Revision Date 19 June 2014

Revision 3

SAFETY DATA SHEET

NITOPRIME 25 BASE

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1. Product identifier

Product name NITOPRIME 25 BASE
Product No. A1936141UK9, A1936161UK9

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Base component of two part epoxy primer system.

1.3. Details of the supplier of the safety data sheet

Supplier FOSROC Limited
Drayton Manor Business Park
Coleshill Road
Tamworth
Staffordshire
B78 3XN
Tel. +44 (0) 1827 262222
Fax. +44 (0) 1827 262444
enquiryuk@fosroc.com

1.4. Emergency telephone number

+44 (0) 1827 265 279 (08.30 to 17.00hrs Mon - Thu; 08.30 to 16.00hrs Fri)

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification (1999/45/EEC) Xi;R36/38. R43. N;R51/53.

2.2. Label elements

Contains EPOXY RESIN (Number average MW <= 700 )
1,6 HEXANEDIOL DIGLYCIDYL ETHER
Labelling

Irritant Dangerous for the

environment
Risk Phrases
R36/38 Irritating to eyes and skin.
R43 May cause sensitisation by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Safety Phrases
S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S37 Wear suitable gloves.
S57 Use appropriate containment to avoid environmental contamination.

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S61 Avoid release to the environment. Refer to special instructions/safety data
sheets.
P5 Contains epoxy constituents. See information supplied by the manufacturer.

2.3. Other hazards

This product does not contain any PBT or vPvB substances.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures

EPOXY RESIN (Number average MW <= 700 ) 60-100%

CAS-No.: 25068-38-6 EC No.: 500-033-5

Classification (EC 1272/2008) Classification (67/548/EEC)

Skin Irrit. 2 - H315 R43
Eye Irrit. 2 - H319 Xi;R36/38
Skin Sens. 1 - H317 N;R51/53
Aquatic Chronic 2 - H411

1,6 HEXANEDIOL DIGLYCIDYL ETHER 10-30%

CAS-No.: 16096-31-4 EC No.: 240-260-4

Classification (EC 1272/2008) Classification (67/548/EEC)

Skin Irrit. 2 - H315 Xi;R36/38.
Eye Irrit. 2 - H319 R43,R52/53.
Skin Sens. 1 - H317
Aquatic Chronic 3 - H412

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures

General information
Get medical attention if any discomfort continues.
Inhalation
Move the exposed person to fresh air at once. Rinse nose and mouth with water. Get medical attention if any discomfort continues.
Ingestion
Remove victim immediately from source of exposure. Provide fresh air, warmth and rest, preferably in comfortable upright sitting position.
If the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomitting may be
dangerous. Do not induce vomiting. If vomiting occurs, the head should be kept low so that stomach vomit doesn't enter the lungs. Get
medical attention if any discomfort continues.
Skin contact
Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water.
Continue to rinse for at least 15 minutes and seek medical attention.
Eye contact
Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly
wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
General information
The severity of the symptoms described will vary dependant of the concentration and the length of exposure.
Inhalation
May cause irritation to the respiratory system.

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Ingestion
May cause discomfort if swallowed.
Skin contact
Skin irritation.
Eye contact
Irritation of eyes and mucous membranes.

4.3. Indication of any immediate medical attention and special treatment needed
Treat Symptomatically.

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media

Extinguishing media
Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.
Unsuitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion products
Carbon monoxide (CO). Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.
Unusual Fire & Explosion Hazards
If heated, volume and pressure increases strongly, resulting in explosion of container.

5.3. Advice for firefighters

Special Fire Fighting Procedures
No specific fire fighting procedure given. Keep run-off water out of sewers and water sources. Dike for water control.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Wear protective clothing as described in Section 8 of this safety data sheet. Provide adequate ventilation. Avoid inhalation of vapours and
aerosol spray.

6.2. Environmental precautions

Avoid discharge into drains, water courses or onto the ground. Spillages or uncontrolled discharges into watercourses must be
IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body.

6.3. Methods and material for containment and cleaning up

Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean spillage area. Do not contaminate
water sources or sewer.

6.4. Reference to other sections

For waste disposal, see section 13.

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Provide good ventilation. Avoid forming spray/aerosol mists. Avoid inhalation of vapours/spray and contact with skin and eyes. Do not eat,
drink or smoke when using the product.

7.2. Conditions for safe storage, including any incompatibilities

Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container.
Storage Class
Chemical storage.

7.3. Specific end use(s)

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The identified uses for this product are detailed in Section 1.2.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Ingredient Comments
No exposure limits noted for ingredient(s).

8.2. Exposure controls

Protective equipment

Engineering measures
Provide adequate ventilation.
Respiratory equipment
Respiratory protection not required.
Hand protection
Use suitable protective gloves if risk of skin contact. Use protective gloves made of: Butyl rubber. Nitrile. Neoprene. Polyvinyl chloride
(PVC). Polyethylene/Ethylene Vinyl Alcohol (PE/EVAL). The most suitable glove must be chosen in consultation with the gloves supplier,
who can inform about the breakthrough time of the glove material.
Eye protection
If risk of splashing, wear safety goggles or face shield.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact.
Hygiene measures
Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or
contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke. DO NOT SMOKE IN
WORK AREA!
Skin protection
Wear apron or protective clothing in case of contact.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance Liquid
Colour Straw.
Odour Mild.
Solubility Insoluble in water
Initial boiling point and boiling >200°C
range (°C)
Relative density 1.20 20°C
Vapour pressure 0.01 kPa 20°C
Flash point (°C) >150°C CC (Closed cup).
Explosive properties
Not determined.

