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Thermodynamics Question

- lattice dissociation: -3888


- entropy change: +181
- dG: -1063 (to 3 SF); increasing the temperature caused dG to decrease because dS
is positive so "-TdS" is negative

- 0.0217
- BaCl2 in excess; 10cm3 of Na2SO4 required
- The least soluble Hydroxide is Mg(OH)2

ALUMINIUM QUESTION:
a) AlCl3 + 6 H2O --> [Al(H2O)6]3+ + 3 Cl-
b) with sodium carbonate a white precipitate forms and there is effervescence:
2[Al(H2O)6]3+ + 3 CO32- --> 2 Al(H2O)3(OH)3 + 3 CO2 + 3 H2O
c) initially a white precipitate would form:
[Al(H2O)6]3+ + 3 OH- --> Al(H2O)3(OH)3 + 3 H2O
the white precipitate would re-dissolve when the OH- is in excess:
EITHER Al(H2O)3(OH)3 + OH- --> [Al(OH)4]- + H2O OR Al(H2O)3(OH)3 + 3 OH-
--> [Al(OH)6]3- + 3 H2O (both accepatble)

Catalysis:
Platinum
-Reactants adzorb, reaction takes place, desorb.
-Lowers Ea held by intermolecular forces so higher probability of successful
collisions with correct orientation (don't think that bits relevant I was just
rambling) The mechanism of how it lowers Ea is a bit fringey on the spec, weakens
bonds in reactant so less energy required for reaction.
Contact Process
-V2O5 + SO2 => SO3 + V2O4
-V2O4 + 1/2O2 => V2O5

6 MARK QUESTION:
- NaBr and NaI are both giant ionic lattices with strong electrostatic attractions
between positive and negative ions which require a lot of energy to be overcome.
However, the I- ion has a larger radius than Br- and therefore a smaller charge
density. Therefore the ionic bonding in NaI is weaker than in NaBr, requiring less
energy to be overcome.
- Na is a metal with metallic bonding between Na+ ions and a sea of delocalised
electrons. However this is not as strong as the ionic bonding in NaBr/NaI because
metallic Na does not exist in a giant lattice.

Ionisation Energy
Comparison of second IE of K and Ca
-K has highest second IE
-Electron removed from 3p rather than 4s
-So less shielding, greater attraction to nucleus, requires more energy to
overcome.
Highest first IE in s-block:
-Beryllium as it has joint least shielding with Lithium
-But an extra proton so stronger attraction to the nucleus, requires more energy to
overcome

ELECTROCHEMICAL CELLS QUESTION:


a) Ions in the salt bridge are free to move, carrying a charge and completing the
electrical circuit.
b) V = 0.34 - EMF
c) Because the concentration of Cu2+ ions in the LHS cell is lower than 1 mol/dm3
which is what's required for the standard electrode potential.
d) The concentration of Cu2+ ions would increase over time
e) EITHER the concentrations of Cu2+ become equal OR all the metallic copper on the
LHS runs out (both acceptable)

KP QUESTION:
- partial pressures were 7.5, 22.5, 120.
- Expression for Kp = ( p.N2 * p3.H2 ) / ( p2.NH3 )
- units for Kp = kPa-2 (2.99x10^-3)
- since the reaction is exothermic, increasing the temperature moves the position
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reducing the partial pressure of NH3 and thereby decreasing Kp.

Isomerism and VSEPR Shapes:


- isomerism is cis-trans (or e/z); the other isomer had the two Cl ligands opposite
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- bond angle was 104.5 degrees. The central N had 6 of its own electrons (5, +1 due
to the overall negative charge).
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Category:Musicals by Rodgers and Hammerstein
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HomeHamiltonWikipedia: Film adaptation


Hamilton Lin-Manuel Miranda
Film adaptation

On February 10, 2017, Miranda revealed that In the Heights book writer Quiara
Alegría Hudes wrote a script for a film adaptation, but reassured that, while a
film would be made someday, it would not happen for years, as he wanted audiences
to watch the stage musical first. He has confirmed that pre-production of the film
adaptation will begin early to mid-2020.[209]

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if answer incorrect:
allow 1 mark for 8 × 25 or
allow 1 mark for answer from candidate’s count × 25
2
(ii)
R
allow P or Q if candidate’s answer to (b)(i) nearer to value for
one of those
do not allow R if the answer to (b)(i) would give an answer of
P or Q
allow R if (b)(i) is blank
1
(iii)
few stomat
allow no stomata on upper sur
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Songs from Rodgers and Hammerstein musicals (4 C, 8 P)

Oklahoma! (1 C, 4 P)

The Sound of Music (1 C, 11 P)


Pages in category "Musicals by Rodgers and Hammerstein"

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A

Allegro (musical)

Carousel (film)
Carousel (musical)
Cinderella (2013 Broadway production)
Cinderella (musical)
Cinderella (1997 film)

Flower Drum Song

A Grand Night for Singing

The King and I

Me and Juliet

Pipe Dream (musical)

South Pacific (musical)


State Fair (1945 film)
State Fair (musical)

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recordingsCompositions by Richard RodgersOscar Hammerstein II

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Two electrons used in bonding to H atoms so two lone pairs. Shape is tetrahedral
but lone pairs repel more than bonding pairs, reducing the bond angle from 109.5 by
about 5 degrees (2.5 per lone pair).

Last question
x = 1
Don't even ask how I did the last question, it just worked.

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