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Water Systems
DOCUMENT No CEEDG007
REVISION HISTORY
Contents
REVISION HISTORY........................................................................................ 1
CONTENTS .................................................................................................... 2
1.0 INTRODUCTION ..................................................................................... 3
2.0 ONCE THROUGH COOLING SYSTEMS ....................................................... 3
3.0 OPEN EVAPORATIVE COOLING SYSTEMS .................................................. 4
4.0 HUMIDIFICATION SYSTEMS .................................................................... 7
5.0 CLOSED WATER SYSTEMS ...................................................................... 8
6.0 COLD AND HOT WATER SYSTEMS ............................................................ 9
7.0 FIRE WATER SYSTEMS ......................................................................... 10
8.0 PROCESS WATER SYSTEMS................................................................... 10
9.0 PHARMACEUTICAL WATER SYSTEMS ...................................................... 11
APPENDIX 1 ................................................................................................ 13
APPENDIX 2 ................................................................................................ 15
APPENDIX 3 ................................................................................................ 16
1.0 INTRODUCTION
Modern industry uses water for many applications including heating, cooling, chemical processing and
product rinsing as well as for "domestic" uses such as drinking, cooking, washing and flushing of WC's.
The problems of scaling and corrosion of mechanical equipment have long been recognised and many
water treatment techniques have been developed to overcome them. However, it is only over the last
decade or so that there has been increasing awareness and growing concern about potential health
hazards associated with water services of various types in modern industrial plant and buildings.
The principle water systems that concern chemical process design engineers are steam raising boilers
(see CEEDG006) and open cooling water systems, although chilled water and hot water are also
sometimes required particularly in batch processing plants like pharmaceutical manufacturing. Many of
the water systems are the province of the Building Services Engineer – potable, hot and cold supplies,
space heating, air cooling and humidification are necessary for staff welfare, so it is useful to have
some background knowledge. All water systems are prone to problems of scale, corrosion and
microbiological contamination. The effects can vary from minimal – maybe a leaking pipe – to
economic – fouled heat exchange surfaces are inefficient – to catastrophic – think release of high
temperature process streams from a corroded heat exchanger or an outbreak of Legionnaires’ disease.
Properly controlled water treatment, combining techniques such as filtration, softening, deionisation or
reverse osmosis together with chemical conditioning, by scale and corrosion inhibitors and disinfecting
agents, protects expensive plant by preventing corrosion, scale deposition and biological fouling in
boilers, cooling towers and heating systems.
In this monograph we shall look at some of the types of water systems and the engineering problems
associated with them.
Coastal power stations and chemical plants frequently take sea water, use it for cooling and then
return it directly to the sea. These systems may be direct – that is the sea water is pumped through
heat exchangers around the site – or indirect where heat exchangers are cooled by a primary closed
circuit filled with treated fresh water and the primary circuit is then cooled by a single heat exchanger
which is directly cooled by sea water. To limit the return temperature, flows are very high and sea
water has a whole series of associated problems like corrosion and biological fouling.
Cooling towers are either natural draught or forced draft. In either case the incoming hot
water is distributed over a packing material to enhance contact with the air stream to
maximise heat and mass transfer. Natural draught towers are used for large scale duties and
are of hyperbolic cross section and constructed from reinforced concrete. Air is drawn upwards
by convection. Capital costs are very high but operating costs are low.
contact between water and air. This is, typically, a proprietary structured plastic medium.
Multi-cell and single cell induced draught and single cell forced draught towers
An atmospheric cooling tower takes C m3/h of recirculating cooling water at T2 °C and cools it
to T1 °C by evaporation. As water evaporates it takes in latent heat (about 2450kJ/kg) from
surrounding water which is, consequently, cooled. The evaporation loss (E m3/h) together with
the loss from windage and drift (W m3/h) is made up by make-up water (M m3/h TDS m mg/l).
Evaporation removes water as vapour leaving salts behind so the circulating water becomes
more concentrated (TDS b mg/l) and the “concentration factor” (CF) of the tower is b/m
(usually this test is carried out using chloride as the test parameter since other salts may be
precipitated as their solubility product is exceeded). The concentration is limited to an
acceptable level by discharging B m3/h of circulating water as blowdown or bleed-off.
