Beruflich Dokumente
Kultur Dokumente
UBA (2017)
3 17th May 2018 | thyssenkrupp AG | Carbon2Chem® | Dr. Wiebke Lüke
N2
CDA and CCS
N2
CO2
• have the potential to reduce CO2
NO CO2 emissions within one sector only
NO
CO2
H2
• are not applicable to
CO2 CO CO CH4 decentralized CO2 sources
• are limited by social acceptance
• have a very heterogenic TRL
level
• increase process efficiency and
not overall system efficiency
• consider CO2 as a waste and not
as a raw material
CCS, CDA
~300.000 m³ Gas
N2 43 %
CO 25 %
CO2 21 %
H2 8%
CH4 2%
Ar < 0,1 %
Blast furnance Coke oven Steel mill
other < 0,1 %
CO2
CCU
• reduces CO2 emissions via a
17 billion Nm³ top gas per year cross industrial network
• provides commercial advantage
through multi product output
(steel and chemical products)
• increases overall system
H2
efficiency
Synthetic fuels
CCU Polymers
Top gas Carbon capture
and usage
Fertilizer
Integrated steel production CO2 capture / gas cleaning / conditioning
L3 – Gas Cleaning
L2 – Methanol production
L4 – Higher alcohols
L1 – Water electrolysis
L5 – Polymers
L6 – Oxymehtylenether
2.993
1.876 1.876
1.617
823
500
1.053 1.117
Depends on
Depends on
technology
technology
Baseline CO2 in CO2 CO2 in methanol Remaining CO2 Baseline steel CO2 in methanol CO2 for steel
steel methanol emissions stand alone CO2 emissions emissions stand alone & methanol
from steel
Assumptions
• 60 % utilization of top gases from steel production; from these 60 % top gases approx. 730 kg methanol can be produced taking into account all process related emissions for the chemical synthesis
In kg CO2 / t CS
• For the methanol reference process 1490 kg CO2 /t Methanol were assumed
• Process efficiencies are strongly depending on given process setup
• Figures from Dechema study „Low carbon energy and feedstock for the European chemical industry“, 2017
• Generation of additionally required H2 for chemical syntheses • Purification and conditioning of the metallurgical gases for the
from renewable energies → H2 with no additional CO2-footprint subsequent chemical syntheses
• Proof of operation with volatile energy supply • Validation of operating strategies for the purification of the
different metallurgical gases
• Development of systemic solutions for energy storage
• Evaluation of various concepts for plant configuration for new
subsequent chemical syntheses
We use renewable energies in a cross industrial network for more than one
product