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2019_Apr_Jee-Main Question Paper_Key & Solutions
2019_Jee-Main Question Paper_Key & Solutions
PHYSICS
1. Four identical particles of mass M are located at the corners of a square of side ‘a’.
What should be their speed if each of them revolves under the influence of others’
gravitational field in a circular orbit circumscribing the square?
GM GM GM GM
1. 1.21 2. 1.41 3. 1.16 4. 1.35
a a a a
Ans:. 3
GM 2 1 GM 2 MV 2
Sol: 2 2     2
 
2
a 2 2a a
GM
V  1.16
a
2. Two particles move at right angle to each other. Their de Broglie wavelengths are
1 and  2 respectively. The particles suffer perfectly inelastic collision. The de
Broglie wavelength  , of the final particle, is given by:
1   2 2 1 1 1 1 1
1.    1 2 2.   3.   4.  
2  1  2  2  12  22
Ans: 4
  
P1  P2  P
Sol:
Sri Chaitanya IIT Academy

# 304, Kasetty Hegihts, Ayappa Society, Madhapur, Hyderabad – 500081
 www. srichaitanya.net,  iconcohyd@srichaitanyacollege.net
P  P12  P22
P 2  P12  P22
h 2 h2 h2
 
 2 12 22
1 1 1
 
 2 12 22
0
3. In SI units, the dimensions of is
0
3
1. AT 3 ML 2 2. A 1TML3 3. AT 2 M 1 L1 4. A 2T 3 M 1 L2
Ans: 4
  1
Sol: P1 0   Impedence
0 z
A2T 3 M 1L2
4. A particle moves in one dimension from rest under the influence of a force that
varies with the distance travelled by the particle as shown in the figure. The kinetic
energy of the particle after it has travelled 3 m is:
1. 5 J 2. 6.5 J 3. 4 J 4. 2.5 J
Ans: 2
1
Sol: W  2 2  15  6.5 J
2
Final K.E.=6.5 J
5. An alternating voltage   t   220sin100 t volt is applied to a purely resistive load
of 50 . The time taken for the current to rise from half of the peak value to the
peak value is:
1. 7.2 ms 2. 5 ms 3. 2.2 ms 4. 3.3 ms
Ans: 4

2 2 1
Sol: T   
 100 50
2   1
t      3.3 ms
3  4  6  50
6. A boy's catapult is made of rubber cord which is 42 cm long, with 6 mm diameter
of cross-section and of negligible mass. The boy keeps a stone weighing 0.02 kg on it
and stretches the cord by 20 cm by applying a constant force. When released, the
stone flies off with a velocity of 20 ms-1. Neglect the change in the area of cross-
section of
the cord while stretched. The Young's modulus of rubber is closest to:
1. 10 6 Nm 2 2. 103 Nm 2 3. 108 Nm 2 4. 10 4 Nm 2
Ans: 1
1 2 1
Sol:    AL  mV
2
2 2
2 4  0.42 106
 2
 3106 Nm2
  9 410
7. The reverse breakdown voltage of a Zener diode is 5.6 V in the given circuit.
The current Iz through the Zener is:

1. 7mA 2. 15mA 3. 10mA 4. 17mA
Ans: 3
5.6
Sol: Current through 800  is  7mA
800
3.4
Current through 200  is  17 mA
200
Then current Iz is 10 mA.
8. Two identical beakers A and B contain equal volumes of two different liquids at
60°C each and left to cool down. Liquid in A has density of 8  10 2 kg/ m3 and
specific heat of 2000J kg-1 K-1 while liquid in B has density of103 kg m-3 and specific
heat of4000J kg-1K-1. Which of the following best describes their temperature versus
time graph schematically? (Assume the emissivity of both the beakers to be the
same)

Ans: 1
dT  AT  T0   AT  T0 
4 4 4 4
Sol:  
dt ms V  s 
 s is more for B.
9. A plane electromagnetic wave travels in free space along the x-direction. The
electric field component of the wave at a particular point of space and time is E = 6
Vm-1 along y-direction. Its corresponding magnetic field component, B would be:
1. 2  10 8 T along z-direction 2. 6  10 8 T along z-direction
3. 6  10 8 T along x-direction 4. 2  10 8 T along y – direction
Ans: 1
E 6
Sol: B0  0   2 108 T
C 3 10 8
Along z-direction
 1  
S
0

EB 
10.
A wire of length 2L, is made by joining two wires A and B of same length but
different radii r and 2r and made of the same material. It is vibrating at a frequency
such that the joint of the two wires forms a node. If the number of antinodes in wire
A is p and that in B is q then the ratio p: q is:
1. 1 : 2 2. 3: 5 3. 1: 4 4. 4 : 9
Ans: 1
V V
Sol: nA A  nB B
2L 2L
n A VB A1 r2
    1: 2
 2r 
2
nB VA A2
11. Radiation coming from transitions n =2 to n=1 of hydrogen atoms fall on He+ ions
in n=1 and n=2 states. The possible transition of helium ions as they absorb energy
from the radiation is:
1. n  2  n  3 2. n  2  n  4 3. n  2  n  5 4. n  1  n  4

