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By Al Kurki, Biodiesel is a renewable and environmentally friendly fuel. This publication surveys many dimensions
Amanda Hill, of biodiesel production and use. Net energy balance, sustainable bioenergy crops, scale of production,
and Mike Morris consumer access, and the economics of biodiesel are all critical when discussing a sustainable energy
NCAT Program future for this country. Above all, increased fuel efficiency and increased diesel engine use in the United
Specialists States will be needed in order for biodiesel to become a meaningful part of our energy future.
© NCAT 2006
Contents
Introduction ..................... 1
Background and
Context .............................. 2
Qualities and Quantities
of Biodiesel and Bio-
diesel Feedstocks ........... 3
Conclusion ........................ 9
References ...................... 10
B
iodiesel offers well-publicized envi- and the link between raising bioenergy
ronmental, economic, and national crops and sustainable, soil-building prac-
security benefits. Biodiesel combus- tices. Other considerations include the
tion emits fewer regulated and non-regulated qualities of different biodiesel feedstocks
pollutants than petrodiesel (with the possible and the economics of production and use.
exception of nitrogen oxides). Further, its This publication also raises other issues,
lubricity extends engine life, and it is a bio- such as access, scale and ownership of pro-
degradable product. duction, co-product development, and the
ATTRA—National Sustainable
Agriculture Information Service Biodiesel could benefit farmers and rural extent to which biodiesel and other biofuels
is managed by the National Cen-
communities, depending on ownership of pro- can effectively replace petroleum fuels.
ter for Appropriate Technology
(NCAT) and is funded under a duction facilities and the mix and marketabil- All dimensions of biodiesel production and
grant from the United States
Department of Agriculture’s ity of useful co-products. And biodiesel could use are fundamentally intertwined with each
Rural Business-Cooperative Ser- reduce dependence on foreign oil and associ- other and with the topic of environmental
vice. Visit the NCAT Web site
(www.ncat.org/agri. ated fluctuations in availability and price. sustainablility. To isolate and address any
html) for more informa-
tion on our sustainable This publication addresses the sustainability single aspect of biodiesel invites reference
agriculture projects. /$"5 dimensions of biodiesel production and use. to others.
Background and Context Biodiesel as a
The Bigger Picture Transportation Fuel
Simply put, biodiesel is the product of mix-
The United States consumes transportation
fuels at an extremely high rate per capita ing vegetable oil or animal fat with alco-
compared to other industrialized countries. hol (usually methanol or ethanol) and a
In 2001, for example, 522 gallons of petro- catalyst, usually lye. Glycerin is the main
leum transportation fuels were expended for by-product.
every man, woman, and child in this coun- Biodiesel performs very similarly to low-
try—compared to 421 gallons per capita in sulfur petroleum-based diesel in terms
Canada, 211 gallons in Germany, and 196 of power, torque, and fuel efficiency, and
Related ATTRA gallons in Japan. (1) does not require major engine modifica-
Publications Two major policy and practical changes tions. Joshua Tickell, the author of several
must occur for biodiesel to have a real books on biodiesel, claims it contains about
Anaerobic Digestion
of Animal Wastes: impact on this country’s energy future: 12 percent less energy than petrodiesel
Factors to Consider • A national commitment to energy effi- (biodiesel = 37 megajoules per kilogram
ciency in every facet of American life. vs. petrodiesel = 42 megajoules per kilo-
Biodiesel—a Primer This may include community redesign, gram). This is partially offset by a seven
Efficient Agricultural broad changes in food production and percent average increase in combustion
Buildings: an Over- delivery systems, greater commitment to efficiency of biodiesel. No overall perceived
view mass transit, and increased mileage effi- decrease in performance is noted for most
Solar-Powered ciency for vehicles. vehicles using biodiesel, even though, on
Livestock Watering • A massive conversion from gasoline-pow- average, there is five percent less torque,
Systems power, and fuel efficiency. (2)
ered autos and light trucks to cleaner-
Wind-powered burning diesel autos. This sort of change Biodiesel is considered a safer fuel than
Electric Systems for is not without precedent. U.S. farmers
petrodiesel. Biodiesel has a high flashpoint
Homes, Farms, and switched from gasoline to diesel powered
Ranches: Resources of over 300ºF (150ºC), compared to 125ºF
farm equipment in the late 1970s and
’80s—an important factor in agriculture’s (52ºC) for petrodiesel. The flashpoint is the
Organic Soybean
Production big energy use reduction since the 1970s. temperature at which a fuel’s vapor can be
Major automakers (General Motors, Toy- ignited. Biodiesel also has a relatively high
Sustainable Corn and boiling point and is generally considered
Soybean Production ota, Ford, and Daimler-Chrysler) plan to
produce more diesel-powered cars for safer to handle.
