrk gSA /kkrq vk;u }kjk vfHkfØ;k esa mRiUu jax]
ds leku jax fyxs.Mksa dh fuf'pr la[;k ds lkFk] milgla;kstu xksyd ;k Hkkx ds fuekZ.k ds dkj.k iznf'kZ r fd, tkrs gSaA bl
vk/kkj ij budh igpku rFkk fu"d"kZ.k] fo'ys"k.k dh :<+ ;k ikjEifjd fof/k;ksa }kjk gksrk gSA
lw=k : IUPAC uke rFkk jax : fcUnq rFkk lkekU; uke
(a) [Cu(NH3)4]SO4 VªsVk,ehudkWij (II) lYQsV : xgjk uhyk : tc NH3 ds vkf/kD; eas CuSO4 ds
lkFk fØ;k gksrh gS rks xgjk uhyk ;kSfxd
izkIr gksrk gSA
(b) Co(gly)3 fVªl (XykflusVks½dksckYV(III): tkequh ,ehuks vEy Xykblhu ds _.kkRed dk
f}nUrqd fyxs.M
(c) [Fe(H2O)5(SCN)]2+ isUVk,DokFkk;kslk;usVk–S–vk;ju(III): yky: Fe3+ vk;u ds fo'ys"k.k esa izkIr gksrk gSA
(d) K2[HgI4] fØLVy bl ladqy dk {kkjh; foy;u] uslyj
vfHkdeZd dgykrk gS] tks NH3 ds fo'ys"k.k
esa iz;qDr gksrk gSA
(e) Co[Hg(SCN)4]: Hg2+ ds xq.kkRed fo'ys"k.k eas xgjk uhyk
fØLVyh; vo{ksi izkIr gksrk gSA
(f) Fe4[Fe(CN)6]3 vk;ju(III)gsDlklk;ukbMksQsjsV(II): izqf'k;e uhyk: Fe2+ ds fo'ys"k.k eas QsjhQsjks lk;ukbM izkIr
gksrk gSA
(g) K3[Co(NO2)6] iksVsf'k;e gsDlkukbVªkbVks–N–dksckYVsV(III): ihyk: Co2+ ds fo'ys"k.k esa ihyk vo{ksi izkIr gksrk
gSA ¼fQ'kj yo.k½
(h) [Ni(dmg)2] fcl(MkbZesfFkyXykbZvkWfDlesVks)fudy(II): xqykch yky: Ni2+ vk;uksa ds fo'ys"k.k esa xqykch yky
vo{ksi izkIr gksrk gSA
(i) K2[PtCl6] iksVsf'k;e gsDlk DyksjhMksIysfVusV(IV): ihyk: K+ vk;uksa ds fo'ys"k.k esa ihyk vo{ksi izkIr
gksrk gSA
(j) Na2[Fe(CN)5NO+] lksfM;e isUVklk;ukbMksukbVªkslksfu;eQsjsV(II): yky S2– vk;u ;k lYQj ds fo'ys"k.k esa lksfM;e
ukbVªksizqlkbM iz;qDr gksrk gSA
(k) [Fe(H2O)5(NO+)]SO4 isUVk,DokukbVªkslksfu;evk;ju(I) lYQsV: Hkwjh foy; Fe2+ vk;u ds fo'ys"k.k esa izkIr gksrk gSA
(l) [Cu(CN)4]3– VsVªklk;ukbMksD;qizsV(I): jaxghu: KCN foy;u dks vkf/kD; esa feykus ij
2+
Cu ds fo'ys"k.k esa ;g LFkk;h jaxghu
foys;'khy ladqy ds :i esa izkIr gksrk gSA
(m) (NH4)2[PtCl6] veksfu;e gsDlkDyksjhMksIysfVusV(IV): ihyk: veksfu;e vk;uksa ds dqN gh ;kSfxd ds
vo{ksi izkIr gksrs gSaA

Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 8
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029
13. Hkwjh oy; okys ladqy eas Fe dh vkWDlhdj.k voLFkk D;k gS?
(A) 0 (B*) 1 (C) 2 (D) 3

14. Ni2+ds fo'ys"k.k esa cus xqykch yky ladqy ds fy, fodYi dk p;u dhft,A
(A) Ni dh leUo; la[;k 4 gSA (B) ladqy oxZleryh; gSA
(C) ladqy esa fdysV fyxs.M mifLFkr gSA (D*) mDr lHkh fodYi lgh gSaA

15. fuEu esa ls dkSulk ladqy uhys jax dk ugha gS?

(A) Co[Hg(SCN)4] (B) Fe4[Fe(CN)6]3 (C) [Cu(NH3)4]SO4 (D*) [Fe(H2O)5(SCN)]2+

16*. fuEu esa ls dkSuls vo{ksi ihys gSa?

(A*) K3[Co(NO2)6 (B) [Fe(H2O)5(NO+)]SO4
(C*) (NH4)2[PtCl6] (D*) K2[PtCl6]

Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 9
Toll Free : 1800 200 2244 | 1800 258 5555| CIN: U80302RJ2007PTC024029