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CONCEPT RECAPITULATION TEST – IV
JEE (Advanced)-2019
PAPER – 2

ANSWERS, HINTS & SOLUTIONS


Physics PART – I

SECTION – A
1. A
Sol. In CM frame both the mass execute SHM with
k 2k
  SHM
 m
Initially particles are at extreme
2k
Distance = L0  ( L  L0 ) cos t
m

2. C
 F-(m+M)g sinθ 
Sol. a=  
 (m+M) 
So, f=ma cos
 F-(m+M)g sinθ 
a= 
(m+M)  m cos 
 
3. B
Sol. a B =2m/s 2 ()
   x3    x2  x3   k1
& x3  3 x4  k2
a2 12
a2  2a3  0  a3    6m / s 2
2 2

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AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 2

[a3  acceleration of P1 pulley]


a 6
 a3  3a4  0  a4  3   2m / s 2
3 3
[a4  acceleration of block B]

4. ABCD
Sol. The above lens mirror combination is an equivalent converging mirror.

5. AC
Sol. f=mg sinθ and PE sin =mg sin .R
q 2 R Esinθ=mg sinθ R
mg
E=
2q

6. ABCD

4r
K rdr R
Sol. (A) v=  2 
0 2
r  (3R) 2 4 0

K rdr
4r
2 R
(B) v=  
0 r 2 0

7. BD
Sol. External electric field and induced charge on outer surface of the sphere will produce a net zero
field inside it. Net field at P must be vertically upward.

8. ACD
Sol. PC -PR =2BAK S=A sin(kx- t)

9. D
10. A
Sol. (for Q. 9 to Q.10)
Let the initial temperature, pressure and volume of gas in ‘A’ be
T0 , P0 ,V0 and the area of the position A and B be a, 2a. Now gas in chamber ‘A’ undergoes
adiabatic compression whereas gas in chamber ‘B’ undergoes isothermal expansion.
Now solving for gas in ‘A’
γ γ
P1A V1A  P2A V2A  P0 V0γ =P2A (0.25V0 )  P2A =8P0
Solving for gas in ‘B’
P1B V1B =P2B V2B  P1B V0 =P2B ×2.5V0  P2B =0.4P1B
Also (P2A ×a)=(P2B ×2a) for gas is chambers 'B'

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3 AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

 8P0 a  P2  2a  P2  4 P0
 0.4 P1 =4P0  P1  10P0
Now comparing the moles of gas in A and B
P0 V0
nA =
RT0
10P0 V0
nB = =10n A
RT0
m B =10m A =10×100gm=1kg
Again for gas is A,ΔQ=ΔU+ΔW
 0  ΔU+ΔW
 V0 
0 0  8 P0 
 PV
 0  ΔU   4

 (  1) 
 
 ΔU=2P0 V0 =2×105 ×10-2 =2000J
F=8P0 a=8×105 ×10-2 =8000N

SECTION – C

11. 7
 v12  v2
Sol. P0   0  PA   gh  2
2 2
 V2  2g  5  10  V1 
 ρv12 ρv 22 
 -  -ρgh=  PA -P0 
 2 2 
ρv2
 PA -P0   -ρgh- 2
2
3
10 103 10  10 7
  10  2      104
2 2 1 2
7 7
 - ×105 N/m 2   atm
20 20
12. 2
Sol. The minima will be heard at P when a crest from S1 and a trough from S2 reach there at the same
time. This will happen if L1 – L2 is λ/2 or λ+  λ/2  or 2λ+  λ/2  and so on. Hence, the increase
in L1 between consecutive minima is 1 and from the data we see that λ=0.40m .
Then λ=v/f  f=340/0.40=850Hz .

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AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 4

13. 6

Sol. X CM 
 dm.x  2 L
 dm 3
Mass of rod;
L 10 3
M   0 x dx 
0 2
Torque about ‘O’;
L 2L
FB cos37 o -Mg cos 37o =TL cos 37o
2 3
1 1 104 2
103 π   ×10 - × =T
π 2 2 3
10 4
T= N
6
14. 1
Sol. V0sin30o =V1cos30 o (i )
o o
eV0 cos 30 =V1sin 30 (ii )
Dividing (i) & (ii)
1 1 1
tan30o = =3
e tan30o e

15. 8
Sol. f=2N
a1Kg=2m/s 2
1
S= ×2×4=4m
2
Wfriction =-2×4=-8J
16. 4
Sol. Since the rod is in translation so   0
 about O,
 
