2018 Jee-Adv P1 Q.Paper Key-Solutions PDF

2018-Jee-Advanced Question Paper-1_Key & Solutions
JEE (ADVANCED) 2018 PAPER 1

PART-I PHYSICS
SECTION 1 (Maximum Marks: 24)
  This section contains SIX (06) questions.
  Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of
these four option(s) is (are) correct option(s).
  For each question, choose the correct option(s) to answer the question.
  Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of
which are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is
a correct options.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : −2 In all other cases.
  For Example: If first, third and fourth are the ONLY three correct options for a question with second option
being an incorrect option; selecting only all the three correct options will result in +4 marks.Selecting only
two of the three correct options (e.g. the first and fourth options), without selecting any incorrect option
(second option in this case), will result in +2 marks. Selecting only one of the three correct options (either
first or third or fourth option),without selecting any incorrect option (second option in this case), will result in +1
marks. Selecting any incorrect option(s) (second option in this case), with or without selection of any correct
option(s) will result in -2 marks.
Q.1 The potential energy of a particle of mass m at a distance r from a fixed point O is given by
r 2 .where is a positive constant of appropriate dimensions. This particle is
V r   k
2
moving in a circular orbit of radius R about the point O. If is the speed of the particle and
L is the magnitude of its angular momentum about O, which of the following statements is
(are) true?
k
A) v  R
2m
k
B) v  R
m
C) L  mk R 2
mk 2
D) L  R
2
Key. (B,C)
Sol:
Sri Chaitanya IIT Academy

Page-2
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 www. srichaitanya.net,  iconcohyd@srichaitanyacollege.net
v
kr 2
V , F  kr At r=R,
2
mv 2 kR 2 k k 2
kR  (Centripetal force) v  R,L  m R
R m m m
Q.2 Consider a body of mass 1.0 at rest at the origin at time t  0 . A force F   t i   j 
is applied on the body, where   1.0 N / s and   1.0N . The torque acting on the body
about the origin at time t  1.0 s is  . Which of the following statements is (are) true?
1
A)   Nm
3
B) The torque  is in the direction of the unit vector  k
1
C) The velocity of the body at t  1s is v  i  2 j m / s
2
1
D) The magnitude of displacement of the body at t  1s is m
6
Key. (A, C)
Sol:
F   t  i   j F  ti  j ,
dv
m  ti  j On integrating
dt
t2 dr t 2
mv  i  t j  i  tj
2 dt 2
t3 t2
On integrating r i  j
6 2
 1 1  1
At t=1s,    r  F    i  j    i  j    k
6 2  3
1  1
At t=1, v   i  j    i  2 j  m / sec
2  2
2 2
1 1 1 1 10
At t=1, s  r1  r0 , s  i  j s       m
6 2 6 2 6

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Q.3 A uniform capillary tube of inner radius r is dipped vertically into a beaker filled with water.
The water rises to a height ℎ in the capillary tube above the water surface in the beaker. The
surface tension of water is . The angle of contact between water and the wall of the capillary
tube is . Ignore the mass of water in the meniscus. Which of the following statements is(are)
true?
A) For a given material of the capillary tube, ℎ decreases with increase in r
B) For a given material of the capillary tube, ℎ is independent of
C) If this experiment is performed in a lift going up with a constant acceleration, then ℎ
decreases
D) ℎ is proportional to contact angle
Key. (A, C)
2 2 r 2 cos 
Sol:   gh h R h
R R g cos  rg
1
(A)For given material ,   constant h
r
(B) h depend on 
(C)If lift is going up with constant acceleration, g eff  ( g  a )
2 cos 
h ,It means h decreases.
r  g  a
(D) h is proportional to cos not 
Q.4 In the figure below, the switches S1 and S 2 are closed simultaneously at t =0 and a current
starts to flow in the circuit. Both the batteries have the same magnitude of the electromotive
force (emf) and the polarities are as indicated in the figure. Ignore mutual inductance between
the inductors. The current I in the middle wire reaches its maximum magnitude I Max at time
t   . Which of the following statements is (are) true?
V
A) I Max 
2R
V
B) I Max 
4R
L
C)   ln 2
R
2L
D)   ln 2
R

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Key. (B, D)
Sol:
R L R 2L
i1 i i2
imax   i2  i1  max
 R   R  R  R
V  t  V  t  V   2 L t  L t 
i   i2  i1   1  e  2L 
  1  e  L
   e  e 
R   R   R  
R R
d  i  V  R  L t  R   2 l t 
For  i max 0  e  e 0
dt R  L  2L  
 R R  R 
 t
 L 1    t   t 1
e  e  2l  , e  2 L  
2 2
 R  2 L
  t  ln 2 , t  ln 2  time, when i is maximum
 2L  R
R  2L  R  2L 
V   L  R ln 2   2 L  R ln 2   V 1 1  1 V
imax  e e  imax   
R   R  4 2  4 R
Q.5 Two infinitely long straight wires lie in the xy-plane along the lines x   R . The wire located at
x   R carries a constant current I1 and the wire located at x   R carries a constant current
I 2 . A circular loop of radius R is suspended with its centre at 0,0, 3R and in a plane  
parallel to the xy-plane. This loop carries a constant current I in the clockwise direction as seen
from above the loop. The current in the wire is taken to be positive if it is in the  j direction.
Which of the following statements regarding the magnetic field B is (are) true?
A) If I1  I 2 , then B cannot be equal to zero at the origin (0, 0, 0)
B) If I1  0 and I 2  0 , then B can be equal to zero at the origin (0, 0, 0)
C) If I1  0 and I 2  0 , then B can be equal to zero at the origin (0, 0, 0)
 0 I 
D) If I1  I 2 , then the z-component of the magnetic field at the centre of the loop is   
 2R 
Key. A, B, D
Sol:
Z
1 C  0,0, 3R 
Y
x  R O xR
Y

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A)At origin , B =0 due to two wires if I1  I 2 ,hence  Bnet  at origin is equal to B due to ring ,
which is non –zero.
B)If I1  0 and I 2  0 , B at origin due to wires will be along + k direction and B due to ring is
along - k direction and hence B can be zero at origin.
C)If I1  0 and I 2  0 , at origin due to wires along - k and also along - k due to ring , hence B
cannot be zero .
Z B1
Bx
B2
X
I1 I2
D)
At centre of ring, B due to wires is along x-axis.
Q.6 One mole of a monatomic ideal gas undergoes a cyclic process as shown in the figure
(where V is the volume and T is the temperature). Which of the statements below is (are)
true?
A) Process I is an isochoric process

B) In process II, gas absorbs heat
C) In process IV, gas releases heat
D) Processes I and III are not isobaric
Key. (B, C, D)
Sol:
A)Process-I is not isochoric,V is decreasing .

