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SECTION – A
1. A
Sol. In CM frame both the mass execute SHM with
k 2k
SHM
m
Initially particles are at extreme
2k
Distance = L0 ( L L0 ) cos t
m
2. C
F-(m+M)g sinθ
Sol. a=
(m+M)
So, f=ma cos
F-(m+M)g sinθ
a=
(m+M) m cos
3. B
Sol. a B =2m/s 2 ()
x3 x2 x3 k1
& x3 3 x4 k2
a2 12
a2 2a3 0 a3 6m / s 2
2 2
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AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 2
4. ABCD
Sol. The above lens mirror combination is an equivalent converging mirror.
5. AC
Sol. f=mg sinθ and PE sin =mg sin .R
q 2 R Esinθ=mg sinθ R
mg
E=
2q
6. ABCD
4r
K rdr R
Sol. (A) v= 2
0 2
r (3R) 2 4 0
K rdr
4r
2 R
(B) v=
0 r 2 0
7. BD
Sol. External electric field and induced charge on outer surface of the sphere will produce a net zero
field inside it. Net field at P must be vertically upward.
8. ACD
Sol. PC -PR =2BAK S=A sin(kx- t)
9. D
10. A
Sol. (for Q. 9 to Q.10)
Let the initial temperature, pressure and volume of gas in ‘A’ be
T0 , P0 ,V0 and the area of the position A and B be a, 2a. Now gas in chamber ‘A’ undergoes
adiabatic compression whereas gas in chamber ‘B’ undergoes isothermal expansion.
Now solving for gas in ‘A’
γ γ
P1A V1A P2A V2A P0 V0γ =P2A (0.25V0 ) P2A =8P0
Solving for gas in ‘B’
P1B V1B =P2B V2B P1B V0 =P2B ×2.5V0 P2B =0.4P1B
Also (P2A ×a)=(P2B ×2a) for gas is chambers 'B'
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3 AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19
8P0 a P2 2a P2 4 P0
0.4 P1 =4P0 P1 10P0
Now comparing the moles of gas in A and B
P0 V0
nA =
RT0
10P0 V0
nB = =10n A
RT0
m B =10m A =10×100gm=1kg
Again for gas is A,ΔQ=ΔU+ΔW
0 ΔU+ΔW
V0
0 0 8 P0
PV
0 ΔU 4
( 1)
ΔU=2P0 V0 =2×105 ×10-2 =2000J
F=8P0 a=8×105 ×10-2 =8000N
SECTION – C
11. 7
v12 v2
Sol. P0 0 PA gh 2
2 2
V2 2g 5 10 V1
ρv12 ρv 22
- -ρgh= PA -P0
2 2
ρv2
PA -P0 -ρgh- 2
2
3
10 103 10 10 7
10 2 104
2 2 1 2
7 7
- ×105 N/m 2 atm
20 20
12. 2
Sol. The minima will be heard at P when a crest from S1 and a trough from S2 reach there at the same
time. This will happen if L1 – L2 is λ/2 or λ+ λ/2 or 2λ+ λ/2 and so on. Hence, the increase
in L1 between consecutive minima is 1 and from the data we see that λ=0.40m .
Then λ=v/f f=340/0.40=850Hz .
