Magnetic Field of a Hollow Conducting Cylinder

CODE : 7 TEST ID : 624
IIT JEE Advance 2012

Time : 3 Hours PAPER 2 Maximum Marks : 198
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The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part consists of three
sections.
12. Section I contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
13. Section II contains 3 paragraphs each describing theory, experiment, data, etc. There are 6 multiple
choice questions relating to three paragraphs with 2 questions on each paragraph. Each question of a
particular paragraph has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
14. Section III contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE are correct.
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(2) Vidyalankar : IIT JEE 2012 Question Paper & Solution
PART I : PHYSICS
SECTION I : Single Correct Answer Type
This section contains 8 multiple choice questions. Each question has four choices
(A), (B), (C) and (D) out of which ONLY ONE is correct.
1. A student is performing the experiment of Resonance Column. The diameter of the

column tube is 4 cm. The frequency of the tuning fork is 512 Hz. The air temperature is
38ºC in which the speed of sound is 336 m/s. The zero of the meter scale coincides with
the top end of the Resonance Column tube. When the first resonance occurs, the reading
of the water level in the column is
(A) 14.0 cm (B) 15.2 cm (C) 16.4 cm (D) 17.6 cm
1. (B)
336
512 =
4(  e)
84
( e) = 100 = 16.4 cm
512
1.2 = 16.4
= 16.4  1.2 = 15.2 cm
2. Two identical discs of same radius R are rotating about their axes in opposite directions
with the same constant angular speed . The discs are in the same horizontal plane. At
time t = 0, the points P and Q are facing each other as shown in the figure. The relative
speed between the two points P and Q is vr. In one time period (T) of rotation of the discs,
vr as a function of time is best represented by
(A) (B)
(C) (D)
2
IIT JEE 2012 Question Paper & Solution (Paper – II) (3)
2. (A)
 
v sin  v sin 


vp vQ
v cos  v cos 
VPQ = VP  VQ
= (  v sin  iˆ  v cos  ˆj)  (v sin  iˆ  v cos  ˆj)
VPQ = 2v sin  iˆ
between 0 to 2
3. A loop carrying current I lies in the x-y plane as shown in the figure. The unit vector k̂ is
coming out of the plane of the paper. The magnetic moment of the current loop is
   
(A) a 2 Ikˆ (B)   1 a 2 Ikˆ (C)    1 a 2 Ikˆ (D) (2  1)a 2Ikˆ
2  2 
3. (B)
M =IA
2 a
a
  a a
A = 4  2
a 2
2 a
 a2
=2 + a2
4
a 
2
 
=    + a2 =   1  a2
 2  2 
 
 M =   1  a2 I k̂
2 
3
4. An infinitely long hollow conducting cylinder with inner radius R/2 and outer radius R
carries a uniform current density along its length. The magnitude of the magnetic field,
| B | as a function of the radial distance r from the axis is best represented by
(A) (B)
(C) (D)
4. (D)
Let current be I.
I
Current density J =
 R2 
 R2  
 4
 
I 4I
J =  Amperian loop
3R 2 3R 2
 R/2
4
r
 R
Field for  r   B = 0
 2 R
R
For rR
2
Applying Ampere’s Law
4I  2 R2  40 I  2 R 2 
B . 2r = 0 .   r   = r  
3R 2  4  3R 2  4 
20 I  R2 
B =  r  
3R 2  4r 
R R
At r = , B = 0  at r = field is continuous.
2 2
From the above expression as r increases B increases.
For r  R B . 2r = 0I
 I 1
B= 0  B
2r r
0 I
At r = R, B=
2R
4
From inside expression at r = R

20 I  R 2  0 I
B = .  R  
3R 2  4R  2R
This proves the continuity in the graph at r = R.
From the above only correct option is (D)
5. A thin uniform cylinder shell, closed at both ends is partially filled with water. It is
floating vertically in water in half-submerged state. If c is the relative density of the
material of the shell with respect to water, then the correct statement is that the shell is
(A) more than half-filled if c is less than 0.5
(B) more than half-filled if c is less than 1.0
(C) half-filled if c is more than 0.5
(D) less than half-filled if c is less than 0.5
5. (A)
If water is half filled
Mshell g = (V)displaced g
V 
(V) =  shell 
 2 
liquid Vshell
Mshell =
2
 Mshell  liquid
 
 shell 
V 2
liquid
shell 
2
1 1
R.d = . If R.d <
2 2
Then, the cylinder should be more than half filled so that it is halfsubmerged and
floating.
6. In the given circuit, a charge of +80 C is given to the upper

plate of the 4 F capacitor. Then in the steady state, the
charge on the upper plate of the 3 F capacitor is
(A) +32 C
(B) +40 C
(C) +48 C
(D) +80 C
6. (C)
Charge on capacitor of 3 F
3
Q = 80  48 C
23
7. Two moles of ideal helium gas are in a rubber balloon at 30ºC. The balloon is fully
expandable and can be assumed to require no energy in its expansion. The temperature of
the gas in the balloon is slowly changed to 35ºC. The amount of heat required in raising
the temperature is nearly (take R = 8.31 J/mol.K)
(A) 62 J (B) 104 J (C) 124 J (D) 208 J
5
7. (D)
3R
Since U =  CV T = 2   5 and W= P V =  R T = 2R  5 = 10R
2
8.31  100 831
so Q = U + W = 15R + 10R = 25R = = = 208 J
4 4
8. Consider a disc rotating in the horizontal plane with a constant angular speed  about its
centre O. The disc has a shaded region on one side of the diameter and an unshaded region
on the other side a shown in the figure. When the disc is in the orientation as shown, two
pebbles P and Q are simultaneously projected at an angle towards R. The velocity of
projection is in the y-z plane and is same for both pebbles with respect to the disc.
1
Assume that (i) they land back on the disc before the disc has completed rotation, (ii)
8
their range is less than half the disc radius, and (iii)  remains constant throughout. Then
(A) P lands in the shaded region and Q in the unshaded region.
(B) P lands in the unshaded region and Q in the shaded region.
(C) Both P and Q land in the unshaded region.
(D) Both P and Q will not land in the shaded region.
8. (C)
According to problem particle is to land on disc
If we consider a time ‘t’ then x component of displacement is Rt
Rsin t < Rt
Thus particle P lands in unshaded region
SECTION II : Paragraph Type

