Process Description and PFDs PDF

Lummus Petrochemicals
Bloomfield, NJ
CLIENT HMEL (HPCL Mittal Energy Ltd) 222334 Process Description

PROJECT Petrochemical Complex Proj. No. DOCUMENT NAME
2.4 Process Description

The following is a brief description of the processing scheme for this proposal, as shown on the Process
Flow Diagrams.
2.4.1 Refinery Off Gas (ROG) Treating Unit

A combined stream of refinery off gas (ROG) from the PFCC and DCU is routed to the ROG Treating
Unit. A mixed LPG produced in the refinery is also fed to the ROG to be used as wash liquid. The ROG
Treating Unit provides the following products:
 ROG Fuel Gas which is sent to the SCU Fuel Gas System
 C2/C3 stream that is fed to the SCU Deethanizer
 C4+ stream that is fed to the Total Hydrogenation Unit (THU)
2.4.1.1 ROG Amine System

The refinery off gas from OSBL is delivered to the ROG Treating Unit on flow control at the battery limit
2
conditions of 9.5 kg/cm g and 40ºC which is then sent to the ROG DGA/Water Wash Column for bulk
removal of CO2 and H2S. An online analyzer on the main feed detects the composition of the refinery off
gas feed including levels of acid gas (CO2 and H2S).
The ROG DGA/Water Wash Column is comprised of two sections. The top portion consists of bubble cap
trays which serve as a water wash section to prevent amine entrainment in the overhead product. Wash
water for the ROG DGA/Water Wash Column comes from the Continuous Blowdown Cooler located in
the SCU. Waste water from the water section (bubble cap trays) is totally drawn off the bottom most tray
and sent to Neutralization (OSBL). The bottom portion is comprised of packed beds and serves as the
amine wash section.
A lean Diglycoamine (DGA) solution, supplied by the DGA Regenerator, is fed to the top of the amine
wash section above the packed beds. The water wash in the top section prevents carry-over of Lean
DGA into the rest of the system. The refinery off gas is fed below the bottom section of the column where
the acid compounds (H2S and CO2) are absorbed into the Lean DGA solution by countercurrent contact
as the vapor continues up the tower. The bottom of the tower will have a higher temperature, due to the
heat of absorption. The overhead of the ROG DGA/Water Wash Column is sent to ROG Caustic/Water
Wash Tower.
Any oils that form in the absorption process can be skimmed off the liquid level in the sump of the ROG
DGA/Water Wash Column and sent to ROG DGA Oil Degassing Drum. Overhead vapor from Degassing
Drum is sent to Wet Flare, while any liquid is sent to the Amine Drain system.
Acid gas leaves the ROG DGA/Water Wash Column bottoms with the rich amine solution where it is sent
to the DGA Regenerator HP Flash Drum. Liquid hydrocarbons are separated out from the amine
solution and sent to the Quench Tower. The Rich DGA from the flash drum is then preheated against the
hot bottoms (regenerated Lean DGA) of the regenerator in the Lean DGA/Rich DGA Exchanger.
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The DGA Regenerator is comprised of bubble cap trays in the top section and packed beds in the middle
and bottom sections. The Rich DGA from the ROG DGA/Water Wash Column is fed to the top of the
packed bed section, and makeup DGA combined with makeup water is fed to the bottom of the
regenerator. The reboiler duty for the regenerator is provided by controlling the amount of LP Steam sent
to the DGA Regenerator Reboiler. The gross overhead from the DGA Regenerator is condensed against
cooling water in the DGA Regenerator Condenser and collected in the DGA Regenerator Reflux Drum.
The DGA Regenerator pressure is controlled by throttling the acid gas vented from the reflux drum, and a
secondary pressure controller introduces nitrogen to the overhead line if the pressure becomes too low.
Any liquid that condenses is pumped by the DGA Regenerator Reflux Pumps and sent as reflux to the top
of the tower. Acid gases are vented off the reflux drum and sent to the Acid Gas Flare.
The bottoms of the DGA Regenerator, Lean DGA, is pumped and cooled by exchanging heat with Rich
DGA feed in the Lean DGA/Rich DGA Exchanger. The Lean DGA is cooled further against cooling water
in the Lean DGA Cooler before being filtered. The Lean DGA is then recycled back to the ROG
DGA/Water Wash Column.
A provision is included the remove heat-stable salts formed in the amine system via the DGA Reclaimer.
The exchanger is used in batch operation utilizing MP steam to evaporate the DGA solution, leaving
behind DGA sludge to be drained to drums and sent for disposal OSBL.
2.4.1.2 ROG Caustic Treatment and Oxygen Converter

A caustic wash removes acid gases (H2S and CO2) by reaction and a non-regenerable waste caustic
stream is created. While the amine treatment is used to remove the bulk amount of the acid gases, the
caustic treatment brings down acid gases down to specifications levels.
The ROG Caustic/Water Wash Tower operates similarly to the SCU Caustic/Water Wash Tower except
the one in the Refinery Off Gas unit functions as two separate caustic/water sections. The overhead from
the ROG DGA/Water Wash Column is sent to the lower section of the ROG Caustic/Water Wash Tower.
The refinery off gas is washed in the lower packed section with weak level caustic to remove CO2 and
H2S. The treated gas is then washed with water in bubble cap trays to prevent caustic carryover. Wash
water for the tower comes from the Continuous Blowdown Cooler located in the SCU. Waste water from
the lower water section (bubble cap trays) is totally drawn off below the bottom most tray and sent to
Waste Water Treatment (OSBL). The refinery off gas vapor is then totally drawn off and sent to the ROG
Oxygen Converter Feed/Effluent Exchanger. On-line analyzers are provided to detect the amounts of
CO2 and H2S entering and leaving this section of ROG Caustic/Water Wash Tower.
The refinery off gas is heated in the ROG Oxygen Converter Feed/Effluent Exchanger and by High
Pressure (HP) Steam in the ROG Oxygen Converter Feed Heater. The hot refinery off gas is passed
through the ROG Oxygen Converter. The catalyst selectivity is moderated by injecting Dimethyl Disulfide
(DMDS) upstream of the ROG Oxygen Converter Feed Heater which is eventually removed in the upper
portion of the ROG Caustic/Water Wash Tower.
The Oxygen Converter catalyst primarily removes oxygen, acetylene, and NOx by reaction to other
species. Oxygen is converted to water and NOx is converted to ammonia and water. The Oxygen

Bloomfield, NJ

Converter also hydrogenates acetylene to ethane and ethylene. The scheme provides a spare reactor
bed for in situ regeneration of the catalyst. On-line analyzers are provided to detect the amounts of C2H2,
C2H4, CO, O2, and NOX, entering and leaving the O2 Converter.
The hot oxygen-free refinery off gas effluent is cooled by cross-exchange in the ROG Oxygen Converter
Feed/Effluent Exchanger. Purge gas recycles from OSBL LLDPE, HDPE and PP units and a vent stream
from the DGA Regenerator HP Flash Drum are compressed by the reciprocating Recycle Gas
Compressor and mixed with the hot oxygen-free refinery off gas before being cooled against cooling
water in the ROG Oxygen Converter Effluent Cooler. The combined streams are then sent to the upper
caustic/water wash section of the ROG Caustic/Water Wash Tower.
The recycle purge streams contain amounts of ethylene and propylene that can be recovered. However,
the recycle streams also contain NOx that may form unstable gums and salts which can result in
exchanger plugging, dangerous reactions during upsets, and reactions forming ammonia salts. By
directing the recycle purge streams back to the ROG Caustic/Water Wash Tower it ensures that the
ethylene and propylene will be recovered also ensuring that the NOx will be removed from the refinery off
gas by the ROG Oxygen Converter before entering the SCU. The ROG has the capability to handle the
external NOx from the purge streams.
The oxygen free refinery off gas and recycle purge gas streams are washed with strong level caustic in a
packed section. This section ensures near complete removal of CO2 and H2S. The acid free ROG vapor
flows to a water wash section comprised of bubble cap trays. Wash water for the tower comes from the
Continuous Blowdown Cooler located in the SCU. Waste water from the lower water section (bubble cap
trays) is totally drawn off below the bottoms most tray and sent to Waste Water Treatment (OSBL).
Strong caustic solution from the upper section of the ROG Caustic/Water Wash Tower is added to the
lower section caustic circulation to maintain the appropriate concentration of caustic solution. A net flow
of caustic from the bottom of this tower is sent to the SCU Spent Caustic Treatment.
Despite low diolefin concentration, polymeric oil (yellow oil) may form to some extent in the ROG
Caustic/Water Wash Tower. Provisions are made for this oil to be decanted from the tower bottom and
sent, along with the spent caustic for treatment in the SCU.
The overhead of the upper section of the ROG Caustic/Water Wash Tower is chilled against 9°C
propylene refrigerant in the ROG Dryer/Treater Feed Chiller. The chilled effluent is sent to ROG
Dryer/Treater Feed Gas KO Drum where condensed water and/or hydrocarbon is knocked out sent to
Waste Water Treatment. The overhead from the KO Drum proceeds to the ROG Dryer/Treater.
The refinery off gas passes through ROG Dryer/Treater for drying and removal of trace impurities such as
water, NH3, COS, CO2, CS2, acetonitrile, aldehydes, and amines to less than 1 ppm (w). After treatment,
the treated refinery off gas is sent through a filter and then to the ROG Cold Box Exchanger No. 1.
One ROG Dryer/Treater is in operation while the second treater is being regenerated or on standby. On-
line analyzers are provided to detect the amounts of H2O, CO2, H2S, NOx, and NH3 entering and leaving
the treaters. A third probe is placed in the bottom portion of the adsorbent bed to detect breakthrough of
impurities.

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Regeneration of the ROG Dryer/Treater is accomplished by circulating hot methane-rich regeneration gas
from the Regeneration Electric Heater at 290°C and heating the bed in order to drive out impurities
adsorbed in the treater bed. The spent regeneration gas is returned to the fuel gas system. After the bed
has reached the required temperature, the bed is cooled with unheated regeneration gas.
2.4.1.3 Mixed LPG Treating

Mixed LPG from OSBL is delivered to the ROG Treating Unit at the battery limit conditions of 12.0
2
kg/cm g and 40ºC which is then passed through the LPG Treater for sulfur removal. The concentration of
the sulfur is reduced to specification levels. On-line analyzers are provided to detect the amounts of H2S
entering and leaving the treater. A third probe is placed in the top portion of the treater to detect
breakthrough of impurities. The treated LPG stream passes through another on-line analyzer for
detection of C2H4, C2H6, C3H6, C3H8, BD, C4s, and C5+ and then through a filter. The treated LPG is
combined with a portion of the Depropanizer heavies’ bottoms before entering the ROG Cold Box
Exchanger No. 1.
One LPG Treater is in operation while the second treater is being regenerated or on standby.
Regeneration of the LPG Treater is accomplished by heating the bed with 290°C regen gas in order to
drive out the impurities adsorbed in the treater bed. The spent regeneration gas is returned to the fuel
gas system. After the bed has reached the required temperature, the bed is cooled with unheated
regeneration gas.
2.4.1.4 Refining Off Gas Chilling & ROG Demethanizer

The treated refinery off gas and LPG enter the ROG Cold Box Exchanger No.1 where the streams are
progressively chilled by 4 levels of propylene refrigeration; the refrigeration levels range from 9°C to -
40°C. The refinery off gas and LPG proceed to the ROG Cold Box Exchanger No.2 in which they are
both chilled by binary refrigerant. The treated refinery off gas enters the ROG Demethanizer between
packed beds in the middle section of the tower. The LPG temperature is controlled to -90°C by
controlling the amount of binary refrigerant flows to ROG Cold Box Exchanger No.2. The LPG is then
mixed with reflux from the ROG Demethanizer Reflux Pumps and used as wash liquid in the ROG
Demethanizer.
In the ROG Demethanizer fractionation is based on the absorption principle whereby the ethylene and
heavier components are absorbed by the LPG wash liquid. The tower is comprised of packed beds and
the fractionation occurs on the basis of the absorption principle whereby the C2’s contained in the refinery
off gas are absorbed by the C3+ LPG Wash Liquid.
The gross overhead of the ROG Demethanizer is partially condensed by binary refrigerant in the ROG
Demethanizer Condenser which is also part of the ROG cold box package. The condenser effluent is
sent to the ROG Demethanizer Reflux Drum where any liquid that condenses is pumped by the ROG
Demethanizer Reflux Pumps as reflux back to the tower. The overhead from the reflux drum, called ROG
Fuel Gas, is comprised primarily of methane and lighter compounds where the temperature of this stream
is progressively heated in the ROG Cold Box Exchanger No. 2 and further heated in the ROG Cold Box
Exchanger No. 1. Once it is heated, the ROG Fuel Gas is sent to the SCU Fuel Gas System. The

Bloomfield, NJ

pressure in the ROG Demethanizer is accomplished by controlling the amount of this stream being sent
to the SCU fuel gas system.
The ROG Demethanizer Reboiler supplies heat to the tower by subcooling 48°C propylene refrigerant.
The temperature in the ROG Demethanizer is controlled by the amount of propylene refrigerant sent to
the reboiler. The LPG wash liquid along with C2 & heavier components from refinery off gas is pumped
from the bottom of the tower to the ROG Depropanizer. An on-line analyzer on this stream detects the
amount of methane that is found in this stream.
2.4.1.5 ROG Depropanizer

The ROG Demethanizer bottoms are pumped by the ROG Demethanizer Bottoms Pump to the ROG
Depropanizer. The gross overhead vapor of the tower is totally condensed in the ROG Depropanizer
Condenser by -27°C propylene refrigerant which is then sent to the ROG Depropanizer Reflux Drum.
Total liquid from the reflux drum is pumped by the ROG Depropanizer Reflux Pumps where a portion is
sent as reflux back to the tower. The balanced overhead liquid product, which contains C2 and C3
components, is sent to the SCU Deethanizer.
Tower reboiler duty is provided by Low Pressure (LP) Steam in the ROG Deethanizer Reboiler. A portion
of the ROG Depropanizer bottoms product, which contains C4 and heavier components, is sent to the
SCU Total Hydrogenation Unit (THU). The remaining balance of the ROG Depropanizer bottoms is sent
back to the ROG Demethanizer to be used as wash liquid.
An on-line analyzer is provided with probes in two locations which detect the top and bottom specification
of the ROG Depropanizer with measurements made for C1, C2, and C3 components. If any methane or
other non-condensable component makes its way to this tower, it will accumulate in the ROG
Depropanizer Reflux Drum. The pressure of the reflux drum is controlled by a pressure controller that
would regulate the amount of non-condensables sent back to the cold box for reprocessing. A hand
control (HC) provides the ability to vent the non-condensables to the Cold Flare in high pressure
scenarios.

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2.4.2 Steam Cracking Unit (SCU)

The Steam Cracker Unit (SCU) is designed to produce the following products and by-products:
 Polymer Grade Ethylene

 Polymer Grade Propylene
 PSA Quality Hydrogen Product
 Fuel Gas
 C5+ Pyrolysis Gasoline
 Carbon Black Feedstock
Capacity and Mode of Operation
The plant is designed for a production capacity of 1200 KTPA of Polymer Grade Ethylene and 500 KTPA
of Polymer grade Propylene (for Design Case-1) and 1200 KTPA of Polymer Grade Ethylene and 720
KTPA Polymer Grade Propylene(for Design Case-2) based on 8000 operating hours per year.
2.4.2.1 Furnace Feed System

Ethane recycle from the Cold Box Offgas Exchanger No. 6 is superheated in the Ethane Feed Preheater
against quench water prior to feeding into the cracking heaters.
For Design Case-1, the major portion of the propane recycle from the Propylene Fractionator No. 2 is
heated and vaporized in the Propane Feed Vaporizer by quench water. The vaporized recycle propane is
then superheated against quench water in the Propane Feed Heater.
For Design Case-1, a small amount of the propane recycle from the Propylene Fractionator No. 2 is
combined with hydrogenated C4/C5’s from the Total Hydrogenation Unit (THU) on flow control to balance
the feeds. For Design Case-2, all propane recycle is combined with the hydrogenated C4/C5’s and then
sent to the C4/C5 Feed Vaporizer Drum where they are vaporized by C4/C5 Feed Vaporizer. The
pressure in the C4/C5 Feed Vaporizer Drum is controlled by adjusting the LP Steam flow to the C4/C5
Feed Vaporizer. The vaporized cracker feed from the vaporizer drum is preheated against LP Steam in
the C4/C5 Feed Heater prior to entering the cracking heaters. Provisions to purge any heavy ends from
the C4/C5 Feed Vaporizer Drum are provided to minimize any fouling in the vaporizer.
Full range Naphtha from OSBL is delivered to the Steam Cracking Unit (SCU) at the battery limit
2
conditions of 9.0 kg/cm g and 40ºC which is then pumped by the Naphtha Feed Pumps, filtered and
combined with C6 raffinate from the Aromatics Extraction Unit (AEU) and C5 recycle from the Pyrolysis
Gasoline Hydrogenation Unit (PGH). The combined stream is preheated with quench water in the
Naphtha Feed Preheater before being sent to the cracking heaters.
Light Kerosene/Heavy Naphtha from OSBL is delivered to the SCU at the battery limit conditions of 6.0
2
kg/cm g and 40ºC which is then pumped by the Kero Feed Pumps, filtered and preheated with quench
water in the Naphtha Feed Preheater before being sent to the cracking heaters.

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2.4.2.2 Cracking Heaters

A total of seven SRT cracking heaters provide the cracking capacity of the plant; six heaters will be in
operation along with one spare heater to allow for decoking or maintenance. There are 6 SRT VII
cracking heaters and 1 SRT VI recycle heater installed.
The SRT VII heaters are grouped to process Kero/Heavy Naphtha, Naphtha and C5 Recycle/C6 Raffinate
as the first group, Propane Recycle and Hydrogenated C4/C5’s as the second group, and one common
spare heater to best process the different feed and recycle streams, simplify operation, and minimize
cost. The SRT VII heaters are designed to crack all feeds, thus providing full feedstock flexibility for easy
operation. Five feed supply headers are provided and the cracking heaters are connected as shown in
the matrix below. This matrix can be updated if necessary to provide more feedstock flexibility.
Feed Supply Header Arrangement
Ethane Propane C4/C5 Naphtha Kero

F-20001 X X
F-20002 X X X
F-20003 X X
F-20004 X X X X X
F-20005 X X
F-20006 X X
F-20007 X X
The SRT VI and SRT VII heaters are a twin radiant cell design which has two radiant cells with a common
convection section between the radiant cells, a common stack with ID fan on top of the convection section
and a common VHP stream drum. The 8-coil SRT VI radiant coil heater design is selected for ethane and
propane recycles cracking to provide long run lengths at optimum TIC without sacrificing cracking
selectivity. The 14-coil SRT VII radiant coil heater design is selected for C4/C5, naphtha and kerosene
cracking to provide maximum cracking selectivity without sacrificing run length.
For Design Case-1, the ethane/propane recycles will be cracked in the SRT VI recycle heater. Ethane
will be split cracked in 2 coils against propane in 2 coils in radiant cell "A" and ethane will be cracked in all
4 coils in cell “B”. A small amount of propane is spilled over into the hydrogenated C4/C5’s for feed
balancing. For Design Case-2, 100% ethane recycle cracking will take place in both cells of the SRT VI
Heater. The propane recycle will be mixed with the hydrogenated C4/C5’s and cracked in the SRT VII
cracking heaters.
For Design Case-1, the C4/C5 feed with spill-over propane recycle will be cracked in 1 full SRT VII
cracking heater and split cracked in 4 coils against naphtha in 3 coils in cell "A" and 100% naphtha in cell
"B" of the second full heater. The remaining naphtha will be cracked in 2 full heaters. Kero will be cracked
in 1 full heater. For Design Case-2, the C4/C5 feed with all the propane recycle will be cracked in 1 full
SRT VII cracking heater and split cracked in 4 coils against naphtha in 3 coils in cell "A" and 100%
naphtha in cell "B" of the second full heater. The most of the remaining naphtha will be cracked in 2 full

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heaters. Split cracking of naphtha in 3 coils against kero in 4 coils will take place in cell "A" and 100%
kero cracking in cell "B" in 1 SRT VII cracking heater.
The two tables below show the heater allocation as discussed above.
Heater Allocation – Design Case 1
coils/
Feed
feed
F-20001 6 Ethane
2 Propane
F-20002 14 C3 + C4/C5’s
F-20003 4 C3 + C4/C5’s
10 Naphtha
F-20004 14 spare
F-20005 14 Naphtha
F-20006 14 Naphtha
F-20007 14 Kero
Heater Allocation – Design Case 2
coils/
Feed
feed
F-20001 8 Ethane
F-20002 14 C3 + C4/C5’s
F-20003 4 C3 + C4/C5’s
10 Naphtha
F-20004 14 spare
F-20005 14 Naphtha
F-20006 14 Naphtha
F-20007 3 Naphtha
11 Kero
The convection section of the SRT VI recycle heater design consist of the following sections from top to
bottom:
 Upper Feed Preheat (UFP)

 BFW Preheat (BFW)
 Lower Feed Preheat (LFP)
 Upper Mixed Preheat (UMP)
 Upper Steam Superheater (USSH)
 Middle Steam Superheater (MSSH)
 Lower Steam Superheater (LSSH)

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 Lower Mixed Preheat (LMP)
The convection section of the SRT VII cracking heater design consist of the following sections from top to
bottom:
 Upper Feed Preheat (UFP)

 BFW Preheat (BFW)
 Lower Feed Preheat (LFP)
 Upper Mixed Preheat (UMP)
 Dilution Steam Superheater (DSSH)
 Upper Steam Superheater (USSH)
 Middle Steam Superheater (MSSH)
 Lower Steam Superheater (LSSH)
 Lower Mixed Preheat (LMP)
The effluent from one radiant coil is fed to a single conventional primary Transfer Line Exchanger and is
cooled against BFW for VHP steam production. The TLEs generate steam at a pressure of 111 kg/cm2g
during normal cracking operation. The BFW to the VHP steam drum is preheated by flue gas in the
convection section. The steam generated in the TLEs is separated in the steam drum and then
superheated in the Upper Steam Superheat (USSH), Middle Steam Superheat (MSSH) and Lower Steam
Superheat (LSSH) coils. To control the final superheated outlet temperature, phosphate-free BFW is
injected into the partially superheated steam between the steam superheat coils. After BFW injection, the
steam is superheated in the LSSH coil for final superheating to 510°C.
There are two desuperheaters per convection section: one at the outlet of the USSH and one at the outlet
of the MSSH. The desuperheaters are required for VHP steam temperature control and to prevent the
steam going below the saturation point after BFW injection during decoking operation.
External crossover piping connects the lower mix preheat coils to the individual coil inlet manifolds.
Critical flow venturis are provided to equalize flow distributions to the inlet tubes of the radiant coil.
DMDS is injected into the dilution steam header at the inlet to each heater as required.
The SRT VII cracking heaters have a two-pass radiant coil with an “8-1” coil configuration. The 8-1
designation refers to the 8 inlet tubes flowing to a single larger outlet tube. One radiant coil is composed
of four 8-1 units exiting to a single TLE. The SRT VII cracking heaters has 14 radiant coils. The length of
the SRT VII radiant coil is 10.36 meter. Below is an illustration of the 8-1 radiant coil configuration (coil
sketch below is for understanding purpose only and not to scale).
The radiant coil of the SRT VI cracking heater is a two-pass radiant coil with a “7-1” coil configuration;
very similar to the SRT VII radiant coil design. The 7-1 designation refers to the 7 inlet tubes flowing to a
single larger outlet tube. One radiant coil is composed of four 7-1 units exiting to a single TLE. The SRT
VI cracking heaters has 8 radiant coils. The length of the SRT VI radiant coil is 13.72 meter.

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8-1 Radiant Coil Configuration of the SRT VII Cracking Heaters
The burner arrangement for the SRT VI recycle heater comprises of hearth and integral burners on the
firebox floor plus 1½ row of wall burners at the top of the firebox. The burner arrangement for the SRT VII
cracking heaters comprises of hearth and integral burners on the firebox floor only. The shorter SRT VII
radiant coil design does not require wall burners. The hearth burners, integral burners and wall burners, if
applicable, are independently controlled. During normal operation, the integral burners and wall burners
are base loaded while the average coil outlet temperature (COT) controller adjusts the hearth firing rate of
the cracking heater. Since fuel gas to the furnace can vary in composition, the fuel flow is compensated
by the caloric value from a Wobbe meter to maintain a constant firing rate. In addition to average COT
control, automatic coil balancing has been furnished to ensure that all coils are operating at the same
outlet temperature.