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AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 4
13. 6
Sol. X CM
dm.x 2 L
dm 3
Mass of rod;
L 10 3
M 0 x dx
0 2
Torque about ‘O’;
L 2L
FB cos37 o -Mg cos 37o =TL cos 37o
2 3
1 1 104 2
103 π ×10 - × =T
π 2 2 3
10 4
T= N
6
14. 1
Sol. V0sin30o =V1cos30 o (i )
o o
eV0 cos 30 =V1sin 30 (ii )
Dividing (i) & (ii)
1 1 1
tan30o = =3
e tan30o e
15. 8
Sol. f=2N
a1Kg=2m/s 2
1
S= ×2×4=4m
2
Wfriction =-2×4=-8J
16. 4
Sol. Since the rod is in translation so 0
about O,
F sin N cos 0
2 2
F sin N cos
N
tan (1)
F
Also, N Mg (2)
Mg 40 2
So, tan
F 60 3
2
tan 1
3
X 3
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5 AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19
17. 4
dT
Sol. H K .2 r /
dr
R2 Hdr T2 2 lk T1 T2
K dT H Hi H f
R1 2 rl T1 R2
ln
R1
18. 2
dN A dN
Sol. 1 N A , B 21 N A 2 N B
dt dt
dN B
N B maximum 0
dt
2
21 N A 2 N Bmax N Bmax 1 N A
2
21
N Bmax N 0 e 1t 2
2
19. 3
Sol. T the FBD of any one rod is T
T N (1)
mg N (2) N
Taking torque of any one rod is mg 37 0
L N P
mg cos37 o =TLsin37 o
g
mg 4 2mg
T= =
2 3 3
2mg 2
=μmg =
3 3
20. 6
1 3 1 1
Sol. = -1 -
f L 2
20 20
FL 20cm
1 1 2 1
= - =-
f -10 20 5
1 1 1 1 1 1
v 30 5 v 30 5
1 1 1
For lens
v 30 20
SECTION – D
21. 00025.00
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AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 6
22. 00030.00
Sol. Consider equation of torque about C
4R mR 2
mg 3π = 2 α
8g 8πg 8πg
α= = 2 =
3πR 3π R 30R
23. 00018.00
Sol. No current passes through capacitors in steady state. Assume
potential at point '4' to be zero.
2V
Then points '1' and '2' are at same potential
3
Hence C1and C 2 can be taken in parallel
V
The potential at point 3 is
3
Equivalent circuit of all three capacitors is shown Hence potential
difference across capacitor C3 is
2C 2V V 2V
= × - =
2C+C 3 3 9
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7 AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19
Chemistry PART – II
SECTION – A
24. B
Sol. NH3 is a stronger field ligand than H2O & causes greater crystal field splitting.
25. C
Sol. Radical are generally non-selective in their attack & readily combine with any species having
unpaired electron & these can be produced by polar species like R – X in gas phase or in non
polar solutions.
26. A
Sol. B C
A K C 106
1 x x x
0 1M 1M
B D A
K C 10 6
1 x 1 x x
x
1 1 106 x 106
11
27. CD
Sol.
PhMgBr
Me3CO CH 2 C N Me3CO CH 2 C NMgBr
Ph
H 2O
O
HI
Ph C CH2 + Me3C I Me3CO-CH 2 C O
OH
Ph
28. ABD
Sol. First step involving formation of carbanion is slow & second is fast. Once the carbanion is
formed, it undergoes rapid attack by an electrophile
29. ABC
Sol. U BC nCV T2 T1 750 R, H CD nC p T2 T1
BC
PB PC
PB 2 bar
TB TC
CD
nCV T2 T1 Pex V2 V1
H ABCD 0 as the whole process is not cyclic
H AB U AB 0 T 0
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AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 8
30. ACD
Sol. ' A ' is CrO3
CrO3 NaOH
Na2CrO4 H 2O
yellow solution
heat
CrO3
Cr2 O3 O2
31. ABD
Sol. Distance between nearest neighbours in BCC = Distance between test & octahedral void in FCC
= 3a / 4 and distance between second nearest neighbours in both is a
32. B
Sol. O
+ HO
OH
+
OCN N C N NCO
O C
O
O O
RNH 2
O
N O O N N
OCN
H H C
Urethane polymer O
O O
O
OCN N O O N
O
H H
RHN C N
urea group H
33. C
Sol. O OH
OH 2
HO
O
3
O
HO OH
3
SECTION – C
34. 5
Sol. n=3
The subshell of this shell contains no radial node as described by wave function
So it is 3d .
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9 AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19
35. 3
3
Sol. SOF4 is sp d hybrid but contains no lone pair.
SeF3 & SeOCl2 contains lone pairs in sp3 orbitals (no d - character)
XeF3 is pentagonal bipyramidal with one lone pair.
BrF6 is perfectly octahedral containing lone pair in pure s-orbital
TeF5 & ICl4 are sp3d2 hybrid with one & two lone pairs respectively.