Ans: 2
2 1 1
Sol: For hydrogen, E  13.6 z   2   10.2 eV
1 2 
2 1 1
For He+, E  13.6 z   2  2   10.2 eV
 2 4 
2  4 transition.
12. For the circuit shown, with R1 =1.0  , R2=2.0  , El=2 V and E2=E3=4 V, the
potential difference between the points ’a' and ‘b’ is approximately (in V) :
1. 3.3 2.2.7 3. 3.7 4. 2.3

Ans: 1
Sol:
2 4 4
 
Va  Vb  2 2 2  5  2  3.3V
1 1 1 3
 
2 2 2
13. Voltage rating of a parallel plate capacitor is 500 V. Its dielectric can withstand a
maximum electric field of 106 V/ m. The plate area is 10-4 m2. What is the dielectric
constant if the capacitance is 15 pF ? (given 0  8.86  10 12 C 2 / Nm 2 )
1. 6.2 2. 4.5 3. 3.8 4. 8.5
Ans: 4
500
Sol: E  106   d  5104
d
K 0 A
 151012
d
K 8.86 1012 104
4
 151012
5 10
75
K  8.5
8.86
14. A solid conducting sphere, having a charge Q, is surrounded by an uncharged

conducting hollow spherical shell. Let the potential difference between the surface of
the solid sphere and that of the outer surface of the hollow shell be V. If the shell
is now given a charge of -4 Q, the new potential difference between the same two
surfaces is :
1. 4V 2. -2v 3. 2v 4. V
Ans: 4
Sol: Initial
Final
Potential difference doesn’t change.
15. A thin strip 10 cm long is on a U shaped wire of negligible resistance and it is
connected to a spring of spring constant 0.5 Nm-1 (see figure). The assembly is kept
in a uniform magnetic field of 0.1 T. If the strip is pulled from its equilibrium
position and released, the number of oscillations it performs before its amplitude
decreases by a factor of e is N. If the mass of the strip is 50 grams, its resistance 10
 . and air drag negligible, N will be close to :
1. 5000 2. 1000 3. 50000 4. 10000

Ans: 1
2 2
BlV
Sol: Force on oscillating wire if it’s speed v is F   bV
R
m
Time period T is = 25
k

t 2m
No. of oscillations is and t is given by t 
T b
16. An upright object is placed at a distance of 40 cm in front of a convergent lens of
focal length 20 cm. A convergent mirror of focal length 10 cm is placed at a distance
of 60 cm on the other side of the lens. The position and size of the final image will
be:
1. 40cm from the convergent lens, twice the size of the object
2. 40cm from the convergent mirror, same size as the object
3. 20cm from the convergent mirror, twice the size of the object
4. 20cm from the convergent mirror, same size as the object
Ans: 4
Sol: Actual final image (3rd image) is formed at object itself with same size but according
to the options best answer is taken for second image.
17. A steel wire having a radius of 2.0 mm, carrying a load of 4 kg, is hanging from a
ceiling. Given that g=3.1  ms-2, what will be the tensile stress that would be
developed in the wire?
1. 5.2  10 6 Nm 2 2. 4.8  10 6 Nm 2 3. 6.2  10 6 Nm 2 4. 3.1  10 6 Nm 2
Ans: 4
4  3.1 2
Sol:    3.110 Nm
6
 2 10 
3 2
18. A thermally insulated vessel contains 150 g of water at 0°C. Then the air from the
vessel is pumped out adiabatically. A fraction of water turns into ice and the rest
evaporates at 0°C itself. The mass of evaporated water will be closest to:
(Latent heat of vaporization of water = 2.10  106J kg-1 and Latent heat of Fusion of
water =3.36  105J kg-1)
1. 35g 2. 20g 3. 130g 4. 150g
Ans: 2
Sol: mLv  150  m  L f

m  2.110  150  m3.3610 
6 5
m  20 g
19. A thin circular plate of mass M and radius R has its density varying as   r    0 r
with 0 as constant and r is the distance from its center. The moment of Inertia of
the circular plate about an axis perpendicular to the plate and passing through its
edge is
I= a MR2. The value of the coefficient a is:
1. 3 2. 3 3. 8 4. 1
2 5 5 2
Ans: 3
R
 dI m   dm r
2
Sol: 0
M   dm   0 2 r 2 dr 
R
 2  0 r 4 dr
0
20 R 5
3MR 2
0 2  R 3
  M
5 5 3
8
I edge  I cm  MR 2  MR 2
5
20. A 20 Henry inductor coil is connected to a 10 ohm resistance in series as shown in
figure. The time at which rate of dissipation of energy (Joule's heat) across
resistance is equal to the rate at which magnetic energy is stored in the inductor, is:
2 1
1. 2. ln 2 3. 2 ln 2 4. ln2
ln 2 2
Ans: 3
di
Sol: L i   i 2 R
dt

i0e  i0 1  et /   R
L t /

10  20 t /
e  1  et /  10
20
t / 
2e  1
t   ln 2  2ln 2
21. Four particles A, B, C and D with masses mA=m, mB=2m, mC=3m and mD=4m
are at the corners of a square. They have accelerations of equal magnitude with
directions as shown. The acceleration of the centre of mass of the particles is:
a   a  
1.  
i j 2. Zero 3. a i  j
  4.  
i j
5 5
Ans: 1
   
m1 a1  m2 a2  m3 a3  m4 a4
Sol: acm 
m1  m2  m3  m4
   
      
ai  2 a j  3 ai  4 a  j  
2ai  2a j 

 
i  j 
   a  
10 10  5 
22. A circular coil having N turns and radius r carries a current I. It is held in the XZ
plane in a magnetic field Bi . The torque on the coil due to the magnetic field is:
B r 2 I Br 2 I
1. 2. 3. zero 4. B r 2 IN
N N
Ans: 4
  