This section contains 6 multiple choice questions relating to three paragraphs with two
questions on each paragraph. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
Paragraph for Questions 9 and 10
The -decay process, discovered around 1900, is basically the decay of a neutron (n). In the
laboratory, a proton (p) and an electron (e) are observed as the decay products of the neutron.
Therefore, considering the decay of a neutron as a two-body decay process, it was predicted
theoretically that the kinetic energy of the electron should be a constant. But experimentally,
it was observed that the electron kinetic energy has a continuous spectrum. Considering a
three-body decay process, i.e. n  p + e + v e , around 1930, Pauli explained the observed
electron energy spectrum. Assuming the anti-neutrino (ve ) to be massless and possessing
negligible energy, and the neutron to be at rest, momentum and energy conservation
principles are applied. From this calculation, the maximum kinetic energy of the electron is
0.8  106 eV. The kinetic energy carried by the proton is only the recoil energy.
6
9. If the anti-neutrino had a mass of 3 eV/c2 (where c is the speed of light) instead of zero
mass, what should be the range of the kinetic energy, K, of the electron?
(A) 0  K  0.8  106 eV (B) 3.0 eV  K  0.8  106 eV
(C) 3.0 eV  K < 0.8  106 eV (D) 0  K < 0.8  106 eV
9. (D)
Q = (m)c2
Assuming antineutrino to be massless:
Q1  mn  (mp  me )  c2  recoil energy of P+ + kinetic energy of e + energy carried by neutrino.
Now suppose antineutrino had a mass as well
of KE of e + KE of recoiled P+ i.e. K  K e  K p  0.8 106 ev  3eV
Thus Ke is definitely less than 0.8  106 eV
K p 0 since proton is massive
Minimum energy is possible if momentum are carried away by P and antineutrino
10. What is the maximum energy of the anti-neutrino?
(A) Zero (B) Much less than 0.8  106 eV
(C) Nearly 0.8  10 eV
6
(D) Much larger than 0.8  106 eV
10. (C)
As per the situation in Q.9. If (K.Ee) = 0
All energy carried by antineutrino only (as proton share very less amount of energy
because of its large inertia)
The general motion of a rigid body can be considered to be a combination of (i) a motion of
its centre of mass about an axis, and (ii) its motion about an instantaneous axis passing
through the centre of mass. These axes need not be stationary. Consider, for example, a thin
uniform disc welded (rigidly fixed) horizontally at its rim to a massless stick, as shown in the
figure. When the disc-stick system is rotated about the origin on a horizontal frictionless
plane with angular speed , the motion at any instant can be taken as a combination of
(i) a rotation of the centre of mass of the disc about the z-axis, and (ii) a rotating of the disc
through an instantaneous vertical axis passing through its centre of mass (as is seen from the
changed orientation of points P and Q). Both these motions have the same angular speed  in
this case.
Now consider two similar systems as shown in the figure: Case (a) the disc with its face
vertical and parallel to x-z plane; Case (b) the disc with its face making an angle of 45º with
x-y plane and its horizontal diameter parallel to x-axis. In both the cases, the dis is welded at
point P, and the systems are rotated with constant angular speed  about the z-axis.
Case (a) Case (b)
7
11. Which of the following statements regarding the angular speed about the instantaneous
axis (passing through the centre of mass) is correct ?
(A) It is 2 for both the cases

(B) It is  for case (a); and for case (b)
2
(C) It is  for case (a); and 2 for case (b)
(D) It is  for both the cases
11. (D)
It is  for both case.
as angular velocity of a rigid body about any point should be same.
v  v PC  vCO
 vPO  rPC    vCO
d  d ˆ
L î =  (kˆ  ˆj)      L  .45 i
2 2  2 
rP  ˆj
 d   d 
rc     cos 45   ˆj   sin 45  kˆ  k̂
 2   2 
d  d 
rPC    cos 45  ˆj   sin 45  kˆ ( + d cos 45º) î
2  2 
 d 
vCO     cos 45   ˆi
 2 
d ˆ d ˆ  î
i (i  j)  
2 2 2 2
P d cos 45º
   k̂
12. Which of the following statements about the instantaneous axis (passing through the
centre of mass) is correct ?
(A) It is vertical for both the cases (a) and (b)
(B) It is vertical for case (a); and is at 45 to the xz plane and lies in the plane of the disc
for case (b)
(C) It is horizontal for case (a); and is at 45 to the xz plane and is normal to the plane of
the disc for case (b)
(D) It is vertical for case (a); and is at 45 to the xz plane and is normal to the plane of
the disc for case (b)
12. (A)
V 
2
 r2
Top View

 2V sin   p1
W    r 2
 2r 
  2
 r2 r  

 0 2
 r2
r 2
r 2
 r 
2 2

=
Here there is a vrel of P’ and Q (not for P, Q) (Vrel)PQ will be in horizontal plane
  must be along vertical
Same situation will be there for P as mentioned  should be same for both cases
8

Most materials have the refractive index, n > 1. So, when a light ray from air enters a
sin 1 n 2
naturally occurring material, then by Snell’s law,  , it is understood that the
sin 2 n1
refracted ray bends towards the normal. But it never emerges on the same side of the normal
as the incident ray. According to electromagnetism, the refractive index of the medium is
c
given by the relation, n       r  r , where c is the speed of electromagnetic waves in
v
vacuum, v its speeds in the medium, r and r are the relative permittivity and permeability of
the medium respectively. In normal materials, both r and r are positive, implying positive n
for the medium. When both r and r are negative, one must choose the negative root of n.
Such negative refractive index materials can now be artificially prepared and are called
metamaterials. They exhibit significantly different optical behavior, without violating any
physical laws. Since n is negative, it results in a change in the direction of propagation of the
refracted light. However, similar to normal materials, the frequency of light remains
unchanged upon refraction even in metamaterials.
13. Choose the correct statement.
(A) The speed of light in the metamaterial is v = c|n|
c
(B) The speed of light in the metamaterial is v =
|n|
(C) The speed of light in the metamaterial is v = c.
(D) The wavelength of the light in the metamaterial (m) is given by  m   air | n | ,
where air is the wavelength of the light in air
13. (B)
C C
  =  v =
v 
 will be ()ve for metal materials but || is (+)ve
C
v =
||
14. For light incident from air on a meta-material, the appropriate ray diagram is
(A) (B)
(C) (D)
9
14. (C)
sin 1 
= 2
sin 2 1
sin 1 
 =
sin 2 1
sin 1
 sin 2 = 