B)Process-II is isothermal expansion U  0, W  0 Q  0
C)Process-IV is isothermal compression ,

U  0, W  0 Q  0
D)Process-I and III are NOT isobaric because in isobaric process T  V hence isobaric T-V
graph will be linear.
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  This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value (in decimal notation, truncated/rounded-off to
the second decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) using the mouse and the on-
screen virtual numeric keypad in the place designated to enter the answer.
Full Marks : +3 If ONLY the correct numerical value is entered as answer.
Zero Marks : 0 In all other cases.
Q.7 Two vectors A and B are defined as A  ai and B  a  cos t i  sin t j  , where is a

constant and   rad / s . If A  B  3 A  B at time t   for the first time, the value of
6
, in seconds, is
Key. (2.00)
Sol:
B
a
t
a A
t t
A  B  2a cos A  B  2a sin
2 2
t  t  t 1
So 2a co s 3  2a sin  tan 
2  2  2 3
t    
  t  t  t  2.00 sec
2 6 3 6 3
Q.8 Two men are walking along a horizontal straight line in the same direction. The man in front
walks at a speed 1.0m / s and the man behind walks at a speed 2.0 m / s . A third man is
standing at a height 12m above the same horizontal line such that all three men are in a
vertical plane. The two walking men are blowing identical whistles which emit a sound of
frequency 1430Hz . The speed of sound in air is 330m / s . At the instant, when the moving men
are 10m apart, the stationary man is equidistant from them. The frequency of beats in
Hz, heard by the stationary man at this instant, is .
Key. (5.00)
Sol:
Observer(stationary)
13m 13m
12m
  B
A
2m/s 5m 5m 1m/s

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 
 330   1   2cos 
f A  1430    1430    1430 1 
 330  2 cos   1 
2 cos 
  330 
 330 
 330   cos 
f B  1430    1430 1 
 330  cos    330 
 3cos  5
f  f A  f B  1430    13cos  13    5.00 Hz
 330   13 
Q.9 A ring and a disc are initially at rest, side by side, at the top of an inclined plane which makes
an angle 60° with the horizontal. They start to roll without slipping at the same instant of
time along the shortest path. If the time difference between their reaching the ground is
2  3 / 10s , then the height of the top of the inclined plane, in meters, is .
Take g  10m / s 2 .
Key. (0.75m)
Sol:
  600
g sin  g sin  2 g sin 

ac  aring  , adisc 
I 2 3
1 C 2
MR
h 1  g sin   2 4h 16h
   t1  t1  2

sin  2  2  g sin  3g
h 1  2 g sin   2 3h 4h 16h 4h 2  3
   t2  t2  2
   
sin  2  3  g sin  g 3g g 10
 4
h

 2  2  3 h
2  3  3  3
 0.75m
 3  4  2 3  2
Q.10 A spring-block system is resting on a frictionless floor as shown in the figure. The spring
constant is 2.0 N / m and the mass of the block is 2.0 g. Ignore the mass of the spring. Initially
the spring is in an unstretched condition. Another block of mass 1.0 moving with
a speed of 2.0 m / s collides elastically with the first block. The collision is such that the
2.0 block does not hit the wall. The distance, in meters, between the two blocks when
the spring returns to its unstretched position for the first time after the collision is .

Page-8

Key. (2.09 m)
Sol:
m
T  2  2 sec
k
T
Block returns to original position in   sec
2
2m/s
0
1kg 2kg Just after collision
2/3m/s 4/3/m/s
1kg 2kg Just after collision
2 2
d     3.14   2.0933m d  2.09m
3 3
Q.11 Three identical capacitors C1 , C2 and C3 have a capacitance of 1.0  F each and they are
uncharged initially. They are connected in a circuit as shown in the figure and C1 is then
filled completely with a dielectric material of relative permittivity  r . The cell electromotive
force (emf) V0  8V . First the switch S1 is closed while the switch S 2 is kept open. When the
capacitor C3 is fully charged, S1 is opened and S 2 is closed simultaneously. When all the
capacitors reach equilibrium, the charge on C3 is found to be 5 C .The value of  r 
Key. 1.50
Sol:
8C
V0  8V 1 F
8C
r 3C
3C 5C
1 F
3C 5C
1 F
3C
5 3 3 3
Applying loop rule   0  2   r  1.50
1 r 1 er

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Q.12 In the xy-plane, the region y > 0 has a uniform magnetic field B1k and the region y < 0 has
another uniform magnetic field B2k A positively charged particle is projected from the origin
along the positive y-axis with speed v0   m / s at t  0 , as shown in the figure. Neglect
gravity in this problem. Let t  T be the time when the particle crosses the x-axis from below
for the first time. If B2  4 B1 , the average speed of the particle, in m / s , along the x-axis in the
time interval T is .
Key. 2.00
Sol: 1)Average speed along x-axis
r1
r2
Vx   Vx dt  d1  d2 2)We have r1 
mv
, r2 
mv
 dt t1  t2 qB1 qB2
B2 m
Since B1   r1  4r2 Time in B1   t1
4 qB1
m
Time in B2   t2
qB2
Total distance along x-axis d1  d 2  2r1  2r2  2  r1  r2   2  5r2 
10r2 mv qB2
Total time T  t1  t2  5t2 Average speed  2  2
5t2 qB2  m
Q.13 Sunlight of intensity 1.3kWm 2 is incident normally on a thin convex lens of focal length
20cm . Ignore the energy loss of light due to the lens and assume that the lens aperture size
is much smaller than its focal length. The average intensity of light, in kWm 2 , at a distance
22cm from the lens on the other side is
Key. 130