9.2. Other information

Not determined.

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity
No specific reactivity hazards associated with this product.

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10.2. Chemical stability
Stable under normal temperature conditions.

10.3. Possibility of hazardous reactions

None under normal conditions of use.

10.4. Conditions to avoid

Avoid excessive heat for prolonged periods of time.

10.5. Incompatible materials

Materials To Avoid
Strong acids. Strong alkalis. Strong oxidising substances.

10.6. Hazardous decomposition products

During fire, toxic gases (CO, CO2) are formed.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Inhalation
Gas or vapour may irritate respiratory system.

Ingestion
May cause discomfort if swallowed.

Skin contact
Irritating to skin. May cause sensitisation by skin contact.

Eye contact
Irritating to eyes.
Route of entry
Skin and/or eye contact.

Toxicological information on ingredients.

EPOXY RESIN (Number average MW <= 700 ) (CAS: 25068-38-6)

Acute toxicity:
Acute Toxicity (Oral LD50)
> 5000 mg/kg Rat

Acute Toxicity (Dermal LD50)

> 2000 mg/kg Rabbit
1,6 HEXANEDIOL DIGLYCIDYL ETHER (CAS: 16096-31-4)

Acute toxicity:
Acute Toxicity (Oral LD50)
2900 mg/kg Rat

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity
Dangerous for the environment: May cause long-term adverse effects in the aquatic environment.

12.1. Toxicity
Acute Fish Toxicity
Toxic to aquatic organisms.

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Ecological information on ingredients.

EPOXY RESIN (Number average MW <= 700 ) (CAS: 25068-38-6)

LC 50, 96 Hrs, Fish mg/l
1.5
EC 50, 48 Hrs, Daphnia, mg/l
2.8
Acute Toxicity - Microorganisms
EC50 3 hours > 100 mg/l

12.2. Persistence and degradability

Degradability
The product is not expected to be biodegradable.

Ecological information on ingredients.

EPOXY RESIN (Number average MW <= 700 ) (CAS: 25068-38-6)

Degradability
The product is not readily biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential
The product contains potentially bioaccumulating substances.

Ecological information on ingredients.

1,6 HEXANEDIOL DIGLYCIDYL ETHER (CAS: 16096-31-4)

Partition coefficient
log Pow = Approximately 3.8 at 25 C

12.4. Mobility in soil

Ecological information on ingredients.

EPOXY RESIN (Number average MW <= 700 ) (CAS: 25068-38-6)

Adsorption/Desorption Coefficient
Soil Koc 445

12.5. Results of PBT and vPvB assessment

This product does not contain any PBT or vPvB substances.

12.6. Other adverse effects

None known.

SECTION 13: DISPOSAL CONSIDERATIONS

General information
Waste is classified as hazardous waste. Disposal to licensed waste disposal site in accordance with the local Waste Disposal Authority.

13.1. Waste treatment methods

Dispose of waste and residues in accordance with local authority requirements.

SECTION 14: TRANSPORT INFORMATION

14.1. UN number

UN No. (ADR/RID/ADN) 3082

UN No. (IMDG) 3082

UN No. (ICAO) 3082

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14.2. UN proper shipping name

Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXY RESIN)

14.3. Transport hazard class(es)

ADR/RID/ADN Class 9

ADR/RID/ADN Class Class 9: Miscellaneous dangerous substances and articles.

ADR Label No. 9

IMDG Class 9

ICAO Class/Division 9

Transport Labels

MISCELLANEOUS
DANGEROUS
GOODS
9

14.4. Packing group

ADR/RID/ADN Packing group III

IMDG Packing group III

ICAO Packing group III

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

14.6. Special precautions for user

EMS F-A, S-F

Emergency Action Code •3Z

Hazard No. (ADR) 90

Tunnel Restriction Code (E)

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable.

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments.
Statutory Instruments
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).
Approved Code Of Practice
Classification and Labelling of Substances and Preparations Dangerous for Supply.

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Safety Data Sheets for Substances and Preparations.
Guidance Notes
Workplace Exposure Limits EH40.
EU Legislation
Dangerous Preparations Directive 1999/45/EC.
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and
packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC)
No 1907/2006 with amendments.

15.2. Chemical Safety Assessment

No chemical safety assessment has been carried out.

SECTION 16: OTHER INFORMATION

General information
The user must be instructed in the proper work procedure and be familiar with the contents of these instructions.
Revision Comments
NOTE: Lines within the margin indicate significant changes from the previous revision.
Revision Date 19 June 2014
Revision 3
Risk Phrases In Full
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R36/38 Irritating to eyes and skin.
R43 May cause sensitisation by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Hazard Statements In Full
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

Disclaimer
The information on this data sheet represents our current data and is reliable provided that the product is used under the prescribed conditions and in
accordance with the application specified on the packaging and/or in the technical guidance literature. Any other use of the product which involves using
the product in combination with any other product or any other process is the responsibility of the user.
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