Eb d17523 Da Gallery Nutrient Water Ebd17523 en PDF

Table of Contents
Water analysis
Alkalinity
Ammonia
Calcium
Chloride
Chromium (VI)
Fluoride
Iron (Ferrous)
Magnesium
Nitrite
Phosphate
Silica
Sulfate
Automated nutrient analysis and
Total Hardness water quality monitoring
Total Oxidized Nitrogen
(TON Hydrazine)
Total Oxidized Nitrogen Fast and accurate Thermo Scientific Gallery discrete industrial analyzers
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Ease-of-use into water analysis
Water analysis
Alkalinity
Ammonia
Calcium
Chloride
Chromium (VI)
Fluoride
Iron (Ferrous)
Magnesium
Nitrite
Phosphate
Silica
Sulfate Clean water in sufficient amounts is an ongoing global challenge. of water and environmental samples. Gallery and Gallery Plus
Water resources are experiencing increasing pressure in many parts provide repeatable results while full automation improves quality and
Total Hardness of the world, requiring countries to improve the management and efficiency. Bar-coded traceable system reagents save technician
protection of water ecosystems. time and reduce errors, thus ensuring confidence in the quality of
(TON Hydrazine) Thermo Scientific™ Gallery™ analyzers are sophisticated discrete the results.
Total Oxidized Nitrogen photometric systems for the precise and easily adaptable analysis
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Alkalinity
Water analysis
Alkalinity
Ammonia
Calcium
Chloride
Chromium (VI)
Fluoride
Iron (Ferrous)
Alkalinity is a measure of the capacity of water to neutralize acids. Measuring range
Measuring alkalinity is important also in determining, e.g., a lake’s
Magnesium Name of the Extended
ability to neutralize acidic pollution from rainfall or waste water. Application
application and range measuring range
Nitrite Chemistry: Bromophenol Blue and phthalate buffer pH 3.5

Alkalinity *- 400 mg CaCO3/L —
References: N/A
Phosphate Calibration
Reagents Kit size Preparation Max. nbr of tests Calibration is 2nd order using 1200 mg CaCO3/L standard in
Silica 984623 Alkalinity R1 4 × 20 mL Ready to use 975 automatic dilution. Calibration standard is prepared from Na2CO3.
984624 Alkalinity R2 4 × 20 mL Ready to use 780 1.00

Sulfate
Response (Abs)
R2 = 0.99896
0.80
Total Hardness Sample matrix 0.60
Drinking, ground, and surface water 0.40

0.20
0.00
(TON Hydrazine)
0 50 100 150 200 250 300 350 400 450
Concentration (mg CaCO3/L)
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Alkalinity
Water analysis
Method Detection Limit (MDL)
Alkalinity
Average MDL
Application Sample n SD
(mg CaCO3/L) (mg CaCO3/L)
Ammonia
blank 7 3.07 1.077 3.41
Alkalinity
Calcium blank 50 3.16 0.735 5.42
1
MDL = 3.14 × SD (blank sample, n=7)
Chloride 2
MDL = 3 × SD + average (blank sample, 3 batches, n=30)
Chromium (VI) Precision

Precision was tested in 10 replicates and 3 batches for each sample.
Fluoride Lake Water Tap Water Lake water
(mg CaCO3/L) (mg CaCO3/L) (mg CaCO3/L)
Iron (Ferrous) N 49 N 50 N 50
Mean 28.8 Mean 32.5 Mean 177.7

Magnesium
SD CV % SD CV % SD CV %
Nitrite Within 0.725 2.5 % 0.849 2.6 % 1.287 0.7 %
Between 0.626 2.2 % 0.196 0.6 % 4.462 2.5 %

Phosphate
Total 0.958 3.3 % 0.871 2.7 % 4.644 2.6 %
Silica
Linearity
Sulfate Method linearity was tested with pure chemicals dissolved in DI water
between 0–400 mg CaCO3/L.
Total Hardness
Measured (mg CaCO3/L)
500
R2 = 0.9993
400
(TON Hydrazine) 300
200
(TON Vanadium) 100
Total Oxidized Nitrogen 0

(TON Enzymatic) 0 50 100 150 200 250 300 350 400 450
Theoretical (mg CaCO3/L)
Gallery analyzers
Table of Contents Ammonia
Water analysis Ammonia (NH3) is a common toxicant derived from wastes, Measuring range
fertilizers, and natural processes. Ammonia is a common cause Extended measuring
Alkalinity of fish kills. Application Range
range (dil. 1+4)
Ammonia Low *- 200 µg N/L Up to 1000 µg N/l
Ammonia Chemistry: Sodium dichloroisocyanurate, sodium salicylate
and sodium nitroprusside Ammonia High 0.2–2 mg N/L Up to 10 mg N/L
Calcium References: NISBN 0117516139, ISO 7150, DIN 38 406,

ISO 15923-1 Calibration
Calibration is linear or 2nd order depending on the range selected
Chloride
Reagents Kit size Preparation Max. nbr of tests using 1000 µg/L as N standard for low range and 10 mg N/L for
high range in automatic dilution.
Chromium (VI) 984362 Ammonia R1 1 × 125 mL Ready to use 2000
0.20 2.00
R2 = 0.9999 R2 = 0.9996
Response (Abs)
Response (Abs)
984363 Ammonia R2 4 × 20 mL Ready to use 1300 0.15 1.50
Fluoride
0.10 1.00
Sample matrix
0.05 0.50
Iron (Ferrous) Drinking, ground, surface, and waste water
0.00 0.00
0 100 200 0.0 0.5 1.0 1.5 2.0 2.5
Magnesium Concentration (µg N/L) Concentration (mg N/L)
Nitrite
Phosphate
Silica
Sulfate
Total Hardness

