Beruflich Dokumente
Kultur Dokumente
into
particle measurement
Prof. Dr.-Ing. Jörg M. Hoffmann
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 1
Content - 1
1 What are particles?
2 Aims of measurements
3 Definition of the size of particles
3.1 Spheric shape
3.2 Equivalent diameter
3.3 Example for different results
3.4 Often used equivalent diameters
4 Presentation of results
4.1 Frequency attributes
4.2 Example for Number and Mass distribution
4.3 Primary result
4.4 Different displaying
5 How to display practically the results
5.1 Estimation of the number of classes
5.2 Important single Parameters of a (Normal-) Distribution: mean
5.3 Important single Parameters of a (Normal-) Distribution: standard deviation
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 2
Content - 2
5.4 Mean error of a single measurand
5.5 Average error of the mean
5.6 Example for drawing a histogram / cumulative histogram
5.7 Hot points and conclusions
6 Measurement of fine dust
6.1 Euro standards and limits
6.2 Typical measurement principles
6.2.1 Gravimetric principles
6.2.2 Photometric principles
6.2.3 Condensation nucleus counters
6.2.4 Aerosol electrometer
6.3 PMG19-01
6.4 Results
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 3
1 What are particles?
At least one material is distributed in another material
For the distributed matter (particles) as well as the connected matter are all
states of aggregation possible.
Examples:
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 4
2 Aims of measurements
● Particle speed
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 5
3 Definition of the size of a particle
Different kind of Pollen
What is the size of a particle?
hawkbit
Fir tree
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 6
3.1 Spheric shape
To describe the size of a particle with only one parameter (the diameter) is
only possible for a completely spheric ball!
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 7
3.2 Equivalent diameter
The size of a particle is defined according to a ball with the same behaviour:
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 8
3.3 Example for different results
Every measurement principle is measuring according to a different
equivalent diameter
Example: particle: Cylinder Ø 100 µm, h=200 µm
And so on!
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 10
4 Presentation of results
Particle size spectrum:
A used
frequency
Attribute
in %
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 11
4.1 Frequency attributes
Mostly used are the number distribution and the volume distribution
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 13
4.3 Primary result
The primary result is depending from the measurement method:
Single particle counting measurements (e.g. scattering light, light blockade) determine
the total number and the number per class by counting.
A calculation into a mass distribution is only possible with the assumption of a spheric
shape of all particles and a equal density. Both is mostly not given.
Gravimetric measurement methods (e.g. sieve analysis) determine the total mass and
the masses per class, e.g. by a balance after separation.
A calculation into a number distribution is only possible with the assumption of a spheric
shape of all particles and a equal density. Both is mostly not given.
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 14
4.4 Different displaying
Histogram Cumulative Histogram
A used A used
frequency frequency
Attribute Attribute
in % in % 100
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 15
5 How to display practically the results
●
The range, in which are the measurands, is to divided in intervals with the
same width ΔY. This intervals (classes) i will dedicated the number of
measurands, which have a value of this range. This is the absolute
frequency Habsi, that means the number of measurands per class.
●
The absolute frequency of a class, divided through the total number of
measurements n is the relative frequency Hi:
ni
H i=
n
●
If the class widths are unequal, is the relatively frequency of the classes to
dividing through the width of each class. This leads to the relatively
frequency, standardised to the class width:
ni
H i=
nYi
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 16
5.1 Estimation of the number of classes
Recommended value for the number of classes: k≈ √ n
Example: It is to draw a histogram with 10.000 measurands.
The number of classes should be roughly: k≈ 10.000=100
Histogram:
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 17
Cumulative histogram
The empirical cumulative histogram S can be calculated by summation of the
relatively frequencies, starting with the lowest class:
n
S (Y ) k i
i1 n
There fore is S (Y ) Y Y 1
max
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 18
5.2 Important single Parameters of a
(Normal-) Distribution: mean
The mean of a sample is the estimation of the expected value of the mean
N→ꝏ
~
µ
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 19
5.3 Important single Parameters of a
(Normal-) Distribution: standard deviation
Normal distribution (Gaussian distribution):
1 N
Mean: Y *Y i
N i 1
1 N
Sample variance: s2 * (Y i Y ) 2
N 1 i 1
N
Experimental 1
standard deviation: s * (Y i Y ) 2
N 1 i 1
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 20
Develop of the standard deviation
Squares of deviations:
2
Y
Y
i
1 N 2
2
S = (Yi Y )
N 1i 1
Root from the mean of the squared
deviations:
Explanation of N-1
5 1 N 2
Explanation of checking: 6 S= (Yi Y )
7
N 1 i 1
Y=6
S = 1.0
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 21
5.4 Mean error of a single measurand
So as Y is the estimation of µ, so S is the estimation of σ
The single standard deviation σ means, that a single measurand is in the range of
μ + 1σ with a probability of 68,3%, or with other words:
68,3% of the measurands are in the range of μ + 1σ
95,5% of the measurands are in the range of μ + 2σ
99,73% of the measurands are in the range of μ + 3σ
For enough big N this context
is also nearly valid for S and Y :
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 22
5.5 Average error of the mean
The Factor t:
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 23
5.6 Example for drawing a histogram /
cumulative histogram
Measured particle Frequency With a device with a resolution of 1µm
size in μm was measured the diameter of 80
33 1 particles.
