CRYODYNAMICS DIVISION Steve Rush – Vice President of Sales and Marketing for Ebara International Corporation, Cryodynamics Division Over 27 years experience in the design, servicing and sales of submerged motor liquefied gas pumps and turbine expanders. Author of several papers and published articles on cryogenic pump and expander related subjects.
AIChE 2009 Spring Meeting
Ammonia Production • One of the most widely produced chemicals in the world • 122,000,000 metric tons produced worldwide in 2006 • Main producers are China, with over 28% of worldwide production, India with 8.9%, Russia with 8.2% and the US with about 6.5%
AIChE 2009 Spring Meeting
Ammonia Properties • Normally stored in bulk at atmospheric pressure at -33 C • Very hazardous to personnel • Difficult to seal • Flammable • Huge affinity for water lending to high potential for conductivity
AIChE 2009 Spring Meeting
‘Standard’ Ammonia Pumps Larger ammonia pumps for cargo and ship loading service are typically line- shaft or deep well type with very long shafts These pumps are heavy and difficult to handle, and have problems with wear due to misalignment, shaft seal leakage, etc.
AIChE 2009 Spring Meeting
‘Standard’ Ammonia Pumps For transfer type duty, the pumps are typically horizontally mounted “canned” type pumps which can also suffer from misalignment and shaft seal leakage
AIChE 2009 Spring Meeting
Cryogenic Submerged Electric Motor Pumps (SEMP) • Widely used since the early 1960’s for LNG, LPG and other liquefied gas applications • Primary reason is due to the safety aspects of the SEMP design
AIChE 2009 Spring Meeting
Safety • Submerged design means the motor is not in the hazardous area • No rotating seals means no leakage of flammable gas into the atmosphere • Explosion Proof Motor is Not Required • Low Noise (Pump and Motor Surrounded in Fluid and Insulated Suction Vessel) AIChE 2009 Spring Meeting Submerged Magnetic Coupling Design
AIChE 2009 Spring Meeting
Submerged Magnetic Coupling Design Can be installed… • In a suction vessel for liquid transfer • In storage tanks for ship loading or transfer • In cargo ships for off-loading
AIChE 2009 Spring Meeting
Submerged Magnetic Coupling Ammonia Pump During Installation (In-Tank Type)
AIChE 2009 Spring Meeting
Submerged Magnetic Coupling Design
AIChE 2009 Spring Meeting
Electrical Systems • Same system as used for thousands of LNG, LPG and other liquefied gas applications • UL listed power cables, developed specially for cryogenic service • Dual seal cable feedthrus to meet stringent electrical code regulations • Explosion-proof junction boxes to meet hazardous area requirements • Space between feedthru seals for purging and monitoring AIChE 2009 Spring Meeting Electrical Systems
AIChE 2009 Spring Meeting
Axial Thrust • Handling axial thrust in any liquefied gas pump is critical • Ebara uses a built-in axial thrust system with no balance drum or extra parts • Ebara “Thrust Equalizing Mechanism” or TEM™ has been used in thousands of liquefied gas pumps and turbine expanders • System provides axial balancing over the entire flow range
AIChE 2009 Spring Meeting
Proven Technology • Eleven magnetic coupling type submerged motor pumps now in operation since the mid 1990’s • Design with electric motor, magnetic coupling and TEM thrust system is patented (US Patent 6,213,736 B1)
AIChE 2009 Spring Meeting
New Development • In the ammonia liquefaction process, pressure must be dropped to place the liquid into storage • Pressure drop is traditionally done with a Joule Thomson (J-T) valve • Enthalpy does not change • Temperature may decrease slightly but normally increases
AIChE 2009 Spring Meeting
New Development • Submerged generator hydraulic turbines have been used in LNG liquefaction since mid 1990’s • Design replaces the J-T valve for more efficient process operation • Provides an isentropic expansion to decrease temperature and increase production • Increases overall process efficiency by 4 to 7%
AIChE 2009 Spring Meeting
New Development By combining the magnetic coupling technology from the submerged ammonia pumps with the proven technology of the LNG turbine expanders, the ammonia liquefaction process can be improved
AIChE 2009 Spring Meeting
Liquefaction Process Improvement (Existing Plants)
AIChE 2009 Spring Meeting
Liquefaction Process Improvement (New Plants)
AIChE 2009 Spring Meeting
Conclusion Remember the 122,000,000 metric tons of ammonia produced in 2006? If those existing plants were retrofitted with LNH3 expanders, at a 3% process efficiency improvement, 3,660,000 additional tons could have been produced. At the current ammonia price of about $200 per metric ton, that’s $732,000,000!!
AIChE 2009 Spring Meeting
Conclusion For pumping liquefied ammonia, the submerged magnetic coupling design offers significant advances in safety and is well proven. By combining the ammonia pump technology with proven submerged turbine expander technology, a liquid or two-phase expander for ammonia is now being developed.