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A jackshaft is provided to adjust the hearth burner air dampers from the DCS and safety interlock system
for automatic preset shutdown conditions to protect the convection section. The integral burners and wall
burners are self-inspirating and do not require any air adjustments.
One ID Fan will be provided for each heater with an inlet damper for firebox draft control. Flue gas
exhaust from the ID Fan is vented to atmosphere via a single stack.
The cracking heater effluent from the TLE is directed to the main transfer line via the Transfer Line Valve
(TLV). The Transfer Line Valve is part of a 3-valve system which also includes the Small (SDV) and
Large Decoke Valves (LDV). The SDV is mechanically linked to the TLV to make sure the heater effluent
will not be blocked and cause overpressure. The objectives of the transfer line valve and decoke valve
system are:
a. To provide heater isolation during decoking

b. To prevent reverse flow during switching
c. To prevent overpressure of the individual heater during switching
The heater’s cracked effluent outlet piping that connects to the main transfer line must be positively
isolated during the decoking operation to prevent leakage of air into the hydrocarbon-carrying main
transfer line during the burn-off phase of the decoking cycle. Likewise, positive isolation is necessary
when maintenance is being performed on the heater (i.e., mechanical cleaning of TLE's), to ensure
against a backflow of hydrocarbon gas into the heater piping or decoke system.
To achieve the objectives described above, Lummus has utilized both mechanical and electronic link
transfer line valve systems in the US Gulf Coast and worldwide. For this project, the 3-valve mechanical
link transfer line valve system using double disc, metal seat gate valves is recommended.
Regardless of feedstock type, the heater effluent from all of the SRT VII cracking heater TLEs is fed to
two main transfer lines. One main transfer line takes the effluent from three of the SRT VII heaters and
the other main transfer line takes the effluent from the remaining SRT VII heaters. Each main transfer
line directs the effluent to one of two Common Quench Fittings at the inlet of the Gasoline Fractionator.
Part of the cracked gas from the SRT VI recycle heater (C2/C3 recycles) is sent to the PFO Stripper Feed
Quench Fitting for viscosity control with the excess cracked gas going to the Gasoline Fractionator via
one of the Common Quench Fittings.
After each run, the cracking heaters are decoked with dilution steam plus decoking air to burn off the coke
deposits in the radiant coils. The decoking effluent is sent to the firebox where the remaining coke fines
are burned. The radiant coil decoke step can be followed by the TLE decoking / polishing step. The steam
drum pressure is increased during TLE decoking using the backpressure valve in the VHP steam line to
battery limit. TLE decoking is typically done every 3 to 5 radiant coil cycles for all feeds except kerosene.
It is recommended to apply TLE decoking for kerosene cracking at every radiant coil cycle. Radiant coil
decoking requires approximately twenty-four (24) to thirty (30) hours from feed-out to feed-in. If any
Primary TLE outlet maximum temperature was reached in the previous run, then an additional ten (10)
hours is necessary on that cracking heater, immediately following the radiant coil decoke, to clean the
Primary TLE(s) with a decoking / polishing step.

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2.4.2.3 Gasoline Fractionator

The hot effluent from the cracking heaters is combined in the main transfer lines, quenched in the quench
fittings, and sent to the Gasoline Fractionator system where they are further cooled to stop the pyrolysis
reactions. Pyrolysis Fuel Oil (PFO) is separated as a bottoms product, a liquid Pyrolysis Gas Oil (PGO)
side stream is withdrawn as product, and gasoline and lighter materials are taken as overhead vapor.
Heat is removed by circulating quench oil from the tower bottom, and is recovered via dilution steam
generation in the Quench Oil / Dilution Steam Reboiler. The slightly cooled quench oil is split, and a
portion is sent to the Common Quench Fitting where it used to cool the main feed to the tower. The
remaining portion of the slightly cooled quench oil is used to preheat the process water in the Quench Oil
/ Dilution Steam Drum Feed Preheater feeding the Dilution Steam Drum. A total draw-off pan oil loop
removes more heat from fractionator by preheating the feed to the Process Water Stripper in the Pan Oil /
Process Water Stripper Feed Preheater. The top of the Gasoline Fractionator is refluxed with gasoline
condensed in the Quench Tower.
The Gasoline Fractionator is comprised of three different sections. The top section is comprised of valve
trays that serve to separate out the gasoline and lighter ends from the heavier hydrocarbons in the
stream. The second section, Packed Bed #1, is comprised of packing which provides a heat removal
zone for the Pan Oil loop. The third section, Packed Bed #2, also containing packing serves as a heat
removal zone for the Quench Oil Loop.
Part of the TLE effluent from the SRT VI Heater (C2/C3 recycles) is used to strip the fuel oil product and
control the viscosity of the circulating quench oil stream. The composition of the quench oil is changed by
increasing the concentration of relatively lighter components. This is accomplished by stripping the
quench oil entering the Pyrolysis Fuel Oil Stripper with part of the Cracking Heater effluent in the PFO
Stripper Feed Quench Fitting prior to entering the stripper. High Pressure steam is substituted for heater
effluent when the heater is being decoked. A relatively high percentage of components boiling between
280°C and 370°C are stripped out and circulated through the quench oil circuit. As a result, these
components do not readily leave the system with the stripped pyrolysis fuel oil and, therefore, concentrate
in the circulating quench oil. The concentration of this mid-boiling range material maintains quench oil
viscosity within the desired limits.
The PFO Stripper is steam stabilized using MP steam to achieve a fuel oil product of acceptable flash
point greater than 110°C. The overhead of PFO Stripper containing vaporized light material is combined
with Pyrolysis Gas Oil (PGO) withdrawn from the trayed section of the Gasoline Fractionator then sent to
the bottoms of the Gasoline Fractionator. The bottoms of stripper, PFO product, is filtered then pumped
via the PFO Pump and cooled against quench water in the PFO Product Cooler prior to being sent to
OSBL storage. The C9+ stream from the BTX Tower bottoms is combined with the PFO product prior to
being cooled in the PFO Product Cooler. There is a small stream of PFO that is circulated back to the
Gasoline Fractionator bottoms, which affects the amount of vaporization in the PFO Stripper Feed
Quench Fitting.

Bloomfield, NJ

The quench oil from the bottom of the Gasoline Fractionator is filtered and then passed through the
Quench Oil Coke Removal Package to improve the quench oil quality for use in the QO/DS Exchangers
as well as in the quench fittings.
The liquid side-draw of pan oil from the bottom section of Packed Bed #1, essentially free of coke fines, is
not filtered prior to use in the pan oil exchangers. A portion of the pan oil is filtered, pumped, and used as
purge oil for the instrumentation prior to returning to the Gasoline Fractionator bottoms.
Provisions for flux oil injection into the circulating quench oil have also been provided.
2.4.2.4 Quench Tower

Overhead vapor from the Gasoline Fractionator is sent to the Quench Tower where it is cooled and
partially condensed by direct counter-current contact with recirculating water, called quench water (QW).
The recirculating quench water is sent from the tower bottoms to supply low level heat to various process
users. Provision for amine injection to the recirculating quench water is provided for pH control.
The circulating quench water is pumped by the Quench Water Circulation Pumps and cooled in various
exchangers. A portion of the high temperature Quench Water is sent to the Propylene Fractionator No. 2
Reboiler and then to the Propylene Fractionator No. 1 Reboiler after which it is sent to the Quench Water
return line. The remaining high temperature quench water undergoes further cooling in the following
exchangers (unless noted otherwise):
st
1 Level: High Temperature Quench Water
 Deethanizer Reboiler
Quench Water not used in providing heat at the high temperature level is bypassed into the medium
temperature header through a differential pressure control valve. The remaining medium temperature
quench water undergoes further cooling in the following exchangers:
nd
2 Level: Medium Temperature Quench Water
 Propane Feed Heater

 Kero Feed Preheater
 Naphtha Feed Preheater
 Ethane Feed Preheater
Quench Water not used in providing heat at the medium temperature level is bypassed into the low
temperature header through a differential pressure control valve. The low temperature quench water
undergoes further cooling in the following exchangers:
rd
3 Level: Low Temperature Quench Water
 Caustic Charge Gas Feed Heater

 Propane Feed Vaporizer
 PFO Product Cooler
The majority of the quench water in the return line is cooled in the Quench Water Cooler No. 1 with a
portion of the total quench water used as a hot quench water bypass to maintain a mid-quench water

Bloomfield, NJ

return temperature of 54°C. A major portion of this flow combines with the hot quench water bypass and
is fed on flow control to the lower section of the Quench Tower. This flow is reset by the Quench Tower
bottom temperature controller to maintain a bottoms temperature of 82°C. The remainder of the quench
water flow is cooled to 38°C in the Quench Water Cooler No. 2 with cooling water and sent on flow control
to the top of the Quench Tower.
The overhead vapor from the Quench Tower is sent to the charge gas compression section. The heavy
gasoline condensed in the Quench Tower is separated from the re-circulating quench water and the
condensed dilution steam in the tower bottom. The majority of the condensed hydrocarbons are returned
to the Gasoline Fractionator on flow control, and the balance hydrocarbons are sent to the Pyrolysis
Hydrogenation Unit (PGU), on flow control reset by level control in the Quench Tower bottoms and to the
Spent Caustic Treatment as wash gasoline.
The Quench Tower also provides a stream of process water feed to the Process Water Stripper.
2.4.2.5 Process Water Stripping and Dilution Steam Generation

The process water leaving the Quench Tower bottoms is preheated against pan oil and routed to the
Process Water Stripper. The process water is stripped with steam generated in the Process Water
Stripper Reboiler in order to remove acid gases and volatile hydrocarbons. A provision for live LP steam
injection is also provided to the bottom of the stripper to ensure continuity of operation. The amount of
vapor sent back to the Quench Tower from the stripper is controlled by setting the amount of LP Steam to
the Process Water Stripper Reboiler.
The stripped process water from the Process Water Stripper is pumped via the Dilution Steam Drum Feed
Pumps and preheated by quench oil in the Quench Oil / Dilution Steam Drum Feed Preheater before
entering the Dilution Steam Drum. This feed is fed on flow control reset by the level controller on the
sump of steam drum. Makeup water from the boiler feed water system is sent to the top of the steam
drum which serves as a wash to prevent caustic from carrying over into the Cracking Heaters. The main
duty for this tower is provided by the Quench Oil / Dilution Steam Reboiler. The remaining duty is
supplemented by the Dilution Steam / MP Steam Exchanger.
The dilution steam generated leaves the top of Dilution Steam Drum and is sent to the Dilution Steam
Separator where any remaining liquid droplets are removed, and combined with the steam drum
blowdown stream. The dilution steam is superheated against Medium Pressure (MP) steam in the
Dilution Steam Superheater and then used as dilution steam in the cracking heaters and as purge steam
to instruments and valves. The pressure of the dilution steam is set by controlling the amount of MP
Steam sent to superheater.
Provisions for amine injection into the Process Water Stripper and Dilution Steam Drum feeds are
provided for pH control.
To prevent a build-up of non-volatiles, a blowdown stream from the Dilution Steam Drum is drawn, cooled
against cooling water in the Dilution Steam Blowdown Cooler and sent on flow control to OSBL waste
treatment facility.

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2.4.2.6 Charge Gas Compression (Stages 1-2)

st
The Quench Tower overhead vapors are sent to the Charge Gas Compressor 1 Stage Suction drum.
Any hydrocarbon and water liquids knocked out in this drum are pumped to the Quench Tower by the
st st
CGC 1 Stage Suction Drum Pumps. The overhead vapor from this drum enters the 1 stage of the
Charge Gas Compressor. A steam turbine utilizing Very High Pressure Steam (VHPS) drives the CG
Compressor. Boiler Feed Water (BFW) is injected into the compressor to help maintain temperature
below 100°C consequently reducing fouling. Wash Oil Injection is provided individually at all three
compression stages to wash the rotors as required.
st
The compressed hydrocarbon stream continues to the Charge Gas Compressor 1 Stage Aftercooler
where it is cooled by cooling water. Continuous vents from the Pyrolysis Gasoline Hydrogenation (PGH)
Unit and Total Hydrogenation Unit (THU), as well as other normally closed vents from other parts of the
nd
SCU are combined with the cooled charge gas and sent to the Charge Gas Compressor 2 Stage
Suction Drum.
nd
Any hydrocarbons condensed in the Charge Gas Compressor 2 Stage Suction Drum are sent to the
nd
Quench Tower. Any water that is knocked out in CGC 2 Stage Suction Drum is sent to the Charge Gas
st nd
Compressor 1 Stage Suction Drum. The overhead vapor from this drum enters the 2 stage of the
Charge Gas Compressor.
nd
The compressed hydrocarbon stream continues to the Charge Gas Compressor 2 Stage Aftercooler
where it is cooled by cooling water. A continuous vent from the Propylene Fractionator Vent Condenser
and the MEA Regenerator HP Flash Drum along with normally closed offspec ethylene BOG vapors are
nd
combined with the cooled charge gas and sent to the Charge Gas Compressor 2 Stage Discharge
Drum.
nd
Any hydrocarbons and water components that are knocked out in the Charge Gas Compressor 2 Stage
nd
Discharge Drum are sent back to Charge Gas Compressor 2 Stage Suction Drum. The vapor from the
nd
CGC 2 Stage Discharge Drum is heated to 45°C by Quench Water in the Caustic Charge Gas Feed
Heater and sent to the SCU Amine/Water Wash Column. This preheat prevents hydrocarbon
condensation which contributes to "yellow oil" formation. However, the temperature should not be
increased above this value since high temperatures can lead to precipitation of salts resulting in plugging.
2.4.2.7 Amine System

nd
Charge gas from the Charge Gas Compressor 2 Stage Discharge Drum is sent to the SCU MEA/Water
Wash Column for bulk removal of CO2 and H2S. An online analyzer on the feed detects the levels of acid
gas (CO2 and H2S) in the charge gas.
The SCU MEA/Water Wash Column is comprised of two sections. The top portion consists of bubble cap
trays which serve as a water wash section to prevent amine entrainment in the overhead product. Wash
water for the SCU MEA/Water Wash Column comes from the Continuous Blowdown Cooler. Waste
water from the water section (bubble cap trays) is totally drawn off the bottom most tray and sent to
Neutralization (OSBL). The bottom portion is comprised of packed beds and serves as the amine wash
section.

Bloomfield, NJ

A lean Monoethanolamine (MEA) solution, supplied by the MEA Regenerator, is fed to the top of the
amine wash section above the packed beds. The water wash in the top section prevents carry-over of
Lean MEA into the rest of the system. The charge gas is heated by Quench Water in the Amine Charge
Gas Feed Heater prior to being fed below the bottom section of the column. The acid compounds (H2S
and CO2) in the charge gas are absorbed into the Lean MEA solution by countercurrent contact as the
vapor continues up the tower. The bottom of the tower will have a higher temperature, due to the heat of
absorption. The overhead of the SCU MEA/Water Wash Column is sent to the Caustic/Water Wash
Tower.
Any oils that form in the absorption process can be skimmed off the liquid level in the sump of the SCU
MEA/Water Wash Column and sent to SCU MEA Oil Degassing Drum. Overhead vapors from Degassing
Drum is sent to Wet Flare, while any liquid is sent to the Amine Drain system.
Acid gas leaves the ROG MEA/Water Wash Column bottoms with the rich amine solution where it is sent
to the MEA Regenerator HP Flash Drum. Liquid hydrocarbons are separated out from the amine solution
and sent to the Quench Tower. The Rich MEA from the flash drum is then preheated against the hot
bottoms (regenerated Lean MEA) of the regenerator in the Lean MEA/Rich MEA Exchanger.
The MEA Regenerator is comprised of bubble cap trays in the top section and packed beds in the middle
and bottom sections. The Rich MEA from the SCU MEA/Water Wash Column is fed to the top of the
packed bed section, and makeup MEA combined with makeup water is fed to the bottom of the
regenerator. The reboiler duty for the regenerator is provided by controlling the amount of LP Steam sent
to the MEA Regenerator Reboiler. The gross overhead from the MEA Regenerator is condensed against
cooling water in the MEA Regenerator Condenser and collected in the MEA Regenerator Reflux Drum.
The MEA Regenerator pressure is controlled by throttling the acid gas vented from the reflux drum, and a
secondary pressure controller introduces nitrogen to the overhead line if the pressure becomes too low.
Any liquid that condenses is pumped by the MEA Regenerator Reflux Pumps and sent as reflux to the top
of the tower. Acid gases are vented off the reflux drum and sent to the Acid Gas Flare.
The bottoms of the MEA Regenerator, Lean MEA, is pumped and cooled by exchanging heat with Rich
MEA feed in the Lean MEA/Rich MEA Exchanger. The Lean MEA is cooled further against cooling water
in the Lean MEA Cooler before being filtered. The Lean MEA is then recycled back to the SCU
MEA/Water Wash Column.
A provision is included the remove heat-stable salts formed in the amine system via the MEA Reclaimer.
The exchanger is used in batch operation utilizing MP steam to evaporate the MEA solution, leaving
behind MEA sludge to be drained to drums and sent for disposal OSBL.
2.4.2.8 Acid Gas Removal

The treated charge gas from the SCU MEA/Water Wash Column is fed to the bottom of the lower packed
bed in the Caustic/Water Wash Tower where acid gases (H2S and CO2) are removed by weak caustic
pumped in by the Weak Caustic Circulation Pump. Acid gases react with caustic to form sodium sulfide
and sodium carbonate salts. The cleaner charge gas continues through to the bottom of the upper
packed bed in the tower where acid gases are removed by medium level caustic pumped to the top of the

Bloomfield, NJ

bed by the Middle Caustic Circulation Pumps. The charge gas then proceeds to the third section of acid
gas removal where strong caustic solution is pumped in from the Strong Caustic Circulation Pumps. In
this section the required CO2 spec in the Ethylene Product is met. Before the acid-free charge gas leaves
the Caustic/Water Wash Tower, wash water is introduced to the top of section of the tower to ensure no
caustic is carried over into downstream equipment. Wash water for the Caustic/Water Wash Tower
comes from the Continuous Blowdown Cooler. Waste water from the water section is totally drawn off
below the bottom most tray of the top section and sent to Spent Caustic Wash Gasoline Mixer.
Any significant breakthrough of H2S or CO2 can jeopardize downstream operations or final product
specifications. 20% Caustic is fed from OSBL to the suction line of the Strong Caustic Circulation Pumps
to make up any caustic that leaves the bottoms (spent caustic) of caustic tower.
2.4.2.9 Charge Gas Compression (Stage 3)

After acid gas removal in the Caustic/Water Wash Tower, the charge gas is cooled by 9°C propylene
rd
refrigeration in the Caustic Tower Effluent Cooler and sent to the Charge Gas Compressor 3 Stage
Suction Drum. In this drum the condensed hydrocarbon and water phases are separated. The
hydrocarbon is split into two streams. One stream is recycled to the Quench Tower to maintain gasoline
rd
inventory. The other stream is pumped by the CGC 3 Stage Suction Drum Pumps to the Liquid
rd
Condensate Coalescer Package. An interface level controller sends water from the 3 Stage Suction
rd
Drum to the Quench Tower. The overhead vapor from this drum enters the 3 stage of the Charge Gas
Compressor.
rd
The compressed hydrocarbon stream continues to the Charge Gas Compressor 3 Stage Aftercooler No.
1 where it is cooled against cooling water. The charge gas undergoes further cooling in the Charge Gas
rd
Compressor 3 Stage Aftercooler No. 2 by 9°C propylene refrigerant and is sent to the Charge Gas
rd
Compressor 3 Stage Discharge Drum. In this drum the condensed hydrocarbon and water phases are
rd
separated. The hydrocarbon stream is pumped by the CGC 3 Stage Discharge Drum Pumps to the
rd
Liquid Condensate Coalescer Package. An interface level controller sends water from 3 Stage
Discharge Drum to the Quench Tower. The overhead vapor from the discharge drum is sent to the
Charge Gas Dryers.
2.4.2.10 Spent Caustic Pretreatment

The spent caustic solution and yellow oil from the SCU and ROG Caustic/Water Wash Towers cannot be
discharged to the environment without further treatment. The spent caustic solution contains sodium
carbonate, sodium sulfide, and a small percentage of free, unreacted, sodium hydroxide. In addition, the
solution may contain dispersed hydrocarbons. The dispersed hydrocarbons may cause considerable
fouling in the OSBL Wet Air Oxidation Unit (WAO) and are therefore removed with a gasoline wash.
Spent caustic leaves the bottom of the SCU and ROG Caustic/Water Wash Towers, along with a cooled
wash gasoline stream is sent to the Spent Caustic Wash Gasoline Mixer and then processed in the Spent
Caustic Coalescer. Wash gasoline is pumped from the Quench Tower on flow ratio control, maintaining a
consistent ratio to the spent caustic flow. Prior to entering the Spent Caustic Coalescer it is cooled by
cooling water in the Spent Caustic Wash Gasoline Cooler. The gasoline wash recovers hydrocarbon
from the spent caustic stream. In the Spent Caustic Coalescer the combined stream is first degassed,

Bloomfield, NJ

then passed through a packed coalescing pad and into the settling compartment where the
gasoline/caustic separation takes place. The spent caustic is routed to the WAO unit where it undergoes
further treatment. The Wet Air Oxidation unit converts the sodium sulfides to sodium sulfates and
thiosulfates.
The spent gasoline from the Spent Caustic Coalescer requires further water washing to reduce the
quantity of entrained caustic which can lead to a pH problem. The gasoline is sent to the Spent
Gasoline/Wash Water Mixer where it is contacted with wash water prior to entering the Spent Gasoline
Coalescer. Wash water is pumped from the Process Water Stripper bottoms on flow ratio control,
maintaining a consistent ratio to the wash gasoline flow from Spent Caustic Coalescer. In the Spent
Gasoline Coalescer the combined stream is passed through a packed coalescing pad and into the settling
compartment where the gasoline/water separation takes place. The spent wash water is sent to the WAO
and the spent gasoline is returned to the Quench Tower.
2.4.2.11 Charge Gas and Liquid Condensate Drying

The charge gas passes through the Charge Gas Dryers for moisture removal. After drying, the charge
gas is sent through the Charge Gas Dryer Outlet Filters and then to the HP Depropanizer. The removal
of water from the charge gas is necessary to prevent the formation of ice and hydrates in the HP
Depropanizer.
Two Charge Gas Dryers are in operation while the third dryer is being regenerated or on standby. Each
dryer contains two desiccant bed sections. A moisture analyzer is provided below the first (main) bed to
indicate the arrival of the wet gas “front”. The second bed (guard) prevents break-through moisture from
leaving the dryer. Any indication of the wet gas “front” reaching the analyzer probes indicates exhaustion
and the dryers should be switched immediately. Regeneration is carried out by circulating hot methane-
rich regeneration gas from the regeneration system at 232°C to drive out moisture adsorbed in the dryer
bed. After the bed has reached the required temperature, the bed is cooled with unheated regeneration
gas. The spent regeneration gas is returned to the fuel gas system.
rd
Liquid condensate is pumped from the CGC 3 Stage Suction and Discharge Drums to the Liquid
Condensate Coalescer Package where the separated hydrocarbon proceeds to the Liquid Condensate
Dryers for moisture removal. Any free water in the feed stream is removed from the bottom boot of Liquid
Condensate Coalescer and sent to the Quench Tower. After drying, the liquid condensate flows through
the filters and then sent directly to the HP Depropanizer.
One Liquid Condensate Dryers is in operation while the second dryer is being regenerated or on standby.
Each dryer contains one desiccant bed. A moisture analyzer is provided towards the end of the bed to
indicate arrival of the wed gas “front”. Any indication of the wet gas “front” reaching the analyzer probe
indicates exhaustion and the dryer should be switched immediately. The regeneration procedure is
similar to that of the Charge Gas Dryers mentioned above. An on-line analyzer on the effluent from the
Liquid Condensate Dryers measures any water that may break through. A separate on-line analyzer
provides a composition of the charge gas, as well as detecting any acid gases (CO2 and H2S).

