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2019_Apr_Jee-Main Question Paper_Key & Solutions
2019_Jee-Main Question Paper_Key & Solutions
PHYSICS
1. The number density of molecules of a gas depends on their distance r from the
origin as, n r   n0er . Then the total number of molecules is proportional to
4
1) n r   n0  3/4 2) n0 1/2 3) n0 3 4) n0 1/ 4

Ans. 1
4
  N   dN  4 N0  er r 2dr
4
Sol. dN  n  r  dv dN  n0e  r 4 r 2 dr
2. A solid sphere, of radius R acquires a terminal velocity 1 when falling (due t

gravity) through a viscous fluid having a coefficient of viscosity  . The sphere is
broken into 27 identical solid spheres. If each of these spheres acquires a terminal
velocity, 2 , when falling through the same fluid, the ratio 1 / 2  equals
1) 9 2) 1/9 3) 1/27 4) 27
Ans. 1
1
Sol. VT 
2 r2  p    g VT  r Rbig   27
2 3
rsmall
9 
Rbig  3rsmall v1  r1 
 
2
R2
9
v2  r2   R / 3 2
3. Two sources of sound S1 and S 2 produce sound waves of same frequency 660 Hz. A
listener is moving from source S1 towards v with a constant speed u m/s and he
hears 10 beats/s. The velocity of sound is 330 m/s. Then, u equals
1) 2.5 m/s 2) 10.0 m/s 3) 5.5 m/s 4) 15.0 m/s
Ans. 1
4 m/s
S1 S2
Sol.
V  u  V  u  V  u V  u  2uf
f 1   f f x   f f x  f 1    f 
 V   V   V  V
2u660 10
10  u  2.5 m / s
330 4
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4. Find the magnetic field at point P due to a straight line segment AB of length 6 cm
carring a current of 5 A.(See figure)  0  4 107 N  A2 
1) 3.0 105 T 2) 2.0 105 T 3) 2.5 105 T 4) 1.5 105 T

Ans. 4
 0i
Sol. B 
4 r
 sin 1  sin  2 
10 7  5 3
B 2
 2   1.5  10 5 T
4  10 5
5. Figure shows a DC voltage regulator circuit, with a zener diode down voltage  6V .
If the unregulated input voltage varies between 10V to 16V , then what is the
maximum zener current?
1) 3.5mA 2) 7.5mA 3) 1.5mA 4) 2.5mA

Ans. 1
16  6 6
Sol. I max   5 mA I L   1.5 mA I zmax  I max  I L  3.5 mA
2 4

6. A moving coil galvanometer, having a resistance G, produces full scale deflection

when a current I g flows through it. This galvanometer can be converted into  i  an
anometer of range 0 to I 0  I 0  I g  by connecting a shunt resistance R A to it and
connecting a shunt resistance R A to is and  ii  into a voltmeter of range 0 to
V V  GI 0  by connecting a series of resistance RV to it. Then,
2 2
 I  R  I0  I g   Ig  RA  I g 
1) RA RV  G 2  g  and A  
2
 2) RA RV  G   and   
 I0  Ig  RV  I g   I0  I g  RV
  I 
 0 g  I  
2
R  I  RA Ig
3) RA RV  G and A   g
2
 4) RA RV  G 2 and 
RV  I 0  I g  RV  I 0  I g 
Ans. 3
G G V  V 
Sol. S  RA  RV  G   1  RV  G   1
i I0 Vg   ig G 
1 1
ig Ig
i  i  G 
RV  G  0   1 RV  G  0  1  G   RA RV  G 2
 ig   ig   RA 
i
G / 0 1
RA ig 1 RA ig2
  2  2
RV  i0   i
G /   1  0  1
 RV i0  i g  
 ig   ig 
7. Half lives of two radio active nuclei A and B are 10 minutes and 20 minutes,
respectively. If , initially a sample has equal number of nuclei, then after 60 minutes,
the ratio of decayed, the ratio of decayed numbers of nuclei A and B will be:
1) 1:8 2) 9:8 3) 8:1 4)3:8
Ans. 2
Sol. Initial A B
No No
T1/ 2 10 min 20 min
t 60 min 60min
n= 6 T1/ 2 3 T1/ 2
N  N 0e   t
Ndecayed  N0  N  No1et 

ln 2 60

N1 1  e 10 0.984375 N1 N1
 ln 2 60
  1.125 9/8
N2  0.825 N 2 N 2
1  e 20
8. In the given circuit, the charge on 4 F capacitor will be:
1) 9.6 C 2) 24 C 3) 5.4 C 4) 13.4 C

Ans. 2
64
Sol. Ceqa   2  5.4 Q  CaV  5.4C OR V4 : V6  6 : 4  3 : 2
6 4
3
V4   10  6V Q4  4V4  24C
5
9. A small speaker delivers 2 W of audio output. At what distance from the speaker
will one detect 120dB in intensity sound? [Given reference intensity of sound as
1012W / m1 ]
1) 10cm 2) 20cm 3) 40cm 4) 30cm
Ans. 3
I  I  12 I
Sol.   10log   120  10log   10 
 I0   I0  I0
 2 1
I 1 2
d2  d  0.3989 m d  40 cm
4 d 4 2
10. A diatomic gas with rigid molecules does 10 J of work when expanded at constant
pressure. When would be the heat energy absorbed by the gas, in this process?
1) 40 J 2) 30 J 3) 35 J 4) 25 J
Ans. 3
Sol. dQP  nCP dT ,   7 5
dw 1 5 2
1  1 
dQ p  7 7