 2 will ()ve w.r.t. to normal.
option (C) is correct.
SECTION III : Multiple Correct Answer(s) Type

This section contains 6 multiple choice questions. Each question has four choices (A), (B),
(C) and (D) out of which ONE or MORE are correct.
15. Six point charges are kept at the vertices of a regular hexagon of side L and centre O, as
1 q
shown in the figure. Given that : K = , which of the following statement(s)
4 0 L2
is(are) correct?
(A) The electric field at O is 6K along OD.

(B) The potential at O is zero.
(C) The potential at all points on the line PR is same.
(D) The potential at all points on the line ST is same.
15. (A), (B), (C)

1 q
K=
40 L2
1  q 2q q q 2g q 
Potential at O =      0
40  L L L L L L 
Any point on line PR is equidistant from the charges F & E; A & D; B & C. Each
mentioned pair of charges are of equal magnitudes and opposite signs. Thus I by
superposition principle; all points of PR have O potential.
Considering the electric field at O;

2K
60
O 4K
60
2K
Net field along OD = 4K   2K  cos60   2K  cos60  6K
10
16. Two spherical planets P and Q have the same uniform density , masses MP and MQ, and
surface areas A and 4A, respectively. A spherical planet R also has uniform density  and
its mass is (MP + MQ). The escape velocities from the planets P, Q and R, are VP, VQ and
VR, respectively. Then
(A) VQ > VR > VP (B) VR > VQ > VP
1
(C) VR/VP = 3 (D) VP/VQ =
2
16. (B), (D)
Escape velocity from a planet of mass M and radius R
2GM 2 4
ve   .G . R 3  ve  R [If  is same for all planets)
R R 3
From given information :
  
4 4R 2p  4R Q
2

 R Q  2R P
VP 1
 
VR 2
MQ = 8MP
4 3 4
 MR = 8MP + MP = 9 MP  R R .   9  3P 
3 3
 RR =  9 
1/3
.R P Clearly VR  VQ  VP
17. The figure shows a system consisting of (i) a ring of outer radius 3R rolling clockwise
without slipping on a horizontal surface with angular speed  and (ii) an inner disc of

radius 2R rotating anti-clockwise with angular speed . The ring and disc are separated
2
by frictionless ball bearings. The system is in the x-z plane. The point P on the inner disc
is at a distance R from the origin, where OP makes an angle of 30 with the horizontal.
Then with respect to the horizontal surface,
(A) the point O has a linear velocity 3R i

11 3
(B) the point P has a linear velocity R i + R k
4 4
13 3
(C) the point P has a linear velocity R i  R k
4 4
 3 1
(D) the point P has a linear velocity  3   R i + R k
 4  4
11
17. (A) (B)
3R
VO = (3R)  i … (A)
60
30
 R 
(VP )O =  
 2 
R R  R 3R 
=  (cos60)i  (sin60)k =   i k
2 2  4 4 
 R 
VP = VPO  VO =    3R  q
 4 
11Ri 3R
VP =  k … (B)
4 4
18. Two solid cylinders P and Q of same mass and same radius start rolling down a fixed
inclined plane from the same height at the same time. Cylinder P has most of its mass
concentrated near its surface, while Q has most of its mass concentrated near the axis.
Which statement(s) is(are) correct?
(A) Both cylinders P and Q reach the ground at the same time
(B) Cylinder P has larger linear acceleration than cylinder Q
(C) Both cylinder reach the ground with same translational kinetic energy
(D) Cylinder Q reaches the ground with larger angular speed
18. (D)
mg sin   f = ma
a
fr = I
r
Ia
 fr =
r2
 I 
mg sin  =  2  m  a 
r 
gsin 
a =
 k2 
 2 1 
r 
2
t =
a
KP  KQ
 aP  aQ  tP  tQ (A) wrong
12
KP > KQ
aP < aQ  (B) wrong
1 2 K2  mgh
mv  1  2  = mgh  (K.E)T =  both will have different T.K.E. (C) wrong
2  r   K2 
 1 2 
 r 
2gh
v=
 K2 
 1 2 
 r 
v 1 2gh
= =
r r  K2 
 1  
 r2 
KP > KQ
 Q > P  (D) Correct
19. A current carrying infinitely long wire is kept along the diameter of a circular wire loop,
without touching it. The correct statement(s) is(are)
(A) The emf induced in the loop is zero if the current is constant
(B) The emf induced in the loop is finite if the current is constant
(C) The emf induced in the loop is zero if the current decreases at a steady rate
(D) The emf induced in the loop is finite if the current decreases at a steady rate
19. (A) (C)
 The Magnetic flux above and below the i

circular loop are equal and opposite due to x
symmetry
 net = 0
 emf induced will be zero
20. In the given circuit, the AC source has  = 100 rad/s. Considering the inductor and
capacitor to be ideal, the correct choice(s) is(are)
(A) The current through the circuit, I is 0.3 A
(B) The current through the circuit, I is 0.3 2 A
(C) The voltage across 100  resistor = 10 2 V
(D) The voltage across 50  resistor = 10 V
20. (A), (C)
I = I1 + I2
13
XL = L = (100) (0.5) = 50 
1 1 106
XC = = = 100 
C 100  100
For inductor circuit,
Z1 = 502  502 = 50 2
50 2 I1 = 20
2
 I1 = A
5
For capacitor circuit,
100 2 I2 = 20
2
I2 = A
10
2 2 1
I = I12  I 22 =  
25 100 10
I = 0.3 A
Voltage across 100  = I2 100
2 I2
=  100
10
= 10 2 V
I1
Voltage across 50  = I1 50
2
=  50 = 10 2 V
5
PART - II : CHEMISTRY
SECTION I : Single Correct Choice Type

