Beruflich Dokumente
Kultur Dokumente
Priyansh Bhimajiyani
16BPE009
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Abstract:
Carbon capture and storage (CCS) technologies remove carbon dioxide from flue gases for
storage in geologic formations or the ocean. We find that CCS is technically feasible and
economically attractive within the range of carbon policies discussed domestically and
internationally. Current costs are about $200 to $250 per ton of carbon, although costs are
sensitive to fuel prices and other assumptions and could be reduced significantly through
technical improvements. Near-term prospects favor CCS for certain industrial sources and
electric power plants, with storage in depleted oil and gas reservoirs. Deep aquifers may
provide an attractive longer-term storage option, whereas ocean storage poses greater
technical and environmental uncertainty. Vast quantities of economically recoverable fossil
fuels, sizable political obstacles to their abandonment, and inherent delay associated with
developing alternative energy sources suggest that CCS should be seriously considered in the
portfolio of options for addressing climate change, alongside energy efficiency and
carbon-free energy.
Introduction:
Carbon capture and geological sequence (CCS) is the process of separating carbon used in
industrial process and sequestering it underground because CCS would allow the continued
use of fossil fuels while simultaneously reducing carbon emission, it is widely seen as one
option to mitigate atmospheric carbon dioxide concentrations. There are two worlds out there:
one where we use fossil fuels and the one where we do not. The where we use them is a lot is
cheaper, even with capture and sequestration[1].
The indications are that CCS is a technically viable option and in most cases there are
potential sequestration near large source of carbon emissions. However technological mastery
of a problem is not sufficient to ensure public acceptance of its implementation. Indeed, many
emerging technologies have stumbled when the technology was deployed. The various
trajectories of biotechnology, stem cell research and nuclear energy, to name but a few, have
been drastically altered because political and societal concerns.
Our goal with this volume is to describe the current state of these technologies and to
assess the technical, legal and socio-economics forces that must coalesce if CCS is to
becomea viable carbon reduction strategy, much like the reports produced by the now
defunded Office of Technology Assessment , Framing the technical factors in the context of
their interplay with legal,regulatory, economic and risk–assessment factors is a unique
contribution of this volume.
The climate change challenge:
Research has shown that the level of carbon dioxide (CO2) released into the
atmosphere has increased significantly since the beginning of the industrial era.
Unless we do something to reduce the amount of CO2 entering the atmosphere, the
world will experience the effects of climate change.
When fossil fuels are burnt in a power plant to make electricity, large amounts of
CO2 are released into the atmosphere. CO2 is released from the ground into the
atmosphere during natural gas production. And industrial processes such as refining
oil or producing iron, steel, cement and ammonia also release large amounts of CO2.
Other major sources of CO2 include emissions from cars, trucks, ships and aeroplanes,
and from domestic sources, such as heating your home.
Long-term monitoring has shown that the increasing amount of CO2 in the
atmosphere due to human activity is causing the Earth to warm and the oceans to
become more acidic. Combating climate change requires urgent action on the part of
many. If we do not act now scientists predict that the temperature will continue to
increase, causing the climate to change, sea levels to rise, and ocean and land
environments to be adversely affected.
How do we know that recent CO2 increases are due to human activities?
Over the last 150 years, carbon dioxide (CO2) concentrations have risen from 280 to nearly
380 parts per million (ppm). This recent relentless rise in CO2 shows a remarkably constant
relationship with fossil-fuel burning, and can be well accounted for based on the simple
premise that about 60 percent of fossil-fuel emissions stay in the air.
Since the industrial revolution, we have been burning fossil fuels at an unprecedented rate and
these processes convert organic carbon into CO2. The roughly 500 billion metric tons of
carbon we have produced is enough to have raised the atmospheric concentration of CO2to
nearly 500 ppm. The concentrations have not reached that level because the ocean and the
terrestrial biosphere have the capacity to absorb some of the CO2 we produce. It is the fact
that we produce CO2 faster than the ocean and biosphere can absorb it that explains the
observed increase[3].
Another, quite independent way that we know that fossil fuel burning are responsible for the
increase in CO2 in the last 150 years is through the measurement of carbon isotopes.
Isotopes are simply different atoms with the same chemical behavior but with different
masses. Carbon is composed of three different isotopes, 14C, 13C and 12C. 12C is the most
common. 13C is about 1% of the total. 14C accounts for only about 1 in 1 trillion carbon atoms.
CO2 produced from burning fossil fuels or burning forests has quite a different isotopic
composition from CO2 in the atmosphere. This is because plants have a preference for the
lighter isotopes (12C vs. 13C); thus they have lower 13C/12C ratios. Since fossil fuels are
ultimately derived from ancient plants, plants and fossil fuels all have roughly the
same 13C/12C ratio – about 2% lower than that of the atmosphere. As CO2 from these materials
is released into, and mixes with, the atmosphere, the average 13C/12C ratio of the atmosphere
decreases[4].