(TON Hydrazine)
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Ammonia
Water analysis Method Detection Limit (MDL) Linearity
Method linearity was tested with pure chemicals dissolved in DI water
Alkalinity Application Sample n
Average
SD
MDL
between 5–2000 µg N/L.
(µg N/L) (µg N/L)
2500
Ammonia blank 7 0.52 0.164 0.51
Ammonia L R2 = 0.99973
2000
Measured (µg N/L)

blank 50 0.55 0.358 1.62
Calcium
1
1500
2
Chloride 1000
Precision
Chromium (VI) Precision was tested in 10 replicates and 5 batches for each sample. 500
Pond water Tap water

0
Fluoride (µg N/L) (µg N/L) 0 500 1000 1500 2000 2500
N 50 N 50 Theoretical (µg N/L)
Iron (Ferrous)
Mean 17 Mean 189
SD CV % SD CV %
Magnesium
Within 0.340 1.9 % 0.849 0.4 %
Nitrite Between 0.786 4.5 % 0.871 0.5 %
Total 0.856 4.9 % 1.216 0.6 %

Phosphate
Silica
Sulfate
Total Hardness

(TON Hydrazine)
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Calcium
Water analysis Calcium is source of hard water but is not harmful. It can cause Calibration
calcification which causes breakdowns of, e.g. boilers or coolers. Calibration is 2nd order using 2000 mg/L standard in automatic
Alkalinity dilution.
Chemistry: Arsenazo III 1.00
Ammonia R2 = 0.99919
References: Tietz Fundamentals of Clinical Chemistry,
Response (Abs)
0.80
5th edition 0.60
Calcium
Reagents Kit size Preparation Max. nbr of tests 0.40
0.20
Chloride 984361 Calcium R1 3 × 20 mL Ready to use 350
0.00
0 50 100 150 200 250
Chromium (VI) Sample matrix Concentration (mg/L)
Drinking, ground, surface, and waste water
Fluoride
Measuring range
Iron (Ferrous) Extended measuring
Application Range
range (dil. 1+4)
Magnesium Calcium *- 200 mg N/L Up to 1000 mg/L
Nitrite
Phosphate
Silica
Sulfate
Total Hardness

(TON Hydrazine)
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Gallery analyzers
Table of Contents Calcium
Average
SD
MDL between 10–1000 mg/L.
(mg/L) (mg/L)
1200
R2 = 0.9994
Ammonia
Measured (mg/L)
Calcium blank 7 1.99 0.369 1.161 1000
1 800
Calcium 600
Precision 400
Chloride Precision was tested in 10 replicates and 5 batches for each sample. 200
0
Tap water Soda water Bottle water 0 200 400 600 800 1000 1200
Chromium (VI) (mg/L) (mg/L) (mg/L) Theoretical (mg/L)
N 50 N 50 N 50
Fluoride
Mean 17 Mean 82 Mean 30
Iron (Ferrous) SD CV % SD CV % SD CV %
Within 0.218 1.3 % 0.449 0.5 % 0.223 0.7 %

Magnesium Between 0.273 1.6 % 2.153 2.6 % 0.694 2.3 %
Total 0.350 2.0 % 2.200 2.7 % 0.729 2.4 %

Nitrite
Phosphate
Silica
Sulfate
Total Hardness

(TON Hydrazine)
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Chloride
Water analysis Chloride in water may be considerably increased by treatment Measuring range
processes in which chlorine or chloride is used.
Extended measuring
Alkalinity Application Range
range (dil. 1+4)
Chemistry: Mercury (II) thiocyanate
Chloride Low *- 20 mg N/L Up to 100 mg/L
Ammonia References: ISBN 0117516260, EPA 325.2, SM 4500 Cl-E, EN
ISO 15682, ISO 15923-1 Chloride High 20–100 mg/L Up to 500 mg/L
Calcium
Reagents Kit size Preparation Max. nbr of tests
Calibration
Chloride 984364 Chloride R1 4 × 20 mL Ready to use 500 Calibration is 2nd order using 100 mg/L standard for low range and
984365 Chloride R1 L 20 × 20 mL Ready to use 2500
500 mg/L for high range in automatic dilution.
Chromium (VI) 0.60 2.00
Response (Abs)
Response (Abs)
Sample matrix R2 = 1 R2 = 0.99927
0.40 1.50
Fluoride Drinking, ground, surface, waste and saline water
0.20 1.00
Iron (Ferrous) 0.00 0.50

0 10 20 20 40 60 80 100 120
Concentration (mg/L) Concentration (mg/L)
Magnesium
Nitrite
Phosphate
Silica
Sulfate
Total Hardness

(TON Hydrazine)
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Chloride
Water analysis Method Detection Limit (MDL)
Average
SD
MDL
(mg/L) (mg/L)
Ammonia blank 7 0.23 0.011 0.0351

Chloride L
blank 50 0.22 0.042 0.3492
Calcium 1
2
Chloride
Precision
Chromium (VI)
Pond water Tap water Pond water
Fluoride (mg/L) (mg/L) (mg/L)
N 50 N 50 N 50
Iron (Ferrous) Mean 2.5 Mean 4.9 Mean 16.5
Magnesium
Within 0.075 0.5 % 0.031 1.2 % 0.030 0.6 %
Nitrite Between 0.224 1.4 % 0.011 0.4 % 0.020 0.4 %
Total 0.236 1.4 % 0.033 1.3 % 0.036 0.7 %