Bloomfield, NJ

2.4.2.12 Regeneration System

Dryers and treaters in the complex operate on the principle of Temperature Swing Adsorption (TSA), in
which water and/or impurities adsorb into a packed bed at one temperature, and are released from the
bed at higher temperature during regeneration. The size of the beds determines how long each
adsorption cycle is, before the beds become saturated and require regeneration.
Fuel gas from the ROG as well as methane rich offgas from the SCU fuel gas system is combined and
used as regeneration gas in the complex. It is split into two cooling and heating regeneration headers.
The cooling regeneration gas is at a temperature of 40°C. The heating regeneration gas is preheated by
the Regeneration Feed/Effluent Exchanger and then against High Pressure (HP) Steam in the Regen
Gas Heater. The temperature of the heating regeneration gas is controlled to 240°C by throttling the
amount of HP Steam sent to Regen Gas Heater. A portion of the spent regeneration gas is further
heated to 290-300°C by the Treater Regeneration Gas Electric Heater and sent to treaters that require
hotter regeneration gas than typically provided. A mixture of heating and cooling regeneration gas is sent
to the dryers and treaters on flow control.
The regeneration procedure consists of several steps including gradual heating by regeneration gas,
holding at this temperature until all water is driven from the molecular sieve, and finally cooling the beds
before returning to service. Flow control on the combined regeneration gas is established by controlling
the heating regeneration gas sent to the dryer or treater. Temperature control on the combined
regeneration gas is established by resetting the set point on the flow controller of the cooling regeneration
gas.
The spent regeneration gas from the users is cooled in the Regeneration Feed/Effluent Exchanger and
cooled in the Regeneration Gas Cooler by cooling water. The cooled regeneration gas continues to the
Regeneration Gas K.O. Drum for removal of water prior to re-entering the fuel gas system. Any
condensed water from the regeneration gas K.O. drum is returned to the Quench Tower.
The reactors in the complex require different types of gases during their regeneration cycles. A Reactor
Reduction Gas Heater heats a Nitrogen (N2) stream along with Hydrogen (H2) when required. The
temperature is controlled by throttling the amount of Medium Pressure (MP) Steam sent to Reactor
Reduction Gas Heater. There are also provisions for Plant Air, Very High Pressure (VHP) Steam, and
Low Pressure (LP) Steam to be sent to reactors during regeneration oxidation steps.
2.4.2.13 Depropanization and Acetylene Hydrogenation

The purpose of the Depropanizer system is to achieve a C4's content in the net overhead consistent with
the allowable specifications of the final C3 product streams. The bottoms composition is adjusted to
maintain the bottoms temperature such that fouling tendencies in the trays and the reboiler are
minimized. The Depropanizer system employs a two tower system, with each tower operating at a
different pressure. By utilizing two distillation towers, refrigeration demand and fouling is minimized,
when compared with single-tower systems.
The charge gas from the Charge Gas Dryers and the condensed hydrocarbon liquid from the Liquid
Condensate Dryer are fed to the bottom and middle of the top section of the High Pressure (HP)
Depropanizer. The gross overhead from the High Pressure Depropanizer is heated by Acetylene

Bloomfield, NJ

Converter reactor effluent in the Acetylene Converter Feed/Effluent Exchanger No. 1 and No. 2. The
temperature of the reactor feed after Feed/Effluent Exchanger No. 2 is set to 53°C by controlling the
amount that bypasses it. An on-line analyzer detects the amount of C4’s in this stream, which indicates
tower separation performance. A separate analyzer detects any carbon monoxide found in the stream,
which is a temporary poison to the Acetylene Converter catalyst that reduces activity.
The reactor feed is heated in the Acetylene Converter Heater. The front end Acetylene Converter system
selectively hydrogenates acetylene to ethylene and ethane. Some methyl-acetylene/ propadiene (MAPD)
are hydrogenated to propylene and propane. An on-line analyzer on this stream measures the amount of
acetylene, ethane, and MAPD in the reactor feed.
The Acetylene Converter contains 3 beds operating in series with intercoolers after each staged cooled
by cooling water. Temperature controllers downstream of each intercooler set the temperature of the
cooled effluent feeding the next bed, by controlling the amount bypassing each intercooler. Reactor
regeneration is performed ex-situ. The reactor vessels are configured to be put in any order to allow
single vessel catalyst replacement if required. The reactor effluent is cooled by in the Acetylene
Converter Aftercooler by cooling water. An on-line analyzer on this stream measures the amount of
acetylene, ethane, and MAPD in the reactor effluent. The reactor effluent then is further cooled in the
Acetylene Converter Feed/Effluent Exchanger No. 2 after which it is sent to the Acetylene Converter
Dryer for moisture removal. The dryer effluent is filtered then further cooled in Acetylene Converter
Feed/Effluent Exchanger No. 1 and then sent to the HP Depropanizer Condenser. The hydrocarbons are
partially condensed by -27°C propylene refrigerant and then enters the HP Depropanizer Reflux Drum.
The liquid from reflux drum is pumped by the HP Depropanizer Reflux Pumps on flow control back to the
HP Depropanizer as reflux.
The condensed liquid from the reflux drum provides some of the reflux to the HP Depropanizer. The net
overhead from the HP Depropanizer, which contains the C3 and lighter components of the charge gas, is
then fed to the chilling train.
Tower reboiler duty is provided by Desuperheated Low Pressure (LP) Steam in the HP Depropanizer
Reboiler. Only one of the reboilers is in operation; a spare is provided for periodic cleaning. The HP
Depropanizer bottoms is cooled by cooling water in the HP Depropanizer Bottoms Cooler and then fed to
the LP Depropanizer. An on-line analyzer provides a measurement of C2’s in the bottoms stream which
is an indication of tower separation performance. Polymerization inhibitor from the Polymerization
Inhibitor Injection System is injected into the HP Depropanizer feed and Reboiler inlet streams.
The bottoms product of the HP Depropanizer is fed to the LP Depropanizer. The gross overhead of the
LP Depropanizer is fully condensed by -27°C refrigerant in the LP Depropanizer Condenser. The
condensed stream leaving the condenser enters the LP Depropanizer Reflux Drum. Total liquid from the
reflux drum is pumped by the LP Depropanizer Reflux Pumps where a portion is sent as reflux back to the
LP Depropanizer. The remaining overhead liquid product is sent to the HP Depropanizer.
Tower reboiler duty is provided by Desuperheated Low Pressure (LP) Steam in the LP Depropanizer
Reboiler. Only one of the reboilers is in operation; a spare is provided for periodic cleaning. The LP
Depropanizer bottoms product, which contains C4 and heavier components, is pumped by the LP

Bloomfield, NJ

Depropanizer Bottoms Pumps to the Debutanizer. On-line analyzers detect the amount of C4’s in the
overhead product stream as well as the C3’s in bottoms product stream, which indicate tower separation
performance. Polymerization inhibitor from the Polymerization Inhibitor Injection System is injected into
the LP Depropanizer feed and Reboiler inlet streams. A normally closed vent stream from the LP
nd
Depropanizer Reflux Drum is provided to rout material back to the Charge Gas Compressor 2 Stage
Suction Drum for reprocessing.
2.4.2.14 Charge Gas Chilling

The charge gas from the HP Depropanizer overhead is progressively chilled against -40°C propylene
refrigerant in the Demethanizer Feed Chiller and then in the Demethanizer Reboiler before it is finally
chilled in the Offgas Exchanger No. 3. The temperature of the charge gas is set to -80°C by controlling
the amount of Binary Refrigerant (BR) sent to Offgas Exchanger No. 3 and the stream is flashed in the
Demethanizer Feed Separator No. 1. The condensate is separated in the Demethanizer Feed Separator
No. 1 and fed to the Demethanizer as the “Bottom Feed”.
The overhead vapor from the Demethanizer Feed Separator No. 1 is further chilled against offgases and
binary refrigerant in the Offgas Exchanger No. 2. The temperature of the charge gas is set to -110°C by
controlling the amount of binary refrigerant sent to Offgas Exchanger No. 2 and the stream is flashed in
the Demethanizer Feed Separator No. 2. The condensate from the Demethanizer Feed Separator No. 2
is sent to the Demethanizer as the “Middle Feed”.
The overhead vapor from the Demethanizer Feed Separator No. 2 is further chilled against offgases and
binary refrigerant in the Offgas Exchanger No. 1, and is mixed with methane wash liquid in the
Demethanizer Feed/Methane Wash Mixer, and is flashed in the Demethanizer Feed Separator No. 3.
The condensate from the Demethanizer Feed Separator No. 3 is sent to the Demethanizer as the “Top
Feed”.
The overhead vapor from the Demethanizer Feed Separator No. 3, called hydrogen rich offgas, is
reheated by charge gas in the cold box system and compressed in the Hydrogen Compressor before
being sent to the Hydrogen Pressure Swing Adsorption (PSA) Unit for hydrogen purification. The
pressure of the Demethanizer Feed Separator No. 3 is controlled by two pressure controllers. Primary
pressure control is accomplished by resetting the speed controller on the H2 Compressor. In a high
pressure scenario, the speed controller for the H2 Compressor may reach its limit and secondary
pressure control is accomplished by sending the hydrogen rich offgas to the fuel gas system.
The Hydrogen Compressor is comprised of two stages and the discharge from each stage is cooled to
45°C by cooling water in the Hydrogen Compressor Intercooler and Aftercooler. The pressure of the
stream is increased to provide sufficient pressure for the purified hydrogen (>99.9 mol.%) from the PSA
Unit to be sent to the following locations:
 Total Hydrogenation Unit (THU)

 MAPD Converter
 Pyrolysis Gasoline Hydrogenation (PGH) Unit

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A portion is sent out as High Pressure (HP) Hydrogen product to OSBL while the remaining high purity H2
from the PSA is exported on flow control as hydrogen product to OSBL.
Offgas from the PSA Unit is recompressed to fuel gas header pressure (to maximize hydrogen recovery)
and is combined with returned regeneration gas and is sent directly to the Fuel Gas system. A portion of
this fuel gas is sent to the Fuel Gas Knock-Out Drum where any liquids are removed on level control and
sent back to the Quench Tower. The pressure of KO drum is controlled by two pressure controllers in the
overhead line. In a high pressure scenario, fuel gas is vented to the Wet Flare. In a low pressure
scenario, supplemental fuel gas is brought into the KO drum from OSBL. The overhead of the KO drum
undergoes further processing in the Fuel Gas Filter/Coalescer where condensate is removed and sent
back to the Quench Tower. The processed fuel gas is consumed by the Cracking Heaters any excess is
sent to OSBL. On-line analyzers detect the composition of this fuel gas stream, to control the firing rate in
the cracking heater burners.
2.4.2.15 Demethanization
The Demethanizer tower is comprised of multiple packed bed sections and its primary purpose is to
separate methane and lighter components from the remaining charge gas. The tower operates at a top
pressure just high enough to permit overhead methane product to get into the fuel gas system. By
minimizing the operating pressure, the separation efficiency is increased which reduces both reflux
requirements and energy consumption.
There are three primary condensed liquid feeds (top/middle/bottom) to the Demethanizer which come
from feed separator drums in the chill train. Demethanizer gross overhead vapor at -130°C is partially
condensed with binary refrigerant in the Demethanizer Condenser and sent to the Demethanizer Reflux
Drum. The overhead of the reflux drum is sent back to the cold box where it is heated before being sent
to the regeneration system; any fuel gas not used for regeneration proceeds to the PSA unit for hydrogen
recovery. A control valve controls the flow of this stream through the control box which sets the pressure
in the Demethanizer tower. The liquid from the reflux drum is pumped by the Demethanizer Reflux
Pumps. A portion is sent on flow control as reflux to the top bed of the Demethanizer, while the remaining
liquid is used as methane wash liquid in the Demethanizer Feed Separator No. 3 in the charge gas
chilling train to reduce ethylene loss.
Tower reboiler duty is provided by heat interchange with hot charge gas from the HP Depropanizer Reflux
Drum in the Demethanizer Reboiler. A temperature controller sets the temperature profile in the tower by
bypassing a portion of the charge gas around the reboiler. The bottoms product is pumped by the
Demethanizer Bottoms Pumps and split into two streams before being heated in the cold box and
eventually entering the Deethanizer. One stream is sent directly as liquid from the cold box to the
Deethanizer as the “Upper Feed”. The other stream is vaporized in the cold box and sent to the
Deethanizer as the “Lower Feed”. A level controller resets the flow controller on the “Lower Feed”
upstream of the cold box. The “Upper Feed” flow controller is set on ratio control relative to the “Lower
Feed”. An on-line analyzer in the tower bottoms detects for methane, an indication of tower separation
performance.
Provisions are made to reprocess vents from ethylene fractionation or the binary refrigeration system.

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2.4.2.16 Deethanization
The Demethanizer bottoms product, which is split into two streams as described in the Demethanizer
section, feeds the Deethanizer. The Deethanizer is comprised of multiple valve trays and its primary
purpose is to create a C2 stream sent to the Ethylene Fractionator and a C3 stream sent to the Propylene
Fractionators. A treated C2/C3 stream from the ROG Depropanizer is fed to the system.
The gross overhead vapor of the Deethanizer is partially condensed against -27°C propylene refrigerant
in the Deethanizer Condenser. The two phase stream leaving the condenser enters the Deethanizer
Reflux Drum where an overhead vapor stream, containing ethane and ethylene, is sent to the Ethylene
Fractionator. The tower overhead pressure is set by a pressure controller in the gross overhead line
resetting the flow controller on the C2s sent to the Ethylene Fractionator. In a high pressure scenario, a
second pressure controller will open a normally closed vent on the reflux drum to the Cold Flare. Total
liquid from reflux drum is pumped by the Deethanizer Reflux Pumps, and sent as reflux back to the tower.
The level in the reflux drum is controlled by throttling the amount of propylene refrigerant sent to the
Deethanizer Condenser.
Tower reboiler duty is provided by Quench Water (QW) in the Deethanizer Reboiler. A tray temperature
controller sets the temperature by resetting the set point of the flow controller on the QW feeding the
reboiler. The Deethanizer LP Steam Reboiler is provided for use as a startup/spare reboiler. The
Deethanizer bottoms product, which contains C3 and heavier components, is pumped by the Deethanizer
Bottoms Pumps to the MAPD Trim Reactor Feed Cooler.
On-line analyzers are provided in the net overhead vapor product and bottoms product to measure their
compositions, and tower separation performance.
2.4.2.17 Ethylene Fractionation

The Ethylene Fractionator is comprised of multiple valve trays and its primary purpose is to produce 99.95
mol.% ethylene overhead product, as well as high purity ethane bottoms product which is recycled to the
cracking heater feed system.
The net overhead vapor product from the Deethanizer Reflux Drum is fed to the Ethylene Fractionator.
The gross overhead vapor of the fractionator is totally condensed against -40°C propylene refrigerant in
the Ethylene Fractionator Condenser before it enters the Ethylene Fractionator Reflux Drum. The tower
overhead pressure is set by a pressure controller in the gross overhead line which controls the amount of
propylene refrigerant sent to the condenser. In a high pressure scenario, a second pressure controller
will open a normally closed vent on the reflux drum to the Cold Flare. If any non-condensables
accumulate in the reflux drum, a hand control (HC) provides the ability to send this material back to the
Demethanizer for reprocessing. The liquid from the reflux drum, ethylene product, is pumped by the
Ethylene Fractionator Reflux Pumps and sent back to the tower as reflux. A portion of this ethylene
product is sent on flow ratio control to the OSBL storage spheres, maintaining a constant ratio to the
reflux flow. This prevents exporting offspec Ethylene Product. The level controller on the reflux drum
resets the reflux flow and, therefore, the product draw-off rate.
Onspec HP Ethylene from OSBL storage is pumped to the Offgas Exchanger No. 6 in the cold box to
heat the stream, before it is vaporized in the kettle side of the Ethylene Product Vaporizer by 9°C

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propylene refrigerant. The vaporized ethylene from product vaporizer undergoes more heating in Offgas
Exchanger No. 6, and is sent as HP Ethylene Product Vapor to OSBL.
A continuous ethylene rundown stream is withdrawn from the Ethylene Fractionator Reflux Drum and is
chilled by binary refrigerant in the Ethylene Rundown Chiller. The ethylene rundown (in liquid phase) is
sent to OSBL Storage. A level controller in OSBL Storage, sends a high level override to control the flow
if the level gets too high. Higher levels of rundown can be achieved during SCU turn down.
Tower reboiler duty is provided by two reboilers which permits the maximum cold recuperation from this
tower. In the kettle type Ethylene Fractionator Side Reboiler a liquid stream withdrawn from the tower is
vaporized by -10°C propylene refrigerant. In the Ethylene Fractionator Reboiler a portion of the bottom
sump is vaporized by 9°C propylene refrigerant. .
The Ethylene Fractionator bottoms product, ethane recycle, is sent to the cold box. In the cold box, the
ethane recycle is heated and vaporized in the Offgas Exchangers No. 5 and 6 before is recycled back to
the cracking heater feed system.
On-line analyzers are provided on the overhead and bottoms product to ensure product specifications are
met.
2.4.2.18 MAPD Conversion

The Deethanizer bottoms is blended with an MAPD Converter recycle stream, and is cooled in the MAPD
Trim Reactor Feed Cooler by cooling water. The effluent from the cooler is sent on flow control to MAPD
Converter. Hydrogen from the PSA is blended with cooled effluent from MAPD Trim Reactor Feed
Cooler. A temperature controller sets this combined stream temperature by controlling the amount of the
Deethanizer bottoms stream bypasses the cooler prior to entering the MAPD Converter.
The MAPD Converter is a trickle flow (down flow) single trim reactor system which reduces the MAPD
content in the effluent stream to specification levels. The amount of hydrogen injected is just slightly
above the amount required to saturate the MAPD so there is not any need for a separator on the outlet.
There is a distributor inside of the reactor to ensure that the hydrogen is properly mixed. As the liquid
reacts with H2 in the reactor a noticeable temperature rise will occur, which leads to vaporization. A
vapor product is removed from the bottom of the converter on back pressure control sent to the Propylene
Fractionator No. 1. Maintaining back pressure, ensures the liquid in the converter bottom sump has
enough pressure to be sent to the fractionator. A portion of the bottom liquid product from the converter
is recycled back to the feed by the MAPD Recycle Pumps which helps control temperature rise, and
henceforth, controlling the vaporization that occurs in the reactor.
On-line analyzers detect the MAPD, propylene, and propane on the feed and product sides of the MAPD
Converter. If too much hydrogen is added, the reactor may become less selective, so it is important to
closely monitor this during operation.

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2.4.2.19 Propylene Fractionation

The two towers, Propylene Fractionator No. 1 and No. 2, work together as essentially one propylene
fractionator. The feed to this system is effluent from the MAPD Converter which enters Propylene
Fractionator No.1. The primary purpose of this upper tower is to produce 99.5 mol.% propylene product,
while the lower tower produces a high purity propane bottoms product which is recycled to the cracking
heater feed system.
The gross overhead vapor of Propylene Fractionator No. 1 is totally condensed against cooling water in
the Propylene Fractionator Condenser before it enters the Propylene Fractionator Reflux Drum. The
tower overhead pressure is set by a “hot vapor bypass”, where a portion of the gross overhead bypasses
the condenser and is fed directly to the reflux drum. Depending on the amount of material that bypasses
the condenser, the operating pressure of the reflux drum will change. By changing the pressure
difference between the condenser and the reflux drum, the liquid level in the condenser will expose or
submerge more condenser tubes. A second pressure controller in the gross overhead line which controls
the amount of cooling water sent to the condenser. In a high pressure scenario, a hand control can open
a vent on the reflux drum to the Cold Flare. A continuous vent from the reflux drum is cooled in the
Propylene Fractionator Vent Condenser by cooling water where any liquid that condenses is sent back to
nd
the CGC 2 Stage Discharge Drum. Any non-condensables are sent on flow control to the Charge Gas
nd
Compressor 2 Stage Discharge Drum. In a low pressure scenario, the pressure controller on the gross
nd
overhead vapor line will cut back on the amount of vented to the CGC 2 Stage Discharge Drum.
The liquid from the reflux drum, is pumped by the Propylene Fractionator No. 1 Reflux Pumps and sent as
reflux to the top of Propylene Fractionator No. 1. A pasteurization section is provided at the top of
Propylene Fractionator No.1 to strip residual hydrogen added in the MAPD Converter from the propylene.
The propylene product (99.5% purity) is withdrawn as a side draw from tower No. 1, and is pumped by
the Propylene Product Pumps and sent to the Propylene Treater Feed Cooler. A flow ratio controller
controls this product side-draw, maintaining a constant ratio to the reflux flow. This prevents the draw-off
of off-spec Propylene Product.
Tower reboiler duty for tower Propylene Fractionator No. 1 is provided by quench water sent to the
Propylene Fractionator No. 1 Reboiler. The bottoms product of tower No. 1 is pumped by the Propylene
Fractionator No. 2 Reflux Pump as reflux to the top of Propylene Fractionator No. 2.
The overhead vapor of Propylene Fractionator No.2 is sent to the bottom of Propylene Fractionator No. 1.
Tower reboiler duty for the tower No. 2 is provided by provided by quench water sent to the Propylene
Fractionator No. 2 Reboiler. The tower bottoms product, primarily propane, is sent to the Propane Feed
Vaporizer and the C4/C5 Feed Vaporizer Drum in the furnace feed system.
On-line analyzers are provided on the overhead and bottoms product to ensure product specifications are
met.

Bloomfield, NJ

2.4.2.20 Propylene Product System

Propylene product from the Propylene Product Pumps is cooled by cooling water in the Propylene Treater
Feed Cooler before entering the PG Propylene Treaters. In the Propylene Treaters, the polymer grade
propylene product is treated for reduction of COS to trace levels (<30 ppbw). The treated polymer grade
propylene is filtered then split into two streams. The first is a propylene rundown stream which is chilled
by propylene refrigerant in the Propylene Rundown Chiller Package. The propylene rundown (in liquid
phase) is sent to OSBL HP Storage. A level controller in OSBL Storage, sends a high level override to
control the flow if the level gets too high. Higher levels of rundown can be achieved during SCU turn
down. The second stream continues to OSBL HP Liquid Propylene Storage. Polymer grade propylene is
pumped from HP storage to product conditions. A provision is made for offspec propylene product to be
reprocessed in the Deethanizer.
One PG Propylene Treater is in operation while the second treater is being regenerated or on standby.
On-line analyzers are provided to detect the amounts of COS entering and leaving the treaters. A third
probe is placed in the bottom portion of the treater to detect breakthrough of impurities.
Regeneration of the PG Propylene Treaters is carried out by circulating hot methane-rich regeneration
gas from the Treater Regeneration Gas Electric Heater at 290°C to drive out the impurities adsorbed in
the treater bed. After the bed has reached the required temperature, the bed is cooled with unheated
regeneration gas. The spent regeneration gas is returned to the fuel gas system.
2.4.2.21 Debutanization
The LP Depropanizer bottoms stream containing C4 and heavier material is fed to the Debutanizer.
Polymerization Inhibitor from the Polymerization Inhibitor Package is injected into the main feed to the
Debutanizer to limit fouling in the tower. The Debutanizer is comprised of multiple valve trays and the
primary purpose of this tower is to separate a mixed C4 product sent to the Total Hydrogenation Unit
(THU) from a C5+ raw pyrolysis gasoline product sent to the Pyrolysis Gasoline Hydrogenation (PGH)
unit.
The gross overhead vapor of the Debutanizer is totally condensed in the Debutanizer Condenser by
cooling water before it enters the Debutanizer Reflux Drum. The tower overhead pressure is set by a “hot
vapor bypass”, where a portion of the gross overhead bypasses the condenser and is fed directly to the
reflux drum. In a high pressure scenario, a second pressure controller in the gross overhead vapor line
can open a vent on the reflux drum to the Wet Flare. If any non-condensables accumulate in the reflux
drum, a hand control (HC) provides the ability to send this material back to the Quench Tower for
reprocessing. Total liquid from the reflux drum is pumped by the Debutanizer Reflux Pumps and a
portion is sent as reflux back to the tower. The remaining overhead liquid product is sent to the THU. A
provision is made to send this mixed C4 product to OSBL storage; the ability to inject TBC into this stream
(to limit polymerization) is provided from the TBC Inhibitor Injection System.
Tower reboiler duty is provided by Low Pressure (LP) Steam in the Debutanizer Reboiler. A tray
temperature controller sets the temperature by resetting the set point of the flow controller on the LP
feeding the reboiler. The bottoms temperature of 130°C should be closely monitored and controlled to
limit fouling. The Debutanizer bottoms product, which is raw pyrolysis gasoline, is sent to the PGH unit.

Bloomfield, NJ

The raw pyrolysis gasoline is combined with gasoline from the Quench Tower, and cooled in the Pyrolysis
Gasoline Cooler by cooling water. Gasoline Polymerization Inhibitor from the Gasoline Polymerization
Inhibitor Package is injected into the raw pyrolysis gasoline product.
An on-line analyzer is provided to detect the top specification of the Debutanizer with measurements
made for C3 and C5 components. A second on-line analyzer detects C4 components that end up in the
raw pyrolysis gasoline product.
2.4.2.22 Propylene Refrigeration System

The Propylene Refrigeration system is a closed loop four stage system, which utilizes a steam turbine
driven centrifugal compressor. The system provides refrigeration at four levels: -40°C, -27°C, -10°C and
9°C.
The compressor discharge vapor is desuperheated and condensed by cooling water. The liquid propylene
refrigerant is subcooled against cold streams in the ROG and SCU areas before being used at each level.
During normal operation, propylene vapor extracted from the compressor 2nd stage discharge is
condensed against the ethylene fractionator side reboiler.
Major propylene refrigeration users in the SCU are the ethylene fractionator condenser, the binary
refrigerant condenser and the HP and LP depropanizer condensers. Other users are the charge gas area
and Demethanizer feed chilling.
The propylene refrigeration system also provides cooling to the ROG, PGH, and THU.
2.4.2.23 Binary Refrigeration System

The binary refrigeration system is a two-component, constant composition mixed refrigeration system
composed of methane and ethylene. It is a closed, three stage system utilizing a steam turbine driven
centrifugal compressor and dry mechanical seals. The system provides four levels of refrigeration to the
ethylene unit users from -40°C to -134°C. It supersedes the ethylene and methane refrigeration systems
of older plants.
The binary refrigerant (BR) compressor discharge vapors are cooled first against cooling water, partially
condensed against three levels of propylene refrigerant and finally condensed against itself in the cold
box. The condensed BR is sub-cooled against Demethanizer bottoms and further sub-cooled against
highest level BR. A portion of the sub-cooled BR stream is then let down to a lower pressure and fully
vaporized by the process users on each level. The remaining BR stream flows to the next lowest level
where it is again further sub-cooled and partially let down. Since the system has a constant composition,
it is not subject to the fluctuations in refrigeration temperature that can be the case with other mixed
refrigeration systems.
Makeup ethylene liquid is provided from HP ethylene storage while liquid methane is provided from the
Demethanizer Reflux Drum. In addition, ethylene vapor is provided from the LP ethylene product header
while makeup methane vapor is provided from the Demethanizer Reflux Drum.
The binary refrigeration system also provides cooling to the ROG unit.