7
dQP   10  35 J
2
11. A transport cube of side d, made of a material of refractive index  2 , is immersed in
a liquid of refractive index 1  1   2  . A ray is incident on the face AB at an angle 
(shown in the figure). Total internal reflection takes place at point E on the face BC.
Then  must satisfy:

22 22 1 1
1)   sin 1 1 2)   sin 1 1 3)   sin 1 4)   sin 1
12 12 2 2
Ans. 2
Sol.
1
sinC  r  90  C 1 sin   2 sin C   2 1  sin 2 C
2
2 2
   
1 sin      sin    2   1   sin 1  0   1
2
2
2
1
 1   1 
12. The ratio of the weight of a body on the Earth’s surface to that on the surface of a
1
planet is 9 : 4 , the mass of the planet is th of that of the Earth. If ‘R’ is the radius of
9
the Earth, what is the radius of the planet? (Take the planets to have the same mass
density)
R R R R
1) 2) 3) 4)
2 9 3 4
Ans. 1

2
GMm WE mE  RP  RP 1 R
Sol. w  ms  2
     RP 
R WP mP  RE  RE 2 2
13. A uniform cylindrical rod of length L and radius r, is made from a material whose
Young’s modulus of Elasticity equal Y. When this rod is heated by temperature T
and simultaneously subjected to a net longitudinal compressional force F, its length
remains unchanged. The co-efficient of volume expansion, of the material of the rod,
is (nearly) equal to:
R
1) F /  3 r 2YT  2) 6 F /  r 2YT  3) 9 F /  r 2YT  4) 3F /  r 2YT 
2
Ans. 4
F 3F 3F
Sol. F  YA T   Y  3  
YAT YAT Y  r 2T
14. Two particles are projected from the same point with the same speed u such that
they have the same range R, but different maximum heights, h1 and h2 which of the
following is correct?
1) R 2  4h1h2 2) R 2  2h1h2 3) R 2  h1h2 4) R 2  16h1h2
Ans. 4
u 2 sin 2 u 2 sin 2  u 2 cos 2 
Sol. R h1  , h2 
g 2g 2g
u 4 sin 2  cos 2  4 R2
h1h2   h h
1 2 
4g 4 16
15. In an amplitude modulator circuit, the carrier wave is given by, C  t   4 sin  2000  t 
while modulating signal is given by m  t   2 sin  2000  t  . The values of modulation
index and index and lower side band frequency are:
1) 0.5and 9kHz 2) 0.2and 9 kHz 3) 0.5 and 10kHz 4) 0.4 and 10kHz
Ans. 1
Vmax  Vmin Am 2 1
Sol. M      0.5 LSB  f c  f m  9 KHz
Vmax  Vmin Ac 4 2
16. A particle is moving with speed   b x along positive x  axis . Calculate the speed of
the particle at time t   (assume that the particle is origin at t  0 )
b 2 b 2 2 b 2
1) 2) 3) b  4)
2 4 2
Ans. 4
x 
dx dx b 2
Sol. V b x  b x b dt 2 x  b x  b / 2 V 
dt 0 x 0
2
17. The electron in a hydrogen atom first jumps from the third excited state to the first
excited state. The ratio of the respective wavelengths, 1 / 2 of the photons emitted in
this process is:
1) 20 / 7 2) 9 / 7 3) 7 / 5 4) 27 / 5
Ans. 1
1 2 1 1 1 2 1 1 1 2 1 1
Sol.  R 1  2  2   R 1  2  2   R 1  2  2 
  n f ni  1  3 9  2 2 3 
1 1
1 4  9 5 / 36 5 9  16 20
    
 2 1  1 7 / 9  16 7 30 7
9 16
18. A system of three polarizers P1 , P2 , P3 is set up such that the pass axis of P3 is crossed
with respect to that of P1 , The pass axis of P2 , when a beam of unpolarized light of
intensity I O is incident on P1 , the intensity of light transmitted by the three
polarizers of light transmitted by the three polarizers is 1. The ratio  I O / I  equal
(nearly):
1)5.33 2) 16.00 3) 10.67 4) 1.80
Ans. 3
300
I0 600
I0 / 2
Sol.
I0 I 3 1 I 0 32
I cos 2 300 cos 2 60 I  0   
2 2 4 4 I 3
19. consider an electron in hyfrogen atom, revolving in its second excited state
(havingradius 4.65A0 ). The de-Broglie wavelength of this electrons is:
1) 9.7A0 2) 6.6 A0 3) 3.5 A0 4) 12.9 A0
Ans. 1
Sol. n  2 rn 3  2  4.65A0   9.7 A0

20. Let a total charges 2 Q be distributed in a sphere of radius R, with the charge
density given by p  r   kr , where r is the distance from the centre. Two charges A
and B, of Q each are placed on diametrically opposite points, at equal distance, a
from the centre. If A and B not experience any force, then:
3R 1 1
1) a  1
2) a  R / 3 3) a  2 4 R 4) a  8 4 R
4
2
Ans. 4
R R
 R4 
Sol.   r   Kr Qtotal  2