21. Using the data provided, calculate the multiple bond energy (kJ mol1) of a C  C bond in
C2H2. That energy is (take the bond energy of a C  H bond as 350 kJ mol1)
2C(s) H2(g) 
C2H2(g) H = 225 kJ mol1
2C(s) 
2C(g) H = 1410 kJ mol1
H2(g) 
2H(g) H = 330 kJ mol1
(A) 1165 (B) 837 (C) 865 (D) 815
14
21. (D)
2C(s)  H2 (g) 
 C2H2 (g)(H  C  C  H)
 B  E(H2 )  HSub (C)  B  E(C  H)  2  B  E(C  C)  Hrxn
 330  1410  [350  2  x]  225  x = 815
22. The major product H of the given reaction sequence is

95% 2SO4
CH3 CH 2 COCH3 
CN
G
Heat

(A) (B)
(C) (D)
22. (A)
O O
CH 3 CH 2 CCH 3 
CN
CH 3 CH 2 CCH 3 (G)
CN
95% H2SO4
CH3 COOH
CH3 CHCCOOHCH3 CH 2 C CH3
(A) OH
23. NiCl2 {P(C2H5)2(C6H5)}2 exhibits temperature dependent magnetic behavior
(paramagnetic / diamagnetic). The coordination geometries of Ni2+ in the paramagnetic
and diamagnetic states are respectively
(A) tetrahedral and tetrahedral (B) square planar and square planar
(C) tetrahedral and square planar (D) square planar and tetrahedral
23. (C)
2
 NiCl2 P(C 2 H 5 ) 2 (C6 H 5 ) 
 2
2
Ni(28) : [Ar]4s o 3d8
24. In the cyanide extraction process of silver from argentite ore, the oxidizing and reducing
agents used are
(A) O2 and CO respectively (B) O2 and Zn dust respectively
(C) HNO3 and Zn dust respectively (D) HNO3 and CO respectively
24. (B)
Ag 2S  4NaCN 2NaAg(CN) 2  Na 2S
0
4Na 2 S 5O2  2H 2O 
 2Na 2SO4 
 4NaOH  2S
ox
1 0
2Na Ag(CN) 2  Zn 
 NaZn(CN) 4  2A g
15
25. The reaction of white phosphorus with aqueous NaOH gives phosphine along with
another phosphorus containing compound. The reaction type ; the oxidation states of
phosphorus in phosphine and the other product are respectively
(A) redox reaction ; 3 and 5 (B) Intramolecular redox reaction; +3 and +5
(C) disproportionation reaction ; 3 and + 1 (D) disproportionation reaction ; 3 and 1
25. (C)
P4 (white)  NaOH  3H2O  PH3  3NaH2PO2
PH3 has 3 and NaH2PO3 has + 1 O.N.
26. The shape of XeO2F2 molecule is

(A) trigonal bipyramidal (B) square planar
(C) tetrahedral (D) see  saw
26. (D)
Shape of XeO2F2 is
1
Hybridisation H   V  M  C  A 
2
1
 8  2  0  0  5(sp3d)
2
27. For a dilute solution containing 2.5 g of a nonvolatile non electrolyte solute in 100 g of
water, the elevation in boiling point at 1 atm pressure is 2C. Assuming concentration of
solute is much lower than the concentration of solvent, the vapour pressure (mm of Hg) of
the solution is (take Kb = 0.76 K kg mol1)
(A) 724 (B) 740 (C) 736 (D) 718
27. (A)
TL = kb  m
Ws
= kb 
M s Wsolution
2.5
2 = 0.76
M s 100
0.762.5
Ms = = 9.5
1002
760  x ns
= Xs =
760 n solution
Ws
Ms 2.518
= = = 36.0
Wsolv 9.5
M solv
x = 760  36 = 724
16
28. The compound that undergoes decarboxylation most readily under mild condition is
(A) COOH (B) COOH
CH2COOH O
(C) COOH (D) CH2COOH

COOH O
28. (B)
O
C OH
O
Is a   keto acid which undergo decarboxylation on slight heating.
O
C OH
O
O Slightheating
 CO

2
SECTION II : Paragraph Type

questions on each paragraph. Each question has four choices (A) , (B) , (C) and (D) out of
Paragraph for Question 29 and 30
The electrochemical cell shown below is a concentration cell.

M | M2+ (saturated solution of a sparingly soluble salt, MX2) || M2+ (0.001 mol dm3) | M
The emf of the cell depends on the difference in concentrations of M 2+ ions at the two
electrodes.
The emf of the cell at 298 K is 0.059 V.
29. The value of G (kJ mol1) for the given cell is (take 1F = 96500 C mol1)
(A) 5.7 (B) 5.7 (C) 11.4 (D) 11.4
29. (D)
G = nFEcell
= 2  96500  0.059
= 11.387 kJ mol1
= 11.4 kJ
30. The solubility product (Ksp ; mol3 dm9) of MX2 at 298 K based on the information
available for the given concentration cell is (take 2.303  R  298 / F = 0.059 V)
(A) 1  1015 (B) 4  1015 (C) 1  1012 (D) 4  1012
17
30. (B)
0.0591 C
E = log10 3
2 10
0.0591  C 
0.059 = log10  3 
2  10 
C
102 = 3
10
C = [M2+] = 105 M.
Ksp = [M+2] [X]2 = 4s3 = 4(105)3 = 4  1015
Paragraph for Question 31 to 32

In the following reaction sequence, the compound J is an intermediate.
J(C9H8O2) gives effervescence on treatment with NaHCO3 and a positive Bayer’s test.
31. The compound K is
(A) (B) (C) (D)
31. (C)
O
C H
 