34
35
36 2 Please calculate and draw:
37 1
● The relatively frequency as empirical
38 7 histogram
39 6
40 7 ● The relatively frequency as empirical
41 11 cumulative histogram
42 14
43 12 ● The mean
44 4
45 13 ● The empirical standard deviation
46
47 2
48
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 24
Decisions and calculations
j ≈ √ 80 ≈ 9 → better j = 8, because then 2 old classes = one new class, ∆xj = 2 µm
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 25
Calculated histogram
H(Y)
30
25
20
15
10
103,25
32.5 103,65
36.5 104,05
40.5 104,45
44.5 104,8548.5 d/um
34.5
103,45 38.5
103,85 42.5
104,25 46.5
104,65
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 26
Calculated cumulated histogram
S(Y)
100
90
80
70
60
Y = 41.68 µm 50
40
30
20
S = 2.68 µm 10
103,25
32.5 103,65
36.5 104,05
40.5 104,45
44.5 104,85
48.5 d/um
34.5
103,45 38.5
103,85 42.5
104,25 46.5
104,65
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 27
5.7 Hot points and conclusions
● Every particle measurement device is measuring according to a special principle.
The principles are very different.
● With the principle is fixed, according to which size criteria (equivalent diameter)
the size of the particles will be determined.
● Calculations from results from one principle to results, received with another
principle are only possible with some assumptions (e.g. fixed form factor, equal
density and so on). This is normally not the case in practise.
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 28
6 Measurement of fine dust
Sizes of particles:
Nebel
fog Sprüh-
mizzle
Farbnebel
colour fog regen
smoke
Rauch Regen-
rain
toba- tropfen
Tabak- drops
cco
rauch
smoke Coarse dust
Grob-Staub
Fine dust
Fein-Staub
(Lungengängig)
(respirable)
sand
Sand
Viren Bakte-
bacil-
virus
rien
lus Kies
grit
Macro-
Makro- flour
Mehl
molecules
moleküle Farb-
colour
pigmente
pigments
(Licht!)
(light)
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 29
Examples for fine dust
Examples: ● Fog
● Pollen
● Laser printer toner
● Smoke (tobacco and other sources)
● Viruses
● Bacillus
● Soot
● Dust from streets
● Abrasion from tires (rubber) ...
Traffic is not the only one source of fine dust. Further sources are:
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 30
Dangerousness of fine dust
Not all particles are dangerous! Its depending from material, shape and so on.
Three examples:
● Salt or salty water drops in the air at the coast line have a positive
influence to many peoples health.
● The smallest pollen from flower are also in the range of fine dust. That´s no problem for
the most of the people, but not for people with pollen allergy!
● Fine dust from combustion processes are mostly harmful to health. Cars produce not
only this particles – they produce also fine dust as abrasion from rubber and swirl dust
from the street. Many other sources (mostly human made) produce also harmful fine dust.
Lung respirable dangerous particles can be the reason for:
● Different kinds of lung diseases
● Cardiac infarction
● Cancer
● Stroke ...
Ultra fine particles (less than 0.1 µm) are cell respirable! The mass plays nearly no role.
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 31
6.1 Euro standards and limits
For cars in mass per km:
Euro 1 (1993): 140 mg Particle / km
Euro 2 (1997): 80/100 mg Particle / km (80 at no direct injection, 100 at direct injection)
Euro 3 (2001): 50 mg Particle / km
Euro 4 (2005): 25 mg Particle / km
Euro 5 (2009): 5 mg Particle / km
Euro 6 (2014): 4,5 mg Particle / km
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 32
Problems at filtering
without filter
→ Mass
→ Number
→
→
→
with filter
Mass ↓
p↑ Number ↑
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 33
6.2 Typical measurement principles
● Gravimetric principles
● Photometric principles
● Aerosol-electrometer
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 34
6.2.1 Gravimetric principles
input
(Cascade-) impactor
0.0 0 0 µg
filter balance
output
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 35
6.2.2 Photometric principles
receiver
Can be:
Photo Multiplayer
Phototransistor
Photo diode ...