 2Q     r  4 r dr 2Q  4 k  r dr 2Q  4 k  
3
 4
0 0
4kR 2 2Q 1 Q2 1 Q2
Q K Force between charges –Q and Q F  
2  R4 4 0  2a2 4 0 4a 2
a
q dv Qa 2 Q2 Q2a2
ds  in E  4a 2   
1
E E F  QE  a 8 4R .
0 0
0 2 0 R 4
16 0 a 2
2 0 R n
21. A tuning fork of frequency 480 Hz is used in an experiment for measuring speed of
sound   in air by resonance tube method. Resonance is observed to occur at two
successive length of the air column, l1  30 cm and l2  70 cm . Then,  is equal to:
1) 332 ms 1 2) 379 ms 1 3) 338 ms 1 4) 384 ms 1
Ans. 4

Sol. V  2 n  l2  l1   2  480 40  10 V  384 m / s
2

22. A block of mass 5Kg is  i  pushed in case  A  and  ii  pulled in case  B  , by a force
F  20 N , making an angle of 300 with the horizontal, as shown in the figures. The co-
efficient of friction between the block and floor is   0.2 . The difference between
the accelerations of the block, in case  B  and case  A  will be:  g  10 ms 2 
1) 0.8ms 2 2) 0 ms 2 3) 3.2 ms 2 4) 0.4 ms 2

Ans. 1
3
Sol. CASE:-(I) Fnet  F cos300  f K1 ma1  20   0.2 N1 5a1  10 3  0.2 50  20sin 300 
2
12
a1  2 3   1.06 m / s 2 CASE:-(II) Fnet  F cos300  f K2
5
5a2  10 3  0.2 50  20sin 300  a2  a1  1.86  1.06  0.8m / s 2

23. A spring whose unstretched length is l has a force constant k. The spring is cut into
two pieces of unstretched lengths l1 and l2 where, l1  nl2 and n is an integer. The
ratio k1 / k 2 of the corresponding force constants, k1and k2 will be:
1 1
1) n 2) n2 3) 4)
n2 n
Ans. 4
k1 l2 1
Sol. Kl  cos t  
k2 l1 n
24. Consider the LR circuit shown in the figure. If the switch S is closed at t  0 then the
L
amount of charge that passes through the battery between t  0 and t  is:
R
2.7 EL EL EL 7.3 EL
1) 2) 3) 4)
R2 7.3 R 2 2.7 R 2 R2
Ans. 1
L
L/ R
  Rt / L
   e  Rt / L   R
Sol. i  1  e  q   idt   t   
R 0 R R   R / L  
 L EL L L  1 L 2.37 L
   2 e1  2  2  2    2  2  0.37 q 
R R R R R  e R R2
25. A plane electromagnetic wave having a frequency v  23.9 GHz propagates along the
positive z-direction in free space. The peak value of the electric field is 60 V / m .
which among the following is the acceptable magnetic field component in the
electromagnetic wave ?

1)  2  10 sin  0.5 10 z  1.5  10 t  iˆ
7 3 11
B
 7
 2 11
2) B  2  10 sin 0.5  10 x  1.5  10 t  iˆ
 7
 3 11
3) B  2  10 sin 0.5  10 z  1.5  10 t  iˆ

4)  60 sin  0.5  10 z  1.5 10 t  iˆ
3 11
B
Ans. 1
E0 60 2 2 f
Sol. E0  60V / M B0   8
 2  107 T B  B0 sin  Kx  t  K  
C 3  10  C

2  23.9  109
 8
 500 m 1 K  0.5  103 m 1 w  2 f  150  109  1.5  1011 rad / sec
3  10
26. An electron, moving along the x  axis with an initial energy of 100eV , enters a region

of magnetic field B  1.5 103 T  kˆ at S (See figure). The field extends between x  0
and x  2 cm . The electron is detected at the point Q on a screen placed 8 cm away
from the point S. The distance d between P and Q (on the screen) is: (electron’s
charge  1.6 1019 C , mass of electron  9.11031 kg )
1)12.87cm 2) 2.25cm 3) 11.65cm 4) 1.22cm

Ans. 1
1 2 1 31 2 19 2 200  1.6
Sol. mv  K  100 ev  9.1  10 v  100  1.6  10 v  12
v  0.59  107
2 2 9.1  10
2
6 1 1  Bqv   x 
v  5.9  10 m / s x1  vt1 y1  at12    
2 2 m   v
2
1  1.5  10 3  1.6  10 19  5.9  106   2  10 2 
y1   
2  9.1  1531   5.9  106   0.00894 m  0.894 cm
mv 9.1  1031  5.9  106 d 2

r  3 19
 2.24 cm sin       63.230
Bq 1.5  10  1.6  10 r 2.24
1 g
y2  u sin t1  gt12 y2  Tan x2  2
x22 x2  6 cm  0.119 m  11.9 cm
2 2 x cos 
r
 
d
d  y1  y2  12.87 cm

27. A smooth wire of the length 2 r is bent into a circle and kept in a vertical plane. A
bead can slide smoothly on the wire. When the circle is rotating with angular speed
 about the vertical diameter AB , as shown in figure, the bead is rest with respect
to the circular ring at position P as shown. Then the value of  2 is equal to:
3g
1) 2 g /  r 3  2) 3)  g 3  / r 4) 2g/ r
2r
Ans. 1
20 N sin 600
N
r
N
600 600
N sin 600
mg
mg
Sol.
mr 2 g 2g 2g
N cos 600  N cos 600  mg Tan600   2 w2 
2 r 2 rw 3r
w
2
28. One kg of water at 200 C , is heated in an electric kettle whose heating element has a
mean (temperature averaged) resistance of 20  . The rms voltage in the mains is
200 V . Ignoring heat loss from the kettle, time taken for water to evaporate fully, is
close to:
1) 22 minutes 2) 16 minutes 3) 3 minutes 4) 10 minutes
Ans. 4
2
Q  Pt msat  mL 
V0
2
 