Page-10

R r
20cm 2cm
Sol:
r 2 1 1
  Ratio of area 
R 20 10 100
E
Let energy incident on lens be E. Given  1.3
A
E a 1
So final ,  ?? E  A  1.30 Also 
a A 100
E A  1.3
Average intensity of light at 22cm    100  1.3  130kW / m 2
a a
Q.14 Two conducting cylinders of equal length but different radii are connected in series between
two heat baths kept at temperatures T1  300 K and T2  100 K , as shown in the figure.
The radius of the bigger cylinder is twice that of the smaller one and the thermal
conductivities of the materials of the smaller and the larger cylinders are K1 and K 2
respectively. If the temperature at the junction of the two cylinders in the steady state is
K1
200K , then 
K2
Key. 4.00
2r
r k1
300k 100k
200k k2
L
Sol: L
   
 200  300   200  100 
We have in steady state,   0
 L   L 
 k  r 2   k  2r 2 
 1   2   
k1 r 2  100 100k2  4r 2 k
   1 4
L L k2

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  This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
  Each question has FOUR options. ONLY ONE of these four options corresponds to the correct answer.
  For each question, choose the option corresponding to the correct answer.
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 f none of the options is chosen (i.e. the question is unanswered).
PARAGRAPH “X”
In electromagnetic theory, the electric and magnetic phenomena are related to each other.
Therefore, the dimensions of electric and magnetic quantities must also be related to each
other. In the questions below,  E  and  B  stand for dimensions of electric and magnetic
fields respectively, while  0  and  0  stand for dimensions of the permittivity and
permeability of free space respectively.  L  and T  are dimensions of length and time
respectively. All the quantities are given in SI units.
(There are two questions based on PARAGRAPH “X”, the question given below is one of them)
Q.15 The relation between  E  and  B  is
A)  E    B  L T 
1
B)  E    B  L T 
1
C)  E    B  L T 
1 1
D)  E    B  L  T 
Key. C
E
Sol: We have  B   E  L1T 1   E    B  L  T 1 
C
PARAGRAPH “X”
In electromagnetic theory, the electric and magnetic phenomena are related to each other.
Therefore, the dimensions of electric and magnetic quantities must also be related to each
other. In the questions below,  E  and  B  stand for dimensions of electric and magnetic
fields respectively, while  0  and  0  stand for dimensions of the permittivity and
permeability of free space respectively.  L  and T  are dimensions of length and time
respectively. All the quantities are given in SI units.
(There are two questions based on PARAGRAPH “X”, the question given below is one of them)
Q.16 The relation between  0  and  0  is
2 2
A)  0    0  L  T 
2
B)  0    0  L  T 2
1 2 2
C)  0    0   L  T 
1 2 2
D)  0    0   L  T 

Page-12

Key. D
 1  2 2 1 1 2 2
Sol: We have  C 2    LT    0    0   L  T 
   0  0 
 0 0 
PARAGRAPH “A”
If the measurement errors in all the independent quantities are known, then it is possible to
determine the error in any dependent quantity. This is done by the use of series expansion and
truncating the expansion at the first power of the error. For example, consider the relation
z  x / y . If the errors in x,yand z are x, y and z , respectively, then
1
x  x x  x   y 
z  z   1  1 
y  y y  x  y 
1
 y 
The series expansion for 1 
y  , to first power in y / y , is 1   y / y  . The relative
 
 x y 
errors in independent variables are always added. So the error in z will be z    
 x y 
The above derivation makes the assumption that x / x  1, y / y  1 . Therefore, the higher
power of these quantities are neglected.
(There are two questions based on PARAGRAPH “A”, the question given below is one of them)
17. Consider the ratio r 

1  a  to be determined by measuring a dimensionless quantity a. If the
1  a 
error in the measurement of a is a  a / a  1 , then what is the error r in determining r?
a
A)
1  a 2
2 a
B)
1  a 2
2 a
C)
1  a 2
2 a a
D)
1  a 2
Key. B
1 a  r  1  a   1  a  a 1  a  1  a 
Sol: r     
1 a  r 1  a  1  a  1  a 1  a 

2a 1  a   2a
1  a 1  a  1  a  1  a 2

Page-13

PARAGRAPH “A”
If the measurement errors in all the independent quantities are known, then it is possible to
determine the error in any dependent quantity. This is done by the use of series expansion and
truncating the expansion at the first power of the error. For example, consider the relation
z  x / y . If the errors in x,yand z are x, y and z , respectively, then
1
x  x x  x   y 
z  z   1  1 
y  y y  x  y 
1
 y 
The series expansion for 1  ,to first power in y / y , is 1   y / y  . The relative
 y 
 x y 
errors in independent variables are always added. So the error in z will be z    
 x y 
The above derivation makes the assumption that x / x  1, y / y  1 . Therefore, the higher
power of these quantities are neglected.
Q.18 In an experiment the initial number of radioactive nuclei is 3000. It is found that 1000 ± 40
nuclei decayed in the first 1.0 s. For |x| ≪ 1, ln(1 +x) = x up to first power in x. The error  ,
in the determination of the decay constant  , in S 1 , is

A) 0.04
B) 0.03
C) 0.02
D) 0.01
Key. C
Sol: N  N 0e  t ln N  ln N 0  t
N 40
 t    0.02  N is number ofnucleileft undecayed 
N 2000  L

Page-14

PART-I CHEMISTRY
  This section contains SIX (06) questions.
 Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of
these four option(s) is (are) correct option(s).
 For each question, choose the correct option(s) to answer the question.
 Answer to each question will be evaluated according to the following marking scheme:
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of
which are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is
a correct options.
 For Example: If first, third and fourth are the ONLY three correct options for a question with
second option being an incorrect option; selecting only all the three correct options will result in +4 marks.
Selecting only two of the three correct options (e.g. the first and fourth options), without selecting any
incorrect option (second option in this case), will result in +2 marks. Selecting only one of the three
correct options (either first or third or fourth option),without selecting any incorrect option (second
option in this case), will result in +1 marks. Selecting any incorrect option(s) (second option in this
case), with or without selection of any correct option(s) will result in -2 marks.
1. The compound(s) which generate(s) N 2 gas upon thermal decomposition below 3000 C is (are)
A) NH 4 NO3
B)  NH 4 2 Cr2O7
C) Ba( N3 ) 2
D) Mg3 N 2
Key. BC