Collection system
projection system
Sample input
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 36
Determination of spectrum
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 37
6.2.3 Condensation nucleus counters
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 38
Measurement of ultra fine particles
● Ultra fine particles (UFP) are defined as particles less than 0.1 µm
● They contribute nearly not to the mass, but contains a high number
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 39
6.2.4 Aerosol electrometer
Corona voltage
Aerosol input
Particle charger
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 40
6.3 PMG19-01
Measurement of:
● Date (deliver from an internal real time clock) in Y – M – D
● Time (deliver from an internal real time clock) in h : m : s
● Longitude
● Attitude
● PM10 in µg/m3
● PM2.5 in µg/m3 ● Minimal sample rate: 1 second
● Air Quality (in OHM) ● Running time with rechargeable battery: 18h
● Temperature in °C ● Displaying of the results in real time
● Air humidity in rel% ● Storage of the results as csv - file
● Air pressure in hPa
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 41
Sensor SDS011
UART connection
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 42
Sensor BME680
Measures:
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 43
Internal wiring of PMG19-01 2 x frei
I2C
5 x I2C/UART Steckplätze
Display UART
I2C
SD011
UART
RTC
Cinch Cinch
Raspberry Pi Zero
5V
HDMI-mini µ-USB µ-5V
I2C BME680
µ-USB µ-USB
USB-A Stecker Stecker
GPS
Schalter:
- Akku USB-A Akku
- Aus
µ-USB
- Netz
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 44
Device PMG19-01
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 45
Further work,
replacement of the particle sensor
By the sensor SPS30 from Sensirion (Switzerland)
Original size: 40 mm x 40 mm x 12 mm
Front side Back side
Measures:
PM10 as mass concentration and number concentration
PM04 as mass concentration and number concentration
PM2.5 as mass concentration and number concentration
PM1.0 as mass concentration and number concentration
PM0.5 as number concentration (no mass concentration)
Minimum size is 0.3 µm
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 46
Adaption of the SPS30 sensor
inlet
inlet
outlet
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 47
Further work: software tasks
● Introduction of the calculation of an Air quality index
(That is currently the task for two students from UTHM)
● Calibration of temperature
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 49
6.4 Results
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 50
2
Result: 2 candles in a 15m kitchen
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 51
Result: Fireworks from 2018 to 2019
Fine dust concentrationSilvester
Feinstaubbelastung at New Year 2018
2018 / 2019
/ 2019
atan
the position
der Position 52,247195 / 7,963868333
300
250
µg/m3
PM10
PM2,5
200
Fine dust concentrationin µg/m3 in
150
Feinstaubkonzentration
100
50
0
7 1 4 7 1 4 7 0 3 7 0 3 6 9 2 6 9 2 6 9 2 5 9 2 5 8 2 5 9 2 6 9 2 5 8 2
1:5 3:2 4:4 6:0 7:3 8:5 0:1 1:4 3:0 4:2 5:5 7:1 8:3 9:5 1:2 2:4 4:0 5:3 6:5 8:1 9:4 1:0 2:2 3:5 5:1 6:3 8:0 9:2 0:4 2:1 3:3 4:5 6:2 7:4 9:0 0:3
:1 :4 :1 :4 :1 :4 :2 :5 :2 :5 :2 :5 :2 :5 :3 :0 :3 :0 :3 :0 :3 :1 :4 :1 :4 :1 :4 :1 :5 :2 :5 :2 :5 :2 :5 :3
16 16 17 17 18 18 19 19 20 20 21 21 22 22 23 00 00 01 01 02 02 03 03 04 04 05 05 06 06 07 07 08 08 09 09 10
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 52
Result: Zoom into fire work
Peakafter
Peak nachmidnight
Mitternacht
250
in µg/m3
Mid night
Mitternacht PM10
PM2,5
200
Fine dust concentration
in µg/m3
150
Feinstaubkonzentration
100
50
0
04 16 28 41 53 05 17 30 42 54 06 19 31 43 56 08 20 33 45 57 09 22 34 46 59 11 23 35 48 00 12 24 37 49 01 13 26 38
45: 46: 47: 48: 49: 51: 52: 53: 54: 55: 57: 58: 59: 00: 01: 03: 04: 05: 06: 07: 09: 10: 11: 12: 13: 15: 16: 17: 18: 20: 21: 22: 23: 24: 26: 27: 28: 29:
: : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : :
23 23 23 23 23 23 23 23 23 23 23 23 23 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00
Time in h:m:s
Zeit
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 53
Result: Air quality resistance in a
2
15m sleeping room (one person)
Air quality sleeping room VOC in OHM
9000000
8000000
Open the window
7000000
6000000
5000000
Air quality in OHM
4000000 Luftqualität
3000000
2000000
1000000
0
2 9 6 2 9 6 3 0 7 3 0 7 4 1 8 4 1 8 5 2 8 5 2 9 6 3 9 6 3 0 7 4 0 7 4 1
5:4 5:5 6:1 6:3 6:4 7:0 7:2 7:4 7:5 8:1 8:3 8:4 9:0 9:2 9:3 9:5 0:1 0:2 0:4 1:0 1:1 1:3 1:5 2:0 2:2 2:4 2:5 3:1 3:3 3:5 4:0 4:2 4:4 4:5 5:1 5:3
:0 :1 :2 :3 :4 :5 :0 :1 :2 :3 :4 :5 :0 :1 :2 :3 :5 :0 :1 :2 :3 :4 :5 :0 :1 :2 :3 :4 :5 :0 :1 :2 :3 :4 :5 :0
02 02 02 02 02 02 03 03 03 03 03 03 04 04 04 04 04 05 05 05 05 05 05 06 06 06 06 06 06 07 07 07 07 07 07 08
time
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 54
That´s it!
Prof. Dr.-Ing. Jörg M. Hoffmann University Tun Hussein Onn Malaysia Slide 55