36. 4
Sol. CO2 H 2O H1 112 1
CH 2O O2
nCO2 nH 2O H 2 356 2
nCH 2O nO2
CH 2 O n H 3 92 k Cal 3
nCH 2O
Equation (1)× n – equation (2) = equation (3)
37. 0
Sol.
O
-
O
CH 3 Mg Br
Cu
CH3
+
In presence of Cu 1,4-addition occurs.
H 3O
CH3
38. 5
Sol. XeF4 , NCl3 , PCl3 , TeF6 , SeBr4 are hydrolysed at room temperature but NF3 , CCl4 & SF6 are
either not hydrolysed or require drastic conditions for hydrolysis.
39. 2
Sol. n f reaction
6
40. 4
Sol. CH3 CH3
O O
OH
O O +
O
H
OH OH
+ OH OH
H3C H 4 optical isomers optically inactive
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AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 10
41. 2
Sol. Sugars differing around C1 & C2 only give same osazone.
42. 5
Sol. 2
r=k O3
d O3 2
k O3
dt
2
k 2 108
43. 5
Sol. Soap solution, acidic sols, sulfide sols, metal sols & acidic dyes are negatively charged.
SECTION – D
44. 00026.10
Sol. electrolysis
2 H 2O 2e H 2 2OH
50 8685
millimoles of OH produced 4.5
96500
Milimoles of acid present 2.25
Mass present 0.261g
Percentage 26.100
45. 05340.00
Sol. H 3O CK a
3
Milligram of AlCl3 C 0.4 M AlCl3 10
46. 00000.06
Sol. H HA1
H HA2 & H Ka.C
0.06 10 5.C
Ecell 0 log
1 103.C
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11 AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19
SECTION – A
47. A
Sol. P a cos , b sin
And Q a cos , b sin
2 2
Q a sin , b cos
Let midpoint of PQ is (x, y), then
2x
cos sin
a
2y
sin cos
b
Squaring and adding equation (iii) and equation (iv), we get
x2 y 2 1
2 2
a b 2
48. B
Sol. Since A.M . G.M .
sin A sin B 2 sin A.sin B
Similarly, sin B sin C 2 sin B.sin C
And sin C sin A 2 sin C .sin A
sin A sin B sin B sin C
sin C sin A 8sin A.sin B.sin C
49. D
z
Sol.
k 2 z
2
But z z k , thus
k2 k2
z z
k k 2 z k 2
2
k2
z
0
Re 0
50. A
Sol. Both the lines passes through the origin. Line L1 is parallel to the vector V1 .
V1 cos 3 ˆi 2 sin ˆj cos 3 kˆ
And L2 is parallel to the vector V 2 .
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AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 12
V1.V 2
cos
a cos 3 b 2 sin c cos 3
V1 V 2 a2 b2 c 2 (cos 3 )2 2 sin 2 (cos 3 )
(a c)cos b 2 sin (a c) 3
=
a2 b2 c 2 2 6
For cos to be independent of , we get
a + c = 0 and b = 0
2a 3 3
cos or
a 2.2 2 2 6
51. ABD
Sol. From the graph it is clear that a < 0 and c > 0.
b
Now since vertex is in first quadrant > 0.
2a
b 0 b 0
52. BC
1 1 1 1
Sol. z1 z2 z1 z2
z2 z1 z2 z1
cos(1 – 2) = 0 where 1 and 2 are arguments of z1 and z2.
53. BCD
Sol. Equating coefficients of x, x 2 and x3 both sides we get,
n(n 1) n(n 1)(n 2)
a1 = n, a2 = 2, a3 2n .
2 6
Now 2a2 = a1 + a3 gives n3 – 9n2 + 26n – 24 = 0
54. AC
Sol. f(x) is a decreasing function and for the major axis to be the x-axis.
f(k2 + 2k + 5) > f(k + 11)
or k2 + 2k + 5 < k + 11
or k (–3, 2)
Then for the remaining values of k, i.e., k ( , 3) (2, ) k, the major axis is the y-axis.