Sol:     B  N  r 2  I  B 

  BN r 2 I
23. If 1022 gas molecules each of mass 10-26 kg collide with a surface (perpendicular to it)
elastically per second over an area 1 m2 with a speed 104 m/s, the pressure exerted
by the gas molecules will be of the order of :
1. 1016 N / m 2 2. 10 3 N / m 2 3. 10 4 N / m 2 4. 108 N / m 2

Ans: Bonus. No answer.

dN
Sol: F  2  mv  2 10 22 1026 104  2 N
dt
Pressure = 2Nm2
24. In figure, the optical fiber is l=2 m long and has a diameter of d =20  m. If a ray of
light is incident on one end of the fiber at angle 1 =40°, the number of reflections it
makes before emerging from the other end is close to : (refractive index of fiber is
1.31 and sin 400= 0.64)
1. 45000 2. 55000 3. 66000 4. 57000

Ans: 4
Sol: n1 sin 1  n2 sin 2
1 0.64  1.31sin 2
0.64
sin 2 
1.31
d
tan 2 
x
x  d / tan 2
l
No. of collisions =  57000
x
25. A 200  resistor has a certain color code. If one replaces the red color by green in
the code, the new resistance will be :
1. 300 2. 100 3. 400 4. 500
Ans: 4
Sol: In the given resistance 200  , 2 stands for red. If it is replaced by green, then the
resistance becomes 500 .
26. The bob of a simple pendulum has mass 2 g and a charge of 5.0  C. It is at rest in a
uniform horizontal electric field of intensity 2000 V/ m. At equilibrium, the angle
that the pendulum makes with the vertical is (take g = 10 m/s2)
1. tan 1 (2.0) 2. tan 1 (0.5) 3. tan 1 (0.2) 4. tan 1 (5.0)
Ans: 2
Eq
 0.5    tan 0.5
1
Sol: tan  
mg


27. Ship A is sailing towards north-east with velocity   30i  50 j km /hr where i
points east and j north. Ship B is at a distance of 80 km east and 150 km north of
Ship A and is sailing towards west at 10 km/hr. A will be at minimum distance from
B in:
1. 3.2 hr 2. 2.6 hr 3. 4.2 hr 4. 2.2 hr
Ans: 2
  
Sol: Velocity of A w.r.t B is VA, B  40i  50 j km / hr
  
rB , A  80i  150 j
 
r cos  V .r
t   2  2.6hr
V V
a1 1
28. In an interference experiment the ratio of amplitudes of coherent waves is  .
a2 3
The ratio of maximum and minimum intensities of fringes will be:
1. 2 2. 18 3. 4 4. 9
Ans: 3
2 2
I max  a1  a2   4
Sol:      4 :1
I min  a1  a2   2
29. Water from a pipe is coming at a rate of 100 liters per minute. If the radius of the
pipe is 5 cm, the Reynolds number for the flow is of the order of : (density of water
=1000 kg/m3, coefficient of viscosity of water= 1 mPa s)
1. 10 4 2. 103 3. 10 2 4. 10 6
Ans: 1
 DV 103  10 1  100  10 3 4
Sol: Re    4   105  2.1  10 4 Order of 4
 60    10   1  10
2 3
6
30. The wavelength of the carrier waves in a modern optical fiber communication
network is close to:
1. 600 nm 2. 2400nm 3. 1500nm 4. 900nm
Ans: 3
Sol: Wavelength used for communication are 1300nm and 1500nm.

CHEMISTRY
31. For the reaction 2A + BC, the values of initial rate at different reactant
concentrations are given in the table below. The rate law for the reaction is:
[A](mol L-1) [B](mol L-1) Initial Rate (mol L-1s-1)
0.05 0.05 0.045
0.10 0.05 0.090
0.20 0.10 0.72
2 2
1. Rate = k[A] [B] 2. Rate = k[A]2[B]
3. Rate = k[A][B] 4. Rate = k[A][B]2
Ans: 4
a b
Sol: rxpt 1  K  A1  B 1
a b
rxpt  2  K  A 2  B 2
a b
rxpt 3  K  A3  B 3
a
rxpt 2 0.090  0.1 
  
rxpt 1 0.045  0.05 
 a 1
rxpt 3 0.720  0.2   0.1  b
   
rxpt  2 0.090  0.1  0.05 
b2
Therefore,
2
r  K  A B 
32. The major product of the following reaction is:
O Cl
(i) AlCl3,heat
O+
(ii)H2O
O
O
O
Cl
1. COOH Cl 2. O