Figure-1. Atmospheric carbon dioxide in ppm.
Figure-2. Atmospheric 13C ratio. Figure-3. 14C ration in tree ring grown at the
(Levin & Hesshaimer 2000) pacific coast (Levin & Hesshaimer 2000)
These isotopic observations confirm that the increase in atmospheric CO2 comes from
biogenic carbon, not from the oceans or volcanoes. Some "skeptics" argue that the
carbon-13(Figure-2) ratio isn't unique to fossil fuels. However, because the
carbon-14(Figure-3) ratio has also decreased significantly , we know it's from the old fossil
fuel sources not modern sources[2].
1) Pre-combustion:-
2) Post Combustion:-
This involves separating CO2 from the flue gas produced by fuel combustion.This method
requires separating the CO2 from other flue gases because sequestration of combustion gases
is not feasible due in part to the cost of gas compression and storage. CO2 can be captured
from the exhaust of a combustion process by absorbing it in a suitable solvent. The absorbed
CO2 is liberated from the solvent and is compressed for transportation and storage. Other
methods for separating CO2 include high pressure membrane filtration, adsorption/desorption
processes and cryogenic Separation.
3) Oxy-combustion:-
Uses:
Recently scientists have discovered a novel way to make plastic from carbon dioxide (CO2)
and inedible plant material, such as agricultural waste and grasses. Many plastic products
today are made from a polymer called polyethylene terephthalate (PET). PET is made from
two components, terephthalic acid and ethylene glycol, which are derived from refined
petroleum and natural gas. Manufacturing PET produces significant amounts of CO2, a
greenhouse gas that contributes to global warming[5].
The use of fossil-fuel feedstocks, combined with the energy required to manufacture PET,
generates more than four tons of CO2 for every ton of PET that’s produced. A promising
alternative to PET is called Polyethylene- furandicarboxylate (PEF). PEF is made from
ethylene glycol and a compound called 2-5-Furandicarboxylic acid (FDCA). But making
FDCA from furfural and CO2 typically requires hazardous chemicals that are expensive and
energy-intensive to make. The Stanford team solved the problem using a far more benign
compound: carbonate. They combined carbonate with CO2 and furoic acid, a derivative of
furfural. She then heated the mixture to about 290 degrees Fahrenheit (200 degrees Celsius) to
form a molten salt.The results were dramatic. After five hours, 89 percent of the molten-salt
mixture had been converted to FDCA. The next step, transforming FDCA into PEF plastic, is
a straightforward process that has been worked out.
The Stanford team’s approach has the potential to significantly reduce greenhouse emissions,
because the CO2 required to make PEF could be obtained from fossil-fuel power plant
emissions or other industrial sites.
Flue gases from industrial processes could be fed directly into ponds containing high
concentrations of microalgae, which can convert solar energy to biomass at about 1% to 3%
efficiency—though bioengineering and other technological improvements promise higher
efficiencies. Biomass grown using this method could be harvested and converted to fuels,
displacing some fossil fuel consumption. Unfortunately, this process would have high water,
natural solar energy, and land requirements—a 500 MW power plant would need 50 to 100
square km of pond area—and these types of inputs are not generally found in the same
locations as power plants.
CO2 is superior to water in its ability to mine heat from hot fractured rock. Carbon dioxide
also offers certain advantages with respect to well-bore hydraulics, in that its larger
compressibility and expansivity as compared to water would increase buoyancy forces and
would reduce the parasitic power consumption of the fluid circulation system. While the
thermal and hydraulic aspects of a CO2-EGS system look promising, major uncertainties
remain with regard to chemical interactions between
fluids and rocks.
A reservoir rock is usually well suited for CO2 storage according to the following
properties[8]:
Porosity: Refers to the volume of fluid that can be contained within the rock between
the rock 'pore spaces', i.e. the minute spaces existing between rock grains.
Permeability: Refers to the connectivity between the rock pore spaces, i.e. the space
or channels linking the pore spaces that fluid can flow through, from one pore space
to the next. A minimum permeability is necessary and especially important in the
early stages of a storage project to avoid CO2 injectivity issues.
Physical and chemical trapping mechanisms are responsible for preventing the injected
CO2 from migrating back to the surface.A requirement for a physical trapping mechanism is
the existence of an impermeable cap-rock formation, overlying the storage reservoir. This
cap-rock acts as an obstacle and stops the vertical migration of the CO2 to the upper parts of
the sedimentary basin and the atmospher[2][8].
Figure-6. Typical geological reservoir and Figure-7. Rocks under the North Sea
contain a cap-rock setting large amount of geological storage
space.