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2.4.3 Total Hydrogenation Unit (THU)

The Total Hydrogenation Unit is designed to operate in two modes. For Design Case-1, the THU will
totally hydrogenate the mixed C4’s from the Debutanizer, the C4+ from the ROG Depentanizer and the
C5’s from the Pyrolysis Gasoline Hydrogenation (PGH) unit Depentanizer. For Design Case-2, the THU
will partially hydrogenate only the mixed C4’s from the Debutanizer and the C4+ from the ROG
Depentanizer; the C5’s are recycled directly to the Cracking Heaters.
The mixed C4’s and C4+ feedstock flows to the C4/C5 Feed Surge Drum, where it is combined with C5
recycle from the PGH Unit (only for Design Case-1). In the feed surge drum, any entrained water, if
present, is separated. The feed is then pumped by the C4/C5 Feed Pump to reactor pressure and mixed
with liquid recycle stream prior to entering the C4/C5 Hydrogenation Reactor.
The THU consists of two reactors; one operating and one spare. A single reactor may operate up to 1
year between regenerations. When End-of-Run conditions are reached, the catalyst is regenerated in-
situ using a conventional steam and air procedure. During the catalyst regeneration period, the spare
reactor may be used for processing the feed.
The recycle liquid from the C4/C5 HP Flash Drum is heated against liquid effluent from the reactor in the
C4/C5 Reactor Feed/Effluent Exchanger prior to mixing with the feed. This recycle liquid is required to
limit vaporization and temperature rise across the reactor. The reactor inlet temperature is controlled by
relative amounts of hot and cold recycle by bypassing the effluent exchanger. A feed preheater, using
MP Steam is provided for start-up only.
The majority of the hydrogen from the PSA Unit is added to the top bed on flow control while interbed
hydrogen injection is added on pressure control. The mixed phase feed passes downward through the
top catalyst bed where most of the butadiene and other diolefins are hydrogenated. The remaining
olefins are hydrogenated in the second bed. The exothermic heat of reaction causes the temperature to
rise. Liquid effluent from the reactor is cooled in the C4/C5 Reactor Feed/Effluent Exchanger. After
combining with the vapor effluent from the reactor, the mixture is partially condensed against cooling
water in the C4/C5 Reactor Effluent Condenser. Effluent from the condenser passes to the C4/C5 HP
Flash Drum where liquid recycle is separated and returned to be mixed with fresh feed to the reactor.
The C4/C5 HP Flash Drum vapor is chilled against Propylene Refrigerant in a vent condenser. Liquid
from the vent condenser flows back to the flash drum and non-condensables are recycled upstream of
the Caustic Tower Effluent Cooler for recovery. The net liquid product is withdrawn from the C4/C5 HP
Flash Drum and recycled back to the C4/C5 Feed Vaporizer Drum, where it is co-cracked in the Cracking
Heaters with the Propane Recycle from the Propylene Fractionator No.2 bottoms.

Bloomfield, NJ

2.4.4 Pyrolysis Gasoline Hydrogenation Unit (PGH)

The Pyrolysis Gasoline Hydrogenation Unit (PGH) is designed to hydrotreat and fractionate raw pygas
from the SCU and to produce the following products:
 C5 Cut Product
 C6 Cut – Light Pygas to Aromatics Extraction Unit
 C7-C8 Cut – Heavy Pygas Product
 C9+ Cut – Heavy Product
2.4.4.1 First Stage PGH Reaction

Raw Pyrolysis Gasoline from the Debutanizer bottoms and Quench Tower after cooling through the
Pyrolysis Gasoline Cooler is fed via filters, for the removal of solids, to the Pyrolysis Gasoline Coalescer,
for removal of any free water. The Raw Pyrolysis Gasoline is then fed to the Pyrolysis Gasoline Surge
Drum where it is then pumped by the PGH First Stage Reactor Feed Pumps to the PGH First Stage
Reactor.
The PGH First Stage Reactor system consists of two catalyst reactors, one operating and one spare. The
fresh feed is mixed with recycle liquid before entering the reactor. Make-up high purity hydrogen from the
PSA Unit, required for reaction, is charged separately to the reactor and enters the top of the reactor
under pressure control and travels down through the catalyst bed in intimate contact with the liquid phase.
The principal reactions occurring are the selective hydrogenation of diolefin, styrene, and indene
compounds to olefins, alkyl benzene, and indane, respectively. A portion of the olefins present are also
hydrogenated.
Pressure drop across the reactor increases from Start-of-Run to End-of-Run. In addition, catalyst activity
decreases with time, requiring raising the reactor inlet temperature.
Reactor inlet temperature is set by controlling the ratio of hot and cold recycle flow in accordance with a
fixed total recycle flow by bypassing the PGH First Stage Reactor Heater. The total quantity of recycle is
controlled to limit the exothermic temperature rise across the reactor. The total quantity of recycle flow
also serves to control fouling.
When the upper limit of operating temperature or pressure drop is reached and product quality can no
longer be maintained, the catalyst is regenerated in-situ using the reactor regeneration system (common
with the SCU) by a conventional steam/air procedure. The off-line reactor can be regenerated while the
other reactor is on-stream. Each reactor system has its dedicated recycle pump, recycle cooler and
recycle heater.
The reactor net effluent is cooled by the PGH First Stage Reactor Offgas Cooler against cooling water
and sent to the PGH First Stage HP Flash Drum where hydrogen-rich gas is separated from the liquid
product. Hydrogen-rich gas from this flash drum is sent to the PGH Recycle Compressor Suction Drum in
the PGH second stage system providing part of the hydrogen make-up requirements for the PGH Second
Stage Reactor. The liquid flows to the PGH First Stage LP Flash Drum where additional hydrogen-rich
gas is separated from the liquid product. Hydrogen-rich gas from this flash drum is combined with

Bloomfield, NJ

Depentanizer vent gas and LP Offgas from the H2S Stripper prior to being sent to the Charge Gas
nd
Compressor 2 Stage Suction Drum. The product liquid flows from the LP Flash Drum to the
Depentanizer for recovery of the C5 fraction.
2.4.4.2 First Stage PGH Fractionation

PGH first stage effluent flows to the Depentanizer where the partially hydrogenated feed is separated into
a C5 cut product stream and a C6+ stream. The tower is reboiled using MP steam in the Depentanizer
Reboiler, which is desuperheated to reduce fouling, and the overhead is condensed against cooling water
by the Depentanizer Condenser. The duty of the reboiler is controlled by a tray temperature controller
where the bottoms temperature is maintained below 150C to minimize fouling. The net C5 overhead
product is pumped by the Depentanizer Reflux Pumps and cooled by the C5 Product Cooler against
cooling water before being recycled to the Naphtha cracking heaters in the SCU. A portion of the net C5
overhead is recycled to the Total Hydrogenation Unit (THU). The balanced overhead product is recycled
back to the tower as reflux. Pressure in the Depentanizer Reflux Drum is controlled by purging of non-
condensables to the SCU CGC system. The C6+ bottoms product flows to the BTX Tower.
Depentanized PGH first stage effluent contains a high concentration of gum-forming compounds which
must be removed prior to hydrogenation in order to prevent fouling. These compounds are removed in
the BTX Tower. In the BTX Tower, the C6+ from the bottom of the Depentanizer is fractionated into two
cuts: a C6-C8 heart cut and a C9+ stream. The C9+ stream is cooled against cooling water in the C9
Plus Product Cooler and sent to battery limits. The BTX Tower is reboiled using MP steam in the BTX
Tower Reboiler, which is desuperheated to minimize fouling, and the tower overhead is condensed with
cooling water by the BTX Tower Condenser. A forced-circulation reboiler is used in order to limit fouling
of the reboiler tubes. The BTX Tower is operated under vacuum to lower the bottom temperature in order
to minimize fouling. Additionally, bottoms temperature is maintained below 160C to minimize fouling.
Non-condensable off gases are boosted using an ejector system, using MP steam as motive fluid, to a
pressure high enough to send the off gas the thermal oxidizer.
The net C6-C8 overhead heart cut product from the overhead of the BTX Tower is pumped to the
discharge of the PGH Recycle Compressor just before the PGH Second Stage Feed/Effluent Exchanger.
The balanced C6-C8 overhead is recycled back to the tower as reflux.
2.4.4.3 Second Stage PGH Reaction

First stage treated C6-C8 heart cut from the PGH Second Stage Reactor Feed Pumps is mixed with
hydrogen-rich recycle gas from the PGH Recycle Compressor. The two-phase mixture is heated by heat
exchange against the PGH Second Stage Reactor effluent in the PGH Second Stage Feed/Effluent
Exchanger to the required reactor inlet temperature. An HP steam exchanger is provided for start-up and
supplemental feed heating for EOR operation. Feed to the PGH Second Stage Reactor is 100% vapor.
In the PGH Second Stage Reactor, the olefins present in the feed are hydrogenated, and the sulfur
compounds are converted to hydrocarbons and H2S over the catalyst. The reactions are exothermic
resulting in a temperature rise across the reactor which is moderated by the recycle gas. The reactor
effluent preheats the reactor feed before finally being cooled and partially condensed against cooling
water in the PGH Second Stage Reactor Effluent Condenser.

Bloomfield, NJ

Pressure drop across the reactor increases from Start-of-Run to End-of-Run. In addition, catalyst activity
decreases with time, requiring raising the reactor inlet temperature.
When the upper limit of the operating temperature or pressure drop range is attained, the catalyst is
regenerated in-situ, using the reactor regeneration system (common with the SCU) by a conventional
steam/air procedure. The PGH Second Stage Reactor system consists of two catalyst reactors, one
operating and one spare. The off-line reactor can be regenerated while the other reactor is on-stream.
The cooled vapor/liquid reactor effluent mixture is separated in the PGH Second Stage HP Flash Drum.
The major portion of the vapor leaving this drum is mixed with the hydrogen vent gas from the PGH First
Stage Reactor section and additional high purity hydrogen from the PSA Unit which is then sent to the
PGH Recycle Compressor Suction Drum. Vapor from this drum is compressed in the PGH Recycle
Compressor and mixed with the C6-C8 heart cut from the PGH first stage. A small net vent flow from the
PGH Second Stage HP Flash Drum is sent upstream of the Caustic Tower Effluent Cooler to purge inerts
and maintain an optimum hydrogen balance. The liquid leaving the PGH Second Stage HP Flash Drum
is fed to the H2S Stripper via the H2S Stripper Feed/Bottoms Exchanger.
2.4.4.4 Second Stage PGH Fractionation

Second stage treated C6-C8 heart cut from the PGH Second Stage HP Flash Drum flows to the H2S
Stripper where H2S and light gasses are stripped from the heart cut product. The H2S Stripper operates
at sufficient pressure to send the stripped C6-C8 product to the Dehexanizer.
The overhead from the H2S Stripper is partially condensed against cooling water in the H2S Stripper
Condenser. The tower is reboiled using MP steam. The duty of the H2S Stripper Reboiler is set by the
flow control of the overhead stream. H2S and light gases are removed in the H2S Stripper and are vented
nd
from the H2S Stripper Reflux Drum to the Charge Gas Compressor 2 Stage Suction Drum. The
condensed overhead is recycled back to the stripper as reflux via the H2S Stripper Reflux Pumps. The
bottoms product of the H2S Stripper is cooled by preheating the H2S Stripper feed which then flows to the
Dehexanizer.
In the Dehexanizer, treated C6-C8 heart cut is fractionated into two cuts: C6 product and C7-C8 product.
The Dehexanizer is reboiled using MP steam and the tower overhead is condensed with cooling water in
the Dehexanizer Condenser. The duty of Dehexanizer Reboiler is controlled by a tray temperature
controller. The net overhead C6 product is pumped by the Dehexanizer Reflux/Product Pumps, cooled in
the C6 Product Cooler against cooling water and then sent to the Aromatics Extraction Unit (AEU).
Provisions are made to send the C6 cut product to OSBL storage and to send a portion as diluent for the
PGH Antioxidant Injection Package. The balanced C6 overhead product is recycled back to the tower as
reflux. The bottoms product is pumped by the Dehexanizer Bottom Pumps, cooled against cooling water
in the C7-C8 Product Cooler, and then sent to OSBL storage.
Provisions are made for antioxidant injection into the C6 cut and C7-C8 cut products sent to OSBL.

Bloomfield, NJ
CLIENT HMEL (HPCL Mittal Energy Ltd) 222334 Process Flow Diagrams
2.5 Process Flow Diagrams

PFD NO. AREA
A1-222334-1200A ROG Amine System
A1-222334-1200B ROG Caustic Water Wash
A1-222334-1200C ROG Oxygen Converter
A1-222334-1200D ROG Dryer/Treater
A1-222334-1200E ROG Chilling & Demethanizer
A1-222334-1200F ROG Depropanizer
A1-222334-1200G ROG DGA Storage
A1-222334-2000A Cracking Heater Feed System

A1-222334-2000B SRT-VI Cracking Heaters F-20001
A1-222334-2000C SRT-VII Cracking Heaters F-20002 thru F-20007
A1-222334-2000D Cracking Heater Steam Drum Blowdown System
A1-222334-2100A Gasoline Fractionator and Pyrolysis Fuel Oil Stripper
A1-222334-2100B Quench Tower
A1-222334-2100C Process Water Stripper and Dilution Steam Generation
A1-222334-2100D Flux Oil/Wash Oil Storage
A1-222334-2200A Charge Gas Compression Stages 1 & 2
A1-222334-2200B Acid Gas Removal – Amine System
A1-222334-2200C Acid Gas Removal – Caustic Water Wash
A1-222334-2200D Charge Gas Compression Stage 3
A1-222334-2200E Spent Caustic Pretreatment
A1-222334-2200F Charge Gas Drying and Regeneration
A1-222334-2200G Front-End High Pressure Depropanizer
A1-222334-2200H Front-End Low Pressure Depropanizer
A1-222334-2200J SCU MEA Storage
A1-222334-2300A Charge Gas Chilling Train (Part 1 of 2)
A1-222334-2300B Charge Gas Chilling Train (Part 2 of 2)
A1-222334-2300C Demethanizer
A1-222334-2300D Hydrogen Purification & Fuel Gas System
A1-222334-2400A Deethanizer
A1-222334-2400B Ethylene Fractionation and Ethylene Product System
A1-222334-2400C Propylene Fractionation
A1-222334-2400D Debutanizer
A1-222334-2400E Propylene Product System
A1-222334-2500A Propylene Refrigeration System (Part 1 of 2)
A1-222334-2500B Propylene Refrigeration System (Part 2 of 2)
A1-222334-2600A Binary Refrigeration System (Part 1 of 2)
A1-222334-2600B Binary Refrigeration System (Part 2 of 2)
A1-222334-2700A C4/C5 Hydrogenation Unit
A1-222334-2800A PGH First Stage Reactor

A1-222334-2800B PGH Depentanizer
A1-222334-2800C PGH Second Stage Reactor and H2S Stripper
A1-222334-2800D PGH Dehexanizer and BTX Columns
A1-222334-3100A ISBL Flare Knockout Drums

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
C-12001 E-12024 E-12020 E-12021A/B C-12020 E-12023 E-12022 V-12020 V-12021 NOTES:
A ROG DGA/WATER WASH LEAN DGA A
LEAN DGA/RICH DGA REGENERATOR DGA REGENERATOR DGA REGENERATOR DGA DGA REGENERATOR DGA REGENERATOR 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1
COLUMN COOLER
DGA EXCHANGER REBOILER CONDENSER RECLAIMER REFLUX DRUM HP FLASH DRUM OPERATION UNLESS OTHERWISE INDICATED.
2. FLOW MEASUREMENTS PRESSURE AND TEMPERATURE
COMPENSATED.
TO WET
FLARE
B B
PC
PC
PC
C 48
kg/cm²g 9.0
C C
FC
CW ACID GAS
FLARE
TC N2
LC
D D
C
kg/cm2g
E E
LC
FC
SP
FC
F F
LC C 54
kg/cm²g 9.3
SP
G FC FC
G
TO AMINE
DRAIN SYSTEM
LP DESUPERHEATED
STEAM MP STEAM
LC
LP COND.
H TC H
NNF
MP COND.
J CW J
NNF
NNF
MP
STEAM
CONDENSATE
LC
K LC K
FEB
0 2017 FOR PROPOSAL RK
FC
ISSUE PROC CLIENT
REV DESCRIPTION CAD LPE PDM PM
A DATE ENG
H2S
TO OSBL CO2 FC
C1
C2H4
LUMMUS PETROCHEMICALS
C 40 C2H6
C3H6 "THIS DOCUMENT IS THE PROPERTY OF LUMMUS TECHNOLOGY INC. (LUMMUS). IT CONTAINS CONFIDENTIAL
WASH WATER kg/cm²g 9.5 C3H8 INFORMATION DESCRIBING TECHNOLOGY OWNED BY LUMMUS. IT IS TO BE USED ONLY IN CONNECTION WITH
C4+ WORK PERFORMED BY LUMMUS. REPRODUCTION IN WHOLE OR IN PART FOR ANY PURPOSE OTHER THAN
L FROM WORK PERFORMED BY LUMMUS IS FORBIDDEN EXCEPT BY EXPRESS WRITTEN PERMISSION OF LUMMUS. IT IS L
E-20014 TO BE SAFEGUARDED AGAINST BOTH DELIBERATE AND INADVERTENT DISCLOSURE TO ANY THIRD PARTY."
DWG. 2000D PROCESS FLOW DIAGRAM

BL BL REFINERY OFF GAS (ROG) UNIT
REFINERY OFF GAS WASH WATER REFINERY
AMINE SYSTEM
HYDROCARBON VENT MAKEUP AMINE 20% CAUSTIC SOLUTION DGA SLUDGE
TO TO OFF GAS TO TO FROM FROM TO
C-12002 NEUTRALIZATION FROM C-21003 K-12001 T-12001 P-22008A/B DRUMS
M DWG. 1200B DWG. 2200C OSBL DWG. 2100B DWG. 1200C DWG. 1200G DWG. 2200C DOC. No: M
SCALE: DWG. No: REV:
6 NONE A1-222334-1200A 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
C-12002 E-12003 V-12005 NOTES:
ROG CAUSTIC/WATER ROG DRYER/TREATER ROG DRYER/TREATER
A WASH TOWER FEED CHILLER FEED GAS KO DRUM 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1 A
OPERATION UNLESS OTHERWISE INDICATED.
B B
TC
C
kg/cm²g TO TCV ON
9°C C3R
DWG. 2500B E-12003 C3R INLET C
FC
DWG. 2500B kg/cm²g
C C
LC
LC
D LC D
LC
C
kg/cm²g
E E
C
kg/cm²g FC
#2
A LC
CO2
F H2S F
LOW LEVEL OVERRIDE

#1
FI
G LC G
C PV FFC
kg/cm²g "A"
NNF
NNF
H H
FI
"B"
NNF
J FC J
NNF
K K
P-12001A/B P-12002A/B FEB
ROG WEAK CAUSTIC ROG STRONG CAUSTIC ISSUE PROC CLIENT
CIRCULATION PUMPS CIRCULATION PUMPS DATE ENG
"THIS DOCUMENT IS THE PROPERTY OF LUMMUS TECHNOLOGY INC. (LUMMUS). IT CONTAINS CONFIDENTIAL
INFORMATION DESCRIBING TECHNOLOGY OWNED BY LUMMUS. IT IS TO BE USED ONLY IN CONNECTION WITH
WORK PERFORMED BY LUMMUS. REPRODUCTION IN WHOLE OR IN PART FOR ANY PURPOSE OTHER THAN
L WORK PERFORMED BY LUMMUS IS FORBIDDEN EXCEPT BY EXPRESS WRITTEN PERMISSION OF LUMMUS. IT IS L
TO BE SAFEGUARDED AGAINST BOTH DELIBERATE AND INADVERTENT DISCLOSURE TO ANY THIRD PARTY."
PROCESS FLOW DIAGRAM

NNF
REFINERY OFF GAS (ROG) UNIT
REFINERY OFF GAS REFINERY OFF GAS REFINERY OFF GAS SPENT 20% CAUSTIC WASTE WATER WASH WATER REFINERY OFF GAS
CAUSTIC/WATER WASH
FROM TO FROM CAUSTIC SOLUTION TO FROM TO
E-12006 E-12004 C-12001 TO TREATMENT FROM SPENT CAUSTIC E-20014 V-12006A/B
M-22002 P-22008A/B NEUTRALIZATION
M DWG. 1200C DWG. 1200C DWG. 1200A DWG. 2200E DWG. 2200C DWG. 2200C DWG. 2000D DWG. 1200D DOC. No: M
5 NONE A1-222334-1200B 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
K-12001A/B E-12006 E-12004 E-12005 R-12001A/B NOTES:
A RECYCLE GAS ROG OXYGEN CONVERTER ROG OXYGEN CONVERTER ROG OXYGEN CONVERTER ROG OXYGEN A
COMPRESSOR EFFLUENT COOLER FEED/EFFLUENT EXCHANGER FEED HEATER CONVERTER 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1
B B
TO TO WET
ATM. FLARE
C C
NNF
NNF
SOR EOR NNF
C 221 240
kg/cm²g 8.4 8.4
START-UP
D D
TC
HS HP COND.
E E
DMDS INJECTION SOR EOR
FROM C 235 260
ME-12001 REGENERATION
C 500
kg/cm²g 1.0
F F
DMDS INJECTION
FROM
ME-12001
G G
CWS
H H
#2 A #1
C2H2
J C2H4 J
CO
O2
NOX
NNF
K K
FEB
ISSUE PROC CLIENT
DATE ENG
C AMB C AMB C AMB INFORMATION DESCRIBING TECHNOLOGY OWNED BY LUMMUS. IT IS TO BE USED ONLY IN CONNECTION WITH
L kg/cm²g 3.0 kg/cm²g 3.0 kg/cm²g 3.5 WORK PERFORMED BY LUMMUS. REPRODUCTION IN WHOLE OR IN PART FOR ANY PURPOSE OTHER THAN
WORK PERFORMED BY LUMMUS IS FORBIDDEN EXCEPT BY EXPRESS WRITTEN PERMISSION OF LUMMUS. IT IS L
BL BL BL
VENT LDPE/HDPE HDPE PP PP REFINERY OFF GAS REFINERY OFF GAS REACTOR REGEN. GAS PURGE GAS
OXYGEN CONVERTER
FROM RECYCLE RECYCLE RECYCLE RECYCLE TO FROM FROM TO
V-12021 TO V-2202 C-12002 C-12002 E-22031 C-21003
M DWG. 1200A DWG. 2200A DWG. 1200B DWG. 1200B DWG. 2200F DWG. 2100B DOC. No: M
3 NONE A1-222334-1200C 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
V-12006A/B V-12012A/B NOTES:

A ROG DRYER/ LPG TREATER 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1
A
TREATER OPERATION UNLESS OTHERWISE INDICATED.
2. ONLY USED IF KOG UNIT IS SOWN.
B B
PC
TO FUEL GAS
DWG. 2300D
TO WET FLARE
REGENERATION
C C
PRESSURIZING
REGENERATION
D D
#3
E E
H2O
#2 A
#1
#2
F F
#1 A #3
H2O
CO2
H2S
NOX
NH3 A
G C2H4 G
C2H6
START-UP
C3H6
C3H8
BD
C4's
C5+
FC
BULK DRAIN
H H
P-12008A/B
LPG TREATER DRAIN
TO FUEL PUMPS
GAS TO WET
DWG. 23001D FLARE
J J
NNF
PC TC
PC FC
NNF
K K
FEB
ISSUE PROC CLIENT
DATE ENG
HEEL DRAIN
SP
FC
COOLING GAS
NOTE 2 "THIS DOCUMENT IS THE PROPERTY OF LUMMUS TECHNOLOGY INC. (LUMMUS). IT CONTAINS CONFIDENTIAL
HEATING GAS

BL
REFINERY OFF GAS TREATED OFF GAS REGEN GAS REGEN GAS REGEN GAS MIXED LPG MIXED LPG MIXED LPG REGENERATION GAS HEEL DRAIN REGENERATION GAS
DRYING AND TREATING
FROM TO FROM FROM TO TO C-12004 FROM TO TO TO FROM
V-12005 ME-12000-E01 ME-23000-E06 E-24018 E-22009 ME-12000-E01 E-22009 C-21003 E-24018
M DWG. 1200B DWG. 1200E DWG. 2200F DWG. 2200F DWG. 2200F DWG. 1200F OSBL DWG. 1200E DWG. 2200F DWG. 2100B DWG. 2200F DOC. No: M
5 NONE A1-222334-1200D 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
ME-12000-E01 ME-12000-E02 C-12003 E-12007 ME-12000-E03 V-12007 NOTES:

A A
ROG COLD BOX ROG COLD BOX ROG ROG DEMETHANIZER ROG DEMETHANIZER ROG DEMETHANIZER 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1
EXCHANGER No. 1 EXCHANGER No. 2 DEMETHANIZER REBOILER CONDENSER REFLUX DRUM OPERATION UNLESS OTHERWISE INDICATED.
(PART OF ME-12000) (PART OF ME-12000) (PART OF ME-12000)
B B
TO TCV
ON ME-12000-E03
INLET
DWG. 2600B
TC
C 9°C -10°C -27°C -40°C BR C

