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0% 18.05571 15.05571 0
XB ΔVmix
(cm3/mol)
1 0
0.388 1.03587738
0.239 1.24623017
0.1386 0.71040376
0.0598 0.20489146
0 0
The literature values of the molar volumes of pure ethanol and pure water are 18.063
cm /mol and 58.534 cm3/mol, respectively. In the graph above, the tangent line was necessary in
3
order to determine the ΔV of ethanol and water. The molar volume of ethanol and water are 1.45
and 0.60 correspondingly. The partial molar volume of water based on the graph was 17.45571
cm3/mol and for ethanol was 55.18464 cm3/mol.
Originally, the calculated values for the molar volumes of ethanol and water are
56.6346375 cm3/mol and 15.05571 cm3/mol, respectively. Comparing the actual/literature value
of the molar volume of the pure compounds water and ethanol which are : Ethanol=58.534
cm3/mol Water = 18.063 cm3/mol (From Perry’s Handbook) to the experimental values obtained :
Ethanol = 56.6346375 cm3/mol Water = 15.05571 cm3/mol there was a significant difference that
may be due to the errors committed in using the pycnometer and maybe due to the fact that ethanol
was a volatile liquid resulting to less molar volumes obtained experimentally. Another reason is
the interactions between the components of the solution. Since no solution is ideal, the interactions
must always be accounted for. This would also mean that there would be a change in volume.
Water has a fairly open structure wherein there would be open spaces or voids in structure
that may be filled by the nonpolar part (hydrocarbon) of ethanol. This is illustrated in the figure
below. Therefore, the total volume of the mixture would be less than the sum of the volumes of
the mixture when separate. This factor may be accounted for the difference of the total volume.
ΔVM = Vmix* - Vm
𝒄𝒎𝟑
VM = 23.40444 − 22.684033 = 𝟎. 𝟕𝟏𝟎𝟒𝟎𝟑𝟕𝟔 33 %
𝒎𝒐𝒍
V. CONCLUSION
Partial molar volumes of ethanol-water system at different concentrations were determined
by utilizing the density and specific gravity measurement. Every concentration had been evaluated
individually; using a pycnometer by means that of the moles of every compound, the mole fraction
of water, the average molecular weight and also the density. These had been determined to get the
molar volume of every concentration and also the change in molar volume because of mixing.
From the information obtained, the various graphs and tables had been made. It was observed that
as the quantity of ethanol is increased, the density is decreased, as proven by the definition of
density giving an inverse proportion relationship with volume. Also, it had been showed that the
partial molar volume once mixed was lesser than the molar volume of pure components. This can
be caused by an ordering effect of solvation that tends to reduce the volume of the solvent. The
decrease in volume of the solution was also because of the intermolecular forces occurring between
ethanol and water molecules. Also, the partial molar volume of water and ethanol had an indirect
relationship due to the contraction that happened after they had been mixed. In this experiment,
the objectives had been effectively met as the partial molar volume of ethanol-water system at
various concentrations had been determined by familiarizing the use of pycnometer for the
measurement of density and specific gravity.
VI. RECOMMENDATION
The group recommends that the volumes of the components in the solution be accurately
measured, in order to clearly observe the changes in the volume of a system or solution.
Additionally, use more values of concentration so that the graph would be more accurate.
VII. REFERENCES
Atkins P. & De Paula J. (2006). Atkins physical chemistry 8th ed. Oxford University Press, Oxford,
New York.
Cooksy, A. (2014). Physical chemistry; Thermodynamics, statistical mechanics, & kinetics.
Pearson Education Inc. New Jersey.
Perry R. (2007). Perry’s Chemical Engineers’ Handbook, 8th ed. New York: McGraw-Hill
Education.