F sin   N cos   0
2 2
 F sin   N cos 
N
 tan        (1)
F
Also, N  Mg    (2)
Mg 40 2
So,  tan    
F 60 3
2
  tan 1  
3
X 3

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5 AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

17. 4
dT
Sol. H   K .2 r /
dr
R2 Hdr T2 2 lk  T1  T2 
   K  dT  H  Hi  H f
R1 2 rl T1 R2
ln
R1

18. 2
dN A dN
Sol.  1 N A , B  21 N A  2 N B
dt dt
dN B
N B  maximum  0
dt
2
 21 N A  2 N Bmax  N Bmax  1 N A
2
21
 N Bmax  N 0 e  1t  2
2
19. 3
Sol. T the FBD of any one rod is T
T   N        (1)
mg  N        (2) N
Taking torque of any one rod is mg 37 0
L N P
mg cos37 o =TLsin37 o
g
mg 4 2mg
T= =
2 3 3
2mg 2
=μmg   =
3 3

20. 6
1  3  1 1 
Sol. = -1 - 
f L  2 
 20 20 
 FL  20cm
1 1 2 1
= - =-
f -10 20 5
1 1 1 1 1 1
    
v 30 5 v 30 5
1 1 1
For lens  
v 30 20
SECTION – D

21. 00025.00

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AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 6

Sol. PQ  152  202  25m


V 2 sin2(45)
25= P ÞVP =5 10m/s
g
2
 VA2 sin 2θ-2×10×12.5= 5 5    VAsinθ=5 15m/s

VA cosθ=VP cos45o =5 5m/s and θ=60o


VA2 sin2θ
 AB= =25 3
g

22. 00030.00
Sol. Consider equation of torque about C
 4R  mR 2
 mg 3π  = 2 α
8g 8πg 8πg
α= = 2 =
3πR 3π R 30R
23. 00018.00
Sol. No current passes through capacitors in steady state. Assume
potential at point '4' to be zero.
2V
Then points '1' and '2' are at same potential
3
Hence C1and C 2 can be taken in parallel
V
The potential at point 3 is
3
 Equivalent circuit of all three capacitors is shown Hence potential
difference across capacitor C3 is
2C  2V V  2V
= × - =
2C+C  3 3  9

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7 AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

Chemistry PART – II
SECTION – A
24. B
Sol. NH3 is a stronger field ligand than H2O & causes greater crystal field splitting.

25. C
Sol. Radical are generally non-selective in their attack & readily combine with any species having
unpaired electron & these can be produced by polar species like R – X in gas phase or in non
polar solutions.

26. A
Sol.  B  C
A  K C  106
1 x x x
 0  1M  1M
B D  A
 K C  10 6
1 x 1 x x
x
1 1  106  x  106
11
27. CD
Sol.
PhMgBr
Me3CO  CH 2  C  N  Me3CO  CH 2  C  NMgBr

Ph

H 2O
O
HI
Ph C CH2 + Me3C  I Me3CO-CH 2  C  O
OH
Ph

28. ABD
Sol. First step involving formation of carbanion is slow & second is fast. Once the carbanion is
formed, it undergoes rapid attack by an electrophile

29. ABC
Sol. U BC  nCV T2  T1   750 R, H CD  nC p  T2  T1 
BC
PB PC
  PB  2 bar
TB TC
CD
nCV  T2  T1    Pex V2  V1 
H ABCD  0 as the whole process is not cyclic
H AB  U AB  0 T  0

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AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 8

30. ACD
Sol. ' A ' is CrO3
CrO3  NaOH 
 Na2CrO4  H 2O
yellow solution
heat
CrO3 
 Cr2 O3  O2

31. ABD
Sol. Distance between nearest neighbours in BCC = Distance between test & octahedral void in FCC
= 3a / 4 and distance between second nearest neighbours in both is a

32. B
Sol.  O 
+ HO

OH
 +
OCN N C N NCO
O C
O

O O

RNH 2
O  
N O O N N
OCN
H H C
 Urethane polymer  O

O O
O
OCN N O O N
O
H H
RHN C N
urea group H

33. C
Sol. O OH
OH 2
  HO
O
3

O
HO OH
3

SECTION – C
34. 5
Sol. n=3
The subshell of this shell contains no radial node as described by wave function
So it is 3d .