(2) Enhanced Oil Recovery (EOR):-
The ultimate storage capacity provided by any CO2-EOR project will depend on a number of
technical and economic factors. At the end of economic oil production, an operator may
choose to use the closed loop system to ensure all CO2 is stored in the reservoir before sealing
and abandoning wells. Alternatively, a significant portion of the CO2 could be produced for
further utilization in other oil fields. Storage capacity could be increased with injection into
residual oil zones beneath the main field, or into the reservoir for storage only.
‘Unminable’ coal seams (or coal that is too deep or difficult to mine) can be used to store
CO2 because it is adsorbed in the coal if the coal is permeable enough to allow CO2 to
penetrate. In the process of absorption the coal releases previously absorbed methane, and the
methane can be recovered. This methane can be used and the process of extracting useful
methane from a coal seam when it is injected with CO2 is called ECBM (or enhanced coal bed
methane).
The sale of the methane can be used to offset a portion of the cost of the CO2 storage.
However as in EOR, burning the resultant methane would produce CO2 which would reduce
some of the benefit of storing the original CO2[2].
(4) Saline aquifers:-
Some deep rock formations contain highly concentrated brine which is present in the rock
pores (which act together like a huge sponge), and have so far been considered of no benefit
to humans. These are known as ‘saline aquifers’. Their main advantage for CCS is their large
potential storage volume and their common occurrence. For example much of the North Sea
and mainland Europe and the Texas Gulf Coast is underlain by large saline aquifers. We need
to understand more about saline aquifer storage, but current research shows that several
trapping mechanisms immobilise the CO2 underground, reducing the risk of leakage.
The IPCC says that for well-selected, designed and managed geological storage sites,
CO2 could be trapped for millions of years, retaining over 99 per cent of the injected CO2 over
1000 years.
Large concentrations of CO2 kill ocean organisms as CO2 acts as an asphyxiant. Also, as
CO2 reacts with the water to form carbonic acid, H2CO3, the acidity of ocean water would
increase.
The IPCC estimates that a power plant equipped with CCS using mineral storage will need
60–180 per cent more energy than a power plant without CCS.
Cost:-
All the options for capturing CO2 from power generation have higher capital and operating
costs as well as lower efficiency than conventional power plants without capture. Capture is
typically the most expensive part of the CCS chain. However, as CCS and power generation
technology become more efficient and better integrated, the increased energy use is likely to
fall significantly below early levels. Much of the work on capture is focused on lowering
costs and improving efficiency as well as improving the integration of the capture and power
generation components. These improvements will reduce energy requirements.
2. China:- Continued support for carbon capture utilization and storage (CCUS) has been
demonstrated in China via targeted project activity, including the decision to commence
construction of China’s first large-scale CCS facility.
4. UK:- After a long period of reassessment, the UK government has renewed its
commitment to CCS investment with its inclusion in the newly released Clean Growth
Strategy. The UK’s Committee on Climate Change has consistently emphasised the
importance of CCS to future UK energy and climate policies and other parliamentary and
audit reports have provided useful learning from close examination of the cancellation of
the UK’s Commercialization Competition.
5. Australia:- There have been references to “technology neutral” policies in the form of
proposals for electricity market incentive mechanisms and around the broadening of
concessional loans to include CCS.
GLOBAL CCS INSTITUTE LEGAL AND REGULATORY INDICATOR 2017:
SUMMARY HIGHLIGHTS
Australia 67.0
Canada 65.5
Denmark 62.0
Summary:-
1. CCS is a climate change technology. It is probably the most versatile and vital climate
mitigation technology that exists. Irrefutable evidence by the IPCC, IEA, plus numerous
other international specialist bodies concur that international climate change targets
cannot be achieved without CCS.
(Note: IEA findings maintain that to reach Paris climate targets of 2˚C, 14% of
cumulative emissions reductions by 2060 must derive from CCS.)
2. CCS has been working safely and effectively for 45 years (since the Apollo 17 moon
landing in 1972). Operations undertaken over almost half a century demonstrates that
CO2 can be safely stored deep below ground. Oil, gas and naturally occurring CO2
reservoirs have proven that fluids can be safely sealed underground for millions of years.
CCS facilities target the same geology.
CCS technology is verifiably well tested. Seventeen largescale facilities are operating
successfully around the world (with four more coming onstream shortly). These 17
facilities are currently capable of capturing more than 30 Mtpa of CO2 per annum.
3. There is no evidence to indicate that CCS causes earthquakes. CO2 injection does have
the potential to cause micro-seismic activity in the same way as other customary
engineering activity, including mining, dam construction and oil or gas development.
This microseismic activity is monitored, and is of such a low magnitude, it cannot be felt
on the surface of the Earth. The meticulous characterisation of CO2 storage sites to
identify and understand below-ground stress and pressure conditions minimises the risks
of seismicity. It is also worth noting that the injection and geological storage of CO2, in
conventional oil and gas fields or deep saline formations, does not require hydraulic
fracturing.