(CH CO) O
3 2
CH COONa (J)
3 C O H2 |Pd | C
I OH

AlCl

SOCl2
3
C O C O
O
(K) Cl OH
32. The compound I is
(A) (B) (C) (D)
32. (A)
Solution is given with Q. 31 solution.
18
Paragraph for Question 33 and 34
Bleaching powder and bleach solution are produced on a large scale and used in several
household products. The effectiveness of bleach solution is often measured by iodometry.
33. 25 mL of household bleach solution was mixed with 30 mL of 0.50 M KI and 10 mL of 4

N acetic acid. In the titration of the liberated iodine, 48 mL of 0.25 N Na2S2O3 was used
to reach the end point. The molarity of the household bleach solution is
(A) 0.48 M (B) 0.96 M (C) 0.24 M (D) 0.024 M
33. (C)
1
No. of moles of bleach solution =  No. of moles of Na2S2O3
2
1
=  (0.25  48  103)
2
= 6  103
Molarity  25  10 = 6  103
3
6
Molarity of bleach solution = = 0.24 M
25
34. Bleaching powder contains a salt of an oxoacid as one of its components. The anhydride
of that oxoacid is
(A) Cl2O (B) Cl2O7 (C) ClO2 (D) Cl2O6
34. (A)
Bleaching powder contains salt of HCl.
It is obtained by adding H2O to Cl2O.

This section contains 6 multiple choice questions. Each question has four choices (A) , (B) ,
35. For the given aqueous reactions, which of the statement(s) is (are) true?
(A) The first reaction is a redox reaction

(B) White precipitate is Zn3 [Fe(ON)6]2.
(C) Addition of filtrate to starch solution gives blue colour.
(D) White precipitate is soluble in NaOH solution.
35. (A), (C), (D)
KI (Excess) + [K3 Fe(CN)6] + H2SO4  K4 [Fe(CN)6] + I2 + KOH
(Brownish-Yellow solution)
KOH + I2 + K4 [Fe(CN)6] + ZnSO4  Zn(OH)2 + I2 (Brown-Yellow Filterate)
I2 + Starch  Blue color
Zn(OH)2 + NaOH (Ecess)  Na2ZnO2 (soluble in alkaline medium)
19
36. With reference to the scheme given, which of the given statement(s) about T, U, V and W
is (are) correct?
(A) T is soluble in hot aqueous NaOH

(B) U is optically active
(C) Molecular formula of W is C10H18O4
(D) V gives effervescence on treatment with aqueous NaHCO3
36. (A), (C), (D)

O
O
CH2 OH CH2 O C CH3
O H2C CH2
 
(CH CO)O


LiAlH 4 OH 3 O
excess
H3C C H CH2 C H O C CH3
(T) H3C CH2 H3C (CH2)2
(U) (W)
+
Cr2O3 H
OH
O
H3C OH
(V)
37. Which of the given statement(s) about N, O, P and Q with respect to M is (are) correct?
(A) M and N are nonmirror image stereoisomers

(B) M and O are identical
(C) M and P are enantiomers
(D) M and Q are identical
20
37. (A) , (B) , (C)

Factual.
38. With respect to graphite and diamond, which of the statement(s) given below is (are)
correct?
(A) Graphite is harder than diamond.
(B) Graphite has higher electrical conductivity than diamond.
(C) Graphite has higher thermal conductivity than diamond.
(D) Graphite has higher CC bond order than diamond.
38. (B), (D)
Graphite is sp2 hybridized and contains Vander Wall Force. While diamond is sp3
hybridized.
39. The given graphs/data I, II, III and IV represent general trends observed for different
physisorption and chemisorption processes under mild conditions of temperature and
pressure. Which of the following choice(s) about I, II, III and IV is (are) correct?
(A) I is physisorption and II is chemisorption

(B) I is physisorption and III is chemisorption
(C) IV is chemisorption and II is chemisorption
(D) IV is chemisorption and III is chemisorption
39. (A), (C)
I: In physisorption, as the temperature increases the amount of gas adsorbed
decreases.
II : In chemisorption, as the temperature increases the amount of gas adsorbed
increases (to a certain range of temperature)
x
III : Fruendlich adsorption isotherms for physisorption kp1/n (at constant T)
m
IV : Hads = 150 KJ is in the range for chemisorption.
21
40. The reversible expansion of an ideal gas under adiabatic and isothermal conditions is
shown in the figure. Which of the following statement(s) is (are) correct?
(A) T1 = T2 (B) T3 > T1

(C) Wisothermal = Wadiabatic (D) Uisothermal > Uadiabatic
40. (A), (D)
Process is isothermal implies T1 = T2 A is correct
T1V11  T3V21
1
T3  V1 
  V2  V1 from the diagram
T1  V2 
1
V V 
 1 1   1  1  T3 < T1
V2  V2 
Option B is incorrect
For an ideal gas, internal energy is a function of Temperature. Final temperature for
adiabatic process is less than its initial temperature, while initial and final temperature for
isothermal process is same. Hence, internal energy change for isothermal process is
greater than internal energy change for adiabatic process (Uiso = 0 and Uadia < 0)
 option D is correct.
PART III - MATHEMATICS

SECTION I : Single Correct Choice Type
41. The value of the integral

 /2
 2  x 

 /2
 x  1n
   x
 cosxdx is

2 2 2
(A) 0 (B) 4 (C) 4 (D)
2 2 2
41. (B)
 
2 2
 x
 x cos x dx    cos x dx
2
n
x
 
2 2
22

2
= 2   x 2 cos x dx  0 [as 2nd integration, as function is odd]
0
      
 2 /2 2    2   /2
2 
= 2  x  sin x  2  x sin x dx  = 2   2  x cos x 0   cos x dx 
 0
0  4  0 
  