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9 AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

35. 3
3
Sol. SOF4 is sp d hybrid but contains no lone pair.
SeF3 & SeOCl2 contains lone pairs in sp3 orbitals (no d - character)
XeF3  is pentagonal bipyramidal with one lone pair.
BrF6 is perfectly octahedral containing lone pair in pure s-orbital
TeF5 & ICl4 are sp3d2 hybrid with one & two lone pairs respectively.
36. 4
Sol.  CO2  H 2O H1  112     1
CH 2O  O2 
 nCO2  nH 2O H 2  356     2 
nCH 2O  nO2 
  CH 2 O n H 3  92 k Cal      3
nCH 2O 
Equation (1)× n – equation (2) = equation (3)
37. 0
Sol.
O
-
O


CH 3 Mg Br

Cu 

CH3
+
In presence of Cu 1,4-addition occurs.
H 3O 

CH3

38. 5
Sol. XeF4 , NCl3 , PCl3 , TeF6 , SeBr4 are hydrolysed at room temperature but NF3 , CCl4 & SF6 are
either not hydrolysed or require drastic conditions for hydrolysis.
39. 2
Sol. n f reaction
6

40. 4
Sol. CH3 CH3

O O
OH
O O +
O 
H
 OH OH
+ OH OH
H3C H 4 optical isomers optically inactive

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AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 10

41. 2
Sol. Sugars differing around C1 & C2 only give same osazone.

42. 5
Sol. 2
r=k  O3 
d  O3  2
  k O3 
dt
2
 k  2 108 

43. 5
Sol. Soap solution, acidic sols, sulfide sols, metal sols & acidic dyes are negatively charged.

SECTION – D

44. 00026.10
Sol. electrolysis
2 H 2O  2e   H 2  2OH 
50  8685
millimoles of OH  produced   4.5
96500
Milimoles of acid present  2.25
Mass present  0.261g
Percentage  26.100
45. 05340.00
Sol.  H 3O    CK a
3
Milligram of AlCl3  C  0.4  M AlCl3  10

46. 00000.06
Sol. H   HA1  
 H   HA2  & H   Ka.C
0.06 10 5.C
Ecell  0  log
1 103.C

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11 AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

Mathematics PART – III

SECTION – A
47. A
Sol.  P   a cos  , b sin  
    
And Q   a cos     , b sin     
 2  2 
Q   a sin  , b cos  
Let midpoint of PQ is (x, y), then
2x
  cos   sin  
a
2y
  sin   cos  
b
Squaring and adding equation (iii) and equation (iv), we get
x2 y 2 1
 2 2 
a b 2
48. B
Sol. Since A.M .  G.M .
 sin A  sin B  2 sin A.sin B
Similarly, sin B  sin C  2 sin B.sin C
And sin C  sin A  2 sin C .sin A
  sin A  sin B  sin B  sin C 
 sin C  sin A   8sin A.sin B.sin C
49. D
z 
Sol. 
k 2  z
2
But z z    k , thus
k2 k2

 z     z  
k k 2 z  k 2
2
k2 
z 
    0
 Re    0

50. A

Sol. Both the lines passes through the origin. Line L1 is parallel to the vector V1 .

   
V1  cos   3 ˆi  2 sin  ˆj cos   3 kˆ


And L2 is parallel to the vector V 2 .

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AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 12

 
V1.V 2
 cos     
   
a cos   3  b  2 sin   c cos   3  
V1 V 2 a2  b2  c 2 (cos   3 )2  2 sin 2 (cos   3 )
(a  c)cos   b 2 sin   (a  c) 3
=
a2  b2  c 2 2  6
For cos to be independent of , we get
a + c = 0 and b = 0
2a 3 3 
 cos    or  
a 2.2 2 2 6

51. ABD
Sol. From the graph it is clear that a < 0 and c > 0.
b
Now since vertex is in first quadrant  > 0.
2a
b  0  b  0

52. BC
1 1 1 1
Sol.     z1  z2  z1  z2
z2 z1 z2 z1
 cos(1 – 2) = 0 where 1 and 2 are arguments of z1 and z2.

53. BCD
Sol. Equating coefficients of x, x 2 and x3 both sides we get,
n(n  1) n(n  1)(n  2)
a1 = n, a2 =  2, a3   2n .
2 6
Now 2a2 = a1 + a3 gives n3 – 9n2 + 26n – 24 = 0

54. AC
Sol. f(x) is a decreasing function and for the major axis to be the x-axis.
f(k2 + 2k + 5) > f(k + 11)
or k2 + 2k + 5 < k + 11
or k (–3, 2)
Then for the remaining values of k, i.e., k  ( ,  3)  (2, ) k, the major axis is the y-axis.