Sol. A) NH 4 NO3 
below 3000 C
 N 2O  2 H 2O

B)  NH 4 2 Cr2O7   N 2  Cr2O3  4 H 2O

C) Ba ( N 3 ) 2   Ba  3 N 2
D) Mg3 N 2 (it does not decompose into N 2 )

2. The correct statement(s) regarding the binary transition metal carbonyl compounds is
(are)(Atomic number: Fe  26, Ni  28 )
A) Total number of valence shell electrons at metal centre in Fe(CO)5 or Ni (CO) 4 is 16
B) These are predominantly low spin in nature
C) Metal-carbon bond strengthens when the oxidation state of the metal is lowered
D) The carbonyl C-O bond weakens when the oxidation state of the metal is increased

Page-15

Key. BC
Sol. A) [Fe(CO)5] & [Ni(CO)4] complexes have 18-electrons in their valence shell.
B) Carbonyl complexes are predominantly low spin complexes due to strong ligand field.
C) As electron density increases on metals (with lowering oxidation state on metals), the extent
of synergic bonding increases. Hence M–C bond strength increases
D) While positive charge on metals increases and the extent of synergic bond decreases and
hence C–O bond becomes stronger.
3. Based on the compounds of group 15 elements, the correct statement(s) is (are)
A) Bi2O5 is more basic than N 2O5
B) NF3 is more covalent than BiF3
C) PH 3 boils at lower temperature than NH 3
D) The N-N single bond is stronger than the P-P single bond
Key. ABC
Sol.
A) Bi2O5 is metallic oxide but N2O5 is non metallic oxide therefore Bi2O5 is basic but N2O5 is
acidic.
B) In NF3 , N and F are non metals but BiF3 , Bi is metal but F is non metal therefore NF3 is
more covalent than BiF3.
C) In PH3 hydrogen bonding is absent but in NH3 hydrogen bonding is present therefore PH3
boils at lower temperature than NH3.
D)Due to small size in N–N single bond l.p. – l.p. repulsion is more than P–P single bond
therefore N–N single bond is weaker than the P–P single bond.
4. In the following reaction sequence, the correct structure(s) of X is (are)
Me N3
1)PBr3, Et2O
X
2)Nal, Me2CO
3)NaN3, HCONMe2 enantiomerically pure
A)
B)
C)
D)
Key. B
Sol.
Me N3
1)PBr3, Et2O
X
2)Nal, Me2CO
3)NaN3, HCONMe2
all the three reaction are S N 2 so X is

Page-16

5. The reaction(s) leading to the formation of 1,3,5-trimethylbenzene is (are)
A)
heated iron tube
B) 873 K
C)
D)
Key. ABD
Sol. A)
Fe
B)
COOH
1 Br2NaOH (3) soda lime

 2 HO
3
HOOC COOH
C)
COOH
ZnHg,HCl
HOOC COOH
D)
6. A reversible cyclic process for an ideal gas is shown below. Here, P,V, and T are pressure,
volume and temperature, respectively. The thermodynamic parameters q, w, H and U are heat,
work, enthalpy and internal energy, respectively.
A(PVT
1, 1, 1) C(PV
2, 1,T2 )
Volume(V)
B(PV T)
2, 2, 1
Temperature(T)
The correct option(s) is (are)

A) qAC  U BC and wAB  P2 V2  V1 
B) wBC  P2 V2  V1  and qBC  H AC
C) H CA  U CA and q AC  U BC
D) qBC  H AC and H CA  U CA

Page-17

Key. BC
Sol.
AC  Isochoric
AB  Isothermal
BC  Isobaric
# qAC = UBC = nCV (T2 – T1)
V
WAB = nRT1 ln 2 A (wrong)
V1
# qBC = HAC = nCP (T2 – T1)
WBC = – P2(V1 – V2) B (correct)
# nCP (T1–T2) < nCV(T1 – T2) C (correct)
 HCA <  UCA
# D (wrong)
  This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value (in decimal notation, truncated/rounded-off to
the second decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) using the mouse and the on-
screen virtual numeric keypad in the place designated to enter the answer.
Full Marks : +3 If ONLY the correct numerical value is entered as answer.
7. Among the species given below, the total number of diamagnetic species is .
H atom, NO2 monomer, O2− (superoxide), dimeric sulphur in vapour phase, Mn3O4,
(NH4)2[FeCl4], (NH4)2[NiCl4], K2MnO4, K2CrO4
Key. 1
Sol. *H-atom = 1S Paramagnetic
O
* NO2 = O odd electron species Paramagnetic
* O2 (superoxide) = One unpaired electrons in  * M.O. Paramagnetic
* S2(in vapour phase) = same as O2 , two unpaired e– s are present

in  * M.O. Paramagnetic
2 4
* Mn3O4  2MnO . MnO 2 Paramagnetic
*  NH 4 2  FeCl4   Fe2  3d 6 4s 0

Page-18

Cl Cl Cl Cl
sp3-hybridisation
Paramagnetic
8 2
* (NH4)2[NiCl4] =Ni = 3d 4s
Ni+2 = 3d8 4s0
Cl Cl Cl Cl
sp3-hybridisation
Paramagnetic
O
2K Mn
O
* K2MnO4 = O O
, Mn 6   Ar  3d 1 Paramagnetic
K2CrO4  2K Cr
O
O
* , Cr 6   Ar  3d 0
O
Diamagnetic
8. The ammonia prepared by treating ammonium sulphate with calcium hydroxide is
completely used by NiCl2.6H2O to form a stable coordination compound. Assume that both the
reactions are 100% complete. If 1584 g of ammonium sulphate and 952 g of NiCl2.6H2O are
used in the preparation, the combined weight (in grams) of gypsum and the nickel-
ammonia coordination compound thus produced is .
(Atomic weights in g mol-1: H = 1, N = 14, O = 16, S = 32, Cl = 35.5, Ca = 40, Ni = 59)
Key. 2992
Sol.
(NH 4)2 SO 4 + Ca(OH)2  CaSO 4.2H 2O+2NH3
1584 g gypsum ( M =172) 24mole
=12 mol 12 mol
NiCl2 .6 H 2O  6 NH 3   Ni  NH 3 6  Cl2  6 H 2O
952 g  4 mol 24 mol  M  232 
4 mol
Total mass  12  172  4  232  2992g