Phosphate
Linearity
Silica
between 2–500 mg/L.
Sulfate
600
R2 = 0.9998
Measured (mg/L)
500
Total Hardness 400
300
(TON Hydrazine) 200
100
(TON Vanadium) 0
0 100 200 300 400 500 600
Total Oxidized Nitrogen Theoretical (mg/L)
(TON Enzymatic)
Gallery analyzers
Table of Contents Chromium (VI)
Water analysis Hexavalent chromium is used for the production of stainless steel, Measuring range
textile dyes, wood preservation, leather tanning, and as anti-
Extended measuring
Alkalinity corrosion and conversion coatings as well as a variety of niche Application Range
range (dil. 1+4)
uses. Hexavalent chromium compounds are genotoxic carcinogens. Chromium Low *- 100 µg/L —
Ammonia
Chemistry: Diphenylcarbizide Chromium High 100–500 µg/L Up to 1000 µg/L
Calcium References: SM 3500 Cr-B, SW 7196 A, DIN EN ISO
23913:2009, ISO 11083 Calibration
Chloride Calibration is 2nd order using 300 µg/L standard for low range and
5000 µg/L high range in automatic dilution.
0.10 0.40
Chromium (VI) 984357 Chromium(VI) 4 × 20 mL Ready to use 480 R2 = 0.99984 R2 = 0.99991
Response (Abs)
Response (Abs)
0.08 0.30
0.05 0.20
Fluoride Sample matrix
0.03 0.10
Drinking, ground, surface, and waste water
Iron (Ferrous) 0.00
0 50 100 150
0.00
0 200 400 600
Concentration (µg/L) Concentration (µg/L)
Magnesium
Nitrite
Phosphate
Silica
Sulfate
Total Hardness

(TON Hydrazine)
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Chromium (VI)
Average
SD
MDL
(µg/L) (µg/L)
Ammonia Chromium (VI) L blank 7 0.41 0.824 2.61

1
Calcium
Precision
Chloride Precision was tested in 10 replicates and 5 batches for each sample.
Waste water Clean water Spiked waste water
Chromium (VI) (µg/L) (µg/L) (µg/L)
N 50 N 50 N 50
Fluoride
Iron (Ferrous)
Within 0.931 2.2 % 1.063 1.3 % 1.532 0.3 %
Magnesium Between 0.831 2.0 % 0.879 1.1 % 2.822 0.6 %
Total 1.248 2.9 % 1.379 1.7 % 3.211 0.7 %

Nitrite
Phosphate Linearity
between 8–1100 µg/L.
Silica
1200
R2 = 0.99992
1000
Measured (µg/L)
Sulfate
800
600
Total Hardness 400
(TON Hydrazine) 0
0 200 400 600 800 1000 1200
Total Oxidized Nitrogen Theoretical (µg/L)
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Fluoride
Water analysis Fluoride exists naturally in water sources and helps prevent
the tooth decay. If present in amounts greater than 4 mg/L
Alkalinity in the drinking water, it may cause health problems. Possible
contamination sources are erosion of natural deposits and
Ammonia
discharge from fertilizer or aluminum factories.
Calcium Chemistry: Alizarine fluorine blue and cerous nitrate

References: EPA 340.3, SM 4500 F-E
Chloride
Chromium (VI) 984629 Fluoride R1 4 × 20 mL Ready to use 2200
984630 Fluoride R2 4 × 20 mL Ready to use 4800

Fluoride
984631 Fluoride R3 4 × 20 mL Ready to use 2200
Iron (Ferrous)
Sample matrix
Magnesium Drinking, ground, surface, waste, and saline water
Nitrite Measuring range

Extended measuring
Phosphate Application Range
range (dil. 1+4)
Fluoride 0.05-1 mg/L up to 5 mg/L
Silica
Sulfate Calibration
Calibration is 2nd order using 3 mg/L standard in automatic dilution.
Total Hardness 0.50

R2 = 0.9979
0.40
Response (Abs)

(TON Hydrazine) 0.30
Total Oxidized Nitrogen 0.20
(TON Vanadium) 0.10

(TON Enzymatic) 0.00 0.20 0.40 0.60 0.80 1.00 1.20
Concentration (mg/L)
Gallery analyzers
Table of Contents Fluoride
Average
SD
MDL between 0.2–5.0 mg/L.
(mg/L) (mg/L)
5.00
Ammonia blank 7 0.03 0.002 0.0071 R2 = 0.99883
Result (mg/L)
Fluoride 4.00
blank 50 0.03 0.021 0.0892 3.00
Calcium 1
MDL = 3.14 × SD (blank sample, n=7) 2.00
2
1.00
Chloride
0.00
Precision 0.00 1.00 2.00 3.00 4.00 5.00
Chromium (VI) Precision was tested in 10 replicates and 5 batches for each sample. Theoretical (mg/L)
Tap water Surface water Ground water

Fluoride (mg/L) (mg/L) (mg/L)
N 50 N 50 N 50
Iron (Ferrous)
Magnesium SD CV % SD CV % SD CV %
Within 0.008 0.9 % 0.004 2.0 % 0.006 1.5 %

Nitrite Between 0.008 0.9 % 0.001 0.4 % 0.007 1.6 %
Total 0.011 1.3 % 0.004 2.0 % 0.009 2.2 %

Phosphate
Silica
Sulfate
Total Hardness

(TON Hydrazine)
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Iron (Ferrous)
Water analysis Iron naturally occurs in ground and surface waters and is also Method Detection Limit (MDL)
a byproduct of production baths at steel mills, foundries, and
Alkalinity chemical plants. Ferrous iron (Fe2+) acts as a strong reducing agent Application Sample n
Average
SD
MDL
(mg/L) (mg/L)
in high pH conditions. It can also be used as an alloy to decrease
Ammonia blank 7 0.01 0.017 0.051
the corrosiveness of metals. Fe2+
blank 30 0.01 0.009 0.042
Calcium Chemistry: Phenanthroline 1
References: ISO 6332-1988, SM 3500 Fe-B MDL = 3 × SD + average (blank sample, 3 batches, n=30)
2
Chloride
Reagents Kit size Preparation Max. nbr of tests Precision
Chromium (VI) Precision was tested in 10 replicates and 3 batches for each sample.
984706 Iron (Ferrous) R1 4 × 20 mL Ready to use 1900
QC-0.4 QC-0.8
984707 Iron (Ferrous) R2 4 × 20 mL Ready to use 1080
Fluoride (mg/L) (mg/L)
N 30 N 30
Iron (Ferrous) Sample matrix
Drinking, surface, and waste water Mean 0.41 Mean 0.81
Magnesium SD CV % SD CV %
Measuring range
Within 0.005 1.3 % 0.011 1.3 %
Nitrite Extended measuring
Application Range Between 0.004 0.9 % 0.002 0.3 %
range (dil. 1+4)
Total 0.006 1.6 % 0.011 1.3 %
Phosphate Fe2+ 0.2–1.0 g/L Up to 5 g/L
Silica Calibration Linearity