C3R FROM C3R FROM C3R FROM C3R FROM FROM
V-25010 V-25011 V-25012 V-25013 V-26004 BR
FROM
DWG. 2500B DWG. 2500B DWG. 2500A DWG. 2500A DWG. 2600B
DWG. 2600B
ME-12000-E01 ME-12000-E02
BR
FROM ME-12000-E03
DWG. 2600B
D D
LC
BR
FROM
TO LCV ON DWG. 2600B
V-25010
DWG. 2500B
LOW TEMP.
OVERRIDE
E SP E
FC
TC A
TO TV
C2H4 °C °C °C
DWG. 2600B
C2H6
C3H8 C
FC TC
°C °C P-12003A/B
B
F RDG DEMETHANIZER F
REFLUX PUMPS
°C °C
METHANOL
A INJECTION
ME-12002
TO FCV
TC ON E-12007
DWG. 2500B
G G
PC
LC
°C °C
H H
48°
C3R
DWG. 2500B
E-12007
METHANOL
J INJECTION
J
ME-12002
K SP
K
FEB
FC A
ISSUE PROC CLIENT
DATE ENG
CH4
P-12004A/B INFORMATION DESCRIBING TECHNOLOGY OWNED BY LUMMUS. IT IS TO BE USED ONLY IN CONNECTION WITH
L NNF WORK PERFORMED BY LUMMUS IS FORBIDDEN EXCEPT BY EXPRESS WRITTEN PERMISSION OF LUMMUS. IT IS L
ROG DEMETHANIZER TO BE SAFEGUARDED AGAINST BOTH DELIBERATE AND INADVERTENT DISCLOSURE TO ANY THIRD PARTY."
BOTTOMS PUMPS
CHILLING & DEMETHANIZER
TREATED C2+
ROG FUEL GAS ROG HEAVIES MIXED LPG TREATED OFF GAS LIGHTS TO
TO FROM FROM FROM FROM C-12004
REGENERATION C-12004 V-12012A/B V-12006A/B V-12008
FUEL GAS DWG. 1200F
M DOC. No: M
DWG. 2300D DWG. 1200F DWG. 1200D DWG. 1200D DWG. 1200F
5 NONE A1-222334-1200E 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
C-12004 E-12008 E-12009 V-12008

A ROG DEPROPANIZER ROG DEPROPANIZER ROG DEPROPANIZER ROG DEPROPANIZER
NOTES: A
REBOILER CONDENSER REFLUX DRUM
1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1
B PC TO PCV ON C3R B
DWG. 2500A
PC
C C
C
TO COLD
D kg/cm²g D
FLARE
HC
-27°C C3R
DWG. 2500A
NNF
E E
NNF
C
kg/cm²g
LC
F F
TC
C
kg/cm²g
LC
METHANOL
SP INJECTION
G FC ME-12002 G
LPS LP COND.
NNF
#2 A #1
H CH4 H
C2H4
C2H6
C3H6
C3H8
FC
J J
P-12027A/B P-12005A/B
ROG DEPROPANIZER ROG DEPROPANIZER
BOTTOMS PUMPS REFLUX PUMPS
LOW LEVEL FC
K OVERRIDE K
SP FEB
FC 0 2017 FOR PROPOSAL RK
ISSUE PROC CLIENT
DATE ENG
SP FC

TREATED C2+ MIXED LPG ROG HEAVIES ROG HEAVIES TREATED C2's/C3's LIGHTS DEPROPANIZER
BOTTOMS TO WASH TO TO TO
FROM THU ME-12000-E01 C-24001 ME-12000-E01
P-12004A/B
M DWG. 1200E DWG. 1200D DWG. 2700A DWG. 1200E DWG. 2400A DWG. 1200E DOC. No: M
3 NONE A1-222334-1200F 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
T-12001 V-12025
A DGA DGA NOTES: A
STORAGE TANK DRAIN DRUM
2. INITIAL DGA FILL FROM TRUCK.
B B
C C
D D
TO ACID GAS
FLARE
"B"
E E
N2
"A" V-12025
PC LC ON/OFF DGA MAKE-UP
PM FROM DRUMS
F F
PC
N2
T-12001
G G
FC
H P-12025 H
PM
DGA
SUMP PUMPS
P-12026A/B
DGA MAKEUP
PUMPS
J FC J
TRUCK
UNLOADING
(NOTE 2)
K K
FEB
ISSUE PROC CLIENT
DATE ENG

WATER / DGA MAKEUP WATER MAKEUP DGA DGA STORAGE
TO FROM DRAIN
C-12020 E-20014
M DWG. 1200A DWG. 2000D DOC. No: M

2 NONE A1-222334-1200G 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
E-20018 V-21001 E-20019 E-20025 E-20026

A PROPANE FEED PROPANE FEED ETHANE FEED C4/C5 FEED C4/C5 FEED C4/C5 FEED NAPHTHA FEED KERO FEED A
VAPORIZER HEATER PREHEATER HEATER VAPORIZER DRUM VAPORIZER PREHEATER PREHEATER 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1
2. SIX CRACKING HEATERS ARE IN OPERATION,
ONE CRACKING HEATER IS STANDBY.
3. SPILLOVER OF PROPANE RECYCLE FOR BALANCING
WET FLARE IN CASE 1.
PC A TO FC ON
B C2 FEED C 60 B
MW DWG. 2000B/2000C kg/cm²g 8.0
WET FLARE
ETHANE
PC A TO FC ON
C3 FEED C 60 NOTE 2
MW DWG. 2000B/2000C kg/cm²g 8.0
C C
F-20001
DWG. 2000B
F-20002
TC TC TO FC ON C 85
TC A C4 FEED DWG. 2000C
kg/cm²g 8.0
PROPANE
D MW DWG. 2000B/2000C D
C4/C5
SP SP
FC FC SP F-20003
FC DWG. 2000C
C3'S A
QW QW C4'S
DWG. 2100B DWG. 2100B C5'S C 60
LPS
kg/cm²g 8.0 F-20004
DWG. 2000C
E E
NAPHTHA
F-20005
TO WET FLARE
A TO FC ON
DWG. 2000C
KEROSENE
NAPHTHA MIX FEED
DENSITY DWG. 2000B/2000C
PC PIONA
F-20006
F DWG. 2000C F
PC
PC F-20007
PC
DWG. 2000C
C 82 C 60
kg/cm²g 8.3 kg/cm²g 8.0
G G
TC TC
SP SP
LC FC FC
SP QW QW
FC DWG. 2100B DWG. 2100B
HIGH LEVEL
OVERRIDE
H H
LPS
TO FC ON
FC C4/C5 RECYCLE
DWG. 2700A
PC
J J
LC NOTE 3
QW
DWG.
2100B
HIGH LEVEL
OVERRIDE
NNF
K FC
K
FEB
NNF
ISSUE PROC CLIENT

DATE ENG
TO FC ON
PROPANE
RECYCLE
DWG. 2400C
L C 40 C 45 C 40 WORK PERFORMED BY LUMMUS IS FORBIDDEN EXCEPT BY EXPRESS WRITTEN PERMISSION OF LUMMUS. IT IS L
kg/cm²g 9.0 kg/cm²g 12 kg/cm²g 6.0 TO BE SAFEGUARDED AGAINST BOTH DELIBERATE AND INADVERTENT DISCLOSURE TO ANY THIRD PARTY."

BL BL
STEAM CRACKER UNIT
ETHANE PROPANE HYDROGENATED HEAVY NAPHTHA START-UP NAPHTHA C6 RAFFINATE C5 RECYCLE KERO/HEAVY
CRACKING HEATER FEED SYSTEM
RECYCLE RECYCLE C4/C5's LIQUID FROM TO FROM FROM NAPHTHA
FROM FROM FROM TO STORAGE V-28002 BZEU PGH UNIT
ME-23000-E06 C-24004 THU C-21003 (VIA STORAGE)
M DWG. 2300A DWG. 2400C DWG. 2700A DWG. 2100B DWG. 2800A OSBL DWG. 2800B
DOC. No: M
OSBL OSBL
11 NONE A1-222334-2000A 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
FROM FC's
NOTES:
A ON OTHER "B" COILS 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1 A
TO FFC B OPERATION UNLESS OTHERWISE INDICATED.
PV
TO OTHER SP FC SP 2. 8 COILS PER HEATER.
NOTE 2,3 "B" COIL FC's B 4 COILS PER CELL.
BIAS FROM PC
TO OTHER PV SP FC TDC B 3. CASE 1: SPLIT CRACKING ETHANE (2 COILS) AND PROPANE (2 COILS)
"B" COILS FROM ANALYZER
B IN CELL "A" AND 100% ETHANE CRACKING IN CELL "B"
ON FEED LINES
DWG. 2000A NOTE 7 CASE 2: 100% ETHANE CRACKING IN BOTH CELLS.
TO 4. ONE SAMPLE CONDITIONING SYSTEM PER CELL. MAXIMUM
B FIVE CONNECTIONS PER ANALYZER.
B
FROM FC's FFC ATMOSPHERE
ON OTHER "A" COILS TO ATMOSPHERE A 5. ETHANE/PROPANE CRACKED GAS TO VISCOSITY CONTROL FOR
FROM FC's TO OTHER TO OTHER F-20001 ONLY. FLOW CONTROL VALVE REQUIRED FOR F-20001 ONLY.
PV HC ON OTHER "A" COILS "A" COILS "B" COILS
TO NAPHTHA NOTE 2 A NOTE 2 6. PURGE STEAM FOR QUENCH FITTINGS, PRESSURE & SAMPLE
TO OTHER SP FC SP SP BIAS FROM FC A
NOTE 2,3 PV CONNECTIONS, TLV, DECOKE VALVES.
COIL "A" FC's A TDC A O2,NOx,
NNF
TO OTHER CO 7. IN OPERATION DURING DECOKING ONLY.
PV SP FC TO OTHER SP FC SP SP BIAS FROM
"A" COIL FROM ANALYZER FFC
A COIL "A" FC's A FC B UFP = UPPER FEED PREHEAT
ON FEED LINES B BFW = BOILER FEED WATER
DWG. 2000A PV SP FC SP LFP = LOWER FEED PREHEAT
C UMP = UPPER MIXED PREHEAT C
A
FROM ANALYZER USSH = UPPER STEAM SUPERHEAT
ON FEED LINES MSSH = MIDDLE STEAM SUPERHEAT
DWG. 2000A UFP LSSH = LOWER STEAM SUPERHEAT
LMP = LOWER MIXED PREHEAT
BFW
NOTE 2,3
D TO OTHER D
"A" COILS
LFP
AT SUPERHEATER OUTLET
UMP
FI
E E
DECOKE
AIR
FROM ME-20001 AT VHP STEAM HEADER
USSH
FC
FC
F F
MSSH
TC
NOTE 2 PFO
TO OTHER GF
TC
"B" COILS
G LSSH G
NOTE 2
TO OTHER TO
"A" COILS PC FCB FC
TDC AVG.
LMP
LC A
TDC
LC TC B FROM
A TI'S
AVG
H A A ON OTHER F-20001 F-20002 F-20003 F-20004 F-20005 F-20006 F-20007 H
A TC "B" COILS
FROM TI's O2 O2 B
pH ON OTHER "A" COILS AVG
NNF
TI CELL CELL TI
A
"A" "B"
CONDUCTIVITY TO V-20015 TO
DWG. 2000D
TLE'S
HC HC
J BLOWDOWN AIR SEC. SEC. J
TO V-20014 PRIM. PRIM.
DAMPER
DWG. 2000D AIR DAMPER
INTEGRAL
HC
INTEGRAL
FROM OTHER HC
TLE'S
A QC
TO OTHER A QC
NOTE 4
HEATERS A C02
K C1 K
FEB
C2 QC 0 2017 FOR PROPOSAL RK
C2 NNF DECOKE EFFLUENT
B ISSUE PROC
C3 REV
DATE
DESCRIPTION CAD
ENG
LPE PDM PM CLIENT
C3
NOTE 6 DMDS
FC INJECTION
ME-20001 ME-20002 QC FROM ME-12001 LUMMUS PETROCHEMICALS
FROM
WOBBE METER "THIS DOCUMENT IS THE PROPERTY OF LUMMUS TECHNOLOGY INC. (LUMMUS). IT CONTAINS CONFIDENTIAL
DWG. 2300D WORK PERFORMED BY LUMMUS. REPRODUCTION IN WHOLE OR IN PART FOR ANY PURPOSE OTHER THAN
L QC L
NOTE 5
WORK PERFORMED BY LUMMUS IS FORBIDDEN EXCEPT BY EXPRESS WRITTEN PERMISSION OF LUMMUS. IT IS

NOTE 5 QC DILUTION STEAM TO BE SAFEGUARDED AGAINST BOTH DELIBERATE AND INADVERTENT DISCLOSURE TO ANY THIRD PARTY."
FROM
E-21010 PROCESS FLOW DIAGRAM
DWG. 2100C STEAM CRACKER UNIT
SRT VI CRACKING HEATER
PROPANE
RECYCLE
ETHANE
RECYCLE
DECOKING AIR
TO
PHOSPHATE
FREE
PURGE STEAM
FROM
CRACKED GAS
TO
CRACKED GAS
TO
PHOSPHATE
TO
FUEL GAS
FROM VHP STEAM
F-20001
FROM FROM F-20002 THRU BFW E-21010 C-21001 C-21002 F-20002 THRU V-23005 TO
M E-20022 E-20021 F-20007 FROM P-32005A-C F-20007 HEADER DOC. No: M
DWG. 2000A DWG. 2000A DWG. 2000C DWG. 3200A DWG. 2100C DWG. 2100A DWG. 2100A DWG. 2000C DWG. 2300D
7 NONE A1-222334-2000B 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
(NOTE 7)
A
FROM FC's NOTES: A
ON OTHER "B" COILS
TO FFC B 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1
PV OPERATION UNLESS OTHERWISE INDICATED.
TO OTHER SP FC SP
NOTE 4,5 "B" COIL FC's B PC 2. F-20002 WILL HAVE THE FLEXIBILITY TO CRACK ETHANE/PROPANE
BIAS FROM RECYCLE AND C4/C5 FEED.
TO OTHER PV SP F-20003 WILL HAVE THE FLEXIBILITY TO CRACK C4/C5 FEED
FC TDC B
"B" COILS FROM ANALYZER B RECYCLE AND NAPHTHA+C5/C6 RECYCLE.
ON FEED LINES
DWG. 2000A NOTE 7 F-20004 WILL HAVE THE FLEXIBILITY TO CRACK ETHANE/PROPANE
RECYCLE, C4/C5 FEED, NAPHTHA+C5/C6 RECYCLE AND KEROSENE.
B TO F-20005 WILL HAVE THE FLEXIBILITY TO CRACK NAPHTHA+C5/C6 B
FROM FC's FFC ATMOSPHERE RECYCLE AND KEROSENE.
ON OTHER "A" COILS TO ATMOSPHERE A F-20006 WILL HAVE THE FLEXIBILITY TO CRACK NAPHTHA+C5/C6
FROM FC's TO OTHER TO OTHER RECYCLE AND KEROSENE.
PV HC ON OTHER "A" COILS "A" COILS "B" COILS F-20007 WILL HAVE THE FLEXIBILITY TO CRACK NAPHTHA+C5/C6
TO NAPHTHA NOTE 4 A NOTE 4 RECYCLE AND KEROSENE.
TO OTHER SP FC SP SP BIAS FROM FC A
NOTE 4,5 COIL "A" FC's A TDC A PV 3. ONE SAMPLE CONDITIONING SYSTEM PER CELL.
O2,NOx, MAXIMUM FIVE CONNECTIONS PER ANALYZER.
NNF
TO OTHER CO
PV SP FC TO OTHER SP FC SP SP BIAS FROM
"A" COILS FROM ANALYZER FFC 4. 14 COILS PER HEATER, 7 COILS PER CELL, 2 CELLS PER HEATER.
A COIL "A" FC's A FC B
ON FEED LINES B 5. CASE 1: SPLIT CRACKING C4/C5 FEED (4 COILS) AND NAPHTHA
DWG. 2000A PV SP FC SP
C (3 COILS) IN CELL "A" AND 100% NAPHTHA CRACKING IN C
A
FROM ANALYZER CELL "B" IN ONE HEATER (F-20003 OR F-20004).
ON FEED LINES CASE 2: SPLIT CRACKING C4/C5 FEED (4 COILS) AND NAPHTHA
DWG. 2000A UFP
(3 COILS) IN CELL "A" AND 100% NAPHTHA CRACKING IN
CELL "B" IN ONE HEATER (F-20003 OR F-20004). SPLIT
CRACKING NAPHTHA (3 COILS) AND KERO (4 COILS)
FROM FC's IN CELL "A" AND 100% KERO CRACKING IN CELL "B" IN
ON OTHER "B" COILS ONE HEATER (F-20006 OR F-20007).
BFW
TO FFC B
PV 6. PURGE STEAM FOR QUENCH FITTINGS, PRESSURE & SAMPLE
NOTE 4,5 CONNECTIONS, TLV, DECOKE VALVES.
D TO OTHER SP FC SP D
TO OTHER 7. IN OPERATION DURING DECOKING ONLY.
"B" COIL FC's B
"A" COILS BIAS FROM
SP FC TDC B UFP = UPPER FEED PREHEAT
FROM ANALYZER BFW = BOILER FEED WATER
B LFP LFP = LOWER FEED PREHEAT
ON FEED LINES
DWG. 2000A UMP = UPPER MIXED PREHEAT
DSSH = DILUTION STEAM SUPERHEAT
USSH = UPPER STEAM SUPERHEAT
MSSH = MIDDLE STEAM SUPERHEAT
UMP LSSH = LOWER STEAM SUPERHEAT
LMP = LOWER MIXED PREHEAT
FI
E E
DSSH
AT SUPERHEATER OUTLET
USSH
FC AT VHP STEAM HEADER

FC DECOKE
AIR
FROM ME-20001
F F
MSSH
TC
NOTE 4 NOTE 4,5
TO OTHER TO OTHER
TC PFO GF
"B" COILS "B" COILS
G LSSH G
NOTE 4
TO OTHER LC TO
"A" COILS PC FCB
TDC AVG.
LMP FC
LC A
TDC
TC B FROM
A TI'S
A AVG
H A A ON OTHER H
pH TC "B" COILS F-20001 F-20002 F-20003 F-20004 F-20005 F-20006 F-20007
FROM TI's O2 O2 B
ON OTHER "A" COILS
NNF
A AVG
FROM
CONDUCTIVITY TO V-20015 OTHER
DWG. 2000D TLE TI CELL CELL TI
"A" "B"
BLOWDOWN TO
TO V-20014
DWG. 2000D TLE'S
HC HC
J AIR PRIM. SEC. PRIM. SEC. J
DAMPER
AIR DAMPER
INTEGRAL
HC
INTEGRAL
HC
TO OTHER TO OTHER QC
TO OTHER
HEATERS HEATERS QC
K HEATERS A K
QC FEB
A B ISSUE PROC CLIENT
NOTE 3 DMDS DATE ENG
C02 INJECTION
A FROM A-130
C1
C2-
NNF DECOKE EFFLUENT DWG. ME-12001 LUMMUS PETROCHEMICALS
C2 QC
NOTE 2 C3- FROM "THIS DOCUMENT IS THE PROPERTY OF LUMMUS TECHNOLOGY INC. (LUMMUS). IT CONTAINS CONFIDENTIAL
C3 WOBBE METER INFORMATION DESCRIBING TECHNOLOGY OWNED BY LUMMUS. IT IS TO BE USED ONLY IN CONNECTION WITH
NAPHTHA ETHANE PROPANE NOTE 6 DWG. 2300D DILUTION STEAM WORK PERFORMED BY LUMMUS. REPRODUCTION IN WHOLE OR IN PART FOR ANY PURPOSE OTHER THAN
L FROM RECYCLE RECYCLE FROM WORK PERFORMED BY LUMMUS IS FORBIDDEN EXCEPT BY EXPRESS WRITTEN PERMISSION OF LUMMUS. IT IS L
E-20025 FROM FROM E-21010 TO BE SAFEGUARDED AGAINST BOTH DELIBERATE AND INADVERTENT DISCLOSURE TO ANY THIRD PARTY."
E-20021 E-20022
DWG. 2000A DWG. 2000A DWG. 2000A DWG. 2100C
NOTE 2 NOTE 2 STEAM CRACKER UNIT
KEROSENE DECOKING AIR C4/C5 FEED PHOSPHATE CRACKED GAS PURGE STEAM PHOSPHATE FUEL GAS SRT VII CRACKING HEATERS
FROM FROM FROM FREE TO FROM FROM FROM VHP STEAM
E-20026 ME-20001 E-20018 BFW
FROM P-32005A-C
M-20001A/B E-21010 ME-20002 V-23005 TO
HEADER
F-20002 THRU F-20007
M DWG. 2000A DWG. 2000B DWG. 2000A DWG. 2000A DWG. 2100A DWG. 2000C DWG. 2000B DWG. 2300D DOC. No: M
NOTE 2 SCALE: DWG. No: REV:
6 NONE A1-222334-2000C 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
V-20014 E-20014 V-20015 E-20015 NOTES:

A A
VHP STEAM CONTINUOUS CONTINUOUS BLOWDOWN VHP STEAM INTERMITTENT INTERMITTENT BLOWDOWN 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1
BLOWDOWN DRUM COOLER BLOWDOWN DRUM COOLER OPERATION UNLESS OTHERWISE INDICATED.
B B
C C
PC
ATM
D D
E E
LC
LC
F F
CWS
NNF
CWS
G G
TC
BFW
H H
J J
K K
FEB FOR PROPOSAL RK
0 2017
ISSUE PROC CLIENT
DATE ENG
NNF
NNF

STEAM CRACKER UNIT
MP STEAM CONTINUOUS CONTINUOUS WASH WATER WASH WATER WASH WATER WASH WATER WASH WATER WASH WATER INTERMITTENT INTERMITTENT WASTE WATER BLOWDOWN SYSTEM
TO BLOWDOWN BLOWDOWN TO TO TO TO TO TO BLOWDOWN BLOWDOWN TO
HEADER FROM FROM C-22002 C-12001 C-12002 C-22001 T-12001 T-22001 FROM FROM COOLING TOWER
V-20001 V-20002 - 7 V-20002 - 7 V-20001 BASIN
M DWG. 2000B DWG. 2000C DWG. 2200B DWG. 1200A DWG. 1200B DWG. 2200C DWG. 1200G DWG. 2200J DWG. 2000C DWG. 2000B OSBL DOC. No: M
6 A1-222334-2000D 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
A A
2. HP STEAM FOR VISCOSITY CONTROL STRIPPING WHEN
F-20001 IS UNAVAILABLE.
3. PFO STRIPPER BYPASS.
C 111 4. TWO TRANSFER LINES. ONE COMMON QUENCH FITTING PER
kg/cm²g 0.33 TRANSFER LINE LOCATED AT MINIMUM DISTANCE FROM
B C-21001. B
FC
5. QUENCH FITTING LOCATED IN HORIZONTAL MINIMUM
DISTANCE FROM C-21002 AND SLOPING TO C-21002.
FC 6. MINIMUM FLOW CONTROL.
7. NORMALLY NO FLOW, DESIGN FLOW = 1-3% OF
TOTAL QUENCH OIL FLOW.
8. INCLUDES V-2100G QUENCH OIL DRAIN DRUM VENT SEAL POT.
TC RESET FC
C C
C 265
TC kg/cm²g 0.43
D D
LC
PROCESS WATER
E STRIPPER FEED E
DWG. 2100C
HC
LI
C 190
kg/cm²g 0.43
LOW LEVEL OVERRIDE

F F
FC
MP
STEAM
NNF
LC C 208
G kg/cm²g 0.54 G
FC
DILUTION STEAM
DRUM FEED FC
DWG. 2100C
TC
MISC.
NNF
QO. DRAINS
H H
FC PM NNF
MP PURGE OIL FOR RETURN TO
STM FC INSTRUMENT FLUSH C-21001
AND PUMP SEAL
NOTE 4 A LP NOTE 3
STM NNF
VISC
NOTE 10
J J
SP
DILUTION PROCESS WATER FC
STEAM DWG. 2100C
NOTE 5
SP
FC
FC TC
FC
K ME-21000
NNF NOTE 2 K
HP FEB
STEAM
NNF ISSUE PROC
REV DESCRIPTION CAD LPE PDM PM CLIENT
QW DATE ENG
TO
DWG. 2100B
OTHER
USERS
DRYCOKE C 90 LUMMUS PETROCHEMICALS
kg/cm²g 4.1
NNF
CHARGE CRACKED GAS

GAS FROM PROCESS FLOW DIAGRAM
TO E-20002A-N
C-21003 THRU E-20007A-N STEAM CRACKER UNIT
BL BL
DWG. 2100B DWG. 2000C GASOLINE FRACTIONATOR AND
SPENT GASOLINE GASOLINE CRACKED GAS FLUX OIL QUENCH OIL CRACKED GAS BTX TOWER PFO PYROLYSIS FUEL OIL STRIPPER
FROM FROM FROM FROM TO FROM BOTTOM TO
V-22009 P-21006A/B E-20001A-H P-21009A/B E-20001A-H FROM STORAGE
M TANK/TRUCK LOADING P-28006A/B
DOC. No: M
DWG. 2200E DWG. 2100B DWG. 2000B DWG. 2100D OSBL DWG. 2000B DWG. 2800D OSBL SCALE: DWG. No: REV:
7 NONE A1-222334-2100A 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
A A
WET FLARE
B B
PC
FC
CW C 38
C C
CW
TO E-21005A-D
TC FC C 54
D D
FUEL GAS
FROM
DWG. 2100B
PC
E CW E
FROM E-21006A-D
INTERFACE
LI
F F
RESET TC LC
E-24011A/B
DWG.
NNF
2400C E-24012A/B AMINE INJECTION
REGENERATION
DWG. ME-21002
NNF
NNF
G 2400C G
NNF
NNF
KNOCK OUT
LIQUID GASOLINE LIQUID LIQUID HEEL DRAIN
FROM FROM FROM FROM FROM
V-23005 V-22002 V-28012 V-12021 V-12012A/B
DWG. 2300D DWG. 2200A DWG. 2800C DWG. 1200A DWG. 1200D
E-22003
DWG.
2200B PROCESS WATER PURGE GAS FROM
SPENT GASOLINE HEAVY LIQUID LIQUID LIQUID R-12001A/B
FROM FROM FROM FROM STRIPPER OVERHEAD R-24001A/B,
H V-22009 V-20012 WET FLARE DRUM V-22018 FROM R-27001A/B,
H
PDC C-21004
pH R-28001A/B & 28002A/B
A DWG. 2200E DWG. 2000A DWG. 2900A DWG. 2200B DWG. 2100C DWG. 2001G
E-21004A-D
RESET
DWG.
2100A E-24002
DWG.
2400A
E-20020
DWG.
2000A E-20022
J DWG. J
2000A
E-20025
DWG. PDC
2000A
NNF
NNF
NNF
E-20026
K K
REGENERATION
DWG. 2000A FEB
ISSUE PROC
FC REV
DATE
DESCRIPTION CAD
ENG
LPE PDM PM CLIENT
E-20021
DWG. 2000A LUMMUS PETROCHEMICALS
PDC
L WASH GASLINE OILY WATER CONDENSATE WORK PERFORMED BY LUMMUS. REPRODUCTION IN WHOLE OR IN PART FOR ANY PURPOSE OTHER THAN
L
TO FROM WATER FROM WORK PERFORMED BY LUMMUS IS FORBIDDEN EXCEPT BY EXPRESS WRITTEN PERMISSION OF LUMMUS. IT IS
E-22008 V-22004/V-22005 FROM S-23001A/B TO BE SAFEGUARDED AGAINST BOTH DELIBERATE AND INADVERTENT DISCLOSURE TO ANY THIRD PARTY."
P-22001A/B
DWG. 2200E DWG. 2200D DWG. 2200A DWG. 2300D
STEAM CRACKER UNIT
CHARGE GAS CHARGE GAS GASOLINE GASOLINE PROCESS WATER GASOLINE CONDENSATE LIQUID FROM QUENCH TOWER
TO FROM TO TO STRIPPER FEED FROM FROM P-3101A/B
V-22001 C-21001 E24015 C-21001 TO V-22004 V-22011
E-21008
M DWG. 2200A DWG. 2100A DWG. 2400D DWG. 2100A DWG. 2100C DWG. 2200D DWG. 2200F DWG. 3100A DOC. No: M
6 NONE A1-222334-2100B 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
A A
B B
FC
C C 109 C 176 C
D D
E E
PO FC
DWG. 2100A
LP STEAM QO
NNF DWG. 2100A LC
SP
FC
LC
F LP COND.
F
LP STEAM
MP MP STEAM
COND.
C 111 QO
kg/cm²g 0.47 DWG. 2100A
G G
NNF
FC FC SP
AMINE
INJECTION PC
FC SP ME-21002
H PC LOW H
NNF PRESSURE
BACK UP
A pH
NNF
CW
J J
A
PH
FC
PC PC
K K
FEB
ISSUE PROC CLIENT
DATE ENG
L C 45 WORK PERFORMED BY LUMMUS. REPRODUCTION IN WHOLE OR IN PART FOR ANY PURPOSE OTHER THAN
L
kg/cm²g 3.1 TO BE SAFEGUARDED AGAINST BOTH DELIBERATE AND INADVERTENT DISCLOSURE TO ANY THIRD PARTY."