9. Consider an ionic solid MX with NaCl structure. Construct a new structure (Z) whose unit cell
is constructed from the unit cell of MX following the sequential instructions given below.
Neglect the charge balance.
(i) Remove all the anions (X) except the central one
(ii) Replace all the face centered cations (M) by anions (X)
(iii) Remove all the corner cations (M)
(iv) Replace the central anion (X) with cation (M)
 number of anions 
The value of   in Z is .
 number of cations 
Key. 3

Page-19


X  O.V .
Sol.
M   FCC
M+ X–
(i) 4 1
(ii) 4–3 3+1
(iii) 4 – 3 – 1 3+1
(iv) 1 3
3
Z  3
1
10. For the electrochemical cell,
Mg(s)  Mg2+ (aq, 1 M)  Cu2+ (aq, 1 M)  Cu(s)
the standard emf of the cell is 2.70 V at 300 K. When the concentration of Mg2+ is changed
to M, the cell potential changes to 2.67 V at 300 K. The value of is .
F
(given,  11500 K V 1 ,where F is the Faraday constant and R is the gas constant,
R
ln(10)=2.30)
Key. 10
2
Sol. Mg  S E 0 Cu  aq   Mg 2  aq  Cu2  s 
2.70
Cell
E  2.67
Cell Mg  x M
Cu 2  1M
0 RT RT
ECell  ECell  ln x 2.67  2.70  ln x
nF nF
R300
0.03    ln x
2F
0.03  2 F 0.03  2  11500
ln x   
300 R 300  1
ln x  2.30  ln 10  X=10
11. A closed tank has two compartments A and B, both filled with oxygen (assumed to be ideal
gas). The partition separating the two compartments is fixed and is a perfect heat insulator
(Figure 1). If the old partition is replaced by a new partition which can slide and conduct heat but
does NOT allow the gas to leak across (Figure 2), the volume (in m3) of the compartment A
after the system attains equilibrium
is .

Page-20

Key. 2.22
Sol. P1= 5 P2 = 1
v1 = 1 v2= 3
T1= 400 T2= 300
5 3
n1  n2 
400 R 300 R
Let volume be(v+x) v=(3-x) 15-5x=4+4x
PA PB nb  R nb2  R
  1 
TA TB vb1 vb2
5 3
 
400  4  x  300 R  3  x 
 53  x  4  4x
11
x
9
11  20 
v  1 x  1     2.22
9  9 
12. Liquids A and B form ideal solution over the entire range of composition. At temperature T,
equimolar binary solution of liquids A and B has vapour pressure 45 Torr. At the same
temperature, a new solution of A and B having mole fractions x A and xB , respectively, has
vapour pressure of 22.5 Torr. The value of x A / xB in the new solution is .
(given that the vapour pressure of pure liquid A is 20 Torr at temperature T)
Key. 19
Sol.
1 1
45  PA0   PB0 
2 2
0 0
PA  PB  90....... 1
given PA0  20 torr
PB0  70 torr  22.5 torr  20 xA  70 1  xA 
 70  50 x A
 70  22.5 
xA     0.95
 50 
xB  0.05
x A 0.95
So   19
xB 0.05
13. The solubility of a salt of weak acid (AB) at pH 3 is Y  10 3 mol L1 . The value of Y is _.
(Given that the value of solubility product of AB  K sp   2  10 10 and the value of ionization
constant of HB  K a   1  108 )
Key. 4.47
 H     103 
Sol. S  K sp     1  2  10 10  8  1  2  105  4.47  103 M
 Ka   10 
 

Page-21

14. The plot given below shows P-T curves(where P is the pressure and T is the temperature) for
two solvents X and Y and isomolal solutions of NaCl in these solvents. NaCl completely
dissociates in both the solvents.
1 2 3 4
760
Pressure(mmHg)
1.solvent X
2.solution of NaCl in solvent X
3.solvent Y
4.solution of NaCl in solvent Y
360
362
368
367
Temperature(K)
On addition of equal number of moles of a non-volatile solute S in equal amount (in kg) of
these solvents, the elevation of boiling point of solvent X is three times that of solvent Y.
Solute S is known to undergo dimerization in these solvents. If the degree of dimerization is
0.7 in solvent Y, the degree of dimerization in solvent X is .
Key. 0.05
Sol. From graph
For solvent X’ Tbx  2
Tbx  mNaCl  K b ( x ) ……….(1) For solvent ‘Y’ Tby  1
Tb y   mNaCl  K b y  ……….(2) Equation (1) /(2)
K b x 
 2 For solute S
K b y 
2  S   S2
1
1   / 2
i  1   / 2
     
Tb x  s    1  1  K b x  Tb x  s   1  2  K b y 
 2  2 
Given Tb x  s   3Tb y  s 
 1   2       
 1   K b x   3   1    K b y  2 1  1   3 1  2 
 2  2   2  2 
 2  0.7 So 1  0.05

  This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
  Each question has FOUR options. ONLY ONE of these four options corresponds to the correct answer.
  For each question, choose the option corresponding to the correct answer.
Zero Marks : 0 f none of the options is chosen (i.e. the question is unanswered).