Calibration is 2nd order using 1 mg/L standard in automatic dilution. Method linearity was tested with pure chemicals dissolved in DI water
Sulfate between 0.2–5.0 mg/L.
0.12
R² = 0.99991
Response (Abs)
0.10 5.00
Measured (mg/L)
Total Hardness 0.08 R² = 0.99991
4.00
0.06
3.00
2.00
(TON Hydrazine) 0.02
1.00
0.00
Total Oxidized Nitrogen 0 0.2 0.4 0.6 0.8 1 1.2 0.00
(TON Vanadium) 0.00 1.00 2.00 3.00 4.00 5.00
Total Oxidized Nitrogen Theoretical (mg/L)
(TON Enzymatic)
Gallery analyzers
Table of Contents Magnesium
Water analysis Hard water has high concentrations of Mg2+ and Ca2+ ions. This is Measuring range
generally not harmful to one’s health but can pose serious problems
Extended measuring
Alkalinity in industrial settings. Application Range
range (dil. 1+3)
Magnesium 10–100 mg/L Up to 400 mg/L
Ammonia Chemistry: Xylidyl Blue I
References: Tietz Fundamentals of Clinical Chemistry,
Calcium 5th edition Calibration
Calibration is 2nd order using 1000 mg/L standard in automatic
Chloride Reagents Kit size Preparation Max. nbr of tests
dilution.
984358 Magnesium R1 8 × 11 mL Ready to use 350
0.70
Chromium (VI) R2 = 0.9995
0.60
Response (Abs)
0.50
Fluoride Sample matrix 0.40
Drinking, ground, surface, and waste water 0.30
0.20
Iron (Ferrous) 0.10
0.00
Magnesium 0 20 40 60 80 100 120
Nitrite
Phosphate
Silica
Sulfate
Total Hardness

(TON Hydrazine)
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Magnesium
Average
SD
(mg/L) (mg/L)
500
Ammonia 7 0.25 0.034 0.11 R2 = 0.99862
Measured (mg/L)
Magnesium blank 400
50 0.41 0.139 0.82
300
Calcium 1
200
2
Chloride 100
Precision 0
Precision was tested in 10 replicates and 3 batches for each sample. 0 50 100 150 200 250 300 350 400 450
Chromium (VI)
Theoretical (mg/L)
Tap water Surface water Waste water
Fluoride
(mg/L) (mg/L) (mg/L)
N 50 N 50 N 50
Iron (Ferrous)
Mean 24 Mean 67 Mean 27
Within 0.247 1.0 % 0.427 0.6 % 0.182 0.7 %

Nitrite
Between 0.603 2.5 % 1.560 2.3 % 0.438 1.6 %
Phosphate Total 0.651 2.7 % 1.617 2.4 % 0.474 1.8 %
Silica
Sulfate
Total Hardness

(TON Hydrazine)
(TON Vanadium)
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Gallery analyzers
Table of Contents Nitrite
Water analysis The major sources of nitrite are runoff from fertilizer use, sewage Calibration
and erosion of natural deposits. Nitrite may cause health problems if Calibration is linear using 2000 µg N/L standard in automatic
Alkalinity present in drinking water greater than 1 mg/L. dilution.
1.40
Ammonia Chemistry: Sulfanilamide coupling with N-(1-naphthyl)- R2 = 0.99998
Response (Abs)
1.20
ethylenediamine dihydrochloride 1.00
0.80
Calcium References: ISBN 0117515930, EPA 353.1, SM 4500 NO2-B, 0.60
ISO 13395:1996, DIN EN 26777, ISO 15923-1 0.40
0.20
Chloride 0.00
0 100 200 300 400 500 600
Chromium (VI) 984371 TON R3 4 × 20 mL Ready to use 1000
Concentration (µg N/L)
984371 TONR3L 20 × 20 mL Ready to use 5000
Fluoride
Sample matrix
Iron (Ferrous) Drinking, ground, surface, waste, and saline water
Measuring range
Magnesium
Extended measuring
Application Range
Nitrite range (dil. 1+4)
Nitrite *- 500 µg N/L Up to 2500 µg N/L
Phosphate
Silica
Sulfate
Total Hardness

(TON Hydrazine)
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Nitrite
Average
SD
MDL
(µg N/L) (µg N/L)
Ammonia 7 0.33 0.126 0.41

Nitrite blank
30 0.16 0.337 1.22
Calcium 1
2
Chloride
Precision
Tap Water Lake Water
Fluoride (µg N/L) (µg N/L)
N 30 N 30
Iron (Ferrous)
Mean 56 Mean 308
Magnesium SD CV % SD CV %
Within 0.177 0.3 % 1.041 0.3 %

Nitrite Between 0.849 1.5 % 4.096 1.3 %
Total 0.867 1.5 % 4.227 1.4 %

Phosphate
Silica Linearity
between 4–2000 µg N/L.
Sulfate
2000
Measured (µg/L)
R2 = 0.9998
Total Hardness 1500
1000
(TON Hydrazine) 500

(TON Vanadium) 0 500 1000 1500 2000
Theoretical (µg N/L)
(TON Enzymatic)
Gallery analyzers
Table of Contents Phosphate
Water analysis Used in farming fertilization, can cause excess aquatic plant growth Sample matrix
and oxygen depletion. It causes many water quality problems Drinking, ground, surface, waste, and saline water
Alkalinity including increased purification costs, decreased recreational and Measuring range
conservation value of an impoundments, loss of livestock and the
Ammonia Extended measuring
possible lethal effect of algal toxins on drinking water. Application Range
range (dil. 1+4)
Calcium Phosphate Low *- 200 µg P/L Up to 1000 µg P/L