Cl O Cl
COOH
3. O 4. O
Ans: 1
O Cl O
(i) AlCl3,heat
O+
(ii)H2O
COOH Cl
Sol: O
33. If solubility product of Zr3(PO4)4 is denoted by KSP and its molar solubility is
denoted by S, then which of the following relation between S and KSP is correct ?
1 1 1 1
7 9 6 7
 K sp   K sp   K sp   K sp 
1. S   2. S   3. S   4. S  
 6912   929   144   216 
Ans: 1
Sol: Zr3  PO4  4 s  3Zr aq4  4 Po43aq
Let “s” be the solubility, then
3 4
K sp   3s   4s 
K sp  6912 s 7
1/7
 K sp 
s
 6912 
34. Maltose on treatment with dilute HCI gives:
1. D – glucose and D-Fructose 2. D – glucose
3. D-Fructose 4. D-Galactose
Ans: 2
Sol: Maltose on treatment with dil.HCl gives D-glucose.
35. The IUPAC name of the following compound is:
CH3 OH
H3C CH CH CH2 COOH
1. 3-Hydroxy-4-methylpentanoic acid
2. 4,4-Dimethyl-3-hydroxybutanoic acid
3. 4-Methyl-3-hydroxypentanoic acid
4. 2-Methyl-3-hydroxypentan-5-oic acid

Ans: 1
CH3 OH
H3C CH CH CH2 COOH
3-hydroxy-4-methylpentanoic acid
Sol:
36. The quantum number of four electrons are given below:
1
I. n = 4 l=2 ml = -2 ms = 
2
1
II. n = 3 l=2 ml = 1 ms= 
2
1
III. n = 4 l=1 ml = 0 ms = 
2
1
IV. n = 3 l=1 ml = 1 ms = 
2
The correct order of their increasing energies will be:
1. IV > III > II >I 2. I > II > III > IV
3. I > III > II > IV 4. IV > II > III > I
Ans: 3
Sol: lower (n +l) value, and followed by lower ‘n’ value (aufbau rule)
IV < II< III< I
(3p)(3d) (4p) (4d)
37. Diborane (B2 H6) reacts independently with O2 and H2O to produce, respectively:
1. B2 O3 and H 3 BO3 2. H 3 BO3 and B2 O3

3. B2 O3 and  BH 4  4. HBO2 and H 3 BO3
Ans: 1
Sol: Diborane burns in O2 forming B2 O3
B2 H 6  3O2  B2O3  3H 2O
Diborane hydrolyses in water producing H 3 BO3
B2 H 6  6 H 2O  2 H 3 BO3  6 H 2
38. 100 mL of a water sample contains 0.81 g of calcium bicarbonate and 0.73 g of
magnesium bicarbonate. The hardness of this water sample expressed in terms of
equivalents of CaCO3 is: (molar mass of calcium bicarbonate is 162 g mol-1 and
magnesium bicarbonate is 146 g mol-1)
1. 1,000ppm 2. 100 ppm 3. 10,000 ppm 4. 5,000 ppm
Ans: 3

Sol: 162g of Ca HCO3   2

 100 gCaCO3
 
100 ml sample contain 0.81g of Ca HCO3 i.e., equal to 5g of CaCO3 / lit and 0.73 g
of Mg HCO3   2
per 100ml is equal to 5g of CaCO3 per lit. total hardness is 10g per
litre or 10,000 ppm
39. The correct order of hydration enthalpies of alkali metal ions is:
1. Li   Na   K   Cs   Rb  2. Na   Li   K   Rb   Cs 
3. Na   Li   K   Cs   Rb  4. Li   Na   K   Rb   Cs 
Ans: 4
Sol: Hydration enthalpies of alkali metal ions decrease down two group
40. For silver, CP( K-1 mol-1) =23 + 0.01T. If the temperature (T) of 3 moles of silver is
raised from 300 K to 1000 K at 1 atm pressure, the value of H will be close to :
1. 21kJ 2. 62kJ 3. 16kJ 4. 13kJ
Ans: 2
Sol: H   nc p dT
1000
  3   23  0.01T  dT
300
=62KJmol-1
41. The correct order of the spin-only magnetic moment of metal ions in the following
3 2
low- spin complexes, [V(CN)6]4- , [Fe(CN)6]4- ,  Ru NH 3 6     
and Cr NH 3 6  is
1. V 2  Cr 2  Ru 3  Fe 2 2. V 2  Ru 3  Cr 2  Fe 2
3. Cr 2  V 2  Ru 3  Fe 2 4. Cr 2  Ru 3  Fe 2  V 2
Ans: 1
Sol: V 2 has d 3 configuration of which all the 3 are unpaired electrons,
Cr 2 has d 4 configuration. On low spin the 4 electrons are arranged as one pair
and 2 unpaired electrons,
Ru 3 has d 5 configuration. In low spin the 5 electrons are arranged as 2 pairs ard 1
electron remain unpaired
Fe 2 has d 6 configuration. In low spin complex all the six electrons are paired so no
unpaired electrons
42. Coupling of benzene diazonium chloride with 1-naphthol in alkaline medium will
give:

OH
OH
N N
N N
1. 2.
OH
OH
N N N N
3. 4.
Ans: 1
OH N2Cl OH
+ Alkaline
medium
N N
Sol:
43. Which of the following amines can be prepared by Gabriel phthalimide reaction ?
1. n- butylamine 2. neo-pentylamine
3. t-butylamine 4. triethylamine
Ans: 1
Sol: Only primary amine can be prepared by Gabriel Pthalimide reaction with better
SN2.
44. Given that EO / H O  1.23V
2 2

E S O 2  / SO 2  2.05V
2 8 4

E Br2 / Br
 1.09V

E Au 3
/ Au
 1.4V The strongest oxidizing agent is:
1. Br2 2. O2 3. Au 3 4. S 2O82
Ans: 2
Sol: Strongest oxidizing agent may have higher reduction potential in standard state
45. Assertion : Ozone is destroyed by CFCs in the upper stratosphere.
Reason : Ozone holes increase the amount of UV radiation reaching the earth.