Page-22

PARAGRAPH “X”
Treatment of benzene with CO/HCl in the presence of anhydrous AlCl3/CuCl
followed by reaction with Ac2O/NaOAc gives compound X as the major product.
Compound X upon reaction with Br2/Na2CO3, followed by heating at 473 K with
moist KOH furnishes Y as the major product. Reaction of X with H2/Pd-C, followed
by H3PO4 treatment gives Z as the major product.
15. The compound Y is
A)
B)
C)
D)
Key. C
Sol.
COHCl
A 
lCl /CuCl

3
PARAGRAPH “X”
Treatment of benzene with CO/HCl in the presence of anhydrous AlCl3/CuCl
followed by reaction with Ac2O/NaOAc gives compound X as the major product.
Compound X upon reaction with Br2/Na2CO3, followed by heating at 473 K with
moist KOH furnishes Y as the major product. Reaction of X with H2/Pd-C, followed
by H3PO4 treatment gives Z as the major product.
16. The compound Z is
A)
B)
C)
D)

Page-23

Key. A
Sol.
PARAGRAPH “A”
An organic acid P (C11H12O2) can easily be oxidized to a dibasic acid which reacts with
ethyleneglycol to produce a polymer dacron. Upon ozonolysis, P gives an aliphatic ketone as
one of the products. P undergoes the following reaction sequences to furnish R via Q. The
compound P also undergoes another set of reactions to produce S.
17. The compound R is
A)
B)
C)
D)
Key. A
COOH
OH
OH
C11H12O2 
O
  dacron
H
 P
COOH

Page-24

Sol.
PARAGRAPH “A”
An organic acid P (C11H12O2) can easily be oxidized to a dibasic acid which reacts with
ethyleneglycol to produce a polymer dacron. Upon ozonolysis, P gives an aliphatic ketone as
one of the products. P undergoes the following reaction sequences to furnish R via Q. The
compound P also undergoes another set of reactions to produce S.
18. The compound S is
A)
B)
C)
D)
Page-25

Key. B
COOH
OH
OH
C11H12O2 
O
 
H
dacron
 P
COOH
Sol.

Page-26

PART-1:MATHEMATICS
SECTION -1 (Maximum Marks: 24)
 This section contains SIX (06) questions
 Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
 For each question, choose the correct option(s) to answer the question.
 Answer to each question will be evaluated according to the following marking scheme:
Partial Marks: +3 if all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen,
both of which are correct options
Partial Marks: +1If two or more options are correct but ONLY one option is chosen and
it is a correct option
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: −2 In all other cases.
For Example: If first, third and fourth are the ONLY three correct options for a question with second
option being an incorrect option; selecting only all the three correct options will result in +4 marks. Selecting
only two of the three correct options (e.g. the first and fourth options),without selecting any incorrect option
(second option in this case), will result in +2 marks. Selecting only one of the three correct options (either first
or third or fourth option) ,without selecting any incorrect option (second option in this case), will result in +1
marks. Selecting any incorrect option(s) (second option in this case), with or without selection of any correct
option(s) will result in -2 marks.
Q1. For a non-zero complex number , let arg ( ) denote the principal argument with   arg( z )   .
Then, which of the following statement(s) is (are) FALSE?

A) arg(1  i )  , where i  1
4
B) the function f :     ,   , defined by f  t   arg  1  it  for all t   , is continuous at all
points of  , where i  1
 z1 
C) For any two non-zero complex numbers z1 and z2 , arg    arg  Z1   arg  Z 2  is an integer
z
 2
multiple of 2
D) For any three given distinct complex numbers z1 , z2 and z3 , the locus of the point satisfying the
  z  z1   z2  z3  
condition arg     , lies on a straight line
  z  z 3   z 2  z1  
Key: A,B,D
3
Sol: a) arg  1  i   
4
   tan 1  t  , t  0
b) f  t   arg  1  it    1
Discontinuous at t  0
  tan  t  t  0
z 
c) arg  1   arg  z1   arg  z2   arg z1  arg  z2   2n  arg  z1   arg  z2   2n
 z2 

Page-27

  z  z1   z2  z3  
  z  z   z  z    
d) arg 
 3 2 1 

 z  z1   z2  z3  is real.  z , z , z , z are concyclic
1 2 3
 z  z3   z2  z1 
Q2. In a triangle , let PQR  30 and the sides PQ and QR have lengths 10 3 and 10, respectively.
Then , which of the following statement(s) is (are) TRUE?
A) QPR  45
B) The area of the triangle PQR is 25 3 and QRP  120
C) The area of the incircle of the triangle PQR is 10 3  15
D) The area of the circumcircle of the triangle is 100
Key: B,C,D
Sol: cos30 
 10 3  2
 10    PR 
2
2  10 3  10
 PR  10  QR  PR  PQR  QPR QPR  30

1 1 1
Area of PQR   10 3  10  sin 30   10  10 3 
2 2 2
 25 3
QRP  180   30  30   120
 25 3 25 3
r  
S  10  10  10 3  10  5 3
 5 3. 2  3  10 3  15  
 
 2 
a 10
R   10  Area   R 2  100
2sin A 2sin30
Q3. Let P1 : 2 x  y  z  3 and P2 : x  2 y  z  2 be two planes. Then, which of the following

statements(s) is (are) TRUE?
A) The line of intersection of P1 and P2 has direction ratios 1,2,−1
3x  4 1  3 y z
B) The line   is perpendicular to the line of intersection of P1 and P2
9 9 3
C) The acute angle between P1 and P2 is 60
D) If P3 is the plane passing through the point (4,2,−2) and perpendicular to the line
2
of intersection of P1 and P2 , then the distance of the point (2,1,1) from the plane P3 is
3

Page-28

Key: C,D
Sol: D.C. of line of intersection (a,b,c)  2a  b  c  0 a  2b  c  0
a b c 3x  4 1  3 y z
   D.C is 1, 1,1  
1  2 1  2 4  1 9 9 3
x  4 / 3 y 1 / 3 z
    lines are parallel
3 3 3
1  2  1  1  2  1  1 
Acute angle between P1 and P2  cos  
 6 6 
3 1
 cos 1    cos 1    60
6 2
Plane is given by  x  4    y  2    z  2   0
x yz0
2 11 2
Distance of  2,1,1 from plane  
3 3
2
Q4. For every twice differentiable function f :    2,2  with  f  0    f
2 1
 0  85 which of the
Following statement(s) is (are) TRUE?
A) There exist r , s   , where r  s , such that f is one-one on the open interval  r.s 
1
B) There exists x0   4,0  such that f  x0   1
C) lim f  x   1
x 
D) The exists    4, 4  such that f    f 11    0 and f 1    0

Key: A,B,D
Sol: ƒ(x) can't be constant throughout the domain. Hence we can find x  (r, s) such that ƒ(x) is one-one
option (A) is true
f  0   f  4 
Option (B) : f 1  x0    1 (LMVT)
4
Option (C): f  x   sin  
85 x satisfies given condition
But limsin
x
 
85 x D.N.E  Incorrect
2

Option (D): g  x   f 2  x   f 1  x  
f 1  x1   1 (by LMVT) f  x1   2 (given)
 g  x1   5 x1   4,0 
Similarly g  x2   5 x2   0,4 
g  0   85  g  x  has maxima in  x1 , x2  say at  .
g 1    0 & g    85 2 f 1    f    f 11     0
1
If f    0  g    f 2    85 Not possible
 f    f 11  0    x1 , x2    4, 4 

Page-29

Option (D) correct.
Q5. Let f :    and g :    be two non-constant differentiable functions. If
f 1  x   e f  x  g  x 
 g  x  for all x   , and f 1  g  2  1, then which of the following
1
statement (s) is (are) TRUE?

