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Safety data sheets for NEW chemicals used in your project (and NOT available in the
laboratory) need to be attached WITH this form.
Once this assessment has been signed by you, a technician, your project supervisor and
safety health officer; an assigned reference number will be given, please submit:
the original document of this assessment to be kept by you.
The copy of the document of this assessment to TECHNICIAN IN-CHARGED [TIC]
of main laboratory used; to be kept in the laboratory safety file.
If more than one laboratory used in this project, submit a copy of this document to
the TIC to be kept in the laboratory safety file.
Ensure this assessment is resubmitted for approval when work out of office hour.
Ensure this assessment is read and signed annually by all concerned.
Postgraduate student is required to submit After hours risk management procedure
together with this submission.
Ensure this assessment is reviewed annually by the project supervisor for posrgraduate.
Remember that anything that you put in this form you must follow!
2. Name of Supervisor
DR. MUZAFAR ZULKIFLI
Supervisor
NIL
Co supervisor
4. Method / Procedure
Synthesization of PANI
1. In preparation of 0.1 M HCl solution, 10 ml of HCl was added into 100 ml deionized
water inside measuring cylinder and stirrred by using glass rod.
2. 2 mL of aniline was obtained via pipette method and mix with 1 M HCl solution
prepared earlier.
3. Both aniline and 1 M HCl solution was added and stirred inside beaker.
4. Mechanical stirrer was set up and ice bath was prepared in suitable container.
5. The solution was stirred for 30 minutes with 500 rpm stirring speed.
6. 6 g of APS is weighed in a beaker.
7. 2 mL of aniline was obtained via pipette method and mix with 1 M HCl solution
prepared earlier.
8. After 30 minutes of stirring, solution of APS was added drop by drop into the aniline
solution.
9. After colour change was observed from colourless to light green, change the stirring
speed to 260 rpm.
PANI-ZnO Methodology
Thermogravimetric Analysis
Handling chemical Always wear proper personal protection equipment (PPE) when handling chemical
5c. Substances used which have potential to cause harm (potential hazard)
NB: This section is concerned with hazards inherent in the substances rather than the way they might be used in this procedure. All columns must be filled
according to Safety Data Sheet.
Inhalation:
If inhaled, remove to fresh air.
If not breathing, give artificial
respiration. If breathing is
difficult, give oxygen. Get
medical attention immediately.
Serious Inhalation:
Evacuate the victim to a safe
area as soon as possible.
Loosen tight clothing such as a
collar, tie, belt or waistband. If
breathing is difficult,
administer oxygen. If the
victim is not breathing,
perform mouth-to-mouth
JSA FORM revision 8 ( Feb 2017) 7
resuscitation. WARNING: It
may be hazardous to the
person providing aid to give
mouth-to-mouth resuscitation
when the inhaled material is
toxic, infectious or corrosive.
Seek immediate medical
attention.
Ingestion:
If swallowed, do not induce
vomiting unless directed to do
so by medical personnel.
Never give anything by mouth
to an unconscious person.
Loosen tight clothing such as a
collar, tie, belt or waistband.
Get medical attention
immediately.
Precautions:
Sodium hydroxide Skin contact (corrosive, STEL: 2 (mg/m3) from Eye Contact:
Keep container dry. Do not
irritant, permeator) ACGIH (TLV) [United
breathe dust. Never add water to Check for and remove any
States]
Eye contact (irritant, this product. In case of contact lenses. In case of
corrosive) TWA: 2 CEIL: 2 (mg/m3) insufficient ventilation, wear contact, immediately flush eyes
from OSHA (PEL) [United suitable respiratory equipment. If with plenty of water for at least
Ingestion
States] CEIL: 2 (mg/m3) from you feel unwell, seek medical 15 minutes. Cold water may be
Inhalation. NIOSHConsult local attention and show the label when used. Get medical attention
authorities for acceptable possible. Avoid contact with skin immediately.
exposure limits. and eyes. Keep away from
incompatibles such as oxidizing
agents, reducing agents, metals, Skin Contact:
acids, alkalis, moisture. In case of contact, immediately
flush skin with plenty of water
for at least 15 minutes while
JSA FORM revision 8 ( Feb 2017) 8
Storage: Keep container tightly removing contaminated
closed. Keep container in a cool, clothing and shoes. Cover the
well-ventilated area. irritated skin with an emollient.
Hygroscopic. Deliquescent. Cold water may be used.Wash
clothing before reuse.
Thoroughly clean shoes before
reuse. Get medical attention
immediately.
Inhalation:
If inhaled, remove to fresh air.
If not breathing, give artificial
respiration. If breathing is
difficult, give oxygen. Get
medical attention immediately.
Serious Inhalation:
Evacuate the victim to a safe
area as soon as possible.
Loosen tight clothing such as a
collar, tie, belt or waistband. If
breathing is difficult,
administer oxygen. If the
Ingestion:
Do NOT induce vomiting
unless directed to do so by
medical personnel. Never give
anything by mouth to an
unconscious person. If large
quantities of this material are
swallowed, call a physician
immediately. Loosen tight
clothing such as a collar, tie,
belt or waistband.