Windage consists of large droplets (0.5-2.0mm) of water lost from the sides of the tower and
is typically up to 0.02% circulation rate although well designed side louvers should reduce it to
Document No: CEEDG007 Revision 2
Effective Date: September 2017 Page 5 of 17
Owner: CEE Design Consultants
Water Systems
less than 0.01%. The typical windage zone is 5-10m from the tower sides. Drift is the loss of
small (50-100µm) droplets of water which are entrained in the air flow leaving the tower.
Efficient drift eliminators should reduce this to less than 0.01% circulation rate. The drift zone
may be up to 500m depending on height and wind speed.
M=E+B+W
Mm = Bb + Wb
M = (B + W)CF
E = (B + W)(CF - 1)
B + W = E/(CF - 1)
M = E.CF/(CF - 1)
That is the evaporation rate is about 0.2% of circulation rate per °C temperature drop across
the tower.
We have seen how water in a recirculatory system becomes more concentrated and this
means that the solubility of low solubility salts like calcium sulphate, calcium phosphate and
can be exceeded. We can predict this by looking at the concentrations of low solubility salts in
the circulating water and calculating solubility products (Appendix 2). Note that calcium and
magnesium salts generally exhibit reverse solubility curves, becoming less soluble with
increasing temperature.
The most common type of scale is calcium carbonate and it’s a double edged sword. A thin
film of calcium carbonate on metal surfaces protects them from corrosion but a thicker deposit
reduces heat transfer and can block pipes and damage the cooling tower fill. Keeping a
balance is not easy. Wilfred Langelier, an American water chemist, developed the Langelier
Saturation Index1 (Appendix 3) to control cooling water chemistry. There are nomographs and
on-line calculators for determining LSI but a reasonable arithmetic approximation for most
systems is:
CaH MAlk
LSI pH log log (2.65 0.0167T )
2000 1000
Where CaH is the calcium concentration or calcium hardness of the circulating water in meq/l
MAlk is the total alkalinity of the circulating water in meq/l
T is the temperature in C
A positive LSI indicates that the water will deposit calcium carbonate whilst a negative value
indicates that the water will dissolve calcium carbonate. Controlling the value between
±0.5 should ensure that the water should cause neither scale nor corrosion. That is not easy
and sometimes not possible. Scaling can be prevented by limiting the concentration factor by
1
Langelier WF (1936) The analytical control of anti-corrosion water treatment. JAWWA 28(10):1500–1521
blowdown, the addition of scale inhibiting chemicals (mainly phosphonates) provided that the
LSI is <2, reducing the LSI by acid dosing or by softening the make-up water.
3.4 Corrosion in Cooling Towers
Contacting water and air in a cooling tower results in the water having a high dissolved
oxygen content producing favourable conditions for aqueous corrosion. If LSI adjustment
cannot achieve protection then it may be necessary to add corrosion inhibiting chemicals
which suppress one or both of the half cell reactions by forming a protective film. These may
be zinc salts which form a zinc hydroxide protective film or amines which form an organo-
metallic film over all metal surfaces. Any break in the protective film will result in intense and
rapid corrosion at the break and the corrosion may spread unobserved beneath the film.
Note: In the UK all open cooling towers have to be registered with the UK Health and
Safety Executive due to the risk of legionella. Guidance on design is provided by the
HSE in a Technical Guidance Document “HSG274 Part 1: The control of legionella
bacteria in evaporative cooling systems” (free to download from HSE).
Suspended solids can be scrubbed from the atmosphere and can contribute to corrosion and
fouling.
Humidifiers increase the humidity of air in air conditioning systems by evaporating water into the air
stream. The preferred types of humidification system are the direct type where steam or water is
injected into the air-stream from a boiler or atomising unit. Other types include ultrasonic, spray, air
washer or pan type humidifiers in which water at room temperature is passed through a humidifying
device in which some water is evaporated whilst the remainder is recirculated. In this section of the
document "humidifier" is taken to include not only the humidifying device itself but also any storage
tank, valves and associated equipment.
2
HSE Approved Code of Practice L8 Legionnaires’ Disease : The Control of Legionella Bacteria in Water Systems
Scale can be deposited in these units as a result of evaporation. Corrosion can also occur due to
'oxygen rich' conditions and galvanic action between dissimilar metals. Contacting of water with air as
part of the humidification process provides ample opportunity for ingress of dust, debris and microbial
agents. The latter can grow to hazardous levels if conditions are favourable causing health risks, e.g.
humidifier fever.
