Desi Wulandari

160332605877
Offering I

3. Diket: [𝐴0 ] = 1.352 M

t/s 0 1800 3600 5400 7800 10800
sucrose
0 0.1350 0.2626 0.3737 0.5028 0.6312
inverted / M

Orde 1
1 [𝐴0 ]
𝑘= 𝑙𝑛
𝑡 [𝐴]
1 1.352
𝑘= 𝑙𝑛
1800 𝑠 [1.352 − 0.1350]
1 1.352
𝑘= 𝑙𝑛
1800 𝑠 1.217
𝑘 = 5.84 x 10−5 𝑠 −1

4. Diket: [NaOH]0 = 0.0511 M

[HCl] = 0.0668 M
V HCl = 10 cm3

NaOH titrat NaOH titrat [NaCl]tertitrasi =

t/s [HCl]sisa / M 1 / [NaOH]
/ cm3 / dm3 [NaOH]
600 4.03 0.00403 0.0205933 0.0462067 21.6418831
1500 5.11 0.00511 0.0261121 0.0406879 24.57733134
2400 5.98 0.00598 0.0305578 0.0362422 27.59214396
3600 6.86 0.00686 0.0350546 0.0317454 31.50062686
4800 7.57 0.00757 0.0386827 0.0281173 35.56529254
6600 8.36 0.00836 0.0427196 0.0240804 41.52754938
 Orde 2:
1 1 1
 𝑘 = 𝑡 ([𝐴] − [𝐴 ])
0

1 1 1
𝑘= ( − )
600 𝑠 0.0462067 0.0511
𝑘 = 3.45 x 10−3 𝑠 −1
1 1 1
 𝑘 = 𝑡 ([𝐴] − [𝐴 ])
0

1 1 1
𝑘= ( − )
1500 𝑠 0.0406879 0.0511
𝑘 = 3.34 x 10−3 𝑠 −1
1 1 1
 𝑘 = 𝑡 ([𝐴] − [𝐴 ])
0

1 1 1
𝑘= ( − )
2400 𝑠 0.0362422 0.0511
𝑘 = 3.34 x 10−3 𝑠 −1
1 1 1
 𝑘 = 𝑡 ([𝐴] − [𝐴 ])
0

1 1 1
𝑘= ( − )
3600 𝑠 0.0317454 0.0511
𝑘 = 3.31 x 10−3 𝑠 −1
1 1 1
 𝑘 = 𝑡 ([𝐴] − [𝐴 ])
0

1 1 1
𝑘= ( − )
4800 𝑠 0.0281173 0.0511
𝑘 = 3.33 x 10−3 𝑠 −1
1 1 1
 𝑘 = 𝑡 ([𝐴] − [𝐴 ])
0

1 1 1
𝑘= ( − )
6600 𝑠 0.0240804 0.0511
𝑘 = 3.33 x 10−3 𝑠 −1
 Maka 𝑘 𝑟𝑎𝑡𝑎 − 𝑟𝑎𝑡𝑎 = 3.35 x 10−3 𝑠 −1
5. Data:
t/h 0 0.167 0.516 1.23 2.21
A (𝞴 = 260 nm) 0.406 0.382 0.338 0.255 0.184

Orde 1
1 [𝐴0 ]
𝑘= 𝑙𝑛
𝑡 [𝐴]
1 0.406
𝑘= 𝑙𝑛
0.167 ℎ 0.382
1 0.406
𝑘= 𝑙𝑛
601.2 𝑠 0.382
𝑘 = 1.01 x 10−4 𝑠 −1