Chemistry: Antimony potassium tartrate, Ammonium molybdate,
Ascorbic acid Phosphate High 0.2–2 mg P/L Up to 10 mg P/L
Chloride References: ISBN 0117515825, EPA 365.1 SM 4500 P-E.,
EN ISO 6878, ISO 15923-1
Calibration
Chromium (VI)
Reagents Kit size Preparation Max. nbr of tests Calibration is linear using 1000 µg P/L standard for low range and
10 mg P/L for high range in automatic dilution.
Fluoride 984366 Phosphate R1 4 × 20 mL Ready to use 2300
984367 Phosphate R1L 20 × 20 mL Ready to use 11700
Response (Abs)
0.15
Response (Abs)
1.00
R2 = 0.99986 R2 = 0.99993
Iron (Ferrous) 0.10 0.75
984368 Phosphate R1 4 × 20 mL Ready to use 3000 0.50
0.05 0.25
Magnesium 0.00 0.00
0 50 100 150 200 0.0 0.5 1.0 1.5 2.0
Concentration (mg P/L)
Nitrite Concentration (µg P/L)
Phosphate
Silica
Sulfate
Total Hardness

(TON Hydrazine)
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Phosphate
Linearity
Average
SD
MDL Method linearity was tested with pure chemicals dissolved in DI water
(µg P/L) (µg P/L) between 10–2000 µg P/L.
Ammonia blank 7 0.19 0.130 0.41
2000
Measured (µg/L)
Phos Low R2 = 0.9998
blank 40 0.82 0.921 3.62 1500
Calcium
1
1000
2
500
Chloride
0
Precision
0 500 1000 1500 2000
Theoretical (µg P/L)
Pond Water Spiked Lake Spiked Tap

Fluoride (µg P/L) Water (µg P/L) Water (µg P/L)
N 40 N 40 N 40
Iron (Ferrous)
Within 0.362 3.8 % 0.991 1.7 % 2.667 1.6 %

Nitrite
Between 0.103 1.1 % 3.554 6.0 % 2.746 1.6 %
Phosphate Total 0.376 4.0 % 3.690 6.3 % 3.828 2.3 %
Silica
Sulfate
Total Hardness

(TON Hydrazine)
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Silica
Water analysis Silica is an unwanted mineral since it deposit on the surfaces and Method Detection Limit (MDL)
form colloidal suspension. Water is typically analyzed for silica as
Alkalinity part of normal water quality analysis procedures. Application Sample n
Average
SD
MDL
(mg SiO2 /L) (mg SiO2 /L)
Ammonia Chemistry: Ammonium molybdate blank 7 0.005 0.002 0.011

Silica
References: ISO 15923-1, USGS I-2700-85, EPA 370.1, blank 50 0.008 0.015 0.052
Calcium SM 4500 SiO2-D 1
2
Chloride
984625 Silica R1 4 × 20 mL Ready to use 970 Precision
Chromium (VI) 984626 Silica R2 4 × 20 mL Ready to use 1950
984627 Silica R3 4 × 20 mL Ready to use 1950 Tap water Natural water Well water
Fluoride
(mg SiO2 /L) (mg SiO2 /L) (mg SiO2 /L)
Iron (Ferrous) Sample matrix N 50 N 50 N 50

Drinking, ground, surface, and waste water Mean 5.52 Mean 7.91 Mean 12.61
Measuring range
Within 0.007 0.3 % 0.016 0.2 % 0.033 0.3 %
Nitrite Extended measuring
Application Range
range (dil. 1+4) Between 0.007 0.3 % 0.022 0.3 % 0.074 0.6 %
Phosphate Silica *- 20 mg SiO2/L Up to 80 mg SiO2/L Total 0.010 0.4 % 0.027 0.3 % 0.081 0.6 %
Silica Calibration Linearity

Calibration is 2nd order using 60 mg/L standard in automatic dilution. Method linearity was tested with pure chemicals dissolved in DI water
Sulfate between 2.5–80 mg SiO2/L.
1.50
100
Measured (mg SiO2/L)

1.20
Response (Abs)
R2 = 0.99995
Total Hardness 0.90
R2 = 1 80
0.60 60
0.30
(TON Hydrazine)
0.00 20
-0.30
(TON Vanadium) 0 5 10 15 20 25 0 10 20 30 40 50 60 70 80 90
Total Oxidized Nitrogen Concantration (mg SiO2/L) Theoretical (mg SiO2/L)
(TON Enzymatic)
Gallery analyzers
Table of Contents Sulfate
Water analysis Sulfate is commonly found in air, soil and water. Since sulfate is Measuring range
easily dissolved, it is found at high concentrations in many surface
Extended measuring
Alkalinity water. Sulfate has laxative effects and imparts an unpleasant taste Application Range
range (dil. 1+4)
to water. Sulphate Low *- 20 mg/L Up to 100 mg/L
Ammonia
Chemistry: Barium chloride Sulphate High 20–100 mg/L Up to 500 mg/L
Calcium References: ISBN 0117533406, EPA 375.4, DIN 38405-D, SM
4500 SO4- E, ISO 15923-1
Chloride Calibration
Reagents Kit size Preparation Max. nbr of tests Calibration is 2nd order using 100 mg/L standard for low range and
500 mg/L for high range in automatic dilution.
Chromium (VI) 984648 Sulphate R1 4 × 20 mL Ready to use 1100
0.12 0.50
984649 Sulphate R1 XL* 4 × 60 mL Ready to use 5100 R2 = 0.99974 R2 = 0.99988
Response (Abs)
Response (Abs)
0.40
Fluoride 0.09
0.30
*60 mL vial for Aquakem analyzers only 0.06
0.20
Iron (Ferrous) Sample matrix
0.03 0.10
0.00 0.00
Drinking, ground, surface, and waste water 0 5 10 15 20 15 35 55 75 95
Magnesium Concentration (mg/L) Concentration (mg/L)
Nitrite
Phosphate
Silica
Sulfate
Total Hardness