1. Assertion and reason are incorrect

2. Assertion is false, but the reason is correct
3. Assertion the reason is the correct explanation for the assertion
4. Assertion and reason are correct, but the reason is not the explanation for the
assertion
Ans: 4
Sol: Ozone is destroyed by CFCs , due to which ozone holes are formed. Through these
holes the amount u.v radiation reaching the earth increases
46. Adsorption of a gas follows Freundlich adsorption isotherm. x is the mass of the
x
gas adsorbed on mass m of the adsorbent. The plot of log versus log p is shown in
m
x
the given graph. is proportional to :
m
3 2
1. P 2
2. P 3 3. P 2 4. P 3
Ans: 4
x 1 x 1
Sol:  p n  log  log P
m m n
1 2

n 3
x
  p2 3
m
47. With respect to an ore, Ellingham diagram helps to predict the feasibility of its
1. Thermal reduction 2. Electrolysis
3. Zone refining 4. Vapour phase refining
Ans: 1
Sol: Ellingham diagrams are related to the G 0 values for the formation of oxides and
can be used for the thermal reduction of ores


OCH3
Conc.HBr(excess)
heat
CH2
Br OH
OH Br
Br Br
1. 2. Br CH3 3. 4. Br CH3
Ans: 4
OCH3 OH
Conc.HBr(excess)
heat
CH2 Br CH3
Sol:
49. In order to oxidise a mixture of one mole of each of FeC2O4, Fe2(C2O4)3, FeSO4 and
Fe2(SO4)3 in acidic medium, the number of moles of KMnO4 required is:
1. 1.5 2. 3 3. 2 4. 1
Ans: 3
Sol: FeC2O4, Fe2(C2O4)3, FeSO4 and Fe2(SO4)3 have valence factors as 3, 6,1 and 0 and
that of KMnO4 is 5. Therefore two moles of oxidizing agent is required
50. The following ligand is
1. tetradentate 2. bidentate 3. hexadentate 4. teidentate

Ans: 1
Sol: tetradentate

51. Which is wrong with respect to our responsibility as a human being to protect
our environment ?
1. Avoiding the use of floodlighted facilities
2. Setting up compost tin in gardens
3. Restricting the use of vehicles
4. Using plastic bags
Ans: 4
Sol: plastic bags are not biodegradable. So usage of plastic bags causes much harm to
environment
52. In the following compounds, the decreasing order of basic strength will be:
 
1. C 2 H 5
2
NH  NH 3  C 2 H 5 NH 2
2. C H 
2 5 2
NH  C2 H 5 NH 2  NH 3
3. C 2 H 5 NH 2  NH 3  C 2 H 5   2
NH
4. NH 3  C 2 H 5 NH 2  C H 
2 5 2
NH
Ans: 2
Sol: basic strength in aq.solution:(C2H5)2NH > C 2H5NH2> NH 3
53. The vapour pressures of pure liquids A and B are 400 and 600 mmHg, respectively
at
298 K. On mixing the two liquids, the sum of their initial volumes is equal to the
volume of the final mixture. The mole fraction of liquid B is 0.5 in the mixture. The
vapour pressure of the final solution, the mole fractions of components A and B in
vapour phase, respectively are:
1. 500 mmHg, 0.4, 0.6 2. 450 mmHg, 0.4, 0.6
3. 500 mmHg, 0.5, 0.5 4. 450 mmHg, 0.5, 0.5
Ans: 1
Sol: A and B forms ideal mixture
PT  PA0 X A  PB0 X B  500mm of H8
X A PA0
YA 

PB0  PA0  PB0 X A 

 0.5  400
600  200  0.5
200
  0.4
500
YB  1  YA  1  0.4  0.6
O
Br
NaBH4
MeOH,250C
OH
OMe OMe
1. 2.
OH
O
Br
3. 4.
Ans: 4
O
Br O
NaBH4
MeOH,250C
Sol:
55. Element ‘B’ forms ccp structure and ‘A’ occupies half of the octahedral voids, while
oxygen atoms occupy all the tetrahedral voids. The structure of bimetallic oxide is:
1. AB2 O4 2. A2 B2O 3. A2 BO4 4. A4 B2O
Ans: 1
1 1
Sol: B forms Fcc lattice per unit cell  8  6   4 Batoms
8 2
‘A’ occupies half the octahedral voids number of octahedral voids 1  4  4
Per Unit cell 2 A atoms
Per unit cell 8 O atoms
Formula of the compound A2 B4O8 i.e. AB2 O4

56. An organic compound neither reacts with neutral ferric chloride solution nor with
Fehling solution. It however, reacts with Grignard reagent and gives positive
iodoform test. The compound is :
OH
O O O
CH3 CH3
C 2H 5 H CH3 C 2H 5
CH3
1. O 2. O 3. OH 4. O
Ans: 4
Sol:
OH
gives postive iodoform
CH3
C 2H 5
reacts with grignard reagent
O
57. An organic compound ‘X’ showing the following solubility profile is:
Water
Insoluble
5%HCl
Insoluble
'X'
10%NaOH Soluble
10%NaHCO3
Insoluble
1. m – Cresol 2. Benzamide 3. Oleic acid 4. o-Toluidine

