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Abstract: Zirconia has become one of the most popular materials in dentistry. D is c u s s t h e d e v e lo p m e n t
o f n e w h ig h - t r a n s l u c e n t
New high-trenslucent zirconia ceramics have favorable optical properties and z ir c o n i a c e r a m ic s
tions, including those made from zirconia materials. Resin bonding supports D e s c r ib e t h e p r o p e r
b o n d in g p r o to c o ls f o r
ceramic restorations and is necessary for onlays, laminate veneers, and resin-
z ir c o n i a r e s t o r a t io n s
bonded fixed dental prostheses. The APC zirconia-bonding concept is based
on decades of research on how to achieve high and long-term durable bond DISCLOSURES: Dr. B latz has received
h on o ra ria fro m N ob e l B iocare
strengths to high-strength ceramics. It includes three practical steps: (A) air- a nd Kuraray N o rita k e D ental, and
research s u p p o rt fro m 3M ESPE.
particle abrasion, (P) zirconia primer, and (C) adhesive composite resin. This Ms. S aw yer is a p a id c o n s u lta n t fo r
K uraray N oritake.
article discusses the history and development of high-translucent zirconia and
explains the necessity for proper cementation. The rationale and science behind a simplified zirconia-bond
ing concept is explained and illustrated with a clinical case presentation.
everal new materials and technologies have had a tre the zirconia framework.2,3Consequently, researchers conducting
S
mendous impact on clinical dentistry and helped rev newer clinical studies could not find differences in the long-term
olutionize traditional restorative treatment concepts. performance between PFZ and porcelain-fused-to-metal (PFM)
Zircon.um-dioxide (Z r0 2, zirconia) ceramics have crowns.3'5Still, widespread concerns about veneer-porcelain chip
fundamentally changed clinical applications and the ping and the more technique-sensitive firing and handling of zirco
nia persisted, and ultimately led to the development of CAD/CAM-
range of indications for all-ceramic restorations, from single-tooth
restoration to full-mouth implant-supported rehabilitations.1’3 fabricated monolithic full-contour zirconia restorations that did
The first CAD/CAM-fabricated zirconia (more accurately not require application of a veneering porcelain.
termed yttria-stabi.ized zirconium dioxide, or yttria-stabilized Numerous products have entered the market. In the meantime,
tetragonal zirconia polycrystals [Y-TZP]) coping was introduced millions of full-contour zirconia restorations have been inserted
in the late 1990s to provide a strong and more esthetic framework and their use has proven to be an efficient and cost-effective alter
for a porcelain-fused-to-zirconia (PFZ) restoration. Nobel Procera® native to layered indirect restorations due the CAD/CAM fabrica
Zirconia (Nobel Biocare, Nobelbiocare.com) was the first popular tion process. Translucency of this second generation of zirconia
product, followed by Lava™ Zirconia (3M ESPE, 3mespe.com) in materials was slightly improved compared with first-generation
the early 2000s. The demand for PFZ crowns increased rapidly materials while retaining similar flexural strength values. However,
due their esthetic properties and the zirconia core material of more customization and individual shading had to be achieved through
than 1000 MPa in high flexural strength. Early studies and clinical soaking or applying liquid dye to the milled green-stage or presin
experiences, however, indicated high incidences of chipping and tered material and external staining after sintering.