A) f  2   1  log e 2
B) f  2   1  log e 2
C) g 1  1  log e 2
D) g 1  1  log e 2
Key: B,C
f 1  x   e
f  x  g  x  
Sol: g1  x  x 
 f  x  g  x
 e . f  x  e g1  x   0
 e 
 f  x  g x
 f 1  x  e .g1  x  dx  C
 f x  g  x
 e e C
  e    e    e    e  
f 1 g 1 f 2 g 2
1 g 1 1
   e    e   
f 2
e e
 f  x
 e  ln 2  1 and  g 1  ln 2  1
 f  2   1  ln 2 and g 1  1  ln 2
x
Q6. Let f :  0,     be a continuous function such that f  x   1  2 x   e x t f  t  dt for all
0
x   0,   . Then, which of the following statement(s) is (are) TRUE ?

A) The curve y  ƒ  x  passes through the point (1, 2)
B) The curve y  ƒ  x  passes through the point (2, –1)
C) The area of the region  x, y 0, 1   : f  x   y  1  x  is  4 2 2
 1
D) The area of the region  x, y    0, 1   : f  x   y  1  x  is
2
4
Key: B,C
x x
x t x x
Sol: f  x   1  2x   e f  t  dt  e f  x  e 1  2 x    e t f  t  dt
0 0
Differentiate w.r.t.w
e  x f  x   e  x f 1  x   e  x 1  2 x   e  x  2   e x f  x 
  f  x   f 1  x    1  2 x   2  f  x   f 1x  2 f  x   2x  3
2 x
Integrating factor  e

Page-30

f  x  .e2 x   e2 x  2 x  3 dx
 2 x  3  e 2 x e 2 x
2 x
  2 x  3  e dx    2   e dx dx  2 x
 
2

2
c
2x  3 1 3 1
f  x    ce 2 x f  0    c 1 c  0  f  x  1  x
2 2 2 2
 1  2
Area   
4 2 4

This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE.
For each question, enter the correct numerical value (in decimal notation, truncated/rounded-off to
the second decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) using the mouse and the
on-screen virtual numeric keypad in the place designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Mark: +3 If ONLY the correct numerical value is entered as answer.
1 1
Q7. The value of  log 9  2

2 log  log 9 
2 2
  7 log 4 7
is ______________________
Key: 8
2 1/2 1
log2  log 2 9
2
2 loglog log 7 4
log 4 7
Sol: log 2 9 7   log 2 9  29
7 2
 4 2  8
Q8. The number of 5 digit numbers which are divisible by 4, with digits from the set
{1, 2, 3, 4, 5} and the repetition of digits is allowed, is .
Key: 625
Sol: Option for last two digits are (12), (24), (32), (44) are (52).
Total No. of digits = 5 × 5 × 5 × 5 = 625
Q9. Let X be the set consisting of the first 2018 terms of the arithmetic progression 1,6,11, …….. and Y be
the set consisting of the first 2018 terms of the arithmetic progression 9, 16, 23, ………… then, the
number of elements in the set X U Y is ____
Key: 3748
Sol: X : 1, 6, 11, ........, 10086

Y : 9, 16, 23, ......, 14128
X  Y : 16, 51, 86, ......
Let m  n  X  Y 
16   m – 1  35  10086 m  288.71 m = 288
n  X  Y   n  X   n Y  – n  X  Y 

Page-31

= 2018 + 2018 – 288 = 3748
Q10. The number of real solutions of the equation
i
  i 1
1

x   1
   x i  i  1 1
sin   x  x       cos          x   lying in the interval  , 
 i 1 i 1  2  
 2  i 1  2  i 1   2 2
  
is __________
  
(Here, the inverse trigonometric functions sin
1
x and cos 1 x assume value in   ,  and 0,  
 2 2
respectively.)
Key: 2
i i

i 1 X2 
x x 
 x x 
i x
Sol: X
i 1

1 X
   
i 1  2  2x
   
i 1  2 2 x
x
i 1

1 x
To have real solutions
  i
 i
i 1X  X  i
 X  X        X 
i 1 i 1  2  i 1  2  i 1
2 2
X X X X
  
1 X 2  X 2  X 1 X

X X 3  2X 2  5X  2  0 
 x  0 and let f  X   X 3  2 X 2  5 X  2
1  1
f  . f    0
2  2
Hence two solutions exist
1
1
Q11. For each positive integer n, let Yn    n  1 n  2  ...  n  n   n For x   ,let  x  be the greatest
n
integer less than or equal to x. If lim yn  L , then the value of  L  is________
n 
Key: 1
1
 1  2   n n
Sol: yn  1  1   ......1   
 n  n   n 
n 1/ n
 r 1 n  r
yn    1    log yn 
l n 1  
r 1  n n r 1  n 
n
1  r
 lim log yn  lim  ln 1  
r 1 n  n
n  x 
1
4 4
 log L   ln 1  x  dx  log L  log  L   L  1
0
e e

Page-32

       
Q12. Let a and b be two unit vectors such that a.b  0 . For some x, y  , let c  xa  yb  a  b .