Ans: 1
Sol:
Water
Insoluble
OH
5%HCl
Insoluble
10%NaOH Soluble
H3C
m-cresol
10%NaHCO3
Insoluble

58. The size of the iso-electronic species Cl- ,Ar and Ca2+is affected by:
1. Nuclear charge
2. Principal quantum number of valence shell
3. azimuthal quantum number of valence shell
4. electron-electron interaction in the outer orbitals
Ans: 1
Sol: Isoelectone species contain same number of shells so their size is effected by the
nuclear charge
59. Which one of the following equations does not correctly represent the first law of
thermodynamics for the given processes involving an ideal gas? (Assume non-
expansion work is zero)
1. Isothermal process: q = -w 2. Cyclic process: q = -w
3. Isochoric process: U  q 4. Adiabatic Process: U   w
Ans: 4
Sol; For ideal gas
Isothermal process q = -w as U  0
For cyclic process  dq    dw as U  0

For isochoric process U  q w0
For adiabatic process U  w q  0
60. The lanthanide ion that would show colour is :
1. Lu 3 2. Sm 3 3. La 3 4. Gd 3
Ans: 2
Sol:    
La 3 f 0 , ba 3 f 7 and Lu 3 ( f 14 ) ions are colourless ions. Having exactly half
filled completely vacant and completely filled f – orbitals are colourless

MATHEMATICS
 1 x   2x 
61. If f  x   log e   , x  1, then f  2 
is equal to
1 x  1 x 
1. 2 f  x  4. 2 f  x
2

2. f  x   3. 2 f x 2 
Ans: 1
1 x   2x   1  x  2 
Sol: f  x   log e   f  2   log  2   2 f  x
 1 x  1 x  1  x  
 
62. All possible numbers are formed using the digits 1,1,2,2,2,2,3,4,4, taken all at a time.
The number of such numbers in which the odd digits occupy even places is:
1. 160 2. 162 3. 175 4. 180
Ans: 4
3 6
Sol: No. of ways  4C3    180
2 42
2  x cos x
63. If f  x  and g  x   log e x , (x>0) then the value of the integral
2  x cos x

4

 g  f  x  dx is:
4
1. log e 3 2. log e 1 3. log e 2 4. log e e

Ans: 2
  
4 4 4
 2  x log x   2  x cos x 
Sol;
I  g  f  x   dx    2  x cos x    2  x cos x dx   I  I  0
log  dx  log

  
4 4 4
The sum of the series 2. C0  5. C1  8. C 2  ........  62. 20C20 is equal to

20 20 20
64.
1. 2 23 2. 2 24 3. 2 26 4. 2 25
Ans: 4
20
20 20 19 25
Sol: S    2  3r  Cr  2.2  3.20.2  2
r 0
65. Let A and B be two non-null events such that A  B . Then, which of the following
statements is always correct?
1. P  A | B   P  B   P  A  2. P  A | B   1
3. P  A | B   P  A  4. P  A | B   P  A 

Ans: 4
p  A  R  P  A
Sol: A  B  P  A / B    P  A
PB P B
66. The magnitude of the projection of the vector 2i  3 j  k on the vector
perpendicular to the plane containing the vectors i  j  k and i  2 j  3k is
3 3
1. 2. 3 6 3. 6 4.
2 2
Ans: 4
3
Sol:  i  j  k    i  2 j  3k   i  2 j  k  RV 
2
67. The sum of all natural numbers ‘n’ such that 100 < n < 200 and H.C.F. (91, n) > 1 is:
1. 3303 2. 3121 3. 3203 4. 3221
Ans: 2
Sol: Given numbers are 101, 102, 103, …..199
Req. value = sum of numbers divisible by 7+sum of numbers divisible by 13-sum of
numbers divisible by 91
14 8
   98  7r     91  13r   182  3121
r 1 r 1
68. Let y = y(x) be the solution of the differential equation,

2 dy 
x 2
1  dx
 
 2 x x 2  1 y  1 such that y(0)=0. If a y 1 
32
, then the value of
‘a’ is:
1 1 1
1. 2. 1 3. 4.
4 16 2
Ans: 3
2x
dy 2 xy 1  2 dx
Sol;  2  2  I .F  e 1 x  x 2  1
dx x  1 x  1
1

 y x2  1   2
x 1

dx  tan 1  x   c & y  0 0  c  0
 1
 2 y 1   a 
4 16
69. The shortest distance between the line y = x and the curve y 2  x  2 is
11 7 7
1. 2. 3. 2 4.
4 2 8 4 2

Ans: 4
1 7
Sol: Eq. of tangent to y 2  x  2 , which is parallel to y =x is y  x  2   y  x
4 4
7
 S .D 
4 2
3 5 
70. If cos      ,sin      and 0   ,   , then  2  is equal to
5 13 4
63 33 63 21
1. 2. 3. 4.
16 52 52 16
Ans: 1
3 4 5 5
Sol: cos       tan      ,sin       tan     
5 3 13 12
4 5

tan  2   tan          3 12  48  15  63
4 5 36  20 16
1
3 12
 cos   sin     R  32  0 1
71. Let A    , such that A  1 0  then a value of  is
 sin  cos    
  