fractures, especially within the veneering porcelain.1Better under To simplify the process, some manufacturers have introduced pre
standing of the material enabled the development of veneering por shaded zirconia blanks, some of them with multiple layers of slightly
celains that better matched the physical and thermal properties of different shades between dentin and enamel areas to better simulate
the appearance of natural teeth. Restorations made with multilay significant influence on the clinical success of all-ceramic restora
ered zirconia can still be modified and customized to a certain degree tions.8'9 In general, adhesive bonding with composite resins and ad
with external stains or simply polished to the desired luster. equate pretreatm ent of the abutm ent tooth and ceramic bonding
The latest generation of zirconia materials has a significantly higher surface have the ability to support ceramic restorations, improve
degre e of translucency, providing greatly improved esthetics. The use retention, reduce microleakage, and increase fracture resistance of
of multilayer high-translucent zirconia materials, in particular, pro the restoration and abutm ent tooth.10The clinical procedures and
vides a great range of esthetic possibilities, specifically for anterior surface pretreatm ent steps differ, depending on the composition
teeth.6 The higher translucency is achieved by slight changes of the and mechanical properties of the ceramic substrate.8 The two m a
yttria (Y20 3) content (5 mol% or more instead of the conventional 3 jor categories of ceramic m aterials are silica based (ie, feldspathic,
mol%), which is used to stabilize the tetragonal zirconia phase, caus leucite-reinforced, lithium disilicate) and non-silica-based high-
ing a higher amount of cubic phase particles. Cubic zirconia offers strength ceramics, which include alumina and zirconia. The quality
significantly greater light transmission but lower physical strength. and durability of the bond between the composite resin and ceramic
High-translucent zirconia has flexural strength values between 550 are key for clinical success.810 They typically depend on the surface
MPa and 800 MPa, depending on the degree of translucency; the topography of the substrate, surface energy, and chemical interac
highe r the translucency, the lower the flexural strength.7Its specific tion w ith the resin.8As with any adhesive interactions, contam ina
properties make it a viable material alternative for the esthetic zone. If tion of the bonding surfaces has adverse effects on bond strengths.
bonded properly, it can be even used for laminate veneers and onlays. Hydrofluoric-acid etching, followed by application of a silane
coupling agent, is recom m ended for glassy-m atrix ceram ics.11
Ceramic Bonding Hydrofluoric-acid etching selectively dissolves the glass m atrix
Ceramic materials are brittle and cannot undergo plastic deforma and produces a porous, irregular surface of increased w ettabil
tion as metal alloys do. Therefore, their modulus of elasticity and ity. Application of a silane-coupling agent on the etched ceramic
behavior under functional stress is different from metals. The crys surface increases adhesion through mechanical interlocking and
talline structure allows for crack propagation when the surface is coupling the silica (silicon oxides) to the organic m atrix of resin
damaged or external forces become excessive. Therefore, the type m aterials by m eans of siloxane bonds.11 The intaglio surfaces of
of luting agent and technique for perm anent cem entation have a silica-based ceramic restorations should not be treated with blunt
Fig 1. Preoperative extraoral view of a patient’s smile exhibiting compromised esthetic situation. Fig 2. Preoperative frontal intraoral view in maxi
mum intercuspation. Fig 3. Preoperative occlusal view of maxillary arch. Fig 4. Diagnostic wax-up to determine functional and esthetic parameters.
ble long-term resin bonds are achieved only a fter surface p re tre a t c f m a x il l a r y a n t e r i o r t e e t h . F g 7. F u l - c o n t o u r r a o r o l i t h i c h i g h - t r a n s l u
c e n t z ir c o n i a c r o w n s f o ' r e s t o r a t i o n s f o r m a x i l a r y a n t e r i o r t e e t h o n t h e
m e n t w ith air-particle abrasio n and use of an adhesive com posite-
m a s te r c a s t.
re sin luting ag en t th a t in co rp o ra te s special adhesive p h o sp h ate
m onom ers, especially 10-m ethacryloyloxydecyl-dihydrogen p h o s
phate (M DP).1648 In fact, som e of those adhesive resin cem ents were b u t lim ited feasibility in da.lv clinical practice routine.
developed to b o n d to m etal-alloy resto ratio n s. To practically achieve the high and long-term durable resin bond
O ur first research studies on bonding to alum ina and zirconia sta rt stre n g th s to zircon.a, w e reco m m en d a th re e -ste p ap p ro ach . To
ed in the early 2000s and have, in the m eantim e, comprised thousands simplify this protocol, we h iv e term ed it the “APC zirconia-bonding
of specim ens and m ost surface p re tre a tm e n t and cem e n t options c oncept:” APC - Step A: Ait -particle abrade th e bonding surface w ith
com m only available8i9'12'13’19'21In contrast to o th er studies, which used alu m in u m oxide; A PC -Ste p P: A pply spec.al zirconia p rim er; and
polished ceram ic samples, we investigated the actual intaglio surfaces A P C -S tep C: Use d u al-cu re or self-cure co m posite resin cem ent.