55. C
5 1
C1 2 C1 3
Sol. 2
10 5
56. B
PF PH / F
Sol. pF / H
P Hi P Hi / F
F fair coin
H head appears
1 1
5 2 1
PH / F
1 1 4 5 6
5 2 5 8
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13 AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19
SECTION – C
57. 6
Sol. A
B C
a P
R
2sin A 3
A B C R
r 4 R sin sin sin
2 2 2 2
P
r
2 3
P
side of r 2
6
2
P
Area = K 6
6
58. 0
Sol. f x 2 f 1 x x 2 1 ..... 1
Replace x by (1-x)
2
f 1 x 2 f x 1 x 1 .... 2
(2) – (1)
2
3 f x 2 1 x 2 x 2 1
f 3 0
59. 1
Sol. Let equation of line along minor axis is
lx my n 0
2 2
x
y
1
a2 b2
l m n 0
only one arbitary constant will be left (size is same)
degree of differential equation will be ‘1’
60. 9
3
Sol. 1 x x 2
x3
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AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 14
3
1 x4 4 3 1
1 x 1 x
1 x
n
Coefficient of x in expansion of 1 x
r n r 1
is Cr
61. 2
Sol. For any line in case of hyperbola we know that PQ PQ
PQ PQ PP PQ P
1 2
PQ PQ PP PQ
P
Q
62. 8
k k
3 4 1 0 2 4
Sol.
1 1 0 1 1 2
2
1 0 2 4 2 – 4
k 1 2 as 1 0
0 1 – 2
1 2k 4k
k 1 2k
n n n(n 1) 2n(n 1)
k
k 1
A n(n 1)
n n(n 1)
2
n
k 2
Let A n 64
k 1
n8
63. 8
Sol. x/9 = x/11 =I
I x / 9 I 1, I x / 11 I 1, Solution is possible only when 11I 9I+9
9
0 I
2
4
Total number of solution (9-2I)-1=24
I 0
64. 2
Sol. f ( x) 2 x x0
2 x x 0
Hence minimum value of f ( x) 2
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15 AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19
65. 3
1 / 2 sin 2 (n 1) sin 2 n
Sol. f (n 1) f (n) d
0 sin 2
/2 /2 / 2
1 sin(2n 1) 1 sin 2n cos d
d 0 cos 2 n d
0
sin 0
sin
/2 /2
1 sin 2n cos d 1
2 (cos cos 3 cos(2n 1)) cos d
0
sin 0
/2
1
(1 cos 2) (cos 2 cos 4) (cos(2n 2) cos 2n)d
0
/2
1 1
d 2
0
1
f ( n 1) f ( n )
2
n 1
f ( n) (as f(1)= )
2 2
f (15 f (3)
Hence, =3
f (15) f (9)
66. 3
2r 3
Sol. General term Tr
3r 1.r(r 1)
1 1
Tr r
r 1
3 .r 3 .(r 1)
1 1
T1
3 1 32 2
1 1
T2 2
3
3 2 3 3
1 1
Tn
3n n 3n 1 (n 1)
1 1
Let Sn = T1 + T2 + …………+ Tn = n1
3 1 3 (n 1)
1 k 1
lim Sn 0 k3
x 3 9 3
SECTION – D
67. 00003.50
1
Sol. The function u f x
is discontinuous at the point x 1 . The function
x 1
1 1
y g u 2 is discontinuous at u 2 and u 1
u u 2 u 2 u 1
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AITS-CRT-IV (Paper-2)-PCM(Sol.)-JEE(Advanced)/19 16
1 1
When u 2, u 2 x
x 1 2
1
When u 1, 1 x 2 . Hence, the composite function y g f x is discontinuous at
x 1
three points x 1/ 2,1, 2 .
68. 00011.40
1 1 1
xb 1 x b ln x
Sol. Let I b 0 ln x dx I' b b
0 ln x dx 0 x dx
1
xb 1 1 db
Or I' b I b ln b 1 c
b 1 0 b 1 b 1
If b 0, then I b 0 c 0. Hence, I b ln b 1
69. 00265.00
Sol. The number of ways when number student falled in any examination =(23 -1)3
The number of ways when out of above cases atleast are subject was not cleaned by any
students 3C1 (3) 3
The number of ways when out of above cases atleast any two subjects were not cleaned by any
3
student 3C 2 (1)
3 3 3
So required cases ( 2 1) 3C1 3 3C 2 = 265
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