t 1  4200  80  1  2260  103 
 2  200  t t  649sec
Sol.
R 20
t  10.8min t  10min
29. A Carnot engine has an efficiency of 1/6. When by 620 C , its efficiency is doubled.
The temperature of the source and the sink are, respectively,
1) 990 C ,37 0 C 2) 1240 C , 620 C 3) 37 0 C , 990 C 4) 620 C ,1240 C
Ans. 1
T2
Sol.   1 
T1
1 T T 1 5  T  62 
 1  2  2  1   2  1   2
6 T1 T1 6 6  T1 
1 62
2   T1  62  6 T1  372 K
6 T1
5
T1  372  273  990 C T2 
 372  310 K T2  310  273  370 C
6
30. Three particles of masses 50 g, 100 g and 150 g are placed at the vertices of an
equilateral triangle of side 1m (as shown in the figure). The  x, y  co-ordinates of the
centre of mass will be:
 3 5   3 7  7 3  7 3 
1)  m, m  2)  m, m  3)  m, m 4)  m, m
 4 12   8 12   12 4   12 8 
Ans. 3
X cm  

m1 x1  m2 x2  m3 x3 0  0  150 3 / 2
 3/4

175 35
  7 / 12 M
Sol.
m1  m2  m3 300 300 60
Ycm  

m1 y1  m2 y2  m3 y3 0  0  150 3 / 2
 3/4

m1  m2  m3 300
CHEMISTRY
31. The ratio of number of atoms present in a simple cubic ,body centered cubic and
face centered cubic structure are respectively
1) 8 : 1: 6 2) 1: 2 : 4 3) 4 : 2 : 3 4)4: 2 : 1
Ans. 2
Sol. simple cubic Z1  1 Body centered cubic Z 2  2
Face centered cubic Z 3  4 Z1 : Z 2 : Z 3  1: 2 : 4 .
32. The temporary hardness of a water sample is due to compound X. Boiling this
sample converts X to compound Y.X and Y respectively, are
1) Ca  HCO3  2 and CaO 2) Ca  HCO3  2 and Ca  OH  2
3) Mg  HCO3  2 and MgCO3 4) Mg  HCO3  2 and Mg  OH  2
Ans. 4
Sol. Mg  HCO3  2   Mg  OH  2  2CO2

33. The molar solubility of Cd  OH  2 is 1.84  1015 M in water. The expected solubility of
Cd  OH  2 in a buffer solution of pH  12 is :
2.49
1) 6.23  10 11 M 2)  109 M 3) 1.84  10 9 M 4) 2.49  1010 M
1.84
Ans. 4
Sol. Ksp  Cd  OH  24.91015  s1 102  S '  2.491010 M .
2 2  2
34. Which one of the following is likely to give a precipitate with AgNO3 solution?
1)  CH 3  3 CC 2) CH 2  CH  C  3) CC 4 4) CHC 3
Ans. 1

CH 3 3 CC   AgNO3  AgC   CH 3 3 C NO3
(Stable Carbocation)
Sol.
35. The IUPAC name for the following compound is:
1) 3  methyl 4  ( 3  methylprop 1  enyl ) 1  heptyne

2) 3  methyl  4  1  methylprop  2  yny1  1  heptene
3) 3,5 – dimethyl  4  propylhept  1  en  6  yne
4) 3,5 – dim ethyl  4  propylhept  6  en  1  yne

Ans. 3
Sol. 3,5  dim ethyl  4  propylhept 1 en  6  yne
CH 3
CH
H 3C
4 5 7
6
2 3 CH
3
CH 2
1
36. The C-C bond length is maximum in

1) C70 2) diamond 3)graphite 4) C60
Ans. 2
Sol. In diamond, carbon undergoes SP hybridization and it has only   bonds .
3
Longest C  C bond is present in diamond.

37. The INCORRECT match in the following is
1) G 0  0, K  1 2) G 0  0, K  1 3) G 0  0, K  1 4) G 0  0, K  1
Ans. 4
Sol. G 0  RT n K
38. Benzene diazonium chloride on reaction with aniline in the presence of dilute
hydrochloric acid gives
Ans. 4
NH 2
N2

+ 
H
 NN NH 2
Yellow dye
Sol.
39. In which one of the following equilibria , K p  KC ?
1) NO2  g   SO2  g   NO  g   SO3  g  2) 2HI  g   H 2  g   I 2  g 
3) 2C  s   O2  g  2CO  g  4) 2NO  g   N 2  g   O2  g 

Ans. 3
Sol. To get Kp  Kc no. of gaseous reactants should not be equal to no. of gaseous products.
40. The correct statement is :
1) Pig iron is obtained from cast iron.
2) Leaching of bauxite using concentrated NaOH solution gives sodium
aluminateand sodium silicate.
3) the blistered appearance of copper during the metallurgical process is due to the
evolution of CO2
4) the Hall- Heroult process is used for the production of aluminium and iron.
Ans. 2
Sol. A 2O3s  2 NaOH aq  3H 2O  2 Na  A OH 4   Na2 SiO3
aq
41. The primary pollutant that leads to photochemical smog is:

1) nitrogen oxides 2) sulphur dioxide
3) acrolein 4) ozone
Ans. 1
Sol. Primary pollutant are nitrogen oxides and hydrocarbons.
42. Among the following , the INCORRECT statement about colloids is :
1) They are larger than small molecules and have high molar mass.
2) The range of diameters of colloidal particles is between 1 and 1000nm.
3) They can scatter light.
4) The osmotic pressure of a colloidal solution is of higher order than the true
solution at the same concentration.
Ans. 4
Sol. Refer NCERT
Osmatic pressure of colloidal solution is less compared to true solution.
43. Among the following , the energy of 2s orbital is lowest in :
1) H 2) Na 3) K 4) Li
Ans. 3
Sol. more no. of protons lesser the energy.
44. The pair that has similar atomic radii is :
1) Mo and W 2) Mn and Re 3) Ti and Hf 4) Sc and Ni
Ans. 1
Sol. Due to lanthanoid contraction, Mo and W have near by atomic radii.
45. Heating of 2-chloro -1-phenylbutane with EtOK/EtOH gives X as major
product.Reaction of X with Hg  OAc  2 / H 2O followed by NaBH 4 gives Y as the
major product.Y is :
Ans. 3
OH
ph 
EtoK
EtoH
 ph 
OMDM
ph
Sol.
46. The correct name of the following polymer is :
1) polyisobutylene 2) polyisobutane 3) polytert –butylenes 4) polyisoprene

Ans. 1
CH 3 CH 3
n CH 2  C 
Polymerisation
 CH 2  C
n
CH 3 CH 3
Sol.
47. Thermal decomposition of a Mn compound  X  at 513 K results in compound Y ,
MnO2 and a gaseous product. MnO2 reacts with NaCl and concentrated H 2 SO4 to
give a pungent gas Z . X ,Y and Z . respectively are
1) K 3 MnO4 , K 2 MnO4 and Cl2 2) KMnO4 , K 2 MnO4 and Cl2
3) K 2 MnO4 , KMnO4 and SO2 4) K 2 MnO4 , KMnO4 and Cl2
Ans. 2
Sol.
2 KMnO4  K 2 MnO4  MnO2  O2
X  Y 
4 NaC   MnO2  4 H 2 SO4  MnC  2  4 NaHSO4  2 H 2O  C  2

Z 

48. The INCORRECT statement is :

1) Licl crystallises from aqueous solution as Licl . 2H 2O
2) LiNO3 decomposes on heating to give LiNO2 and O2
3) Lithium is least reactive with water among the alkali metals
4) Lithium is the strongest reducing agent among the alkali metals.
Ans. 2

Sol. LiNO3   Li2O  NO2  O2
49. In the following skew conformation of ethane H '  C  C  H '' dihedral angle is
1) 1510 2) 1490 3) 580 4)1200

Ans. 1
H H'
290
'' H
1800
H
Sol.
H ' C  C  H '' dihedral angle  1800  290  1510
50. What will be the major product when m- cresol is reacted with propargyl bromide
 HC  C  CH 2 Br  in presence of K 2CO3 in acetone?

Ans. 3
OH O O  CH 2  C  CH
CH CCH 2 Br

K2 CO3
 
 SN 2 
CH 3 CH 3 CH 3
Sol.
51. 25 g of an unknown hydrocarbon upon burning produces 88 g of CO2 and 9 g of
H 2O. This unknown hydrocarbon contains.
1) 22 g of carbon and 3 g of hydrogen
Ans. 4
Sol. 88g of CO2  24 g of carbon is present
9g of H 2O  1g of hydrogen is present.
52. A solution is prepared by dissolving 0.6 g of urea ( molar mass =60 g mol 1 ) and 1 .8
g of glucose (molar mass =180 g mol 1 ) in 100 mL of water at 27 0 C . The osmotic

pressure of the solution is : R  0.08206 L atm K 1 mol 1 
1) 2.46 atm 2) 1.64 atm 3) 4.92 atm 4) 8.2 atm
Ans. 3
 0.01 0.01 
Sol.   C1  C2  RT   1000  1000 0.08206300 = 4.92 atm.
 100 100 
53. The coordination numbers of Co and Al ion Co  Cl  en 2  Cl and K 3  Al  C2O4 3 
respectively, are ( en = ethane 1,2-diamine)
1) 3 and 3 2) 6 and 6 3) 5 and 3 4) 5 and 6
Ans. 4
Sol. CO C en2  C   co.ordination number of co is 5
K 3  A C2O4 3   co.ordination number of co is 6.
54. The decreasing order of electrical conductivity of the following aqueous solutions is
0.1 M Formic acid (A) 0.1 M Acetic acid (B) 0.1 M Benzoic acid (C)
1) C > A >B 2) C > B > A 3) A > C > B 4) A > B > C
Ans. 3
Sol. Ka is more conductivity is more
Formic acid  Ka   Benzoic acid  Ka  Aceticacid  Ka

55. which of the given statements is INCORRECT about glycogen?