Precautions: Keep locked up..
Aniline Skin contact (irritant, TWA: 7.6 (mg/m3) from Eye Contact:
Keep away from heat. Keep away
permeator) ACGIH (TLV) [United
from sources of ignition. Ground Check for and remove any
States] SKIN TWA: 2 (ppm)
Eye contact (irritant) all equipment containing contact lenses. Immediately
from ACGIH (TLV) [United
material. Do not ingest. Do not flush eyes with running water
Ingestion States] SKIN TWA: 2
breathe gas/fumes/ vapor/spray. for at least 15 minutes, keeping
Inhalation [Canada] TWA: 7.6 (mg/m3)
Wear suitable protective eyelids open. Cold water may
[Canada] TWA: 5 (ppm) from be used. Get medical attention.
clothing. In case of insufficient
OSHA (PEL) [United States]
ventilation, wear suitable Finish by rinsing thoroughly
TWA: 19 (mg/m3) from
respiratory equipment. If with running water to avoid a
OSHA (PEL) [United States]
ingested, seek medical advice possible infection.
JSA FORM revision 8 ( Feb 2017) 10
TWA: 1 (ppm) [United immediately and show the
Kingdom (UK)] TWA: 4 container or the label. Avoid
Skin Contact:
(mg/m3) [United Kingdom contact with skin and eyes. Keep
(UK)]Consult local authorities away from incompatibles such as In case of contact, immediately
for acceptable exposure oxidizing agents, metals, acids, flush skin with plenty of water.
limits. alkalis. Cover the irritated skin with an
emollient. Remove
contaminated clothing and
Storage: Air and light sensitive. shoes. Cold water may be
Store in light-resistance used.Wash clothing before
container. Keep container in a reuse. Thoroughly clean shoes
cool, well-ventilated area. Keep before reuse. Get medical
container tightly closed and attention.
sealed until ready for use. Avoid
all possible sources of ignition
(spark or flame). Serious Skin Contact:
Wash with a disinfectant soap
and cover the contaminated
skin with an anti-bacterial
cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air.
If not breathing, give artificial
respiration. If breathing is
difficult, give oxygen. Get
medical attention immediately.
Serious Inhalation:
Storage:
Store in a well-ventilated place. Ingestion:
Keep container tightly closed. Rinse mouth with water.
Store locked up. Dispose of Immediately after ingestion:
contents/container to comply give lots of water to drink. Do
with local, state and federal not give milk/oil to drink. Do
regulations. Keep cool. not induce vomiting. Give
activated charcoal. Call Poison
Information Centre
(www.big.be/antigif.htm).
Consult a doctor/medical
service if you feel unwell.
Ingestion of large quantities:
immediately to hospital.
Doctor: gastric lavage.
Inhalation:
Remove the victim into fresh
air. Respiratory problems:
consult a doctor/medical
service.
Serious Inhalation:
Evacuate the victim to a safe
area as soon as possible.
Loosen tight clothing such as a
collar, tie, belt or waistband. If
breathing is difficult,
administer oxygen. If the
Ingestion:
Do NOT induce vomiting
unless directed to do so by
medical personnel. Never give
anything by mouth to an
unconscious person. If large
quantities of this material are
swallowed, call a physician
immediately. Loosen tight
clothing such as a collar, tie,
belt or waistband.
Eye Contact:
Rinse thoroughly with plenty of
water at least 15 minutes and
consult a physician.
Swallowed:
Never give anything by mouth
to an unconcious person. Rinse
mouth with water. Consult a
physician.
Full safety data sheets for the above chemicals must available in file at the laboratory in use.
Please ensure data sheets for any previously unused chemical are added to the laboratory's safety file.
Nomenclature
CoSHH: Control of Substances Hazardous to Health MEL: Maximum exposure limit TWA: Time weighted average
SDS : Safety Data Sheet [or the old term is called OEL: Occupational exposure limit TLV: Threshold limit value
CSDS-CHEMICAL SAFETY DATA SHEET or
MSDS-MATERIAL SAFETY DATA SHEET
NOTE:
ALL EQUIPMENTS USED ELECTRICAL POWER WILL HAVE ELECTRICAL HAZARDS.
6. Laboratories required
Polymer Processing, Testing and Analysis Lab 15 , Analytical Chemistry Lab 2C
Glove /
Mask /
Chemical (Spent /
HCL, APS, aniline)
NOTE:The following list of scheduled wastes are not exhausted, the above regulation must be
referred to complete this section.
NOTE:
PLEASE SPECIFY YOUR BIOHAZARD WASTE - ROUTE OF DISPOSAL
√ Category A
work may not be carried out except under the direct supervision of a
specified member of staff who is present continuously
work may not be started without the supervisor's advice and approval, some
Category B additional training and initial direct supervision
work may not be started without the supervisor's advice and approval and
Category C some additional training - no direct supervision required
Category D although extra care must be observed, workers should already be competent
and adequately-trained for this task
risks are insignificant and supervision unnecessary
Category E
No NAME CONTACT NO
Date