Humidifier fever is an allergenic reaction caused by the inhalation of fine droplets of water, carried
over in the airstream from humidifiers which have become contaminated with various micro-organisms.
It is characterised by chest tightness and other flu-like symptoms which typically occur on the first day
of a workshift and then reduce during the next few days giving a cyclic pattern.
Biocides, scale and corrosion inhibitors must not be used as these can be carried over in the air
stream and inhaled. Control of microbial growths is achieved by the regular programme of off-line
cleaning and disinfection. This may be supplemented by further off-line disinfection if needed.
Scale and deposit control is best achieved by using softened or low solids water for make-up. In hard
supply water areas make-up water should be pretreated by either base exchange softening or
demineralisation. Corrosion protection should be afforded by the use of corrosion resistant materials.
Electrode type steam humidifiers must be fed with water which has been pretreated to achieve a total
hardness of less than 0.1meq/l and must be regularly blowndown. Regular bleed-off should be
provided for water storage humidifiers to control the levels of dissolved and suspended solids.
Systems consist of a hot water boiler or steam heated heat exchanger (called a calorifier), a
pumping station and recirculation pipework. Corrosion and scale deposition are accentuated in
hot water heating systems due to the operating conditions (i.e. temperatures and pressures).
Scaling problems can arise at temperatures above 60C when solids precipitate from solution.
Corrosion processes are accelerated at high temperatures and in the presence of oxygen rapid
pitting corrosion of water lines and boiler internals can occur. Microbial contamination is not
normally a problem with the system owing to the high temperatures but can occur in systems
where lower temperatures (below 60C) occur.
Pretreatment of the make-up and initial fill water should be considered for HTHW and MTHW
systems, which should preferably be filled and made-up with water containing 50 mg/litre
dissolved solids or less as recommended by the boiler manufacturer. If permitted by the
boiler manufacturer base exchange softened water may be used as an alternative. LTHW
systems with boilers having high heat release rates or modular boilers with a low water
content should be filled and made-up with softened water having a total hardness of less than
0.1meq/l. Other LTHW systems should be filled with mains water or a blended water with a
total hardness not exceeding 2meq/l.
Chemical conditioning requirements for these systems are dependent upon the make-up water
quality and system operating temperatures and pressures. In HTHW and MTHW systems
chemical conditioning programmes should aim to minimise the accumulation of dissolved
solids. These should typically include an oxygen scavenger for controlling corrosion, a pH
Document No: CEEDG007 Revision 2
Effective Date: September 2017 Page 8 of 17
Owner: CEE Design Consultants
Water Systems
elevant to assist corrosion control and a dispersant to assist in scale and sludge control.
Chemical conditioning for LTHW systems is usually based upon the formation of passive films
over the metal surface rather than utilising the oxygen scavenging approach. It is important
therefore that the conditioning agents used are compatible with and can provide effective
corrosion control for all metals present in the system. Typical chemical conditioning agents
used in these systems include corrosion inhibitors, dispersants for scale/sludge control and
compatible non-oxidising biocides for microbial control if necessary.
Closed chilled water systems including closed condenser systems and direct expansion units,
are pressurised and normally operated in the temperature range of 5 to 16 oC. They comprise
a chilled water circuit, chiller batteries and chiller plant. These systems can be affected by
corrosion and to a lesser extent microbial contamination and scale/deposit accumulation. At
low temperatures it is ususal to add glycol to the water to prevent freezing on the chiller coil
and this reduces the heat transfer coefficient. Both microbial growth and scale deposition are
suppressed by low temperatures. Corrosion problems are most frequently encountered due to
the ingress of dissolved gases, principally oxygen and carbon dioxide with the make-up water
and to microbial activity which can also produce biofilms causing pipework blockage.
Pretreatment of make-up water should be considered for chilled water systems. They should
preferably be filled with a mains water or a blended water with a total hardness not exceeding
2meq/l. Make-up requirements are usually small because only minimal evaporation or
concentration of the recirculating water occurs at the low operating temperatures. Corrosion
inhibitors – typically nitrite/borate mixtures – should be dosed as required to accommodate
any make-up to the system and chemical degradation. Microbial activity should be controlled
using a non-oxidising biocide which is dosed when needed.
Cold and hot water down services supply water for domestic purposes other than drinking.
Conventional vented systems usually consist of a cold water storage cistern feeding a cold water
distribution system or a hot water distribution system via a hot water storage vessel (e.g. calorifier or
direct feed boiler).