1) It is Present in animal cells.
2) It is a straight chain polymer similar to amylose.
3) It is present in some yeast and fungi.
4) Only  -linkages are present in the molecule.
Ans. 2
Sol. glycogen structure is similar to amylopectin and is more highly branched.
56. Consider the following reactions
1) CH 2  CH 2 2) CH 3  C  CH 3) CH 3  C  C  CH 3 4) CH  CH
Ans. 2
O OH
2 
CH3  C  CH 
Hg /H
 CH 3  C  CH 3 
NaBH 4
 CH3  CH  CH 3
Lucas Reagent
C
CH 3  CH  CH 3
white ppt
Sol.
57. In comparison to boron, beryllium has
1) greater nuclear charge and lesser first ionization enthalpy.
2) lesser nuclear charge and greater first ionization enthalpy
3) greater nuclear charge and greater first ionization enthalpy.
4)lesser nuclear charge and lesser first ionization enthalpy
Ans. 2
Sol. Be has lesser nuclear charge, greater the IE.

58. An ‘Assertion’ and a ‘Reasaon’ are given below Choose the correct answer from the
following options :
Assertion (A) : Vinyl halides do not undergo nucleophilic substitution easily.
Reasaon (R) : Even though the intermediate carbocation is stabilized by loosely held
 -electrons the cleavage is difficult because of strong bonding.
1) Both (A) and (R) are correct statements and (R) is the correct explanation of (A)
2) Both (A) and (R) are wrong statements.
3) Both (A) and (R) are correct Statements but (R) is not the correct explanation of
(A)
4) (A) is a correct statement but (R) is a Wrong statement.
Ans. 4
Sol. Vinyl halides doesn’t form stable carbocation.
59. The compound use in the treatment of lead poisoning is

1) EDTA 2) desferrioxime B
3) D- penicillamine 4) Cis –platin
Ans. 1
Sol. EDTA used in the treatment of lead poisoning.
60. NO2 required for a reaction is produced by the decomposition of N 2O5 in CCl4 as
per the equation 2 N 2O5  g   4 NO2  g   O2  g  The initial concentration of N 2O5 is
3.00 mol L1 and it is 2.75 mol L1 after 30 minutes the rate of formation of NO2 is
1) 2.083 X103 mol L1 min 1 2) 8.333 X103 mol L1 min 1
3) 4.167X 103 mol L1 min 1 4) 1.667 X102 mol L1 min 1
Ans. 4
1 d  N 2O5  1 d  NO2  d  N 2O5   2.75  3.00  0.25 d  NO2   0.25 

Sol.  2 dt  4 dt      
 30 
2
dt  30  30 dt
=1.667 X102 mol L1 min 1 .

MATHEMATICS
 sin x  cos x  x    
61. The derivative of tan1   with respect to , where x  0,  is
 sin x  cos x  2   2 
1 2
1) 2) 1 3) 2 4)
2 3
Ans. 3
 tan x 1     
Let y  tan 1    tan 1 
 tan  x      x   
Sol. 
 tan x  1    
4   4 
Let z  x 2
dy

dy
dx

 
1
2.
dz dz
dx
1 
2   
62. The equation of a common tangent to the curves, y 2  16x and xy  4 , is
1) x  y  4  0 2) 2x  y  2  0 3) x  2y  16  0 4) x  y  4  0
Ans. 4
4
Sol. Tangent to parabola with slope m is y  mx  1
m
This is tangent to xy  4 2
 4
Elemenating y from 1, 2 x mx    4
 m
 mx 2  4 x  4m  0 Now   0  m 1
 The common tangent is y  x  4 .
63. The angle of elevation of the top of a vertical tower standing on a horizontal plane is
observed to be 450 from a point A on the plane. Let B be the point 30 m vertically
above the point A. If the angle of elevation of the top of the tower from B be 300 ,
then the distance (in m) of the foot of the tower from the point A is
1) 15 1  3  2) 15 5  3  3) 15 3  3  4) 15 3  3 
Ans. 4
Q
x  30
B 300
x N
30m
450
A x P x  30
Sol. From QBN Tan300 
x
 30 3 
 x     15 3
 3 1
  
3  1  15 3  3 . 

64. An ellipse, with foci at (0, 2) and (0, -2) and minor axis of length 4, passes through
which of the following points ?
1) 1,2 2  2)  2,2 3) 2,2 2  4) 2, 2 
Ans. 2
Sol. 2be  4, 2a  4 b 2 e 2  b 2  a 2 4  b 2  4  b 2  8
x2 y 2
Equation of ellipse:
4
  1 This is satisfied by
8
 
2, 2 .
65. If ,  and  are three consecutive terms of a non-constant G.P. such that the
equations  x 2  2 x    0 and x 2  x 1  0 have a common root, then      is
equal to
1)  2)  3) 0 4) 
Ans. 1
let ,   r   r 2  x 2  2 x    0  x  r   0
2
Sol.
x  r is a root of x 2  x 1  0  1  r 2
       r  r 2   r r 2   
  
66. Let   R and the three vectors a  i  j  3k , b  2i  j  k and c  i  2j  3k .
  

Then the set S   : a , b and c are coplanar 
1) contains exactly two positive numbers
2) is singleton
3) is empty
4) contains exactly two numbers only one of which is positive
Ans. 3
 1 3
Sol. 2 1   0
 2 3
 3  2    6   2   34     0  3 2  18  has no real value.
67. If a1, a 2 , a 3 ,............. are in A.P. such that a1  a 7  a16  40 , then the sum of the first
15 terms of this A.P. is
1) 150 2) 200 3) 120 4) 280
Ans. 2
15 
Sol. a1  a1  6d   a1  15d   40 3a1  21d  40  1 S15  2a1  14d 
2 
40
 15 a1  7 d   15  200 units .
3