(TON Hydrazine)
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Sulfate
Average
SD
(mg/L) (mg/L)
500
Measured (mg/L)
Ammonia Sulphate L Std 0.2 mg/L 7 1.05 0.084 1.261 R2 = 0.9997
400
1
300
Calcium 200
Precision
100
Chloride 0
Tap water Pond water 0 100 200 300 400 500
Chromium (VI) (mg/L) (mg/L) Theoretical (mg/L)
N 50 N 50
Fluoride Mean 24.0 Mean 72.0
SD CV % SD CV %
Iron (Ferrous)
Within 0.254 1.1 % 0.320 0.4 %
Magnesium Between 0.063 0.3 % 0.282 0.4 %
Total 0.262 1.1 % 0.427 0.6 %

Nitrite
Phosphate
Silica
Sulfate
Total Hardness

(TON Hydrazine)
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Total Hardness
Water analysis
Alkalinity
Ammonia
Calcium
Chloride
Chromium (VI)
Fluoride
Iron (Ferrous) Measuring range

High levels of hard-water ions such as Ca2+ and Mg2+ can cause
deposits in plumbing. These two ions also combine chemically with Extended measuring
Magnesium Application Range
range (dil. 1+4)
soap molecules, resulting in decreased cleansing action.
Total Hardness 20–200 mg CaCO3/L Up to 500 mg CaCO3/L
Nitrite Chemistry: Calmagite
References: EPA 130.1 Calibration
Phosphate Calibration is spline using 1000 mg/L as CaCO3 standard in
Reagents Kit size Preparation Max. nbr of tests automatic dilution.
Silica Concentration (mg CaCO3/L)
984620 Total Hardness R1 4 × 20 mL Ready to use 1100
20 40 60 80 100 120 140 160 180 200 220
Sulfate 984621 Total Hardness R2 4 × 20 mL Ready to use 975 0.00
Response (Abs)
R2 = 0.999
984622 Total Hardness R3 4 × 20 mL Ready to use 4300
-0.50
Total Hardness
Sample matrix -1.00
Total Oxidized Nitrogen Drinking, ground and surface water -1.50
(TON Hydrazine)
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Total Hardness
Average
SD
MDL between 20–500 mg CaCO3/L.
(mg/L CaCO3) (mg/L CaCO3)
600
Measured (mg CaCO3/L)

R2 = 0.99935
Ammonia blank 7 7.6 0.637 21
500
THardness
blank 50 7.7 0.612 102 400
Calcium 1
MDL = 3.14 × SD (blank sample, n=7) 300
2
200
Chloride
Precision 100
Chromium (VI) 0
0 100 200 300 400 500 600
Tap water Spiked tap water Ground water
Theoretical (mg CaCO3/L)
Fluoride (mg CaCO3/L) (mg CaCO3/L) (mg CaCO3/L)
N 50 N 50 N 50
Iron (Ferrous) Mean 52 Mean 157 Mean 82
Magnesium
Within 0.762 1.5 % 1.668 1.1 % 0.835 1.0 %
Nitrite Between 0.620 1.2 % 2.494 1.6 % 1.348 1.6 %
Total 0.983 1.9 % 3.001 1.9 % 1.586 1.9 %

Phosphate
Silica
Sulfate
Total Hardness

(TON Hydrazine)
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Total Oxidized Nitrogen (TON)/Nitrate
Water analysis
Alkalinity A plant nutrient and inorganic fertilizer, nitrate is found in septic Reagents Kit size Preparation Max. nbr of tests
systems, animal feed lots, agricultural fertilizers, manure, industrial
984369 TON R1 125 mL Ready to use 1300
Ammonia waste waters, sanitary landfills, and garbage dumps. Nitrate is
determined by subtracting Nitrite result from TON result with an 984370 TON R2 4 × 20 mL Ready to use 750
Calcium automated calculation. For Gallery analyzers, three system reagent 984652 TON R2 XL 6 x 60 mL Ready to us 3400
kits for TON/Nitrate are available. 984371 TON R3 4 × 20 mL Ready to us 1000
Chloride
TON (Hydrazine) 984372 TON R3 L 20 × 20 mL Ready to us 5000
Chromium (VI) Chemistry: Hydrazine Sample matrix

References: ISBN 0117515930, EPA 353.1, SM 4500-NO3- H, Drinking, ground, surface and waste water
Fluoride ISO 15923-1
Measuring range
Iron (Ferrous)
Extended measuring
Application Range
range (dil. 1+4)
Magnesium
TON Low *-500 µg N/L Up to 2500 µg N/L
TON High 0.5–5 mg N/L Up to 25 mg N/L

Nitrite
Phosphate
Silica
Sulfate
Total Hardness

(TON Hydrazine)
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Total Oxidized Nitrogen (TON)/Nitrate
Water analysis
Alkalinity Calibration Precision

Calibration is linear using 2000 µg N/L standard for low range and Precision was tested in 10 replicates and 5 batches for each sample.
Ammonia 2nd order using 20 mg N/L for high range in automatic dilution.
Lake water Pond water Tap water
0.50 0.50 (µg N/L) (µg N/L) (µg N/L)
R2 = 0.9972 R2 = 0.9997
Response (Abs)
Calcium
Response (Abs)
0.40 0.40
N 50 N 50 N 50
0.30 0.30
0.20 0.20 Mean 61 Mean 292 Mean 404
Chloride 0.10 0.10
0.00 0.00 SD CV % SD CV % SD CV %
0 200 400 0.5 1.5 2.5 3.5 4.5 5.5
Chromium (VI) Concentration (µg N/L) Concentration (mg N/L) Within 1.557 2.6 % 5.531 1.9 % 7.968 2.0 %
Between 4.581 7.5 % 13.071 4.5 % 4.779 1.2 %