 2
 
 /2   2
= 2   2 0  sin x 0  = 2   2(1)  =
4  4


2
2
4
42. Let a1, a2, a3, … be in harmonic progression with a1 = 5 and a20 = 25. The least positive
integer n for which an < 0 is
(A) 22 (B) 23 (C) 24 (D) 25
42. (D)
a1, a2, …… a20 H.P.
1 1 1
, ,...... A.P.
a1 a 2 a 20
1 1 4
   19d  d 
25 5 475
1  4 
T25    24   
5  475 
1 96
T25  
5 475
1
T25 
475
43. The equation of a plane passing through the line of intersection of the planes x+2y+3z = 2
2
and x  y + z = 3 and at a distance from the point (3, 1, 1) is
3
(A) 5x  11y + z = 17 (B) 2xy3 2  1
(C) x + y + z = 3 (D) x 2y1 2
43. (A)
Equation of family of planes passing through
x + 2y + 3z  2 = 0 and x  y + z  3 = 0 is
(x + 2y + 3z  2) +  (x  y + z  3) = 0
 (1 + ) x + (2  ) y + (3 + ) z  (2 + 3) = 0
 Distance of (3, 1, 1) from required plane is
(1  )3  (2  )1  (3  )(1)  (2  3) 2

(1  )  (2  )  (3  )
2 2 2 3
 2 7
    
3 2  4  14 3 2
Hence equation of required plane is
5 11 z 21
 x  y 2  0
2 2 2 2
 5x  11y + z = 17
23
7 5
44. Let PQR be a triangle of area  with a = 2, b = and c = , where a, b and c are the
2 2
lengths of the sides of the triangle opposite to the angles at P, Q and R respectively. Then
2sinP  sin2P
equals.
2sinPsin2P
2 2
3 45  3   45 
(A) (B) (C)   (D)  
4 4  4   4 
44. (C)
2sin P  2sin P cos P P

2sin P  2sin P cos P
1  cos P 3
  5/2 7/2
1  cos P 32
29
cos P =
35
1 5 7 8 6 R Q
=   
2 2 2 35
2
 3 
 = 6   
 4 
45. If aandb are vectors such that a  b = 29 and a  (2iˆ  3jˆ  4k)
ˆ (2iˆ  3jˆ  4k)
ˆ b ,
then a possible value of (a  b)  (7iˆ  2ˆj  3k)

ˆ is
(A) 0 (B) 3 (C) 4 (D) 8
45. (C)
a  b  29
  
a  2i  3j  4k  2i  3j  4k  b 
a   2i  3j  4k    2i  3j  4k   b  0
a   2i  3j  4k   b   2i  3j  4k   0
 a  b    2i  3j  4k   0
a  b 2i  3j  4k sin  n  0
sin θ = 0
  
It means a  b and 2i  3j  4k are parallel. The angle a  b & 2i  3j  4k will form 
  
same angle will be form by 2i  3j  4k & 7i  2 j  3k . 
Let θ is the angle between this pair then
cos  
 2i  3j  4k . 7i  2 j  3k 
 2i  3j  4k   7i  2 j  3k 
14  6  12 4
cos   
29 61 29 61
Now the possible value of
24
 a  b . 7i  2 j  3k   a  b  7i  2 j  3k cos 

4
= 29 61. =4
29 61
46. If P is a 3 3 matrix such that PT = 2P + I, where PT is he transpose of P and I is the 3  3

 x  0
identity matrix, then there exists a column matrix X =  y  0 such that
 z  0
0 
(A) PX0  (B) PXX (C) PX = 2X (D) PX = X
 0 
46. (D)
P is a 3  3 matrix
PT = 2P + I
a b c
Let P =    
 
 l m n 
a  l 
P =  b  m 
T
 c  n 
PT = 2P + I
a  l   2a 2b 2c  1 0 0 
b  m  =  2 2 2   +  0 1 0 
     
 c  n   2l 2m 2n   0 0 1 
a  l   2a  1 2b 2c 
b  m  
= 2 2  1 2 
   
 c  n   2l 2m 2n  1
a = 2a + 1  a = 1
 = 2 + 1   = 1
n = 2n + 1  n = 1
2b = , b = 2. It is possible when b =  = 0
Similarly, c = l = 0
and m==0
 1 0 0 
The matrix P is  0 1 0 
 
 0 0 1
So, PX = X
Correct answer is (D)
25
47. Let (a) and (a) be the roots of the equation

3
    
1  a 1 x 2  1  a  1 x 6 1  a 1 = 0 where a > 1.
Then lim a 0 (a) and lim a 0 (a)are
5 1 7 9
(A)  and1 (B)  and 1 (C)  and2 (D)  and3
2 2 2 2
47. (B)
 3 1  a  x 2   1  a 1 x 1  a 10, where a > 1
6
1  a 1
6
  1  a  1
(a) (a) = (a) + (a) =
1a  1
3
 3 1  a 1
a  0+ (a)  (a) (1  a)1/ 2  11/ 2
(1  a)1/6  11/6  a(a) =
a 0 (1  a)1/3  11/3
(1  a)  1
= lt 
a 0 (1  a)  11/3 (1  a)1/2  11/2
1/3
(1  a)  1
(a)(a) = (1  1/3
a)  1
1 a 0 
(1  a)  11/3
=
2 (1  a)  1
3
=
2
(a)  (a) = 1/2

(a) + (a) = 3/2
By solving (a) 1/ 2and(a)  1
a 0 a 0
48. Four fair dice D1, D2, D3 and D4, each having six faces numbered 1, 2, 3, 4, 5 and 6, are
rolled simultaneously. The probability that D4 shows a number appearing on one of D1, D2
and D3 is
91 108 125 127
(A) (B) (C) (D)
216 216 216 216
48. (A)
n(S) = 6  6  6  6 = (6)4
n  E  = 6  5  5  5
6  5  5  5 125
P(E) = 
6  6  6  6 216
125 91
P(E) = 1  P(E ) = 1  
216 216
SECTION II
Paragraph Type
questions on each paragraph. Each question has four choices (A) , (B) , (C) and (D) out of
26
 2(t  1)
x

Let f(x) = (1x) sin x + x for all x  IR, and let g(x) =    1nt  f (t)dt for all
2 2 2
1 t 1 
x  (1, ).
49. Consider the statements :

P : There exists some x  IR such that f(x) + 2x = 2(1+x2)
Q : There exists some x  IR such that 2f(x) +1 = 2x(1+x)
Then
(A) both P and Q are true (B) P is true and Q is false
(C) P is false and Q is true (D) both P and Q are false.
49. (C)
P : f(x) + 2x = 2 (1 + x2)
(1  x)2 sin2 x + x2 + 2x = 2 + 2x2
(1  x)2 sin2 x + 2x = x2 + 2
(x2  2x + 1) sin2 x + 2x = x2 + 2
2x cos2 x = x2 cos2 x + cos2 x + 1
cos2 x (x2  2x + 1) + 1 = 0
(1  x)2 cos2 x + 1 = 0 Hence no solution
Also
Q : 2f(x) + 1 = 2x + 2x2
1
1  x 2 sin 2 x  x 2   x  x 2
2
1
Let g(x) = 1  x  sin 2 x   x
2
2
1
g(0) =  0
2
1
g() =    0
2
 There exists a solution of g(x) in [0, ]. Hence statement Q is true.
50. Which of the following is true ?