2z  n
68. Let z  C with Im z   10 and it satisfies  2i  1 for some natural number n.
2z  n
Then
1) n  20 and Re z   10 2) n  40 and Re z   10
3) n  40 and Re z   10 4) n  20 and Re z   10
Ans. 2
2  x 10i  n
Sol. Let z  x  10i Then  2i 1
2  x  10i   n
  2 x  n  20i  2 x  n  20i2i 1
 2 x  n   2 x  n  40  4 x  40 x  10
Comparing im. parts  Re  z   10 20  2 2 x  n 20  n  40 .
69. Let   0,  /2 be fixed. If the integral
tan x  tan 
 dx  A x  cos 2  B x  sin 2  C ,
tan x  tan 
where c is a constant of integration, then the functions A x  and B x  are
respectively
1) x   and log e cos x    2) x   and log e sin x   
3) x   and log e sin x    4) x   and log e sin x   
Ans. 2
sin  x    sin  x    2 
Sol.  sin  x   
dx  sin  x   
dx, x   
cos 
cos 2  d   sin2  d   cos 2  x     sin 2 log sin  x     C .
sin 
x  2sin x
70. lim
x 0
x 2  2sin x  1  sin2 x  x  1
1) 6 2) 1 3) 3 4) 2
Ans. 4
3x  x2  2 x 1  x 2  x 1 2
Sol. xLt
0 3x
The tangents to the curve y  x  2  1 at its points of intersection with the line
2
71.
x  y  3 , intersect at the point
 5  5   5  5 
1)  ,1 2)  ,1 3)  , 1 4)  , 1
 2  2   2  2 
Ans. 4
Sol.  x  3  x  4 x  3 x  2,3 P 2, 1 3, 0 m = 0, 2 y  1 2x  y  6 x  5 .
2
2
1 x 8   2 3 
6
72. 
The term independent of x in the expansion of   .2x  2  is equal to
 60 81  x 
1) -72 2) -36 3) 36 4) -108
Ans. 2
1 6 1 6
C3  2 3  72 T6  C5  2 3  36 .
3 3 3 3
Sol. T4 
60 81
73. If the area (in sq. units) bounded by the parabola y 2  4 x and the line y   x ,
1
  0 , is , then  is equal to
9
1) 48 2) 4 3 3) 2 6 4) 24
Ans. 4
4/ 
Sol. A   
4 x   x dx   24 .
0
74. The Boolean expression   p   q  is equivalent to

1) q  p 2) p  q 3) p  q 4)  p   q
Ans. 2
Sol.    p V  q   p  q .
75. A straight line L at a distance of 4 units from the origin makes positive intercepts on
the coordinate axes and the perpendicular from the origin to this line makes an
angle of 600 with the line x  y  0 . Then an equation of the line L is
1) x  3y  8 2) 3x  y  8
3)  3 1 x    
3 1 y  8 2 4)  
3 1 x   
3 1 y  8 2
Ans. 3
Sol. x cos 75  y sin 75  4
750
76. A plane which bisects the angle between the two given planes 2x  y  2z  4  0 and
x  2y  2z  2  0 , passes through the point
1) 1, 4,1 2) 1, 4, 1 3) 2, 4,1 4) 2,4,1
Ans. 3
2x  y  2z  4 x  2 y  2z  2
Sol.  3x  y  4 z  6  0 x  3 y  2  0 .
3 3

77. A circle touching the x-axis at (3,0) and making an intercept of length 8 on the y-axis
passes thorough the point
1) 3,10 2) 1,5 3) 3,5 4) 2,3
Ans. 1
Sol. x  2 gx  c   x  3 g  3 c  9 f  5 x  y  6 x  10 y  9  0 .
2 2 2 2
78. For an initial screening of an admission test, a candidate is given fifty problems to
4
solve. If the probability that the candidate can solve any problem is , then the
5
probability that he is unable to solve less than two problems is
164  1  54  4  316  4  201  1 
48 49 48 49
1)   2)   3)   4)  
25  5  5  5  25  5  5  5 
Ans. 2
4 4 1 5 4  4 
50 49 49
Sol. P  x  0  P  x  1 50 C 50    50 C 49   .   

 5   5  5 5  5 
79. Let A,B and C be sets such that   A  B  C . Then which of the following
statements is not true ?
1) If A  C   B , then A  B 2) C  A   C  B   C
3) If A  B   C , then A  C 4) B  C  
Ans. 1
Sol. A  2 B  1, 2, 3, 4 and C  2,5 A  B  2  C
A B
A  C     B But .
80. Let f x   5  x  2 and g x   x  1 , x  R . If f x  attains maximum value at 
x  1x 2  5x  6
and g x  attains minimum value at  , then lim is equal to
x  2
x  6x  8
1) 1/ 2 2)1/ 2 3) 3 / 2 4) 3 / 2
Ans. 2
1
Sol.   2,   1    2 Required limit  .
2
81. If  x  denotes the greatest integer  x , then the system of linear equations
sin   x   cos  y  0 cot   x  y  0
  2   7 
1) have infinitely many solutions if    ,   , 
2 3   6 
  2   7 
2) have infinitely many solutions if    ,  and has a unique solutions if   , 
 2 3   6 
  2   7 
3) has a unique solution if    ,   , 
2 3   6 
  2   7 
4) has a unique solution if    ,  and have infinitely many solutions if   , 
2 3   6
Ans. 2