Fluoride
Method Detection Limit (MDL) Total 4.838 7.9 % 14.193 4.9 % 9.291 2.3 %
Iron (Ferrous) Average MDL

Application Sample n
(µg N/L)
SD
(µg N/L) Linearity
Method linearity was tested with matrix samples comparing against
Magnesium blank 7 1.2 0.197 0.61 TON Vanadium method (see section TON (Vanadium).
TON Low
blank 50 3.4 2.700 11.52
Nitrite
1
2
Phosphate
Silica
Sulfate
Total Hardness

(TON Hydrazine)
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Total Oxidized Nitrogen (TON Vanadium)
Water analysis Chemistry: Vanadium Chloride Calibration
References: Automated Nitrate (TON) Assay Method Using Calibrations are using manually diluted standards as N. Calibration
Alkalinity Vanadium as Reductant - Correlation to Cadmium and Hydrazine is linear for TON-V SW and TON-V Low and 2nd order for TON-V
Reductant Methods in Sea, Natural and Waste Waters, January High.
Ammonia 2013 TON-V SW
0.20
Response (Abs)
R2 = 0.99931
0.15
Calcium Reagents Kit size Preparation Max. nbr of tests
0.10
984350 TON-V R1 4 × 10 mL Ready to use* 360
0.05
Chloride
984351 TON-V R2 4 × 10 mL Ready to use* 500 0.00
*Possibility to run 2-reagent or single (mix) reagent methods 0 20 40 60 80 100 120
Chromium (VI)
Concentration (µg N/L)
Sample matrix
Fluoride Drinking, ground, surface, waste and saline water TON-V Low TON-V High
0.20 0.75
R2 = 0.99981
Response (Abs)
Response (Abs)
R2 = 0.99999
0.15
Iron (Ferrous) Measuring range 0.50
0.10
Extended measuring 0.25
0.05
Magnesium Application Range
range (dil. 1+4) 0.00 0.00
TON-V High (surface and 0 100 200 300 400 0.0 2.0 4.0 6.0
*-5 mg N/L Up to 50 mg N/L
Nitrite waste water) Concentration (µg N/L) Concentration (mg N/L)
TON-V SW (saline water) *-100 µg N/L Up to 500 µg N/L

Phosphate TON-V Low (drinking and
*-400 µg N/L N/A
ground water)
Silica
Sulfate
Total Hardness

(TON Hydrazine)
(TON Vanadium)
(TON Enzymatic)
Gallery analyzers
Table of Contents Total Oxidized Nitrogen (TON Vanadium)
Water analysis
Alkalinity
Ammonia Average MDL
(μg/L) (μg/L)
Calcium TON-V SW× SD (blank
Saline water n=7) 7 2.35 0.215 0.681
1
MDL = 3.14 sample,
TON-V Low Blank 7 2.35 0.224 0.681

Chloride
Chromium (VI) Linearity and method comparison

Method linearity was tested with matrix samples comparing against
Fluoride TON Hydrazine method. Method comparison was performed against
Ton Cd method.
Iron (Ferrous) Linearity with surface water samples
5000
TON Vanadium (µg/L)
R2 = 0.994
Magnesium 4000
3000
Nitrite 2000
1000
Phosphate
0
0 500 1000 1500 2000 2500 3000 3500 4000 4500
Silica
TON Hydrazine (µg/L)
Sulfate Method comparison against Cd with surface water samples

300
R2 = 0.993
TON Vanadium (µg/L)
Total Hardness 250
200
150
(TON Hydrazine)
100
(TON Vanadium) 50

(TON Enzymatic) 0 50 100 150 200 250 300
TON Cd (µg/L)
Gallery analyzers
Table of Contents Total Oxidized Nitrogen (TON Enzymatic)
Water analysis Chemistry: Nitrate reductase Linearity and method comparison
References: ASTM D7781-14, EPA 40 CFR Part 141 Method linearity was tested with pure chemicals dissolved in DI water
Alkalinity and matrix samples comparing against TON Hydrazine method.
Reagents Kit size Preparation Max. nbr of tests 3.00
TON Enzymatic (mg N/L)

Ammonia 984187 contains: 2.50
See package R2 = 0.9987
AtNaR 3 U/vial 2.00
insert for 275
Calcium Enzyme diluent bulb 1 vial
details 1.50
NADH 2 mg/vial
1.00
Chloride 984371 TON R3 4 × 20 mL Ready to use 1000
0.50
0.00
Chromium (VI) Sample matrix 0.00 0.50 1.00 1.50 2.00 2.50 3.00
Drinking, ground, surface, waste and saline water TON Hydrazine (mg N/L)
Fluoride
Measuring range
Iron (Ferrous) Extended measuring
Application Range
range (dil. 1+4)
Magnesium TON Enz *- 0.5 mg N/L Up to 2.5 mg N/L
Nitrite
Calibration
Calibration is 2nd order using 2 mg N/L standard in automatic dilution.
Phosphate
0.50
R2 = 0.99991
Response (Abs)
0.40
Silica
0.30
0.20
Sulfate
0.10
0.00
Total Hardness
0.00 0.10 0.20 0.30 0.40 0.50 0.60
Total Oxidized Nitrogen Concentration (mg N/L)
(TON Hydrazine)
(TON Vanadium) Average MDL
Total Oxidized Nitrogen (μg/L) (μg/L)
(TON Enzymatic) TON Enz Blank 7 0.075 0.112 0.3511
Gallery analyzers 1
Table of Contents
Water analysis
Alkalinity
Ammonia
Gallery Gallery Plus