Tanks should be inspected at least annually and where excessive microbial growth is observed or
bacterial dip-slide checks exceed 105cfu/ml tanks should be cleaned and disinfected in accordance
with BS6700.
The distribution systems serve the individual outlets including taps, mixing valves and showers. Hot
water can be produced directly by heating appliances or indirectly on the secondary side of steam or
hot water calorifiers. Both cold and hot water services are vulnerable to microbial contamination,
which on formation of aerosols can be inhaled causing respiratory illnesses, such as Legionnaires'
Disease or Pontiac Fever. Water from these systems can also be ingested, if they are used
inadvertently for the preparation of food or drinks.
In order to restrict microbial growth a water temperature ideally below 15°C but not exceeding 20oC
should be maintained in cold water storage and distribution systems whilst hot water services must
ensure a water temperature leaving the hot water storage vessel or calorifier of 60 oC and a minimum
in distribution and delivery to the water service outlets of 50oC.
Water treatment by chemical conditioning is normally unnecessary for supply waters in the United
Kingdom. If chemical conditioning agents are deemed necessary they must be approved for use in
potable water. Scaling, corrosion and discolouration can be controlled by using proprietary chemicals
based upon complexed phosphates or silicates. Chemicals should be dosed either into the cistern or
the cold supply pipe downstream. Where water supplies are particularly hard or where a building has
a history of scaling problems consideration should be given to partial softening of the water for hot
and cold services.
Much of the fire protection guidance used in process industries is based on the US National Fire
Protection Association standards3. In the UK, fire protection in industrial plant is covered by COMAH
regulations. HSE provide guidance in their Technical Measures - Active and Passive Fire Protection
Systems4. In the case of active fire protection systems, delivery rates and durations for various types
of application are specified in BS 5306 Code of practice for fire extinguishing installations and
equipment on premises. For fire engulfment protection a water rate of 0.6m 3/h/m2 over the exposed
vessel surface and its supports is standard. Automatic sprinkler systems for commercial and industrial
premises are covered by BS EN 12845:2004 – Fixed Fire Fighting Systems.
Note that, in the event of a fire, fire water has to be contained and, if required, treated prior to
discharge to prevent a possible pollution incident5.
3
http://www.nfpa.org/
4 http://www.hse.gov.uk/comah/sragtech/techmeasfire.htm
5
HSE Guidance Note EH 70, the control of fire water run-off from CIMAH sites to prevent environmental damage, HSE, 1995
international brewers ABInBev, and soft drinks manufacturers Coca Cola and Pepsico, work to
much tighter in-house standards to ensure consistency and shelf life of their product wherever
it is produced. Other examples of in-house process water standards include water for surface
finishing in the automotive industry (Ford, VW), water for concrete mixing in construction
(Wimpey) and water for . Again these are predicated on product quality. The pharmaceutical
industry, for obvious reasons, is strictly regulated and has developed engineering standards to
ensure that water quality is met and maintained. This is discussed in the next section and
similar standards are increasingly being applied in healthcare and food and beverage process
water systems. The purest water, with maximum contaminant concentrations measured in
ng/l, is that used for manufacturing silicon chips. The need to prevent this water from
becoming contaminated by contact with construction materials resulted in the development of
a range of pipework and fitting made from high purity PVDF (See CEEDG204).
Note that water systems should include appropriate water storage to ensure a constant supply
even if plant components fail. If water is taken from a municipal drinking water supply it will
be necessary to provide isolation to prevent possible contamination of the supply by
backsiphonage and this will be covered by local water bye-laws. In the water supply industry,
materials of construction and products such as pipe fittings and valves must comply with local
legislation (in the UK this requires approval by the Drinking Water Inspectorate).
WFI is used for the manufacture of parenteral solutions (vaccines, saline drips and other
products that are injected rather than ingested). The standards are similar as for Purified
9.3 Engineering
6
ISPE Baseline Guide Volume 4: Water and Steam Systems
APPENDIX 1
In a cooling tower, heat and mass transfer occur simultaneously driven by a difference in enthalpy.