of CA D /CA M -fabricated ceram ic restorations. We found that, in ad
dition to th e adhesive com posite resins, specific prim ers containing APC-Step A
adhesive phosp h ate m onom ers, ie, MDP, have th e ability to b e tte r A fter resto ratio n cleaning, z.rconia should be air-particle abraded
w et the slightly rough surfaces and provide superior long-term bond (A PC -Step A) w ith alum ina o r silica-coated alum ina particles; som e
strengths to air-p article-ab rad ed h ig h -strength ceram ics. Several call this procedure sandblasting o r microetching. A chairside m icro
o th er treatm en ts have been exam ined, including th e use o f various etcher using small perticles (£0 pm to 60 pm) at a low pressure (below
acid etchants and plasma coating. Some have shown prom ising results, 2 bar) is sufficient.9'1s“°'22 The overall effect of alum ina p retreatm en t
Fig 8. Maxillary occlusal view of cemented anterior full-contour high-translucent zirconia crowns and refined conservative preparations of posterior
teeth for onlays and crowns. Fig 9. Occlusal view of posterior monolithic high-translucent zirconia restorations on the model. Fig 10. Lingual view of
maxilla y right posterior high-translucent zirconia restorations on the model. Fig 11. Lingual view of maxillary left posterior high-translucent zirconia
restorations on the model. Fig 12. Posterior monolithic high-translucent zirconia onlay and crown restorations.
Fig 18. Careful interproximal removal of excess composite material. Fig 19. Light polymerization of composite resin for 60 seconds from each side. Fig 20.
Postoperative occlusal view of maxillary arch with full-contour monolithic high-translucent zirconia restorations on all teeth. Fig 21. Postoperative frontal
intraoral view in maximum intercuspation with full-contour high-translucent zirconia restorations. Fig 22. Postoperative extraoral view of patient’s smile.
8 9 TH A N N U A L M EETIN G
"W M C H IC AG O 2017 OF THE A M E R IC A N P R O S T H O D O N T I C SO C IE T Y
che AMERICAN PROSTHODONTIC SOCIETY
FEBRUARY 23-24, 2017 I SWISSOTEL I CHICAGO, ILLINOIS
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1. The increased translucency of recent high-translucent zirconia 6. The preferred surface treatment when bonding to silica-based
materials is due to: ceramics is:
A. a higher amount of cubic-phase particles. A. hydrofluoric-acid etching and silane application.
B. a lower amount of cubic-phase particles. B. grinding with diamond bur and silane application.
C. new staining techniques. C. air-particle abrasion without any other surface treatment.
D. excessive sintering. D. silane application without any other surface treatment.
2. High-translucent zirconia has flexural strength values between: 7. The preferred surface treatment when bonding to zirconia is:
A. 100 MPa and 240 MPa. A. hydrofluoric-acid etching and silane application.
B. 240 MPa and 550 MPa. B. grinding with diamond bur and silane application.
C. 550 MPa and 800 MPa. C. air-particle abrasion with alumina and zirconia
D. 1000 MPa and 1500 MPa. primer application.
D. silane application without any other surface treatment.
3. As a general rule for zirconia:
A. the higher the translucency, the higher the flexural strength. 8. Air-particle abrasion of zirconia bonding surfaces:
B. the higher the translucency, the lower the flexural strength. A. should never be done.
C. the lower the translucency, the lower the flexural strength. B. is not necessary.
D. the degree of translucency is not correlated with C. must be done with large alumina particles (at least 110 pm) at
flexural strength. high pressure of above 4 bar.
D. can sufficiently be done with small alumina particles (50 pm
4. Ce-amic materials are brittle and: to 60 pm) at low pressure below 2 bar.
A. undergo plastic deformation as metal alloys do.
B. behave like metals under functional stress. 9. Special zirconia primers:
C. have the same modulus of elasticity as metals. A. typically contain adhesive phosphate monomers, such as
D. cannot undergo plastic deformation as metal alloys do. MDP, which bond to metal oxides.
B. are not necessary.
5. Adhesive bonding of ceramic restorations: C. always come in different shades to match the adjacent
A. increases their fracture resistance. tooth color.
B. reduces microleakage D. must be applied before air-particle abrasion.
C. improves retention.
D. All of the above 10. Composite resins for zirconia bonding:
A. should be light-cure materials.
B. should be dual- or self-cure materials.
C. are not available in different shades.
D. None of the above
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