BL STEAM CRACKER UNIT
PROCESS WATER PROCESS WATER BFW INJECTION BFW INJECTION MAKEUP WATER WASH WATER BLOWDOWN PURGE STEAM
TO
PURGE STEAM
TO F-20002
DILUTION STEAM DILUTION STEAM PROCESS WATER STRIPPING
STRIPPER OVHD STRIPPER FEED TO TO TO F-20001 TO F-20002
TO
C-21003
FROM
P-21005A/B
K-22001 TO K-22001
STAGE 3
FROM
P-32005A/B/C
TO
M-22003 WWTP F-20001 THRU F-20007 THRU F-20007 AND DILUTION STEAM GENERATION
STAGES 1 & 2 (PHOSPHATE FREE)
M DWG. 2100B DWG. 2100B DWG. 2200A DWG. 2200D DWG. 3200A DWG. 2200E DWG. 2000B DWG. 2000C DWG. 2000B DWG. 2000C DOC. No: M
6 NONE A1-222334-2100C 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
T-21001 T-21002 NOTES:

A FLUX OIL WASH OIL A
STORAGE TANK STORAGE TANK 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1
B B
C C
LI
N2
D D
E E
TRUCK
UNLOADING
LI
N2
F F
G G
TRUCK
UNLOADING
P-21010
WASH OIL P-21010A/B
PUMP FLUX OIL
PUMPS
H H
J J
K K
FEB FOR PROPOSAL RK
0 2017
ISSUE PROC CLIENT
DATE ENG
BL BL
STEAM CRACKER UNIT
FLUX OIL
FROM
WASH OIL
FROM
WASH OIL
FROM
WASH OIL
TO
FLUX OIL
TO
FLUX OIL/ WASH OIL STORAGE
E-28020 K-22001 C-21001
1ST, 2ND & 3RD STAGE
M OSBL OSBL DWG. 2800D DWG. 2200A/D DWG. 2100A DOC. No: M
6 A1-222334-2100D 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
V-22001 K-22001 E-22001A/B V-22002 E-22002A/B V-22003 NOTES:

A CHARGE GAS COMPRESSOR CHARGE GAS COMPRESSOR CHARGE GAS COMPRESSOR CHARGE GAS COMPRESSOR CHARGE GAS COMPRESSOR CHARGE GAS COMPRESSOR A
1ST STAGE SUCTION DRUM 1ST AND 2ND STAGE 1ST STAGE AFTERCOOLER 2ND STAGE SUCTION DRUM 2ND STAGE AFTERCOOLER 2ND STAGE DISCHARGE DRUM 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1
MIN. FLOW BYPASS

B B
WET FLARE
C PC C
PC SC
D D
LC
E E
INTERFACE
LC LC LC
F F
G G
H H
CWS CWS
WASH OIL WASH OIL
INJECTION INJECTION
DWG. 2100D FC
DWG. 2100D
FC
1ST STAGE 2ND STAGE
J J
VHP
P-22001A/B WASH OIL

INJECTION
WASH OIL
INJECTION
CGC 1ST STAGE DWG. 2100D DWG. 2100D
SUCTION DRUM PUMPS HP BFW HP BFW
INJECTION INJECTION
DWG. 2100C DWG. 2100C
K K
FEB FOR PROPOSAL RK
0 2017
ISSUE PROC CLIENT
DATE ENG
NNF
NNF
NNF
NNF
NNF

STEAM CRACKER UNIT
CHARGE GAS START-UP WATER VENT VENT VENT RECYCLE VENT VENT PP RECYCLE GASOLINE PROPYLENE VENT CHARGE GAS CHARGE GAS
FROM NATURAL GAS TO FROM FROM FROM FROM FROM FROM FROM TO FROM TO
C-21003 FROM C-21003 V-22018 V-28006/V-28013 V-22015 V-22014A/B V-25005 THU OSBL C-21003 E-24010 C-22004 COMPRESSION STAGES 1 & 2
ME-23000-E06
M DWG. 2100B DWG. 2300A DWG. 2100B DWG. 2200B DWG. 2800B DWG. 2200H DWG. 2200G DWG. 2500B DWG. 2700A DWG. 1200C DWG. 2100B DWG. 2400C DWG. 2200B DOC. No: M
5 A1-222334-2200A 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
E-22003 C-22004 E-22018 E-22019 E-22022A/B C-22005 E-22020 E-22021 V-22017 V-22018 NOTES:
A A
AMINE CHARGE GAS SCU MEA//WATER WASH LEAN MEA LEAN MEA/RICH MEA REGENERATOR MEA REGENERATOR MEA REGENERATOR MEA MEA REGENERATOR MEA REGENERATOR 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1
FEED HEATER COLUMN COOLER MEA EXCHANGER REBOILER CONDENSER RECLAIMER REFLUX DRUM HP FLASH DRUM OPERATION UNLESS OTHERWISE INDICATED.
2. FLOW MEASUREMENTS PRESSURE AND TEMPERATURE
COMPENSATED.
TO WET
FLARE
B B
PC
PC
PC
C 45
kg/cm²g 7.0
C C
FC
CW TO ACID GAS
FLARE
TC N2
LC
D D
C
kg/cm2g
TC
E E
LC
FC
SP
FC
F F
LC C 54
kg/cm²g 7.2
SP
G FC FC
G
TO AMINE
DRAIN SYSTEM
LP DESUPERHEATED
STEAM MP STEAM
LC
LP COND.
H TC H
NNF
MP COND.
J CW J
NNF
NNF
MP
STEAM
QW
DWG. 2100B TDC
CONDENSATE
LC
K LC K
FEB
ISSUE PROC CLIENT
DATE ENG
FC
WASH WATER INFORMATION DESCRIBING TECHNOLOGY OWNED BY LUMMUS. IT IS TO BE USED ONLY IN CONNECTION WITH
FROM WORK PERFORMED BY LUMMUS. REPRODUCTION IN WHOLE OR IN PART FOR ANY PURPOSE OTHER THAN
E-20014
DWG. 2000D PROCESS FLOW DIAGRAM

CHARGE GAS WASH WATER CHARGE GAS
ACID GAS REMOVAL
TO TO FROM
HYDROCARBON
TO
VENT
TO
MAKEUP AMINE
FROM
20% CAUSTIC SOLUTION
FROM
MEA SLUDGE
TO AMINE TREATMENT SYSTEM
C-22001 NEUTRALIZATION V-22003 C-21003 K-22001 2ND STAGE T-22001 P-22008A/B DRUMS
M DWG. 2200C DWG. 2200C DWG. 2200A DWG. 2100B DWG. 2200A DWG. 2200J DWG. 2200C DOC. No: M
6 NONE A1-222334-2200B 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
E-22003 V-22032 C-22001 NOTES:

A CAUSTIC CHARGE GAS 20% CAUSTIC CAUSTIC/WATER A
FEED HEATER SURGE DRUM WASH TOWER 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1
2. P-22003A IS A COMMON SPARE FOR P-22003B AND P-22002.
B B
A
CO2
H2S
FC
C C
LC
D D
E E
A
CO2
F H2S
F
LC
FI FI FI
WASH LC
WATER
G DWG. 2000D G
NNF
LC NNF
NNF
NNF
LOW LEVEL
OVERRIDE
FC
NNF
NNF
H H
PV FFC
NNF
NNF
J J
P-22008A/B P-22002 P-22003A/B P-22004A/B

20% CAUSTIC WEAK CAUSTIC MEDIUM CAUSTIC STRONG CAUSTIC
FEED PUMPS CIRCULATION PUMP CIRCULATION PUMPS CIRCULATION PUMPS
K K
FEB FOR PROPOSAL RK
0 2017
ISSUE PROC CLIENT
DATE ENG
NNF NNF
NNF
BL PROCESS FLOW DIAGRAM

STEAM CRACKER UNIT
CHARGE GAS 20% CAUSTIC 20% CAUSTIC 20% CAUSTIC 20% CAUSTIC SPENT WASH WATER SPENT WASH WATER SPENT WASH WATER SPENT WASH WATER WASH WATER CHARGE GAS ACID GAS REMOVAL
FROM SOLUTION SOLUTION SOLUTION SOLUTION CAUSTIC TO FROM FROM FROM FROM TO
C-22004 FROM TO
E-22021
TO
P-12002A/B
TO
E-12022
TO
V-22008
SPENT CAUSTIC
NEUTRALIZATION
C-12001 C-12002 C-22004 V-20007 E-22005 CAUSTIC WATER WASH SYSTEM
M DWG. 2200B OSBL DWG. 2200B DWG. 1200B DWG. 1200A DWG. 2200E DWG. 3000B DWG. 1200A DWG. 1200B DWG. 2200B DWG. 2000D DWG. 2200D DOC. No: M
5 A1-222334-2200C 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
E-22005 V-22004 K-22001 E-22006A/B E-22007 V-22005 ME-22002 V-22017 V-22007A/B

A CAUSTIC TOWER CHARGE GAS COMPRESSOR CHARGE GAS COMPRESSOR CHARGE GAS COMPRESSOR CHARGE GAS COMPRESSOR CHARGE GAS COMPRESSOR LIQUID CONDENSATE CHARGE GAS COMPRESSOR LIQUID CONDENSATE A
EFFLUENT COOLER 3RD STAGE SUCTION DRUM 3RD STAGE 3RD STAGE AFTERCOOLER No. 1 3RD STAGE AFTERCOOLER No. 2 3RD STAGE DISCHARGE DRUM COALESCER PACKAGE CASING DRAIN DRUM DRYERS 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1
MIN. FLOW BYPASS

B B
WET FLARE
TO LCV TO LCV
ON E-22005 TC PC A ON E-22007 TC
C3R INLET C3R INLET
DWG. 2500B CO DWG. 2500B
C C
REGENERATION
D D
LC LC A A
9°C C3R
DWG. 2500B
H2O H2O
LC
LC
E E
INTERFACE INTERFACE INTERFACE
LC LC
9°C C3R
DWG. 25001B
F F
A
CWS
H2O
FC
G G
WASH OIL
INJECTION
DWG. 2100D
TO
WET FLARE
LOW LEVEL
OVERRIDE
PC
H H
SP
FC FC 3RD STAGE FC
J J
WASH OIL
P-22006A/B INJECTION P-22007A/B
DWG. 2100D
CGC 3RD STAGE CGC 3RD STAGE
SUCTION DRUM PUMPS HP BFW DISCHARGE DRUM PUMPS
INJECTION
DWG. 2100C
K K
FEB FOR PROPOSAL RK
0 2017
ISSUE PROC CLIENT
NNF DATE ENG
K-22001
CASING
DRAINS LUMMUS PETROCHEMICALS
NNF
L OFF GAS REGEN GAS CHARGE GAS WORK PERFORMED BY LUMMUS IS FORBIDDEN EXCEPT BY EXPRESS WRITTEN PERMISSION OF LUMMUS. IT IS L
NNF FROM TO
FROM TO BE SAFEGUARDED AGAINST BOTH DELIBERATE AND INADVERTENT DISCLOSURE TO ANY THIRD PARTY."
V-27002 E-22011 V-22010A/B/C
DWG. 2200D DWG. 2200F DWG. 2200F
STEAM CRACKER UNIT
CHARGE GAS
FROM
HP OFF GAS
FROM
OILY WATER
TO
GASOLINE
TO
CRACKED
CONDENSATE
REGEN GAS
TO
CHARGE GAS
C-22001 V-28011 C-21003 C-21003 TO
C-22002
E-22009 COMPRESSION STAGE 3
M DWG. 2200C DWG. 2800C DWG. 2100B DWG. 2100B DWG. 2200G DWG. 2200F DOC. No: M
6 A1-222334-2200D 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
E-22008 V-22008 V-22009

A SPENT CAUSTIC SPENT CAUSTIC SPENT GASOLINE A
WASH GASOLINE COOLER COALESCER COALESCER 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1
TO TO
WET FLARE WET FLARE
B B
PC PC
PC PC
C C
NITROGEN NITROGEN
D D
C 45 C 67
LC LC LC LC
E E
F F
FC
G G
H H
J FI PV FFC J
PV
FFC
K K
FEB FOR PROPOSAL RK
0 2017
ISSUE PROC
CWS REV DESCRIPTION CAD LPE PDM PM CLIENT
C 55 DATE ENG
kg/cm²g 2.5
NNF

STEAM CRACKER UNIT
SPENT CAUSTIC SPENT CAUSTIC WASH GASOLINE WASH WATER SPENT GASOLINE SPENT GASOLINE SPENT CAUSTIC SPENT CAUSTIC PRETREATMENT
FROM FROM FROM FROM TO TO TO
C-22001 ROG P-21006A/B P-21007A/B C-21001 C-21003 WAO UNIT
C-12002
M DWG. 2200C DWG. 1200B DWG. 2100B DWG. 2100C DWG. 2100A DWG. 2100B DWG. 3000A DOC. No: M
5 A1-222334-2200E 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
V-22010A/B/C E-22011 V-22011 E-22009 E-22010 E-22031 E-24018 NOTES:

A CHARGE GAS REGEN GAS REGENERATION REGENERATION FEED REGENERATION REACTOR REDUCTION TREATER REGENERATION OPERATION UNLESS OTHERWISE INDICATED. A
DRYERS HEATER GAS K.O. DRUM EFFLUENT EXCHANGER GAS COOLER GAS HEATER GAS ELETRIC HEATER
REGEN.
C 12 C 232
LIQ. COND. DRYER ACET. CONV. DRYER ROG DRYER / TREATER LPG TREATER PG PROPYLENE TREATER PGH REACTOR C4/C5 HYDRO REACTOR MAPD CONVERTER
REGENERATION REGENERATION REGENERATION REGENERATION REGENERATION REGENERATION REGENERATION REGENERATION
GAS TO/FROM GAS TO/FROM GAS TO/FROM GAS TO/FROM GAS TO FROM GAS TO/FROM GAS TO/FROM GAS TO/FROM
B V-22007A/B V-22014A/B V-12012A/B V-12006A/B V-24006A/B R-28001A/B, R-28002A/B R-27001A/B R-24001A/B REACTOR B
REGENERATION
DWG. 2200D DWG. 2200G DWG. 1200D DWG. 1200D DWG. 2400E DWG. 2800A & C DWG. 2700A DWG. 2400C GAS TO
R-12001A/B
TC TC TC TC TC TC TC TC DWG. 1200C
FC FC FC FC FC FC FC FC
C H2O C
REACTOR
PRE-REDUCTION
SP GAS TO
R-22001A/B/C
FC TC FC FC FC FC FC FC FC FC
SP
SP
SP
SP
SP
SP
SP
SP
DWG. 2200G
FC
D D
COOLING
HEATING
TC A
RETURN
H2O
E HS E
HEATING GAS
HP COND
TC
F F
C 45
kg/cm²g 5.4 CWS
A
H2
C1
C2-
G C2 G
C3-
C3 TC
CO2
H2S
A
H2O
LC
MPS
H H
MP COND
TC
FC
J J
(REGENERATION ONLY)
(REGENERATION ONLY)
PLANT
AIR
PDC
SP
FC FC PC
VHS
K K
FEB FOR PROPOSAL RK
0 2017
ISSUE PROC CLIENT
LPS DATE ENG
FC
NNF
NITROGEN "THIS DOCUMENT IS THE PROPERTY OF LUMMUS TECHNOLOGY INC. (LUMMUS). IT CONTAINS CONFIDENTIAL
L CHARGE GAS WORK PERFORMED BY LUMMUS. REPRODUCTION IN WHOLE OR IN PART FOR ANY PURPOSE OTHER THAN
L
TO
C-22002
FC PROCESS FLOW DIAGRAM
DWG. 2200G
STEAM CRACKER UNIT
HYDROGEN
CHARGE GAS EXCESS HYDROGEN METHANE OFFGAS REGEN OFFGAS CONDENSATE DWG. 2300D CHARGE GAS DRYING & REGENRATION
FROM FROM FROM TO TO
V-22005 ME-23001 ME-23000-E06 FUEL GAS SYSTEM C-21003
BYPASS
M DWG. 2200D DWG. 2300D DWG. 2300A DWG. 2300D DWG. 2100B
DOC. No: M
6 A1-222334-2200F 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
E-22020A/B E-22021 C-22002 E-22012 E-22015 E-22016 E-22017 E-22014 R-22001A/B/C E-22018 V-22012
A HP DEPROPANIZER HP DEPROPANIZER HP DEPROPANIZER ACETYLENE CONVERTER FEED/ ACETYLENE CONVERTER ACETYLENE CONVERTER ACETYLENE CONVERTER ACETYLENE CONVERTER ACETYLENE HP DEPROPANIZER HP DEPROPANIZER A
REBOILER BOTTOMS COOLER EFFLUENT EXCHANGER NO. 1 INTERCOOLER No. 1 INTERCOOLER No. 2 AFTERCOOLER HEATER CONVERTER CONDENSER REFLUX DRUM
E-22013 V-22014
ACETYLENE CONVERTER FEED/ ACETYLENE CONVERTER
EFFLUENT EXCHANGER NO. 2 DRYER
TO COLD
B FLARE B
A A TC
MPS
CO C4'S
PC PC
-27°C C3R
DWG. 25001A
C C
MP COND
FC
D D
NNF
TC
CO INJECTION NNF
FROM BOTTLES NNF
START-UP
A C2H2 LC
NNF
NITROGEN & HYDROGEN C2H6
DWG. 2200F START-UP MAPD
NNF
E A C2H2 E
C2H6 TO LCV ON
MAPD SOR EOR E-22018 INLET
START-UP
C2H2 DWG. 2500A
C2H6 C 66 116
A
MAPD
CO
SOR EOR
C 78 131 METHANOL
NNF
INJECTION
CWS
F ME-12002 F
NNF
TC
TC
TO COLD SOR EOR
FLARE
C 69 117
PC
SOR EOR
G C 75 128 G
RESET TC CWS
NNF
TC
TC
SOR EOR
C 69 118
LC
FC
H H
DS LPS SOR EOR
C 74 125
RESET
LP COND CWS
NOTE 4
J J
H2O
H2O
A A
START-UP
NNF
K CWS K
FEB FOR PROPOSAL RK
NNF 0 2017
FC ISSUE PROC CLIENT
DATE ENG
FC
FC POLYMERIZATION
C2's
INHIBITOR INJECTION
ME-22000 A
REGENERATION ONLY
REGENERATION ONLY

L L
NNF

START-UP TO BE SAFEGUARDED AGAINST BOTH DELIBERATE AND INADVERTENT DISCLOSURE TO ANY THIRD PARTY."
NNF
P-22010A/B PROPYLENE FILL

FROM PROCESS FLOW DIAGRAM
HP DEPROPANIZER OSBL
REFLUX PUMPS STEAM CRACKER UNIT
DWG. 2400E
FRONT-END HIGH PRESSURE DEPROPANIZER
OFF SPEC ETHYLENE CRACKED CONDENSATE CHARGE GAS HP DEPROPANIZER LP DEPROPANIZER RECYCLE REGEN GAS REGEN GAS START-UP CHARGE GAS
FROM FROM FROM BOTTOMS OVERHEAD TO FROM TO PROPYLENE VAPOR TO
OSBL V-22007A/B V-22010A/B/C TO FROM V-22002 E-22011 E-22009 FROM E-23001
C-22003 P-22011A/B C-24003
M DOC. No: M
DWG. 2400B DWG. 2200D DWG. 2200F DWG. 2200H DWG. 2200H DWG. 2200A DWG. 2200F DWG. 2200F DWG. 2400C DWG. 2300C
11 A1-222334-2200G 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
E-22023A/B C-22003 E-22022 V-22015 NOTES:

A LP DEPROPANIZER LP DEPROPANIZER LP DEPROPANIZER LP DEPROPANIZER 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1 A
REBOILER CONDENSER REFLUX DRUM OPERATION UNLESS OTHERWISE INDICATED.
2. ONE OPERATING, ONE STAND BY.
B TO LCV ON
B
E-22022 INLET
DWG. 2500A
PC PC
C C
-27° C3R
DWG. 2500A
TO COLD
FLARE
D HC D
E E
LC
POLYMERIZATION
INHIBITOR INJECTION
ME-22000
RESET TC
F F
FC
LC
DS LPS LP COND
G G
METHANOL
INJECTION
NOTE 2 ME-12002
H POLYMERIZATION H
INHIBITOR INJECTION
ME-22000
A
FC
C3's FC AI
C4's
J J
P-22012A/B P-22011A/B
FC
K K
FEB FOR PROPOSAL RK
0 2017
ISSUE PROC CLIENT
DATE ENG
NNF

STEAM CRACKER UNIT
HP DEPROPANIZER LP DEPROPANIZER LP DEPROPANIZER VENT FRONT-END LOW PRESSURE DEPROPANIZER
BOTTOMS BOTTOMS OVERHEAD TO
FROM TO TO V-22002
E-22021 C-24005 C-22002
M DWG. 2200G DWG. 2400D DWG. 2200G DWG. 2200A DOC. No: M
6 A1-222334-2200H 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
T-22001 V-22019
A MEA MEA NOTES: A
STORAGE TANK DRAIN DRUM
2. INITIAL MEA FILL FROM TRUCK.
B B
C C
D D
TO ACID GAS
FLARE
"B"
E E
N2
"A" V-22019
PC LC ON/OFF MEA MAKE-UP
PM FROM DRUMS
F F
PC
N2
T-12001
G G
FC
H P-22015 H
PM
MEA
SUMP PUMPS
P-22016A/B
MEA MAKEUP
PUMPS
J FC J
TRUCK
UNLOADING
(NOTE 2)
K K
FEB
ISSUE PROC CLIENT
DATE ENG

STEAM CRACKER UNIT
WATER / DGA MAKEUP WATER MAKEUP MEA MEA STORAGE
TO FROM DRAIN
C-22005 E-20014
M DWG. 2200B DWG. 2000D DOC. No: M