4. On a like-for-like total system cost basis, CCS is cheaper than intermittent renewables
and costs continue to decrease as more facilities commercialise. In the power sector,
CCS can provide the necessary backup and other services to complement intermittent
renewables, and costs continue to decrease as more facilities commercialise. Since the
Boundary Dam CCS facility in Canada began operations in 2014, savings of as much as
30% have been identified for construction of a like (or follow-up) facility.iii This
demonstrates the declining costs of deployment. As a simple law of economics, costs
will continue to fall as more facilities come onstream. What is expensive is not doing
anything at all.
5. CCS is commercially successful as the 17 largescale facilities operating around the world
attest. Similarly, the four plants poised to come onstream and the raft of other facilities in
development (seven in China alone) further demonstrate its commercial viability and
versatility.
6. CCS is not a “front” for the coal or wider fossil fuel industry. Rather, it is a pragmatic
technology with wide application that can bridge the gap between our current fossil fuel
dependence and a future that is fossil free.
It is the only clean technology able to address emissions across major industrial sectors
(including steel, cement, chemicals, fertiliser, petrochemicals, paper and pulp).
Furthermore, CCS is the only technology able to curtail emissions from the more than
500 new coal plants (Units) currently being built around the world today (and an
additional 1,000 in planning). CCS’s ability to retrofit aged coal plants keeps jobs and
economies alive as the world transitions to a lowcarbon future. Even critical and
supercritical coal technologies like HELE (high-efficiency lowemission) technology,
need CCS to mitigate CO2 emissions. There is no such thing as clean coal without CCS.
8. There is abundant global CO2 storage resources to support widespread CCS deployment.
Detailed surveys have been undertaken in many countries, including the United States
(US), Canada, Australia, Japan, China, Norway and the United Kingdom (UK), where
potential storage sites are well defined and well documented. Many other countries are
progressing storage studies.
9. CCS works effectively and its wide adoption and escalating deployment supports that
fact. CCS still deserves greater awareness and increased incentivisation through policy
parity with other low-carbon emission technologies (the same sort of market instruments
that renewables enjoy).
10. CCS is needed because the amount of fossil fuels we burn continues to rise. Last year,
fossil fuels reached a record 83.6 billion barrels of oil equivalent (Bboe) compared to
73.3 Bboe 10 years ago. There are no signs of abatement. In 25 of the last 26 years, we
burned more fossil fuels than the year before. The only year recording a decrease in the
last 25 years was 2009 (caused by the global recession). CO2 emissions have increased
every year since 1960 and in the last two years, these hit all-time records.
The renewables’ (solar and wind’s) share of gross electricity generation is currently less
than 5%, rising to 17% by 2040.vi Fossil fuels’ share of electricity generation will equate
to 50% by 2040. This confirms the urgency at which CCS must be applied to power and
wider industry.
11. The reason why some CCS facilities have not matured has nothing to do with technology,
cost or capability. For example, the Kemper CCS facility in Mississippi made the
decision to run the plant with natural gas instead of coal. This made the need for a
gasifier redundant. Since carbon capture was linked to the gasifier, CCS is now not
applicable. The Petra Nova CCS Plant in Texas and the Boundary Dam facility in
Canada are testament to the capability of CCS and its profitability in the power sector.
2. http://www.bgs.ac.uk/discoveringGeology/climateChange/CCS/howCanCo2BeStored.ht
ml
3. http://www.realclimate.org/index.php/archives/2004/12/how-do-we-know-that-recent-co
sub2sub-increases-are-due-to-human-activities-updated/
4. https://www.skepticalscience.com/co2-increase-is-natural-not-human-caused.htm
5. https://news.stanford.edu/2016/03/09/low-carbon-bioplastic-030916/
6. Enhanced geothermal systems (EGS) using CO2 as working fluid—A novel approach for
generating renewable energy with simultaneous sequestration of carbon.Karsten Pruess
paper
7. https://hub.globalccsinstitute.com/publications/accelerating-uptake-ccs-industrial-use-ca
ptured-carbon-dioxide/appendix-c-co2-working
8. https://hub.globalccsinstitute.com/publications/brazilian-atlas-co2-capture-and-geologic
al-storage/co2-geological-storage
9. http://www.ccsassociation.org/
10. https://hub.globalccsinstitute.com/publications/global-status-ccs-2012/21-overview-larg
e-scale-integrated-ccs-projects
11. http://www.ccsassociation.org/what-is-ccs/capture/
12. CO2 capture and separation technologies for end-of-pipe applications e A review- Abass
A. Olajire
13. The Global Status Of CCS-2017 by Global CCS institute.
14. India CCS Scoping Study: Final Report prepared for The Global CCS institute (January
2013) (Project Code 2011BE02)