Beruflich Dokumente
Kultur Dokumente
Solids
Solids
Crystalline Amorphous
UNIT CELLS- Small repetitive
entities which form a complete
solid structure
Ref: W. D. Callister
Crystal systems
Triclinic
Monoclinic
Hexagonal
Orthorhombic
Rhombohedral Cubic
Atomic packing fraction
h= √(a2-(a/2)2) = a√(3/4)
x= (2/3)h = (2/3)* a√(3/4) = a/√3
c/2 = √(a2-x2)
= a√(2/3)
C/a = √(8/3) = 1.633
Density computation
2. Iron has a BCC crystal structure, an atomic radius of 0.124 nm, and
an atomic weight of 55.85 g/mol. Compute its density. Ans.
7.8g/cm3.
3. Calculate the radius of an iridium atom given that It has FCC crystal
structure, a density of 22.4 g/cm3, and an atomic weight of 192.2
g/mol. Ans. 136 nm
1. Calculate the no. of atoms per mm2 surface area of (100) plane,
(110) plane and (111) plane for aluminium having FCC crystal
structure. R= 143 pm
Path difference = nλ
= SQ + QT
For BCC iron, compute (a) the interplanar spacing, and (b) the
diffraction angle for the (220) set of planes. The lattice
parameter for Fe is 0.2866 nm. Also, assume that
monochromatic radiation having a wavelength of 0.1790 nm
is used, and the order of reflection is 1.
Problems
1. Calculate interplanar spacing for (200) and (111)set of planes
in lead crystal. Lead has a FCC structure with edge length 4.95
Å.
2. A metal X is having FCC structure with interatomic distance as
3.499 Å. Find the number of atoms per sq. mm in (100) plane.
1) 2.475 Å, 2.857 Å
2) 8.16 x 1012
3) BCC