  2 
Sol.    ,   sin    0, cos    0 and cot    1  x  y infinitely many solutions.
 2 3 
 7 
And   ,   sin    7, cos    0 and cot    0  x  0, y  0 unique solution.
 6
If 20 C1  22  C2  32  C3  .............  202  C20  A 2  , then the ordered pair  A,   is
20 20 20
82.
equal to
1) 420,18 2) 380,18 3) 380,19 4) 420,19
Ans. 1
20
Sol.   r2 20
Cr  20  20 1 218  420 18 .
r 1
83. Let S be the set of all   R such that the equation, cos 2 x   sin x  2  7 has a
solution. Then S is equal to
1) 1, 4 2) R 3) 3, 7  4)  2,6
Ans. 4
 4  4
Sol. 2sin 2 x   sin x  2  8  0  sin x  , 2 1  1  2    6
2 2
84. The length of the perpendicular drawn from the point 2,1, 4 to the plane containing
 
      
the lines r  i  j   i  2j  k and r  i  j   i  j  2k is 
1 1
1) 3 2) 3) 4) 3
3 3
Ans. 1
x 1 y 1 z
2 1 4
Sol. 1 2 1  0 x  y  z  0 Distance from (2, 1, 4),  3.
3
1 1 2
 1
dx  9 
  is
85. A value of  such that   x   x   1  log e  8 

1 1
1) -2 2)  3) 2 4)
2 2
Ans. 1
 1
log x     log  9  log 
    2  1  9 
Sol.  log      2 .
 x    1  8  4   1  8 
86. A person throws two fair dice. He wins Rs. 15 for throwing a doublet (same
numbers on the two dice), wins Rs. 12 when the throw results in the sum of 9, and
loses Rs. 6 for any other outcome on the throw. Then the expected gain/loss (in Rs.)
of the person is
1 1 1
1) gain 2) loss 3) loss 4) 2 gain
2 2 4
Ans. 2
6 4 26 90  48 156 18 1
Sol. Range of x : 15 12  6 P  x : Expection    .
36 36 36 36 36 2

87. A group of students comprises of 5 boys and n girls. If the number of ways, in which
a team of 3 students can randomly be selected from this group such that there is at
least one boy and at least one girl in each team, is 1750, then n is equal to
1) 27 2) 24 3) 28 4) 25
Ans. 4
Sol. C2 . C1  C1. C2  1750 n  3n  700 n  25 .
5 n 5 n 2
88. A triangle has a vertex at (1, 2) and the mid points of the two sides through it are (-
1, 1) and (2, 3). Then the centroid of this triangle is
 7 1 5 1  1 
1) 1,  2)  ,  3)  ,1 4)  , 2
 3  3 3 3  3 
Ans. 4
1, 2
3,0 3, 4
Sol. The Ans. Is centroid.
89. The general solution of the differential equation  y 2  x 3  dx  xydy  0  x  0 is
(where c is a constant of integration)
1) y 2  2 x 2  cx 3  0 2) y 2  2 x 3  cx 2  0
3) y 2  2 x 2  cx3  0 4) y 2  2 x 3  cx 2  0
Ans. 2
dy y x 2 dy 2 y 2 dz 2
Sol.   2y   x 2 , y 2  z  z  2 x 2
dx x y dx x dx x
1  cos 2  sin 2  4 cos 6
90. A value of   0,  / 3 , for which cos  2
1  sin  2
4 cos 6  0 , is
cos 2  sin 2  1  4 cos 6
 7 7 
1) 2) 3) 4)
18 24 36 9
Ans. 4
Sol. R2  R1 R3  R2 2  4 cos 6  0 cos 6   1    .
2 9
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2019_Apr_Jee-Main Question Paper_Key & Solutions

2019_Jee-Main Question Paper_Key & Solutions

1) n r   n0  3/4 2) n0 1/2 3) n0 3 4) n0 1/ 4

2. A solid sphere, of radius R acquires a terminal velocity 1 when falling (due t

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1) 3.0 105 T 2) 2.0 105 T 3) 2.5 105 T 4) 1.5 105 T

1) 3.5mA 2) 7.5mA 3) 1.5mA 4) 2.5mA

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6. A moving coil galvanometer, having a resistance G, produces full scale deflection

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1) 9.6 C 2) 24 C 3) 5.4 C 4) 13.4 C

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Sol. n  2 rn 3  2  4.65A0   9.7 A0

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1) 0.8ms 2 2) 0 ms 2 3) 3.2 ms 2 4) 0.4 ms 2

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1)12.87cm 2) 2.25cm 3) 11.65cm 4) 1.22cm

mv 9.1  1031  5.9  106 d 2

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1) 3  methyl 4  ( 3  methylprop 1  enyl ) 1  heptyne

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36. The C-C bond length is maximum in

Longest C  C bond is present in diamond.

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41. The primary pollutant that leads to photochemical smog is:

1) polyisobutylene 2) polyisobutane 3) polytert –butylenes 4) polyisoprene

4 NaC   MnO2  4 H 2 SO4  MnC  2  4 NaHSO4  2 H 2O  C  2

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48. The INCORRECT statement is :

1) 1510 2) 1490 3) 580 4)1200

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55. which of the given statements is INCORRECT about glycogen?

56. Consider the following reactions

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59. The compound use in the treatment of lead poisoning is

per the equation 2 N 2O5  g   4 NO2  g   O2  g  The initial concentration of N 2O5 is

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74. The Boolean expression   p   q  is equivalent to

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Sol. P  x  0  P  x  1 50 C 50    50 C 49   .   

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... Prepared by Sri Chaitanya Faculty

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