 
  
If c  2 and the vector c is inclined at the same angle  to both a and b , then the value of
8cos 2  is ___________
Key: 3
    
Sol: c  xa  yb  a  b

c.a  x and x  2cos 

c.a  y and y  2cos 
      
Also, a  b  1  
c  2cos a  b  a  b 
   2   2    
   
c 2  4cos 2  a  b  a  b  2cos  a  b . a  b   
4  8cos 2   1 8cos 2   3
Q13. Let a, b, c be three non-zero real numbers such that the equation
   
3a cos x  2b sin x  c, x    ,  has two distinct real roots  and  with     . Then,
 2 2 3
b
the value of is ………
a
Key: 0.5
2b c 2b c
Sol: 3 cos x  sin x  Now, 3 cos   sin   -----------(1)
a a a a
2b c
3 cos   sin   ------------ (2)
a a
2b
3  cos   cos     sin   sin    0
a
            2b           
3  2sin   sin     2cos   sin    0
  2   2   a   2   2 
b b 1
 3  2 3.  0   0.5
a a 2
Q14. A farmer F1 has a land in the shape of a triangle with vertices at (0,0), (1,1) and (2,0). From this
land, a neighbouring farmer F2 takes away the region which lies between the side and a curve of the
n
form y  x  n  1 . If the area of the region taken away by the farmer F2 is exactly 30% of the area of
PQR , then the value of is
Key: 4
1
3
  X  X  dX  10
n
Sol: Area 
0
1
 X 2 X n 1  3 1 1 3
 2  n  1   10    n 1 5  n4
 0 2 n  1 10

Page-33


This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
Each question has FOUR options. ONLY ONE of these four options corresponds to the correct answer.
For each question, choose the option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
************************************************************************************
Paragraph "X"
2 2
Let S be the circle in the xy-plane defined by the equation x  y  4 .
(There are two question based on Paragraph "X", the question given below is one of them)
Q15. Let E1E2 and F1F2 be the chord of S passing through the point P0 1, 1 and parallel to the x-
axis and the y-axis, respectively. Let G1G2 be the chord of S passing through P0 and having
slope –1. Let the tangents to S at E1 and E2 meet a E3 , the tangents of S at F1 an F2 meet at F3 ,
and the tangents to S at G1 and G2 meet at G3 . Then, the points E3 , F3 and G3 lie on the curve
A) x  y  4
2 2
B)  x – 4    y – 4  16
C)  x – 4   y – 4   4
D) xy  4
Key: A
Sol:
2 2
co-ordinates of E1 and E 2 are obtained by solving y  1 and x  y  4
 
 E1  3,1 and E2  3,1  
co-ordinates of F1 and F2 are obtained by solving x=1 and x 2  y 2  4
 
F1 1, 3 and F2 1,  3   Tangent at E1 :  3 x  y  4
Tangent at E2 :  3 x  y  4  E3  0, 4 
Tangent at F1 : x  3y  4 Tangent at F2 : x  3 y  4  F3  4,0 
And similarly G3  2, 2   0,4  ,  4,0  and  2,2  lies on x  y  4
Page-34

Paragraph "X"
2 2
Let S be the circle in the xy-plane defined by the equation x  y  4 .
(There are two question based on Paragraph "X", the question given below is one of them)
Q16. Let be a point on the circle with both coordinates being positive. Let the tangent to at intersect
the coordinate axes at the points and . Then, the mid-point of the line segment must lie on the
curve
2
A)  x  y   3xy
2/3
B) x  y 2/3  24/3
2 2
C) x  y  2 xy
2 2 2 2
D) x  y  x y
Key: D
Sol:
Tangent at P  2cos , 2sin   is x cos  y sin   2
M  2sec ,0  and N  0,2cos ec 
Let midpoint be  h, k  h  sec , k  cos ec
1 1 1 1
  1  1
h2 k 2 x2 y 2
PARAGRAPH “A”
There are five students S1 , S 2 , S3 , S 4 and S5 in a music class and for them there are five seats R1 , R2 , R3 , R4 ,
and R5 arranged in a row, where initially the seat Ri is allotted to the student S i , =1,2,3,4,5. But, on the
examination day, the five students are randomly allotted the five seats.
Q17. The probability that, on the examination day, the student S1 gets the previously allotted seat R1 , and NONE
of the remaining students gets the seat previously allotted to him/her is
3
A)
40
1
B)
8
7
C)
40
1
D)
5
Key: A
Page-35

1 1 1
4!   
Sol: Required probability 
 2! 3! 4!   9  3
5! 120 40
PARAGRAPH “A”
There are five students S1 , S 2 , S3 , S 4 and S5 in a music class and for them there are five seats R1 , R2 , R3 , R4 ,
and R5 arranged in a row, where initially the seat Ri is allotted to the student S i , =1,2,3,4,5. But, on the
examination day, the five students are randomly allotted the five seats.
Q18. For =1,2,3,4, letTi denote the event that the students S i and Si 1 do NOT sit adjacent to each other on the
day of the examination. Then, the probability of the event T1  T2  T3  T4 is
1
A)
15
1
B)
10
7
C)
60
1
D)
5
Key: C
Sol: n T1  T2  T3  T4   Total  n  T1  T2  T3  T4 

 5!  4
C1 4!2!  3 C1.3!2! 3 C1 3!2!2!   2 C1 2!2! 4 C1.2.2!  2   14
14 7
Probability  
5! 60

Page-36


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2018-Jee-Advanced Question Paper-1_Key & Solutions

JEE (ADVANCED) 2018 PAPER 1

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

A) Process I is an isochoric process

A)Process-I is not isochoric,V is decreasing .

C)Process-IV is isothermal compression ,

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

SECTION 2 (Maximum Marks: 24)

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

g sin  g sin  2 g sin 

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

1kg 2kg Just after collision

capacitors reach equilibrium, the charge on C3 is found to be 5 C .The value of  r 

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

17. Consider the ratio r 

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

in the determination of the decay constant  , in S 1 , is

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

D) Mg3 N 2 (it does not decompose into N 2 )

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

all the three reaction are S N 2 so X is

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# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

1 Br2NaOH (3) soda lime

The correct option(s) is (are)

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# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

SECTION 2 (Maximum Marks: 24)

Sol. *H-atom = 1S Paramagnetic

* O2 (superoxide) = One unpaired electrons in  * M.O. Paramagnetic

* S2(in vapour phase) = same as O2 , two unpaired e– s are present

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Total mass  12  172  4  232  2992g

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

SECTION 3 (Maximum Marks: 12)

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# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Sri Chaitanya IIT Academy