2 NONE A1-222334-2200J 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
ME-23000-E06 E-23005 ME-23000-E05 ME-23000-E04 NOTES:
OFFGAS EXCHANGER No. 6 ETHYLENE PRODUCT OFFGAS EXCHANGER No. 5 OFFGAS EXCHANGER No. 4
A (PART OF ME-23000) VAPORIZER (PART OF ME-23000) (PART OF ME-23000) 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1 A
2. START-UP ETHYLENE WILL BE BACKED IN.
B B
48°C C3R 9°C C3R -11°C C3R -28°C C3R
FROM V-25005 FROM V-25004 FROM V-25003 FROM V-25002
DWG. 2500B DWG. 2500B DWG. 2500A DWG. 2500A
BR
DWG. 2600A
C A CH4 H C
C2H4
A A A
DWG. 2300B
B B B
PC PC A F F
COLD C2H4
COLD FLARE
D FLARE E E D
J G G G BR
DWG. 2600A
C C C C
FROM PC ON C-23001 D D D
E DWG. 2300C E
BR -40°C C3R
DWG. 2600A J F J E FROM V-25009
DWG. 2600A
FROM PC
ON V-23003
DWG. 2300B
F F
HIGH LEVEL
NNF OVERRIDE
9°C C3R
LC
FROM V-25004
DWG. 2500B
FC
SP
G G
FFC PV FC
FROM LC
PC ON C-23001
BOTTOMS
H COLD DWG. 2300C H
FLARE
J J
PC
K K
FEB FOR PROPOSAL RK
0 2017
NNF
NNF
NNF
NNF
ISSUE PROC CLIENT

DATE ENG
START-UP START-UP ETHYLENE WORK PERFORMED BY LUMMUS. REPRODUCTION IN WHOLE OR IN PART FOR ANY PURPOSE OTHER THAN
L NATURAL GAS ETHYLENE VAPOR MAKE UP WORK PERFORMED BY LUMMUS IS FORBIDDEN EXCEPT BY EXPRESS WRITTEN PERMISSION OF LUMMUS. IT IS L
TO TO TO V-26003 TO BE SAFEGUARDED AGAINST BOTH DELIBERATE AND INADVERTENT DISCLOSURE TO ANY THIRD PARTY."
V-22001 E-24001 NOTE 2
DWG. 2200A DWG. 2400A DWG. 2600A
CHARGE GAS CHILLING TRAIN
RAW HYDROGEN
TO
METHANE OFFGAS
TO
START-UP HP ETHYLENE
PRODUCT VAPOR
ETHANE RECYCLE
TO
DEETHANIZER
LOWER FEED
DEETHANIZER
UPPER FEED
HP ETHYLENE
FROM
ETHANE RECYCLE
FROM
DEMETHANIZER
BOTTOMS
(PAGE 1 OF 2)
ETHYLENE VAPOR
K-23001 REGENERATION/ TO TO E-20021 TO TO SPHERES C-24002 FROM
M FUEL GAS E-24003 C-24001 C-24001 P-23002A/B DOC. No: M
DWG. 2300D DWG. 2200F DWG. 2400B OSBL DWG. 2000A DWG. 2400A DWG. 2400A DWG. 2400D DWG. 2400B DWG. 2300C
3 A1-222334-2300A 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
ME-23000-E03 V-23001 ME-23000-E02 V-23002 ME-23000-E01 M-23001 V-23003 NOTES:

A OFFGAS EXCHANGER No. 3 DEMETHANIZER FEED OFFGAS EXCHANGER No. 2 DEMETHANIZER FEED OFFGAS EXCHANGER No. 1 DEMETHANIZER FEED/ DEMETHANIZER FEED A
(PART OF ME-23000) SEPARATOR No. 1 (PART OF ME-23000) SEPARATOR No. 2 (PART OF ME-23000) METHANE WASH MIXER SEPARATOR No. 3 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1
B B
A A A
DWG. 2300A
C B B B C
BR
D BR BR D
BR BR BR BR
TC TC TC PC
E E
METHANOL METHANOL
INJECTION INJECTION
ME-23002 ME-23002
TO BR TCV TO BR TCV TO BR TCV TO PCV
ON ME-23000-E03 INLET ON ME-23000-E02 INLET ON ME-23000-E01 INLET ON H2 TO REGEN.
DWG. 2600A DWG. 2600A DWG. 2600A DWG. 2300A
HC HC
F F
NNF NNF
G G
LC LC LC
H H
FC FC FC
J J
METHANOL
K INJECTION K
ME-12002 FEB FOR PROPOSAL RK
0 2017
DWG. 27001A
ISSUE PROC CLIENT
DATE ENG

STEAM CRACKER UNIT
CHARGE GAS CHILLING TRAIN
CHARGE GAS
FROM
DEMETHANIZER
BOTTOMS
DEMETHANIZER
MIDDLE FEED
METHANE
WASH LIQUID
DEMETHANIZER
TOP FEED
DEMETHANIZER
NET OVERHEAD (PART 2 OF 2)
E-23001/E-23002 FEED TO TO FROM TO FROM
C-23001 C-23001 P-23001A/B C-23001 V-23004
M DOC. No: M
DWG. 2300C DWG. 2300C DWG. 2300C DWG. 2300C DWG. 2300C DWG. 2300C
4 A1-222334-2300B 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
C-23001 E-23002 E-23001 V-23004 ME-23000-E07 NOTES:
DEMETHANIZER DEMETHANIZER DEMETHANIZER DEMETHANIZER DEMETHANIZER
A REBOILER FEED CHILLER REFLUX DRUM CONDENSER 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1 A
(PART OF ME-23000) OPERATION UNLESS OTHERWISE INDICATED.
BR
DWG. 2600A
B B
FC
C C
D D
METHANOL
INJECTION
ME-23002
TC
E E
LC
F F
PC LC
TO BR LCV
ON ME-23000-E07 INLET
DWG. 2600A
TO FC ON
TO PCV ON HP METHANE
ME-23000-E04 INLET
G DOWNSTREAM OF ME-23000-E06
DWG. 2300A METHANOL G
DWG. 2300A
INJECTION
ME-23002
FC
H H
-40°C C3R
DWG. 2500A
A
CH4
J J
P-23002A/B P-23001A/B
FC
K K
FEB FOR PROPOSAL RK
0 2017
ISSUE PROC CLIENT
DATE ENG
NNF
NNF
NNF
NNF
NNF

STEAM CRACKER UNIT
DEMETHANIZER DEMETHANIZER DEMETHANIZER CHARGE GAS CHARGE GAS METHANE DEMETHANIZER METHANE MAKEUP LIQUID METHANE
DEMETHANIZER
DEMETHANIZER BR DRAIN ETHYLENE VENT BINARY REFRIG.
TOP FEED MIDDLE FEED FROM FROM VENT BOTTOMS FROM TO WASH LIQUID NET OVERHEAD TO MAKEUP
BOTTOM FEED V-26001 TO
FROM FROM FROM V-26004 / V-26005 V-24002 FROM TO V-22012 ME-23000-E03 TO TO
V-23003 V-23002 V-26004 / 26006 ME-23000-E04 OVERHEAD V-23003 ME-23000-E01 BR SYSTEM
V-23001
M DWG. 2600A DWG. 2600A
DOC. No: M
DWG. 2300B DWG. 2300B DWG. 2300B DWG. 2600A DWG. 2400B DWG. 2600A DWG. 2300A DWG. 2200G DWG. 2300B DWG. 2300B DWG. 2300B
3 A1-222334-2300C 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
K-23001 E-23003 E-23004 ME-23001 V-23005 NOTES:

A HYDROGEN HYDROGEN COMPRESSOR HYDROGEN COMPRESSOR HYDROGEN FUEL GAS 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1 A
COMPRESSOR INTERCOOLER AFTERCOOLER PSA UNIT KNOCK-OUT DRUM OPERATION UNLESS OTHERWISE INDICATED.
B B
C WET FLARE C
PC PC A CO PC
CH4
C2H2
C2H4
D D
FUEL GAS
TO
F-20001
TO WET DWG. 2000B

FLARE
FUEL GAS
TO
E F-20002 E
PC PC A
GC DWG. 2000C
WOBBE
FUEL GAS
TO
F-20003
AC
DWG. 2000C
F F
MINIMUM FLOW
FUEL GAS
TO
CWS F-20004
DWG. 2000C
LC SP
FC FC
G FUEL GAS G
TO
F-20005
DWG. 2000C
FUEL GAS
TO
F-20006
H H
DWG. 2000C
FUEL GAS FUEL GAS

CWS TO VACUUM TO
BREAKER F-20007
DWG. 2100B
DWG. 2000C
J START UP J
K K
FEB FOR PROPOSAL RK
0 2017
ISSUE PROC CLIENT
DATE ENG
CONDENSATE
L L
NNF
NNF
NNF

ROG FUEL HYDROGEN TO BE SAFEGUARDED AGAINST BOTH DELIBERATE AND INADVERTENT DISCLOSURE TO ANY THIRD PARTY."
GAS TO
E-22031 PROCESS FLOW DIAGRAM
DWG. 1200E
BL BL
DWG. 2200F STEAM CRACKER UNIT
HYDROGEN PURIFICATION
EXCESS HYDROGEN
TO
HYDROGEN
FROM
REGEN OFFGAS
FROM
FUEL GAS
TO
LIQUID
TO
CONDENSATE
TO
HYDROGEN
EXPORT
HYDROGEN
TO
HYDROGEN
TO
HYDROGEN
TO
FUEL GAS SYSTEM
REGENERATION ME-23000-E06 REGEN SYSTEM OSBL C-21003 C-21003 TO R-27001A/B R-24001A/B R-28001A/B &
M /FUEL GAS OSBL R-28002A/B DOC. No: M
DWG. 2200F DWG. 2300A DWG. 2200F DWG. 2100B DWG. 2100B DWG. 2700A DWG. 2400C DWG. 2800A SCALE: DWG. No: REV:
6 A1-222334-2300D 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
E-24002 C-24001 E-24016 (NOTE 2) E-24001 V-24001 NOTES:

A DEETHANIZER DEETHANIZER DEETHANIZER DEETHANIZER DEETHANIZER A
REBOILER LP STEAM REBOILER CONDENSER REFLUX DRUM 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1
2. STARTUP/ SPARE REBOILER.
3. EXCHANGER UTILIZED AS START UP PROPYLENE VAPORIZER.
B B
PC PC
C C
TO COLD
FLARE
METHANOL -27°C C3R

INJECTION DWG. 2500A
ME-12002 FC
NNF
D D
C2H4 A
C3H6
C3H8
E E
LC
TC
F F
TO FC ON TO LCV
E-24002 INLET ON E-24001
DWG. 2100B DWG. 2500A
NOTE 2,3 FC METHANOL

INJECTION
LC ME-12002
G G
LP COND LPS
NNF
QW
DWG. 2100B
NNF
H H
A
C2H4
C2H6
C3H4
FC
J J
P-24002A/B P-24001A/B
TO FFC ON
FC FC HYDROGEN
TO R-24001A/B
DWG. 2400C
K K
FEB FOR PROPOSAL RK
0 2017
ISSUE PROC CLIENT
DATE ENG
START-UP
START-UP
START-UP
NNF
NNF
NNF
NNF

STEAM CRACKER UNIT
DEETHANIZER OFF SPEC DEETHANIZER TREATED C2/C3'S DEETHANIZER PROPYLENE START UP START UP DEETHANIZER STARTUP DEETHANIZER
UPPER FEED PROPYLENE LOWER FEED FROM BOTTOMS FROM OSBL PROPYLENE VAPOR PROPYLENE VAPOR OVERHEAD ETHYLENE VAPOR
FROM FROM FROM C-12004 TO TO E-25001A-D TO C-24004 TO FROM
ME-23000-E06 OSBL ME-23000-E06 E-24008 C-24002 ME-23000-E06
M DWG. 2300A DWG. 2400E DWG. 2300A DWG. 1200F DWG. 2400C DWG. 2400E DWG. 2500B DWG. 2400C DWG. 2400B DWG. 2300A DOC. No: M
5 A1-222334-2400A 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
E-24006 C-24002 E-24007 E-24003A/B V-24002 ME-24000

A ETHYLENE FRACTIONATOR ETHYLENE ETHYLENE FRACTIONATOR ETHYLENE FRACTIONATOR ETHYLENE FRACTIONATOR ETHYLENE RUNDOWN A
SIDE REBOILER FRACTIONATOR REBOILER CONDENSER REFLUX DRUM CHILLER
B B
TO PV ON
PC PC
E-24003
C3R INLET
DWG. 2500A
C C
-40°C C3R
DWG. 2500A
TO
COLD FLARE
VAPOR BALANCE
D D
HC
E E
LC
METHANOL
INJECTION
ME-12002
OSBL
FC
F ONSPEC OFFSPEC
F
HP HP
LIQUID LIQUID
ETHYLENE ETHYLENE
STORAGE STORAGE
PV
FFC
NOTE 2
C2H4
AC
G NNF G
A
TO FC ON C3R
-10°C C3R LC TO E-24007 CH4
DWG. 2500A DWG. 2500B C2H2
C2H4
LC C2H6
CO2
C3H6
FC
H H
HIGH LEVEL 9°C C3R
DWG. 2500B
NNF
OVERRIDE
A
H2
CH4
C2H2
C2H4
P-24003A/B C2H6
C3H6
J H2O J
BR CO
DWG. 2600B CO2
CH3OH
A TOTAL S
O2
C2H4
NH3
BR
DWG. 2600B
TC BR
DWG. 2600B
K FC K
FEB FOR PROPOSAL RK
FC 0 2017
START-UP REV
ISSUE
DESCRIPTION CAD
PROC
LPE PDM PM CLIENT
DATE ENG
NNF
BL
NNF
NNF
START-UP
NNF
NNF

STEAM CRACKER UNIT
ETHYLENE FRACTIONATION AND
DEETHANIZER
OVERHEAD
ETHANE
RECYCLE
STARTUP
ETHYLENE VAPOR
ETHYLENE
RUNDOWN
OFF-SPEC
PRODUCT
ETHYLENE FILL
TO
HP ETHYLENE
PRODUCT
OFFSPEC ETHYLENE
TO
ETHYLENE VENT
TO ETHYLENE PRODUCT SYSTEM
FROM TO FROM TO FROM P-24001A/B V-26004 TO C-22002 C-23001
M V-24001 ME-23000-E05 ME-23000-E06 STORAGE ME-23000-E06 DOC. No: M
DWG. 2400A DWG. 2300A DWG. 2300A OSBL DWG. 2400A DWG. 2600A DWG. 2300A DWG. 2200G DWG. 2300C
5 A1-222334-2400B 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
E-24008 R-24001A/B E-24012A/B C-24004 C-24003 E-24011A/B E-24009A/B/C/D V-24003 E-24010 NOTES:
A MAPD TRIM REACTOR MAPD PROPYLENE FRACTIONATOR No. 2 PROPYLENE PROPYLENE PROPYLENE FRACTIONATOR No. 1 PROPYLENE FRACTIONATOR PROPYLENE FRACTIONATOR PROPYLENE FRACTIONATOR A
FEED COOLER CONVERTER REBOILER FRACTIONATOR No. 2 FRACTIONATOR No. 1 REBOILER CONDENSER REFLUX DRUM VENT CONDENSER 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1
2. LOCATE TC CLOSE TO REACTOR R-24001A/B INLET.
PC
3. CONTINUOUS ANALYSER.
PC 4. E-24011 B IS A SPARE REBOILER.
LOW PRESSURE OVERRIDE

B B
FC
CWS
C C
NOTE 2
TC
NNF CWS
HC
SOR EOR TO
C 37.7 COLD FLARE
kg/cm²g 23.7
D D
A
MAPD
C3H8
LC
PdC
NOTE 3
AI
FC
E C3H6
E
LC
F LC LC F
NNF
NOTE 4
START-UP
FC FC
NNF
NOTE 4
QW QW QW
QW
DWG. TO FROM DWG. 2100B
2100B E-24011A/B E-24012A/B
QW
DWG. 2100B
G G
SETPOINT
MAPD FC FFC
C3H6
START-UP
H TO TO H
P-24004A/B ATM. WET
FLARE
P-24006A/B P-24007A/B P-24005A/B
NNF
A
MAPD
C3H8
J FC J
FC A
H2
CH4
HIGH LEVEL OVERRIDE
C2H4
C2H6
MAPD
FROM E-20020
C3H8
DWG. 2000A
CWS
K FFC K
FEB FOR PROPOSAL RK
0
REGENERATION ONLY
REGENERATION ONLY
2017
ISSUE PROC CLIENT
DATE ENG
FROM FC
ON C-24001
BTMS
DWG. 2400A
L START UP WORK PERFORMED BY LUMMUS IS FORBIDDEN EXCEPT BY EXPRESS WRITTEN PERMISSION OF LUMMUS. IT IS L
PROPYLENE VAPOR TO BE SAFEGUARDED AGAINST BOTH DELIBERATE AND INADVERTENT DISCLOSURE TO ANY THIRD PARTY."
REACTOR REDUCTION REGENERATION TO C-22002 AND
GAS
FROM
EFFLUENT
TO
R-22001A/B/C
DWG. 2200G
E-22031 E-22009 STEAM CRACKER UNIT
DWG. 2200F DWG. 2200F
PROPYLENE FRACTIONATION
HYDROGEN DEETHANIZER REACTOR REGEN GAS REGEN GAS PROPANE RECYCLE START-UP PROPYLENE PRODUCT PRESSURIZATION START UP DEINVENTORY PROPYLENE VENT
FROM BOTTOMS FROM FROM TO PROPYLENE VAPOR TO GAS TO PROPYLENE FILL FROM TO
HYDROGEN PSA FROM HEADER E-22011 E-20020 FROM E-24017 V-24006A/B FROM V-24006A/B V-22003
M P-24002A/B E-24016 OSBL DOC. No: M
DWG. 2300D DWG. 2400A DWG. 2200F DWG. 2200F DWG. 2000A DWG. 2400A DWG. 2400E DWG. 2400E DWG. 2400E DWG. 24000E DWG. 2200A SCALE: DWG. No: REV:
6 A1-222334-2400C 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
E-24014A/B C-24005 E-24015 E-24013 V-24004 NOTES:

A DEBUTANIZER DEBUTANIZER PYROLYSIS GASOLINE DEBUTANIZER DEBUTANIZER A
REBOILER COOLER CONDENSER REFLUX DRUM 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1
2. ONE OPERATING, ONE STAND BY.
B B
PC PC
C C
TO WET
FLARE
D HC D
CWS
E E
LC
POLYMERIZATION
INHIBITOR
INJECTION
ME-22000
TC
F F
FC
LC
DS LPS LP COND
G G
NOTE 2
H C4's H
FC
FC A
C3'S
C5'S
J J
FC
P-24008A/B
CWS
K K
FEB FOR PROPOSAL RK
0 2017
NNF NNF ISSUE PROC
REV DESCRIPTION CAD LPE PDM PM CLIENT
GASOLINE DATE ENG
POLYNIERIZATION
INHIBITOR TBC INHIBITOR
INJECTION
ME-21001
INJECTION
ME-24002
NNF
BL BL BL PROCESS FLOW DIAGRAM

STEAM CRACKER UNIT
LP DEPROPANIZER GASOLINE RAW PYROLYSIS RAW PYROLYSIS MIXED C4S MIXED C4's VENT DEBUTANIZER
BOTTOMS FROM GASOLINE TO GASOLINE TO/FROM TO TO
FROM P-21006A/B PGH UNIT STORAGE V-27001 V-22002
C-22003
M DWG. 2200H DWG. 2100B DWG. 2800A OSBL OSBL DWG. 2700A DWG. 2100B DOC. No: M
5 A1-222334-2400D 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
V-24006A/B ME-24001 NOTES:
PG PROPYLENE PROPYLENE RUNDOWN
A TREATERS CHILLER PACKAGE 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1 A
B B
C C
D D
COS
OSBL
E ONSPEC OFFSPEC
E
HP HP
LIQUID LIQUID
PROPYLENE PROPYLENE
STORAGE STORAGE
NOTE 2
A
F F
COS
NNF
G G
NNF
H CWS
H
C3R A
DWG. 25001B
H2
CH4
C2H4
C3R C2H6
DWG. 25001B MAPD
C3H8
J H2O
J
COS
CO
CH3OH
FC
K K
FEB FOR PROPOSAL RK
0 2017
NNF
ISSUE PROC CLIENT
DATE ENG
BL
DEINVENTORY START UP "THIS DOCUMENT IS THE PROPERTY OF LUMMUS TECHNOLOGY INC. (LUMMUS). IT CONTAINS CONFIDENTIAL
TO PROPYLENE FILL INFORMATION DESCRIBING TECHNOLOGY OWNED BY LUMMUS. IT IS TO BE USED ONLY IN CONNECTION WITH
NNF
NNF
NNF
L V-24003 TO
L
V-24003 TO BE SAFEGUARDED AGAINST BOTH DELIBERATE AND INADVERTENT DISCLOSURE TO ANY THIRD PARTY."
NNF
NNF
DWG. 24000C DWG. 24000C
BL BL STEAM CRACKER UNIT
PROPYLENE PRODUCT SYSTEM
PROPYLENE PRODUCT REGEN GAS REGEN GAS PRESSURIZING GAS
FROM FROM TO FROM PROPYLENE PROPYLENE REFRIG. POLYMER GRADE START UP OFFSPEC PROPYLENE PROPYLENE FILL START UP
P-24007A/B E-24018 E-22009 C-24003 RUNDOWN PUMPOUT PROYLENE PROPYLENE TO TO AND MAKEUP PROPYLENE FILL
TO FROM PRODUCT E-24016 C-24001 TO TO
M STORAGE P-25001 V-25004 V-22012 DOC. No: M
DWG. 24000C DWG. 22000E DWG. 22000E DWG. 24000C
OSBL DWG. 25000A DWG. 24000A DWG. 24000A DWG. 25000B DWG. 22000F SCALE: DWG. No: REV:
5 A1-222334-2400E 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
V-25001 V-25009 V-25013 V-25017 V-25002 V-25008 K-25001 V-25003 V-25012 V-25016 NOTES:
A PROPYLENE REFRIG. COMPRESSOR LIQUID PROPYLENE LIQUID PROPYLENE LIQUID PROPYLENE PROPYLENE REFRIG. COMPRESSOR LIQUID PROPYLENE PROPYLENE REFRIGERANT PROPYLENE REFRIG. COMPRESSOR LIQUID PROPYLENE LIQUID PROPYLENE A
1ST STAGE SUCTION DRUM ACCUMULATOR ACCUMULATOR No. 4 ACCUMULATOR No. 4 2ND STAGE SUCTION DRUM ACCUMULATOR FOR E-24006 COMPRESSOR 3RD STAGE SUCTION DRUM ACCUMULATOR No. 3 ACCUMULATOR No. 3 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1
FOR ME-23000-E05 FOR ME-12000-E01 FOR ME-24001 FOR ME-12000-E01 FOR ME-24001 OPERATION UNLESS OTHERWISE INDICATED.
2. MULTI-POINT METHANOL INJECTION FROM ME-12002.
C3R VAPOR
FROM
V-25011/V-25015/
E-11003
B B
DWG. 24001A DWG. 2500B
LC
FROM LC
ON V-24001
HIGH LEVEL
OVERRIDE
LC DWG. 2400A LC
DWG.
D D 2400A
C G G LC C
C C
BR MeOH
DWG. 22001G NOTE 2
DWG. 2300A FROM PC
LC
ON LP
DEC3 OVHD
HIGH LEVEL
OVERRIDE
MeOH DWG. 2200H
NOTE 2 MeOH MeOH
NOTE 2 NOTE 2
D DWG. 24001B DWG. D
2200H
LC
FROM PC
ON C-24002
HIGH LEVEL
OVERRIDE
DWG. 2400B LC MeOH LC

DWG. 22001F NOTE 2 MeOH
COLD FLARE COLD FLARE NOTE 2 COLD FLARE
LC
DWG. FROM LC
2400B ON V-22012
HIGH LEVEL
OVERRIDE
DWG. 2200G
E E
MeOH
PC NOTE 2 PC DWG. PC
MeOH 2200G
NOTE 2
DWG. 23001C MeOH

DWG. 12001F NOTE 2
LC
FROM PC
LC
ON C-12004
F OVHD F
HIGH LEVEL
OVERRIDE
DWG. 1200F
PC TC
DWG.
2200D DWG.
1200F
PROPYLENE
LC FROM
MeOH V-25006/25007,
NOTE 2 MeOH ME-23000-E06
NOTE 2 DWG. 2500B
G G
FROM C3R
LC
ON ME-23000-E06
DWG. 2500B
NNF
NNF
DWG. 2400B
HC TO TO
P-25001 C2 SIDE DRAW P-25001
DWG. 2400B
H H
MeOH
NOTE 2
C2
RECYCLE
DEC2 OFFGASSES MeOH
LC
FEED DWG. 2300A NOTE 2
TC
C2
RECYCLE
DEC2 OFFGASSES
FEED DWG. 2300A C3R QUENCH
FROM FROM
J V-25002 V-25004 J
V-25003
V-25004
FY DWG. 2500B
FC FY
NNF
NNF
C3R
FROM
K-25001 DISCH.
DWG. 2500B
NORMAL
FC STONEWALL FLOW RUNDOWN
K FC
K
FEB FOR PROPOSAL
PROPYLENE 0 2017
RK
TO
V-25004 REV
ISSUE
DESCRIPTION CAD
PROC
LPE PDM PM CLIENT
DATE ENG
NNF
DWG. 2500B
P-25001 C3R VAPOR
FROM "THIS DOCUMENT IS THE PROPERTY OF LUMMUS TECHNOLOGY INC. (LUMMUS). IT CONTAINS CONFIDENTIAL
V-25004 INFORMATION DESCRIBING TECHNOLOGY OWNED BY LUMMUS. IT IS TO BE USED ONLY IN CONNECTION WITH
TC FC WORK PERFORMED BY LUMMUS. REPRODUCTION IN WHOLE OR IN PART FOR ANY PURPOSE OTHER THAN
DWG. 2500B TO BE SAFEGUARDED AGAINST BOTH DELIBERATE AND INADVERTENT DISCLOSURE TO ANY THIRD PARTY."
TO FCV
FC
ON V-25004 INLET
DWG. 2500B PROPYLENE
SC TO
E-25001A-D
STEAM CRACKER UNIT
PROPYLENE REFRIGERATION SYSTEM
PROPYLENE
REFRIG. PUMPOUT
SHP STEAM DWG. 2500B
SHEET 1 OF 2
TO
M STORAGE DOC. No: M
DWG. 2400E
4 A1-222334-2500A 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
V-25006 V-25007 V-25011 V-25015 E-28019 V-25004 V-25005 V-25014 V-25010 E-25001A-D E-27003 NOTES:
LIQUID PROPYLENE LIQUID PROPYLENE LIQUID PROPYLENE LIQUID PROPYLENE BTX TOWER VENT PROPYLENE REFRIG. COMPRESSOR PROPYLENE REFRIGERANT LIQUID PROPYLENE LIQUID PROPYLENE PROPYLENE REFRIGERATION C4/C5 HP FLASH
A ACCUMULATOR ACCUMULATOR ACCUMULATOR No. 2 ACCUMULATOR No. 2 CONDENSER 4TH STAGE SUCTION DRUM ACCUMULATOR ACCUMULATOR No. 1 ACCUMULATOR No. 1 CONDENSERS VENT CONDENSER 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1 A
FOR E-24007 FOR E-23005 FOR ME-12000-E01 FOR ME-24001 FOR ME-24001 FOR ME-12000-E01 OPERATION UNLESS OTHERWISE INDICATED.
2. MULTI-POINT METHANOL INJECTION FROM ME-12002.
C3R VAPOR
TO
V-25003
B B
DWG. 2500A
LC
LOW TEMP FROM TC ON