(A) g is increasing on (1, )
(B) g is decreasing on (1, )
(C) g is increasing on (1, 2) and decreasing on (2, )
(D) g is decreasing on (1, 2) and increasing on (2, )
50. (B)
x
 2(t  1) 
g(x) =    n t  f (t) dt  x (1, )
1
t 1 
 2(x  1) 
g(x) =   n x  f (x)
 x 1 
we know,
f(x) > 0  x  .
2(x  1)
Let h(x) =  nx
x 1
27
4
h(x) = 2   nx
x 1
4 1 4x  (x  1) 2
h(x) =  =
(x  1) 2 x x(x  1) 2
(x  1)2
=
(x  1)2
 h(x) < 0
 h is decreasing x > 1
h(x) < h(1)
2(x  1)
  n x 0
x 1
  x  (1, )
2(x  1)
 nx  0
x 1
 g(x) < 0  x  (1, )
 g is decreasing in (1, )
A tangent PT is drawn to the circle x2 + y2 = 4 at the point P  

3,1 . A straight line L,
perpendicular to PT is a tangent to the circle (x  3)2 + y2 = 1
51. A common tangent of the two circles is

(A) x = 4 (B) y = 2 (C) x  3y  4 (D) x  2 2y  6
51. (D)
Tangent in slope to x2 + y2 = 4 is y  mx  2 1  m2
Similarly tangent to (x  3)2 + y2 = 1 is y  m  x  3  1  m 2 …… (1)
 y  mx  3m  1  m2 …… (2)
(1) & (2) identical
2 1  m 2
 1
3m  1  m 2
  3m  1  m2  2 1  m2
Taking (+) sign
3m  1  m2  2 1  m2
3m  1  m2 P
Squaring 9m2 = 1 + m2
1
m
2 2
(3, 0)
Taking () sign
3m  1  m2  2 1  m2
3m  3 1  m2
m2 = 1 + m2
28
(This is not possible)

So put (1)
y  mn  2 1  m2
1 1
y x  2 1
2 2 8
1 23
y x
2 2 2 2
2 2y   x  6
Taking (+) 2y   x  6
 x  2 2y  6
(only this option given)
52. A possible equation of L is

(A) x  3y  1 (B) x  3y  1 (C) x  3y  1 (D) x  3y  5
52. (A)
 
Equation of tangent at P 3,1 to x2 + y2 = 4 is
x 3y4
Slope of tangent is =  3
1
So, Slope of L is =
3
1
So, equation of L (is tangent to (x  3)2 + y2 = 1 & slope = )
3
1 1
y  x  3  1 
3 3
3y  x  3  2
Taking (+) sign, 3y  x  3  2
x  3y  1
Taking () sign, 3y  x  3  2
x  3y  5
Let an denote the number of all ndigit positive integers formed by the digits 0, 1 or both such
that no consecutive digits in them are 0. Let bn = the number of such ndigit integers ending
with digit 1 and cn = the number of such ndigit integers ending with digit 0.
53. Which of the following is correct?

(A) a17 = a16 + a15 (B) c17 ≠ c16 + c15 (C) b17 ≠ b16 + c16 (D) a17 = c17 + b16
53. (A)
a1 = 1
a2 = 2
a3 = 3
a4 = 5
an is following fibonacci series. Hence a17 = a16 + a15 .
29
54. The value of b6 is

(A) 7 (B) 8 (C) 9 (D) 11
54. (B)
1    1
Total no of ways exactly two consecutive two is = 5 ways
Total no of ways exactly three consecutive two is = 2 ways
Total no of ways exactly four consecutive two is = 1 ways
So, b6 = 5 + 2 + 1 = 8

This section contains 6 multiple choice questions. Each question has four choices (A) , (B) ,
x 1 y  1 z x 1 y 1 z
55. If the straight lines   and   are coplanar, then the plane (s)
2 k 2 5 2 k
containing these two lines is (are)
(A) y + 2z = 1 (B) y + z = 1 (C) y  z = 1 (D) y 2z = 1
55. (B), (C)
Points (1, 1, 0) & (1, 1, 0) lies on the required plane.
The normal to the plane required is
i j k
 
= 2 k 2  ˆi k 2  4  ˆj(2k 10)  kˆ (4  5k)
5 2 k
 The equation of required plane containing both the lines is
(k2  4) x + (10  2k) y + (4  5k) z = d ……………. (1)
Point (1, 1, 0) lies on the plane (1)
(k2  4) + (2k  10) = d
 Equation of plane is
(k2  4) x + (10  2k) y + (4  5k) z = k2 + 2k  14 …………… (2)
 k2  4 = 0  k = ± 2
from (2) we get, for k = 2,
6y  6z = 6  y  z = 1
for k = 2
14 y + 14 z = 14
y + z = 1
1 4 4 
56. If the adjoint of a 3 3 matrix P is  2 1 7  , then the possible value(s) of the
 1 1 3 
determinant of P is (are)
(A) 2 (B) 1 (C) 1 (D) 2
56. (A), (D)
1 4 4 
adjP   2 1 7   adj P  4
1 1 3 
30
n 1
We know, adj P  P (where n is order of matrix)
2
 adj P  P
2
4 P
 P  2
2    
57. Let f : (1, 1)  IR be such that f(cos 4) = for   0,   ,  , Then the
2  sec 
2
 4 4 2
1
value(s) of f   is (are)
3
3 3 2 2
(A) 1  (B) 1  (C) 1  (D) 1 
2 2 3 3
57. (A), (B)
2
f  cos   
2  sec2 
2cos 2  1  cos 2
f  cos    
cos 2 cos 2
1
cos 4 
3
1
2cos 2 2  1 
3
2
1
cos2  
2 1
f  3  3 2
3 3 2 2
3
2
1
1
 f    1
3
and
 