55. C
5 1
C1  2 C1 3
Sol. 2 
10 5
56. B
PF  PH / F 
Sol. pF / H  
 P  Hi   P  Hi / F 
F  fair coin
H  head appears
1 1

5 2 1
PH / F   
1 1 4 5 6
  
5 2 5 8

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13 AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

SECTION – C
57. 6
Sol. A

B C
a P
R 
2sin A 3
A B C R
r  4 R sin sin sin 
2 2 2 2
P
r
2 3
P
 side of  r 2 
6
2
P
Area = K 6
6
58. 0
Sol. f  x   2 f 1  x   x 2  1 ..... 1
Replace x by (1-x)
2
f 1  x   2 f  x   1  x   1 ....  2 
(2) – (1)
2
3 f  x   2 1  x   2  x 2  1
f  3  0

59. 1
Sol. Let equation of line along minor axis is
lx  my  n  0
2 2
 x   
y
1
a2 b2
l  m  n  0
 only one arbitary constant will be left (size is same)
 degree of differential equation will be ‘1’
60. 9
3
Sol. 1  x  x 2
 x3 

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AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 14

3
 1  x4  4 3 1
   1  x  1  x 
 1 x 
n
Coefficient of x in expansion of 1  x 
r n  r 1
is Cr

61. 2
Sol. For any line in case of hyperbola we know that PQ  PQ
PQ PQ PP  PQ P
  1 2
PQ PQ PP  PQ

P
Q

62. 8
k k
3  4   1 0   2  4 
Sol.       
1  1   0 1 1  2 
2
1 0  2  4  2 – 4 

   k 1  2  as 1  0
0 1     – 2 

1  2k  4k 

 k 1  2k 
n n  n(n  1)  2n(n  1) 
k
 k 1
A   n(n  1)


n  n(n  1)
 2 
n
 k 2
 Let   A   n  64
 k 1 
 n8

63. 8
Sol.  x/9 =  x/11 =I
 I  x / 9  I  1, I  x / 11  I  1, Solution is possible only when 11I  9I+9
9
 0 I 
2
4
Total number of solution  (9-2I)-1=24
I 0

64. 2
Sol. f ( x)  2  x x0
2 x x  0
Hence minimum value of f ( x)  2

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15 AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19

65. 3
1  / 2  sin 2 (n  1)  sin 2 n 
Sol. f (n  1)  f (n)     d
 0  sin 2  
/2 /2 / 2
1 sin(2n  1) 1 sin 2n cos d 
  d     0 cos 2 n d 
 0
sin    0
sin  

/2 /2
1 sin 2n cos d 1
   2  (cos   cos 3   cos(2n  1)) cos d
 0
sin   0
/2
1
  (1  cos 2)  (cos 2  cos 4)    (cos(2n  2)  cos 2n)d
 0
/2
1 1
  d  2
 0

1
 f ( n  1)  f ( n ) 
2
n 1
 f ( n)  (as f(1)= )
2 2
f (15  f (3)
Hence, =3
f (15)  f (9)

66. 3
2r  3
Sol. General term Tr 
3r 1.r(r  1)
1 1
 Tr  r
 r 1
3 .r 3 .(r  1)
1 1
 T1  
3  1 32  2
1 1
 T2  2
 3
3 2 3 3
1 1
 Tn  
3n  n 3n 1  (n  1)
1 1
Let Sn = T1 + T2 + …………+ Tn =  n1
3 1 3  (n  1)
1 k 1
lim Sn  0   k3
x 3 9 3

SECTION – D
67. 00003.50
1
Sol. The function u  f x 
is discontinuous at the point x  1 . The function
x 1
1 1
y  g u   2  is discontinuous at u  2 and u  1
u  u  2  u  2  u  1

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AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 16

1 1
When u  2,  u  2  x 
x 1 2
1
When u  1,  1  x  2 . Hence, the composite function y  g  f  x   is discontinuous at
x 1
three points x  1/ 2,1, 2 .

68. 00011.40
1 1 1
xb  1 x b ln x
Sol. Let I  b   0 ln x dx  I'  b   b
0 ln x dx  0 x dx
1
 xb 1  1 db
Or I'  b       I b     ln  b  1  c
 b  1 0 b  1 b 1
If b  0, then I  b   0  c  0. Hence, I  b   ln  b  1

69. 00265.00
Sol. The number of ways when number student falled in any examination =(23 -1)3
The number of ways when out of above cases atleast are subject was not cleaned by any
students  3C1 (3) 3
The number of ways when out of above cases atleast any two subjects were not cleaned by any
3
student  3C 2 (1)
3 3 3
So required cases  ( 2  1)  3C1 3  3C 2 = 265

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