1. 0 2. 3. 4.
32 16 64
Ans: 4
 cos   sin   2  cos 2  sin 2  3  cos3  sin 3 
Sol: A   A   sin 2 cos 2   A   sin 3
 sin  cos      cos3 
cos 32  sin 32   0 1 
A32       
 sin 32 cos 32   1 0  64
72. If S1 and S 2 are respectively the sets of local minimum and local maximum points of
the function, f  x   9 x 4  12 x 3  36 x 2  25 , x  R , then:
1. S1  1 ; S 2  0, 2 2. S1  2,1 ; S 2  0
3. S1  2 ; S 2  0,1 4. S1  2,0 ; S 2  1
Ans: 2
Sol;
f '  x   36 x 3  36 x 2  72 x  36 x  x 2  x  2   36 x  x  1 x  2 
 S1   2,1 , S 2   0

73. The mean and variance of seven observations are 8 and 16, respectively. If 5 of the
observations are 2,4,10,12,14, then the product of the remaining two observations is:
1. 48 2. 45 3. 40 4. 49
Ans: 1
Sol; Let the remaining numbers are a,b
a  b  42 a 2  b 2  460
 8  a  b  14,  64  16  a 2  b 2  100
7 7
 a, b  6,8  ab  48
74. A point on the straight line, 3x+5y=15 which is equidistant from the coordinate axes
will lie only in
1. 1st and 2nd quadrants 2. 1st quadrant
3. 1st ,2nd and 4th quadrants 4. 4th quadrant
Ans: 1
Sol: req.point lies on y=x or x + y = 0
 15 15   15 15 
,
Req.point is  8 8   or   , 
 2 2
75. The sum of the squares of the lengths of the chords intercepted on the circle,
x 2  y 2  16 , by the lines, x + y = n, n  N , where N is the set of all natural
numbers, is:
1. 210 2. 105 3. 160 4. 320
Ans: 1
5
Sol: l 2
 2  32  n 2   210
n1
76. The contra positive of the statement “If you are born in India then you are a citizen
of India” is
1. If you are not born in India, then you are not a citizen of India
2. If you are born in India, then you are not a citizen of India
3. If you are not a citizen of India then you are not born in India
4. If you are a citizen of India then you are born in India
Ans: 3
Sol: If you are not a citizen of India then you are not born in India
77. The sum of the co-efficient of all even degree terms in x in the expansion of
6 6
x    
x  1  x  x  1 ,  x  1 is equal to:
3 3
1. 32 2. 24 3. 29 4. 26
Ans:2

Sol:
    
2

2 6C 0 x 6  6C 2 x 4 x 3  1  6C 4 x 2 x 3  1  6C 6 x 3  1 
3

Sum of coefficient of even powers of x = 2 6C0  6 C2  2  6C4  3 6C6  6C6  24 
78. If  and  be the roots of the equation x 2  2 x  2  0 , then the least value of n for
n

which    1 is:
 
1. 3 2. 4 3. 2 4. 5
Ans: 2
Sol;  x  1 2  1  i 2  x  1  i
n n
 1 i
      in  1  n  4
  1 i
79. The equation of a plane containing the line of intersection of the planes 2x – y – 4 = 0
and y + 2z – 4 = 0 and passing through the point (1 , 1, 0) is:
1. x – 3y -2z = -2 2. x – y – z = 0 3. 2x – z = 2 4. x + 3y + z = 4
Ans: 2
x4 y4 z
Sol; Eq of the line is  
1 2 1
x 1 y 1 z
Eq of plane is 3 3 0 0 x yz 0
1 2 1
sin 2 x
lim
80.
x 0 2  1  cos x equals:
1. 2 2 2. 4 3. 4 2 4. 2
Ans: 3
sin 2 x x2
Sol; lim
x 0
 lim
2  1  cos x x 0 1  cos x
 
2  1  cos x  2  2 2  4 2
81. The length of the perpendicular from the point (2, -1, 4) on the straight line,
x3 y2 z
  is:
10 7 1
1. Less than 2 2. greater than 3 but less than 4
3. Greater than 4 4. greater than 2 but less than 3
Ans: 2

x3 y2 z
Sol;   
10 7 1
10  3,  7  2,  
 2, 1, 4
Dr’s 10  5,  7  3,   4
10 10  5  7  7   3  1   4  0
1

2
50
perpendicular distance =  3, 4
4
82. Let O(0,0) and A(0,1) be two fixed points. Then the locus of a point P such that the
perimeter of AOP is 4, is:
1. 9 x 2  8 y 2  8 y  16 2. 8 x 2  9 y 2  9 y  18
3. 8 x 2  9 y 2  9 y  18 3. 9 x 2  8 y 2  8 y  16
Ans: 4
Sol: OP  AP  OA  4  OP  AP  3 , locus of P is an ellipse and eq. to the locus is
 1
2  y 
x  2
 1
 8  9
   
4 4
83. The greatest value of c  R for which the system of linear equations
x –c y –c z = 0
cx - y + c z = 0
cx + cy – z = 0 has non – trivial solution, is:
1
1. -1 2. 0 3. 4. 2
2
Ans: 3
1 c c
Sol: c 1 c 0
c c 1
2 1 1
 2c 3  3c 2  1  0   c  1  c    0  c  1,
 2 2

84. The area (in sq. units) of the region

A   x, y   R  R | 0  x  3, 0  y  4, y  x 2  3 x} is:
59 53 26
1. 2. 3. 8 4.
6 6 3
Ans: 1
1
x 
2
Sol:  3x dx  8
0
59

