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MIT 5.61 Physical Chemistry, Fall 2017


• MIT OpenCourseWare
• 36 videos
• 15,528 views
• Last updated on Jan 9, 2019

Instructor: Professor Robert Field


View the complete course: https://ocw.mit.edu/5-61F17

This course is an introduction to quantum chemistry. Topics include particles and waves; wave
mechanics; matrix mechanics; perturbation theory; molecular orbital theory; molecular structure; and
photochemistry.

License: Creative Commons BY-NC-SA


More information at https://ocw.mit.edu/terms
More courses at https://ocw.mit.edu less
Instructor: Professor Robert Field
View the complete course: https://ocw.mit.edu/5-61F17

This course is an introduction to quantum chemistry. Topics include particles and waves; wave
mechanics; matrix mechanics; perturbation theory; molecular orb... more
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1. Quantum Mechanics—Historical Background,


Photoelectric Effect, Compton Scattering 45:25
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2. Wave Nature of the Electron and the Internal Structure of


an Atom 45:16
by MIT OpenCourseWare
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3. Two-Slit Experiment; Quantum Weirdness


50:58
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4. Classical Wave Equation and Separation of Variables


49:54
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5. Quantum Mechanics: Free Particle and Particle in 1D 54:39
Box
by MIT OpenCourseWare
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6. 3-D Box and QM Separation of Variables


49:51
by MIT OpenCourseWare
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7. Classical Mechanical Harmonic Oscillator


51:11
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8. Quantum Mechanical Harmonic Oscillator


52:28
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9. The Harmonic Oscillator: Creation and Annihilation


Operators 48:14
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10. The Time-Dependent Schrödinger Equation


52:23
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11. Wavepacket Dynamics for Harmonic Oscillator and PIB


54:59
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12. Catch Up and Review & Postulates


55:16
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13. From Hij Integrals to H Matrices I


54:36
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14. From Hij Integrals to H Matrices II


53:54
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15. Non-Degenerate Perturbation Theory I 52:08
by MIT OpenCourseWare

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16. Non-Degenerate Perturbation Theory II: HO using a,a†


52:47
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17. Rigid Rotor I; Orbital Angular Momentum


51:29
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18. Rigid Rotor II. Derivation by Commutation Rules


54:10
by MIT OpenCourseWare
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19. Spectroscopy: Probing Molecules with Light


50:37
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20. Hydrogen Atom I


48:57
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21. Hydrogen Atom II; Rydberg States


52:42
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22. Helium Atom


52:41
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23. Many-Electron Atoms


51:06
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24. Molecular Orbital Theory I; Variational Principle and


Matrix Mechanics 52:11
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25. Molecular Orbital Theory II; H2+, A2, AB Diatomics 53:06
by MIT OpenCourseWare

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26. Qualitative MO Theory: Hückel


52:48
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27. Non-Degenerate Perturbation Theory III


52:36
by MIT OpenCourseWare
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28. Modern Electronic Structure Theory: Basis Sets


50:06
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29. Modern Electronic Structure Theory: Electronic


Correlation 52:13
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30. Time-Dependent Perturbation Theory I: H is Time-


Independent, Zewail Wavepacket. 52:29
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31. Time-Dependent Perturbation Theory II: H is Time-


Dependent: Two-Level Problem 52:45
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32. Intermolecular Interactions by Non-Degenerate


Perturbation Theory 54:30
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33. Electronic Spectroscopy: Franck-Condon


51:58
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34. Chirped Pulse Microwave: Free Induction Decay, Bloch 50:27
Visualization
by MIT OpenCourseWare
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35. Delta-Functions, Eigen-Functions of X, Discrete


Variable Representation 48:42
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36. Time Dependence of Two-Level Systems: Density


Matrix, Rotating Wave Approximation 48:41
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• Location: India
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