1
f  3  3 2
 3 2 3 2  2

3
1 3
f    1
 3 2
1 1 1
58. Let X and Y be two events such that P(X | Y) = , P(Y | X) = , and P(X  Y) = .
2 3 6
Which of the following is (are) correct?
2
(A) P(X  Y) (B) X and Y are independent
3
1
(C) X and Y are not independent (D) P(Xc  Y)
3
58. (A) and (B)
 X  P(X  Y) 1 1
P     P(Y)2P(X  Y)  P(Y)2 
Y P(Y) 2 6
1
 P(Y) = … (1)
3
31
 Y  P(X  Y) 1
P     P(X) = 3P(X  Y)
X P(X) 3
1 1
= 3 =
6 2
1
= P(X) = … (2)
2
P(XY) = P(X) + P(Y)  P(XY)
1 1 1
=  
2 3 6
5 1 2
=   (A : correct)
6 6 3
1 1 1
P(X Y) =   = P(X)  P(Y)
6 2 3
 X & Y are in dependent (B : correct)
= Xc & Y are in dependent.
P(Xc  Y) = P  Xc   P  X 
= 1  P  X    P  Y 
 1 1 1 1
= 1    = 
 2 3 6 3
 (A), (B) correct.
x
59. If f(x) =  et (t2)(t  3)dt for all x  (0, ), then
2
0
(A) f has a local maximum at x = 2
(B) f is decreasing on (2, 3)
(C) there exists some c  (0, ) such that f(c) = 0
(D) f has a local minimum at x = 3
59. (A), (B), (C), (D)
x
2
f(x) =  e t (t  2) (t  3) dt  x  (0, )
0
2
f (x) = ex (x  2) (x  3)
 f is increasing in (, 2)  (3, )
f is decreasing in (2, 3)
f (2) = f (3) = 0
3
& f (x) is differentiable on (2, 3) 2
and also continuous on [2, 3]
 By Rolle's theorem,
at least one c such that c (2, 3)
f (x) = 0
32
60. For every integer n, let an and bn be real numbers. Let function f : IR  IR be given by
a sinx, forx[2n,2n  1]
f(x) =  n ,forallintegersn.
bn  cos x, forx(2n1,2n)
If f is continuous, then which of the following hold(s) for all n?
(A) a n 1 b n 10 (B) a n  b n  1
(C) a n  b n 1  1 (D) a n 1  b n  1
60. (B), (D)

f is continuous on
f(2n) = an + sin ( . 2n)
= an
At x = 2n
Lt f (x) = Lt b n  cos x
x 2n  x 2n 
= b n  cos(2n)
= bn + 1
Lt f (x) = Lt a n  sin ( x)
x 2n  x 2n 
= an + sin (2 n)
= an
 an = bn + 1  a n  bn  1
At x = 2n + 1
f(2n + 1) = an + sin ( (2n + 1))
= an + sin (2n + ) = an
Lt f(x) = Lt a n  sin  x  a n  sin (2n   ) = an
 
x  2n 1 x  2n 1
Lt f (x) = Lt bn 1  cos x
x (2n 1)  x  2n 1

= bn1  cos  (2n  1) 

= b n 1  1
 an = bn+1  1  a n  bn 1  1

33

Magnetic Field of a Hollow Conducting Cylinder

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CODE : 7 TEST ID : 624

IIT JEE Advance 2012

INSTRUCTED TO DO SO BY THE INVIGILATOR

1. A student is performing the experiment of Resonance Column. The diameter of the

From inside expression at r = R

6. In the given circuit, a charge of +80 C is given to the upper

SECTION II : Paragraph Type

Case (a) Case (b)

Paragraph for Questions 13 and 14

SECTION III : Multiple Correct Answer(s) Type

(A) The electric field at O is 6K along OD.

15. (A), (B), (C)

Considering the electric field at O;

Net field along OD = 4K   2K  cos60   2K  cos60  6K

(A) the point O has a linear velocity 3R i

17. (A) (B)

 The Magnetic flux above and below the i

20. (A), (C)

SECTION I : Single Correct Choice Type

22. The major product H of the given reaction sequence is

26. The shape of XeO2F2 molecule is

(C) COOH (D) CH2COOH

SECTION II : Paragraph Type

The electrochemical cell shown below is a concentration cell.

Paragraph for Question 31 to 32

31. The compound K is

(A) (B) (C) (D)

(A) (B) (C) (D)

Paragraph for Question 33 and 34

33. 25 mL of household bleach solution was mixed with 30 mL of 0.50 M KI and 10 mL of 4

SECTION III : Multiple Correct Answer(s) Type

(A) The first reaction is a redox reaction

(A) T is soluble in hot aqueous NaOH

36. (A), (C), (D)

(A) M and N are nonmirror image stereoisomers

37. (A) , (B) , (C)

(A) I is physisorption and II is chemisorption

(A) T1 = T2 (B) T3 > T1

PART III - MATHEMATICS

41. The value of the integral

then a possible value of (a  b)  (7iˆ  2ˆj  3k)

 a  b . 7i  2 j  3k   a  b  7i  2 j  3k cos 

46. If P is a 3 3 matrix such that PT = 2P + I, where PT is he transpose of P and I is the 3  3

47. Let (a) and (a) be the roots of the equation

(a)  (a) = 1/2

Paragraph for Questions 49 and 50

49. Consider the statements :

50. Which of the following is true ?

Paragraph for Questions 51 and 52

A tangent PT is drawn to the circle x2 + y2 = 4 at the point P  

51. A common tangent of the two circles is

(This is not possible)

52. A possible equation of L is

53. Which of the following is correct?

54. The value of b6 is

SECTION III : Multiple Correct Answer(s) Type

60. (B), (D)

= bn1  cos  (2n  1) 

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