LC OVERRIDE DWG. 1200E
FC
TUBE SIDE
DWG. 2800D
C LC LC C
DWG. 12001B
LC
FROM TC
ON C-12002
HIGH LEVEL
OVERRIDE
DWG.1200B
DWG.
D 1200B LC D
TUBE SIDE FC
DWG. 2700A
COLD FLARE
LC
E E
DWG. 2300A
PC
LC
DWG. DWG. 2200D

FROM AC 2300A FROM TC
F ON C-24002 LC F
ON V-22004
DWG. 2400B GC OUTLET
HIGH LEVEL
OVERRIDE
DWG. 2200D
LOW LEVEL
OVERRIDE
DWG. 2400B FC
DWG.
2200D
LC
PROPYLENE
TO DWG. 2200D
V-25003
FROM TC
G C2 BOTTOMS LC
ON V-22005 G
DWG. 2500A DWG. 2400B LI GC OUTLET
HIGH LEVEL
OVERRIDE
DWG. 2200D
NNF
TO LC ON DWG.
V-25003 MeOH 2200D
DWG. 2500A TO NOTE 2
P-25001
DWG. 2500A
MeOH
H NOTE 2
H
C2 DEC2
RECYCLE FEED C2
RECYCLE
C3R VAPOR DEC2 OFFGASSES
TO FEED DWG. 2300A OFFGASSES
J K-25001 DWG. 2300A J
FROM TC
FC
DWG. 2500A ON C-12003
DWG. 1200E RDG
DEC 1
C3R QUENCH
TO
V-25001/25002,
25003
DWG. 2500A FROM FC DWG. 1200E
ON K-25001
PROPYLENE DWG. 2500A
K FROM K
P-25001 FEB FOR PROPOSAL
0 RK
TO V-22002 2017
DWG. 2500A DWG. 2200A REV
ISSUE
DESCRIPTION CAD
PROC
LPE PDM PM CLIENT
DATE ENG
C3R MIN FLOW
TO HC
V-25001/25002/25003
WET FLARE
DWG. 2500A
LOW
MIN. FLOW BYPASS

LEVEL LC WORK PERFORMED BY LUMMUS. REPRODUCTION IN WHOLE OR IN PART FOR ANY PURPOSE OTHER THAN
OVERRIDE
NNF
HC PC FC
PROPYLENE
FROM
K-25001
STEAM CRACKER UNIT
PROPYLENE REFRIGERATION SYSTEM
NNF
DWG. 2500A
STARTUP PROPYLENE FILL
CWS SHEET 2 OF 2
PROPYLENE VAPOR AND MAKE-UP
M FROM FROM DOC. No: M
E-24016 OSBL
DWG. 2400A DWG. 2400E
6 A1-222334-2500B 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
V-26006 V-26007 K-26001 V-26005 V-26001 E-26001 V-26002 V-26003 V-26004 NOTES:
BINARY REFRIGERANT REFRIGERANT COMPRESSOR BINARY REFRIGERANT BINARY REFRIGERANT COMPRESSOR BINARY REFRIGERANT COMPRESSOR BINARY REFRIGERANT BINARY REFRIGERANT COMPRESSOR BINARY REFRIGERANT COMPRESSOR BINARY REFRIGERANT
A RETROGRADE CASING DRAIN POT COMPRESSOR SUCTION DRUM BLOWCASE 1ST STAGE SUCTION DRUM COOLER 2ND STAGE SUCTION DRUM 3RD STAGE SUCTION DRUM ACCUMULATOR 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1 A
NOTE 2 OPERATION UNLESS OTHERWISE INDICATED.
HP ETHYLENE DEC1 BTMS 2. DRUM SHARED WITH K-25001.
FROM STORAGE TO C-24001 3. MULTI-POINT METHANOL INJECTION FROM ME-12002.
SPHERES DWG. 2300A
DWG. 2300A
CHARGE GAS CHARGE GAS DEMETHANIZER ETHANE HP ETHYLENE HP ETHYLENE
CHARGE GAS CHARGE GAS CHARGE GAS CHARGE GAS TO V-23001 FROM E-23001 / E-23002 BOTTOMS RECYCLE FROM E-23005 TO E-23005
TO V-23003 FROM V-23002 TO V-23002 FROM V-23001 DWG. 2300D DWG. 2300C DWG. 2300C DWG. 2300A DWG. 2300A DWG. 2300A
B B
DWG. 2300B J E F J
E
DWG. 2300B DWG. 2300B DWG. 2300B
TO DEC 1
VENT V-23004 OVERHEAD F
TO C-23001
DWG. 2300C
HC A A HYDROGEN TO
DWG. 2300C HYDROGEN K-23001
FROM V-23003
C HC
B B METHANE TO C
METHANE
NNF
REGENERATION / FUEL GAS

FROM V-23004
D ETHANE TO
E-2001
NNF
J HP ETHYLENE VAPOR
TO OSBL
Q DWG. 2300A
J
C C
D D
FROM TC ON G G G G
METHANOL
CHARGE GAS NOTE 3
FROM ME-23000-E02 FROM TC ON
NNF
H
DWG. 2300B CHARGE GAS
FROM ME-23000-E03
FROM LC DWG. 2300B
TI METHANOL
ON V-23004
DWG. 2300C NOTE 3
DWG. 2300A 9°C 48°C
LI -28°C -11°C
TC G C3R C3R
E -40°C C3R C3R E
FROM TC ON C3R
TI
CHARGE GAS
FROM ME-23000-E01
DWG. 2300B DWG. 2300B
TI TI TI
FY
PC
TO COLD TO COLD TO COLD
F FLARE FLARE FLARE F
TO C-23001 TO COLD
DWG. 2300C FLARE
FC PC PC TC FC PC TC PC TC
NNF
NNF
HC
G G
HC PC
LOW LEVEL LC
OVERRIDE
NNF
H LI LC LC H
MIN. FLOW
MIN. FLOW
MIN. FLOW
QUENCH
QUENCH
QUENCH
LIQUID
LIQUID
LIQUID
NNF
NNF
NNF
NNF
LIQUID QUENCH NNF
J TO COLD J
FLARE
NNF TI
HC
LI
#2
FC
K K
FEB FOR PROPOSAL RK
0 2017
NNF
ISSUE PROC CLIENT
DATE ENG
MIN. FLOW H2 A LUMMUS PETROCHEMICALS

MIN. FLOW
CH4
SC FC PC
VAPOR
C2H4
C2H6 #1
NNF

FC WORK PERFORMED BY LUMMUS. REPRODUCTION IN WHOLE OR IN PART FOR ANY PURPOSE OTHER THAN
HC
LIQUID METHANE
MAKEUP
CWS PROCESS FLOW DIAGRAM
FROM HS STEAM CRACKER UNIT
NNF
NNF
NNF
NNF
V-23004
DWG. 2300C
COLD FLARE
BINARY REFRIGERATION SYSTEM
K-25001
(PART 1 OF 2)
METHANE MAKEUP BR BR VAPOR ETHYLENE BR BR DRAIN LIQUID ETHYLENE FILL
FROM FROM FROM MAKEUP TO TO FOR START-UP
M V-23004 ME-24000/ ME-24000/ FROM ME-24000-E07 C-23001 FROM DOC. No: M
ME-12000-E02 ME-12000-E02 ME-23000-E06 OSBL STORAGE
DWG. 2300C DWG. 2600B DWG. 2600B DWG. 2300A DWG. 2600B DWG. 2300C DWG. 2400B 4 A1-222334-2600A 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
NOTES:
A 1. TEMPERATURES & PRESSURES ARE SHOWN FOR CASE 1 A
B B
C C
PC
ETHYLENE
RUNDOWN TC
DWG. 2400B
DWG. 2400B
DWG. 1200E
D TC D
ETHYLENE TO C-12003
TO STORAGE V-12007 OVERHEAD
DWG. 1200E DWG. 1200E
TC
E FROM TC ON E
MIXED LPG FEED
TO C-12007
DWG. 1200E
FROM TC
ON V-12007
OVERHEAD
DWG. 1200E
F F
FUEL GAS FROM C FUEL GAS TO

V-12007 V-22011
DWG. 1200E DWG. 2200F
MIXED LPG TO B MIXED LPG

C-12003 FROM V-12012A/B
DWG. 1200E DWG. 1200E
TREATED A TREATED
G DRY GAS TO DRY GAS G
C-12003 FROM V-12006A/B
DWG. 1200E DWG. 1200E
DWG. 1200E
H H
J J
K K
FEB FOR PROPOSAL RK
0 2017
ISSUE PROC CLIENT
DATE ENG

STEAM CRACKER UNIT
BINARY REFRIGERATION SYSTEM
BR
TO
BR
TO
BR
FROM (PART 2 OF 2)
V-26001 V-26002 V-26004
M DOC. No: M
DWG. 2600A DWG. 2600A DWG. 2600A
3 A1-222334-2600B 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
NOTES:
A A
B B
PC
NORMAL OPERATION
SOR EOR
C
C kg/cm²g C
TC
FC
SOR EOR
C
kg/cm²g
MPS
D WET FLARE D
MP COND. HC
E E
NORMAL OPERATION CW
LC
SOR EOR 9°C
C C3R
kg/cm²g DWG. 2500B
LC
F F
RESET
NNF
TO WET
TO FLARE
G ATM. G
PC C
kg/cm²g
LC FC FC
H H
RESET
HIGH LEVEL
OVERRIDE
FC FC
NNF
J FROM LC ON J
V-21001
DWG. 2000A
K FI K
FEB
ISSUE PROC CLIENT
DATE ENG
START-UP ONLY

C4/C5 HYDROGENATION UNIT
REGENERATION HYDROGEN REGEN. MIXED C4'S ROG HEAVIES C5 RECYCLE MIXED SATURATED C4/C5 RECYCLE OFFGAS
GAS FROM EFFLUENT FROM FROM FROM LPG TO TO
FROM ME-23001 TO P-24008A/B P-12027A/B P-28003A/B FROM V-20012 V-22004
M E-22011 C-21003 DOC. No: M
DWG. 2200F DWG. 2300D DWG. 2100B DWG. 2400D DWG. 1200F DWG. 2800B OSBL DWG. 2000A DWG. 2200D
8 NONE A1-222334-2700A 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
A A
2. TWO RECYCLE EXCHANGERS ARE PROVIDED. ONE
FOR EACH REACTOR WITH ONLY ONE EXCHANGER IN
OPERATION DURING NORMAL OPERATION.
3. P-28002A IS DEDICATED TO R-28001A,
P-28003B IS DEDICATED TO R-28001B,
PC P-28002C WILL BE A COMMON SPARE.
B B
NORMAL OPERATION
SOR EOR
TO OTHER C
REACTOR TC REGENERATION
C kg/cm²g C
C 480
kg/cm²g 1.0
"B"
WET
FLARE
FROM OTHER
REACTOR
"A"
NORMAL OPERATION TO WET
NITROGEN SOR EOR FLARE
D FC D
C
PC kg/cm²g
HC
C LC
kg/cm²g C 45
kg/cm²g 3.8
SOR EOR
E E
C
kg/cm²g
CW
LC
FC
F F
"B"
LC
OWS NOTE 2
"A"
G HS HP FROM OTHER G
COND. REACTOR
SP FC
NOTE 2
H H
CW
REGENERATION
REGENERATION
J J
NOTE 3
FI
K FI K
FEB
ISSUE PROC CLIENT
DATE ENG
FC
NNF

BL PYROLYSIS GASOLINE HYDROGENATION UNIT
PGH FIRST STAGE REACTOR
RAW PYROLYSIS HYDROGEN HYDROGEN START-UP NAPHTHA START-UP NAPHTHA FIRST STAGE OFFGAS REACTOR REACTOR
GASOLINE FEED TO TO FROM REACTOR EFFLUENT TO REGEN GAS REGEN GAS
FROM FROM ME-23001 V-28012 C-28003 P-20001A/B TO V-28005 V-28012 TO SCU FROM SCU
E-24015
M DWG. 2400D DWG. 2300D DWG. 2800C DWG. 2800C DWG. 2000A DWG. 2800B DWG. 2800C DWG. 2800C DWG. 2800C DOC. No: M
5 NONE A1-222334-2800A 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
A A
2. CASE 1: C5's TO C4/C5 HYDROGENATION UNIT.
CASE 2: C5's TO CRACKING HEATERS.
PC
B B
PC
C
C kg/cm²g C
C
kg/cm²g
CW
D D
LC
SP
FC "B"
E E
SP TC
C
LC kg/cm²g
FC
F C
LC F
kg/cm²g
DS MPS MP COND.
LI
SP
NNF
G G
SP
FC FC
OWS
H H
J J
FC
K K
FEB
ISSUE PROC CLIENT
DATE ENG
NOTE 2 "THIS DOCUMENT IS THE PROPERTY OF LUMMUS TECHNOLOGY INC. (LUMMUS). IT CONTAINS CONFIDENTIAL
NOTE 2 PROCESS FLOW DIAGRAM

PYROLYSIS GASOLINE HYDROGENATION UNIT
DEPENTANIZER
PGH FIRST STAGE C6+ C5's C5 RECYCLE LP OFFGAS LP OFFGAS
REACTOR EFFLUENT TO TO TO FROM TO
FROM C-28002 F-20002/F-20007 THU V-28013 V-22001
M V-28003
DOC. No: M
DWG. 2800A DWG. 2800D DWG. 2000A DWG. 2700A DWG. 2800C DWG. 2200A SCALE: DWG. No: REV:
3 NONE A1-222334-2800B 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
A A
B B
TC
PGH
PRESULFIDING SP CORROSION
INJECTION FC INHIBITOR INJECTION
FROM ME-12001
FROM ME-28002
PGH
CORROSION
INHIBITOR INJECTION C 144
C FROM ME-28002 C
TO WET kg/cm²g 4.5
NORMAL OPERATION FLARE
SOR EOR CW
TO WET
C FLARE
HC
kg/cm²g
HC
CW PC
D TI PC D
REGENERATION
C 480 C 161
kg/cm²g 1.0 kg/cm²g 4.7 C 45
C 45 kg/cm²g 4.0
kg/cm²g 25.2
E E
NORMAL OPERATION
SOR EOR
C
kg/cm²g
FC
MINIMUM FLOW BYPASS
NNF
LC COND.
LC
F F
MPS
REGENERATION
REGENERATION
HS TO MP OWS
SP
STEAM STEAM
G G
FC
FC LP OFFGAS HP OFFGAS
TO TO
SCU V-22004
H H
DWG. 2800B DWG. 2200D
A
H2S
FC
J J
M
FC SP
FC
K K
NNF
FEB
ME-28002 0 2017 FOR PROPOSAL RK
ISSUE PROC CLIENT
DATE ENG
PGH CORROSION
INHIBITOR
INJECTION PACKAGE
REACTOR INFORMATION DESCRIBING TECHNOLOGY OWNED BY LUMMUS. IT IS TO BE USED ONLY IN CONNECTION WITH
L REDUCTION GAS KNOCK OUT WORK PERFORMED BY LUMMUS IS FORBIDDEN EXCEPT BY EXPRESS WRITTEN PERMISSION OF LUMMUS. IT IS L
FROM LIQUID TO BE SAFEGUARDED AGAINST BOTH DELIBERATE AND INADVERTENT DISCLOSURE TO ANY THIRD PARTY."
SCU TO
DWG. 2200F C-21003 PROCESS FLOW DIAGRAM
DWG. 2100B PYROLYSIS GASOLINE HYDROGENATION UNIT
PGH SECOND STAGE REACTOR AND
REACTOR REGEN/ REACTOR REGEN/ REACTOR REACTOR C6-C8 CUT HYDROGEN HYDROGEN RICH PGH SECOND STAGE START-UP NAPHTHA H2S STRIPPER
HEATING/COOLING HEATING/COOLING REGENERATION GAS REGEN GAS FROM FROM FROM GAS FROM REACTOR EFFLUENT FROM
GAS TO GAS FROM EFFLUENT R-28001A/B P-28005A/B ME-23001 V-28003 TO STORAGE
R-28001A/B SCU TO SCU C-28004
M DOC. No: M
DWG. 2800A DWG. 2200F DWG. 2200F DWG. 2800A DWG. 2800D DWG. 2800A DWG. 2800A DWG. 2800D DWG. 2800A
5 NONE A1-222334-2800C 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
A A
MPS NITROGEN
B B
PC PC
C C
CW
C 72
CW kg/cm²g -0.7
D LP VENT D
C 99
kg/cm²g C 90 HC
0.8 CW
kg/cm²g 0.5
-11° C 42
C3R kg/cm²g -0.8
DWG. 2500B
LC
E FC E
LC
FC
TC
F F
TC
LP VENT
SP LC
C 40
FC kg/cm²g 0.5 SP
LC FC
G G
MPS
LC C 157
kg/cm²g -0.3 DS MPS
MP COND.
C 150
MP COND.
kg/cm²g 1.4
ON / OFF
H H
SP
FC
M
J J
FC
SP
SP
FC
SP
K K
FC FEB
DILUENT 0 2017 FOR PROPOSAL RK
TO
CW NNF ME-28003 REV
ISSUE
DATE
DESCRIPTION CAD
PROC
ENG
LPE PDM PM CLIENT
CW
CW
ME-28003 PGH ANTIOXIDANT PGH ANTIOXIDANT C 40 LUMMUS PETROCHEMICALS
INJECTION INJECTION kg/cm²g 3.5 PGH ANTIOXIDANT
FROM ME-28003 FROM ME-28003
PGH ANTIOXIDANT INJECTION "THIS DOCUMENT IS THE PROPERTY OF LUMMUS TECHNOLOGY INC. (LUMMUS). IT CONTAINS CONFIDENTIAL
INJECTION FROM ME-28003 INFORMATION DESCRIBING TECHNOLOGY OWNED BY LUMMUS. IT IS TO BE USED ONLY IN CONNECTION WITH
L PACKAGE C 42 C 42 C 44 WORK PERFORMED BY LUMMUS IS FORBIDDEN EXCEPT BY EXPRESS WRITTEN PERMISSION OF LUMMUS. IT IS L
kg/cm²g 4.0 kg/cm²g 4.1 kg/cm²g 5.0 TO BE SAFEGUARDED AGAINST BOTH DELIBERATE AND INADVERTENT DISCLOSURE TO ANY THIRD PARTY."
BL BL BL
PYROLYSIS GASOLINE HYDROGENATION UNIT
PGH SECOND STAGE C7-C8 PRODUCT C6 CUT C6 CUT EJECTOR C6 - C8 CUT C6+ WASH OIL C9+ CUT DEHEXANIZER AND BTX COLUMNS
REACTOR EFFLUENT TO TO TO CONDENSATE TO FROM TO TO
FROM STORAGE STORAGE BZEU TO E-28009 C-28002 T-21002 E-21004A/B
E-28012 OSBL
DWG. 2800C OSBL OSBL (GTC) DWG. 2800C DWG. 2800B DWG. 2100A DWG. 2100A
M DOC. No: M
7 NONE A1-222334-2800D 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
NOTES:
A A
B B
HP FLARE
FROM BZU
METHANOL
C DESUPERHEATED C
LP COND.
LP STEAM
D D
E E
METHANOL
DESUPERHEATED LP COND.
F LP STEAM F
G G
H H
WET FLARE DRY FLARE

FROM C4 HYDRO & PGH FROM C4 HYDRO & PGH
J COLD BLOWDOWN
J
FROM C4 HYDRO & PGH
RO RO
K K
FEB
ISSUE PROC CLIENT
DATE ENG

STEAM CRACKER UNIT
HP FLARE WET C4 AND ROG LIQUID TO FUEL GAS SWEEP COLD DRY
ISBL FLARE KNOCK OUT DRUMS
TO FLARE DRAIN QUENCH TOWER FROM BLOWDOWN FLARE
HEADER HEADER C-21003 FUEL GAS SYSTEM HEADER HEADER
M OSBL (LIQUID DRAIN) DWG. 1001E (LIQUID DRAIN) DOC. No: M

3 NONE A1-222334-3100A 0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
A1-222334-3100A Last Revised: 2/7/2017 12:38 PM by rajkumar

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Lummus Petrochemicals

CLIENT HMEL (HPCL Mittal Energy Ltd) 222334 Process Description

2.4 Process Description

2.4.1 Refinery Off Gas (ROG) Treating Unit

2.4.1.1 ROG Amine System

Page 1 of 31 CONFIDENTIAL 2/14/2017

CLIENT HMEL (HPCL Mittal Energy Ltd) 222334 Process Description

2.4.1.2 ROG Caustic Treatment and Oxygen Converter

Page 2 of 31 CONFIDENTIAL 2/14/2017

CLIENT HMEL (HPCL Mittal Energy Ltd) 222334 Process Description

Page 3 of 31 CONFIDENTIAL 2/14/2017

CLIENT HMEL (HPCL Mittal Energy Ltd) 222334 Process Description

2.4.1.3 Mixed LPG Treating

2.4.1.4 Refining Off Gas Chilling & ROG Demethanizer

Page 4 of 31 CONFIDENTIAL 2/14/2017

CLIENT HMEL (HPCL Mittal Energy Ltd) 222334 Process Description

2.4.1.5 ROG Depropanizer

Page 5 of 31 CONFIDENTIAL 2/14/2017

CLIENT HMEL (HPCL Mittal Energy Ltd) 222334 Process Description

2.4.2 Steam Cracking Unit (SCU)

 Polymer Grade Ethylene

Capacity and Mode of Operation

2.4.2.1 Furnace Feed System

Page 6 of 31 CONFIDENTIAL 2/14/2017

CLIENT HMEL (HPCL Mittal Energy Ltd) 222334 Process Description

2.4.2.2 Cracking Heaters

Feed Supply Header Arrangement

Ethane Propane C4/C5 Naphtha Kero

Page 7 of 31 CONFIDENTIAL 2/14/2017

CLIENT HMEL (HPCL Mittal Energy Ltd) 222334 Process Description

Heater Allocation – Design Case 1

Heater Allocation – Design Case 2

 Upper Feed Preheat (UFP)

Page 8 of 31 CONFIDENTIAL 2/14/2017

CLIENT HMEL (HPCL Mittal Energy Ltd) 222334 Process Description

 Lower Mixed Preheat (LMP)

 Upper Feed Preheat (UFP)

Page 9 of 31 CONFIDENTIAL 2/14/2017

CLIENT HMEL (HPCL Mittal Energy Ltd) 222334 Process Description

8-1 Radiant Coil Configuration of the SRT VII Cracking Heaters

Page 10 of 31 CONFIDENTIAL 2/14/2017

CLIENT HMEL (HPCL Mittal Energy Ltd) 222334 Process Description

a. To provide heater isolation during decoking

Page 11 of 31 CONFIDENTIAL 2/14/2017

CLIENT HMEL (HPCL Mittal Energy Ltd) 222334 Process Description

2.4.2.3 Gasoline Fractionator

Page 12 of 31 CONFIDENTIAL 2/14/2017

CLIENT HMEL (HPCL Mittal Energy Ltd) 222334 Process Description

2.4.2.4 Quench Tower

 Propane Feed Heater

 Caustic Charge Gas Feed Heater

Page 13 of 31 CONFIDENTIAL 2/14/2017

CLIENT HMEL (HPCL Mittal Energy Ltd) 222334 Process Description

2.4.2.5 Process Water Stripping and Dilution Steam Generation

Page 14 of 31 CONFIDENTIAL 2/14/2017

CLIENT HMEL (HPCL Mittal Energy Ltd) 222334 Process Description

2.4.2.6 Charge Gas Compression (Stages 1-2)

2.4.2.7 Amine System

Page 15 of 31 CONFIDENTIAL 2/14/2017

CLIENT HMEL (HPCL Mittal Energy Ltd) 222334 Process Description

2.4.2.8 Acid Gas Removal

Page 16 of 31 CONFIDENTIAL 2/14/2017