6
 3  1 
85. If   cos 1   ,   tan 1   , where 0   ,   , then    is equal to:
  5   3 2
1  9  1  9  1  9  1  9 
1. tan   2. tan   3. sin   4. cos  
 5 10  14  5 10   5 10 
Ans: 3
 4 1 
4 1 1
 33  1  9 
Sol; tan   , tan        tan   tan
3 3 4 1  
 13 
1 . 
 3 3
86. Let f:[0, 2]  R be a twice differentiable function such that f’’(x)>0, for all
x   0, 2  . If   x   f  x   f  2  x  , then  is:
1. Increasing on (0, 1) and decreasing on (1, 2)
2. Decreasing on (0, 1) and increasing on (1, 2)
3. Decreasing on (0, 2)
4. Increasing on (0, 2)
Ans: 2
Sol: f ''  x   0  f’(x) is increasing in [0,2].
  x  f  x  f  2  x   '  x  f '  x  f '  2  x
For x   0,1  x  2  x  f '  x   f '  2  x    '  x   0

For x  1, 2  x  2  x   '  x   0
87. The sum of the solutions of the equation x 2  x  

x  4  2  0,  x  0 is
equal to:
1. 10 2. 4 3. 12 4. 9
Ans: 4
2
Sol: x 2  x  
x  4  2   x 2   x 2 20
 x  2  1  x  3 or 1  x  1 or 9
2
  3 cos x  sin x     dy
88. If 2 y   cot 1   , x   0,  then is equal to:
  cos x  3 sin x   2 dx
   
1. x  2. x 3. 2 x  4. x
6 3 3 6
Ans: 1
2
  3 cos x  sin x    
Sol: 2 y   cot 1    , x   0, 
   2
  cos x  3 sin x  
2
  dy 
 2 y    x   x
6  dx 6
89. If the tangents on the ellipse 4 x 2  y 2  8 at the points (1, 2) and (a, b) are
perpendicular to each other, then a 2 is equal to:

64 2 4 128
1. 2. 3. 4.
17 17 17 17
Ans: 2
Sol: Eq. of tangent at (1, 2) is 4x+2y=8  2 x  y  4  m1  2
Eq.of tangent (a, b) is 4 2 cos  x  2 2 sin  y  8
1 2
 m2   2 cot   tan   4  a 2 
2 17

5x
sin
2 dx is equal to:
90.  x
sin
2
(Where c is a constant of integration)
1. x + 2 sinx + 2 sin2x + c 2. 2x + sinx + sin2x + c
3. 2x + sinx + 2 sin2x + c 4. x + 2 sinx + sin2x + c
Ans: 4
5x
sin
2 dx  sin 3 x  sin x dx 
Sol; 
  sin x   
3  4sin 2 x   2cos x dx 
sin
2
 x  sin 2 x  2sin x  c
... Prepared by Sri Chaitanya Faculty


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2019_Apr_Jee-Main Question Paper_Key & Solutions

2019_Jee-Main Question Paper_Key & Solutions

Sri Chaitanya IIT Academy

Sri Chaitanya IIT Academy

The current Iz through the Zener is:

Sri Chaitanya IIT Academy

Sri Chaitanya IIT Academy

1. 3.3 2.2.7 3. 3.7 4. 2.3

14. A solid conducting sphere, having a charge Q, is surrounded by an uncharged

1. 5000 2. 1000 3. 50000 4. 10000

Sri Chaitanya IIT Academy

Sol: mLv  150  m  L f

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Sri Chaitanya IIT Academy

Ans: Bonus. No answer.

1. 45000 2. 55000 3. 66000 4. 57000

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Sri Chaitanya IIT Academy

Sri Chaitanya IIT Academy

Sri Chaitanya IIT Academy

Sri Chaitanya IIT Academy

Sol: 162g of Ca HCO3   2

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Sri Chaitanya IIT Academy

1. Assertion and reason are incorrect

Sri Chaitanya IIT Academy

48. The major product of the following reaction is:

1. tetradentate 2. bidentate 3. hexadentate 4. teidentate

Sri Chaitanya IIT Academy

Sri Chaitanya IIT Academy

1. m – Cresol 2. Benzamide 3. Oleic acid 4. o-Toluidine

Sri Chaitanya IIT Academy

For cyclic process  dq    dw as U  0

filled completely vacant and completely filled f – orbitals are colourless

Sri Chaitanya IIT Academy

1. log e 3 2. log e 1 3. log e 2 4. log e e

The sum of the series 2. C0  5. C1  8. C 2  ........  62. 20C20 is equal to

Sri Chaitanya IIT Academy

68. Let y = y(x) be the solution of the differential equation,

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Sri Chaitanya IIT Academy

Sri Chaitanya IIT Academy

Sri Chaitanya IIT Academy

Sri Chaitanya IIT Academy

84. The area (in sq. units) of the region

For x   0,1  x  2  x  f '  x   f '  2  x    '  x   0

Sri Chaitanya IIT Academy

For x  1, 2  x  2  x   '  x   0

87. The sum of the solutions of the equation x 2  x  

perpendicular to each other, then a 2 is equal to:

Eq.of tangent (a, b) is 4 2 cos  x  2 2 sin  y  8

Sri Chaitanya IIT Academy

... Prepared by Sri Chaitanya Faculty

Sri Chaitanya IIT Academy

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