The controlling equation is the Merkel equation which gives the number of transfer units required:
T
KaV 1 dT
NTU
L h ha
T2 i
h
EQUILIBRIUM LINE
ENTHALPY
ha2
OPERATING LINE
ha1
APPROAC H T
Tw T2 T1
TEMPERATURE
APPENDIX 2
SOLUBILITY PRODUCTS
At the limit of its equilibrium solubility, a compound is said to form a saturated solution in the
water. If the ions reach a concentration higher than saturation, they precipitate. This can
happen if a saturated solution is cooled. The dissolution of a solid salt is represented by the
equation:
Cm An mCn+ + nAm-
Where M is the cation and A the anion and the equilibrium constant is given by:
KSP = [ C ]m [ A ]n
Where [] indicate concentration in mol/L. For example for calcium sulphate we have:
The constant KSP is called the “molar solubility product” of the salt. If the product of the
concentrations of the ions dissolved in water exceed the solubility product then precipitation
will occur forming scale on heat transfer surfaces and within the fill. For example adding
sodium sulphate to a solution of calcium chloride is likely to cause the solubility product of
calcium sulphate to be exceeded and calcium sulphate will precipitate to form scale. Values for
the molar solubility products of some common scale forming salts are given in the table below.
Note that these refer to pure water, as the presence of other contaminants can influence the
solubility of a compound.
APPENDIX 3
The compounds CO2, HCO3- and CO32- are actually linked by a complex series of reversible
reactions leading to kinetic equilibria. The reactions are normally collectively referred to as
carbonate chemistry. They begin with CO2 in the atmosphere. When atmospheric air comes
into contact with pure water, CO2 dissolves in water, the amount varying with the partial
pressure according to Henry's Law. Dissolved CO2 combines with water to form carbonic acid
(H2CO3) in another reversible reaction and then bicarbonate and finally carbonate:
Carbonic acid is an extremely unstable compound, so unstable that it only exists temporarily
before breaking down to form carbon dioxide and water, or else dissociating to form acid and
bicarbonate. It none-the-less exists in solution, if only fleetingly, and forms part of the
sequence of reactions of carbonate, all of which are subject to the Law of Mass Action when
the reactions are all in equilibrium.
-
[H + ] [HCO 3 ]
K = 4.14 10 7
[CO 2 ]
Using the definition of pH = -log[H+] and putting in the numerical value of K we have:
[HCO3 ]
log10 pH 6.38
[CO2 ]
In the case of normal waters, in which Ca2+ is the major cation, this equation holds quite well
between pH 4.5 and 8.2 and we can use it to predict changes in pH resulting from acid or
alkali dosing. Adding one mole of acid converts one mole of bicarbonate alkalinity to one mole
of carbon dioxide:
[HCO3 x]
log10 pH 6.38
[CO2 x]
Similarly adding one mole of hydroxide converts one mole of CO2 into one mole of bicarbonate
The term Total Alkalinity or M Alkalinity, when used in water treatment parlance, refers to the
total concentration of bicarbonate, carbonate (usually low) and hydroxide (negligible at pH
<8.5) ions in water, so the bicarbonate concentration can usually be taken as the Alkalinity.
In an evaporative cooling tower the draft of air strips carbon dioxide from solution. If no
dissolved CO2 is available HCO3- ions take up H+ ions reverting to H2O and CO2. The CO2 which
is produced in this way is continuously taken away also, so that no equilibrium can be
established. H+ ions are therefore consumed and the pH rises. When it reaches 8.3, the
bicarbonate ions start to dissociate to form carbonate:
-
[H+] [CO 3 ]
K =
[HCO3]
The CO32- forms CaCO3 with any Ca2+ in the water and precipitates, which is how a scale or
“fur” forms in kettles and pipes. The overall reaction can be written:
The amount of hardness which will precipitate in this way is called the Temporary Hardness or
Carbonate Hardness. It is the amount of hardness or bicarbonate in the analysis, whichever is
the lower. In most waters the HCO3- content is lower than the hardness. The hardness which
is left after that is called the Permanent Hardness or Non-carbonate Hardness.
If we consider a water which is just saturated with calcium carbonate (that is, it will neither
deposit nor dissolve scale) we can write, using the shorthand form of pX = -logX:
This calculated value of pH is called the saturation pH and is designated as pHs. The difference
between the actual pH of the water and its theoretical pH s value (pH - pHs) is called the
Langelier Saturation Index and indicates whether the water will deposit calcium carbonate
(“scaling”) or dissolve calcium carbonate (“corrosive”). A positive LSI value indicates a scaling
water and a negative LSI a corrosive water.