Calcium
Capacity Up to 200 photometric tests per hour Up to 350 photometric tests per hour
Chloride On-Board Sample Capacity

Maximum of 90 using five 9- or 18-position
Maximum of 108 using six 9- or 18-position sample racks
sample racks and one 6-position reagent rack
Chromium (VI) On-Board Reagent Capacity

Maximum of 30 using one 9- or 18-position
Maximum of 42 reagent positions
sample rack and five 6-position reagent racks
Fluoride Walk-away Time Up to 2 hours Up to 3 hours
Water Consumption 1.5 liters per hour 2.5 liters per hour
Iron (Ferrous)
75 cm W × 70 cm D × 62 cm H/130 cm H 94 cm W × 70 cm D x 62 cm H/130 cm H
(with the open cover) and 85 kg (with the open cover) and 110 kg
Dimensions and Weight
Magnesium 27.5 in W × 27.6 in D × 24.4 in H/57 in H 37 in W × 27.6 in D x 24 in H/51 in H
(with the open cover) and187 lbs (with the open cover) and 242 lbs
Nitrite Continuous access to samples, reagents, and cuvettes without interrupting the test cycle.
Spectral range from 340–880 nm with different filter configurations available.
Additional Features
Bi-directional LIMS connection available.
Phosphate Optional electrochemical unit available for conductivity and pH measurements.
Silica
Gallery analyzers with system reagents, Benefits of automated discrete analysis
Sulfate a complete solution for water analysis • Fast – ready for immediate analysis: no reagent priming,
Thermo Scientific System Reagents are ready to go, saving the no method changeover time
Total Hardness technician’s time and reducing errors. The unique low volume
cuvette design guarantees small reagent volumes, minimizes • Flexible – various tests can be performed on each sample;
Total Oxidized Nitrogen reagent waste, and as a result reduces reagent costs. Optimized kit there is no limitation to the number of tests
(TON Hydrazine) sizes and on-board stability further minimize the amount of waste
produced and increase cost efficiency. • Precise – specific measurements with high reproducibility
(TON Vanadium)
Total Oxidized Nitrogen Find out more at thermofisher.com/discreteanalysis
(TON Enzymatic)
For Research Use Only. Not for use in diagnostic procedures. © 2018 Thermo Fisher Scientific Inc. All rights reserved. All trademarks
Gallery analyzers are the property of Thermo Fisher Scientific and its subsidiaries. The information and technical specifications are subject to change without
notice. Product availability may vary from country to country. Please contact your local sales representative for more information.
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Table of Contents

Nitrite Chemistry: Bromophenol Blue and phthalate buffer pH 3.5

984624 Alkalinity R2 4 × 20 mL Ready to use 780 1.00

Total Hardness Sample matrix 0.60

Drinking, ground, and surface water 0.40

Chromium (VI) Precision

Mean 28.8 Mean 32.5 Mean 177.7

Nitrite Within 0.725 2.5 % 0.849 2.6 % 1.287 0.7 %

Between 0.626 2.2 % 0.196 0.6 % 4.462 2.5 %

Total Oxidized Nitrogen 0

Calcium References: NISBN 0117516139, ISO 7150, DIN 38 406,

Total Oxidized Nitrogen

Measured (µg N/L)

Pond water Tap water

Total 0.856 4.9 % 1.216 0.6 %

Total Oxidized Nitrogen

Total Oxidized Nitrogen

Within 0.218 1.3 % 0.449 0.5 % 0.223 0.7 %

Total 0.350 2.0 % 2.200 2.7 % 0.729 2.4 %

Total Oxidized Nitrogen

Iron (Ferrous) 0.00 0.50

Total Oxidized Nitrogen

Ammonia blank 7 0.23 0.011 0.0351

Nitrite Between 0.224 1.4 % 0.011 0.4 % 0.020 0.4 %

Total 0.236 1.4 % 0.033 1.3 % 0.036 0.7 %

Total Oxidized Nitrogen

Ammonia Chromium (VI) L blank 7 0.41 0.824 2.61

Total 1.248 2.9 % 1.379 1.7 % 3.211 0.7 %

Total Oxidized Nitrogen 200

Calcium Chemistry: Alizarine fluorine blue and cerous nitrate

984630 Fluoride R2 4 × 20 mL Ready to use 4800

Nitrite Measuring range

Total Hardness 0.50

Total Oxidized Nitrogen

Total Oxidized Nitrogen 0.20

(TON Vanadium) 0.10

Total Oxidized Nitrogen 0.00

Tap water Surface water Ground water

Within 0.008 0.9 % 0.004 2.0 % 0.006 1.5 %

Total 0.011 1.3 % 0.004 2.0 % 0.009 2.2 %

Total Oxidized Nitrogen

Silica Calibration Linearity

Total Oxidized Nitrogen

Within 0.247 1.0 % 0.427 0.6 % 0.182 0.7 %

Phosphate Total 0.651 2.7 % 1.617 2.4 % 0.474 1.8 %

Total Oxidized Nitrogen

Total Oxidized Nitrogen

Ammonia 7 0.33 0.126 0.41

Within 0.177 0.3 % 1.041 0.3 %

Total 0.867 1.5 % 4.227 1.4 %

Total Oxidized Nitrogen 0

Calcium Phosphate Low *- 200 µg P/L Up to 1000 µg P/L

984367 Phosphate R1L 20 × 20 mL Ready to use 11700

Total Oxidized Nitrogen

Pond Water Spiked Lake Spiked Tap

Within 0.362 3.8 % 0.991 1.7 % 2.667 1.6 %

Phosphate Total 0.376 4.0 % 3.690 6.3 % 3.828 2.3 %

Total Oxidized Nitrogen

Ammonia Chemistry: Ammonium molybdate blank 7 0.005 0.002 0.011

Iron (Ferrous) Sample matrix N 50 N 50 N 50

Silica Calibration Linearity

Measured (mg SiO2/L)

Total Oxidized Nitrogen