Oilseed Processing for the U.S. market in the years ahead.
Small-Scale Producers Modern diesel fuels are injected into a
Most farmers and ranchers operate against highly compressed chamber where combus-
Moving Beyond
Conventional Cash tight margins. Capturing energy efficien- tion occurs without a spark plug. Biodie-
Cropping cies and making the best use of biofuels may sel reacts more rapidly in the chamber
be nearly impossible without retooling cur- with less combustion delay than most pet-
rent food production and distribution sys- rodiesel fuels and is, therefore, assigned
tems. For example, when food is shipped a higher cetane number—the measure of
over shorter distances, energy consumption ignition quality. Many of biodiesel’s emis-
and freight costs are reduced. Creating local sion benefits stem from its high ignition
markets for locally grown foods can accom- quality. (3)
plish this. Rotating nitrogen-producing or
phosphorous-availing crops with cash crops Biodiesel can be produced from virtually
can save energy on the farm. Changing till- any kind of vegetable oil—new or used.
age methods or technologies, and properly The U.S. Department of Energy estimates
scaling equipment to the farm operation that about 26.7 million gallons of biodie-
can also save energy. These changes may sel were sold in 2003. Total U.S. diesel
be important precursors to the cost-effective consumption that year was more than 39.9
production of biodiesel. billion gallons. (4)
Page 2 ATTRA Biodiesel: The Sustainablility Dimensions
Qualities and Quantities resource, however, reduces the environ-
mental degradation and costs of disposal
of Biodiesel and in landfills.
Biodiesel Feedstocks The quantity of biodiesel produced from
At cold temperatures, diesel fuels form crops is also limited. If rapeseed were grown
wax crystals that cloud the product and on every acre of cropland available in the
affect fuel performance. This tempera- United States in 2002, an estimated 36.3
ture threshold is called the cloud point billion gallons of oil could be produced—
and occurs at 20º F (-7ºC) for most com- very close to current national demand. (6)
monly used grades of petrodiesel. Biodiesel But of course it is not practical to use all
fuels generally have a cloud point between available farmland to produce transporta-
25 and 60ºF (4 to 16ºC), depending on tion fuels. Moreover, very serious ethical
N
the amount of free fatty acids in the prod- issues are raised by sacrificing croplands inety per-
uct. Waste vegetable oil contains more free for vehicle fuel in a world where people are cent of the
fatty acids (FFAs) than virgin oils. Free fatty hungry and populations are growing. (For a
biodiesel
acids raise the cloud point of the fuel, so discussion of the “food vs. fuel” controversy,
biodiesel made from used cooking oil or ani- see the Web site Journey to Forever, www. virgin oil feedstock
mal fat will cloud at higher temperatures journeytoforever.org.) in the United States
than biodiesel made from new vegetable oil Charles L. Peterson, PhD., of the Univer- in 2001 was from
feedstock. sity of Idaho, notes that 37 million acres of soybeans.
The American Society for Testing and Mate- cropland were reported idle in 2002. That
rials (ASTM) recommended in 1996 that acreage might meet 11 percent of U.S. diesel
biodiesel have a cloud point of at most 38º demand with 3.7 billion gallons of vegetable
F. The cloud point can be lowered with win- oil. Practical use of idle land would be less
terizing additives formulated for diesel fuels. than the 37 million acres, though, because
Biodiesel blends such as B20 (20 percent much of the acreage is highly erodible, dry,
biodiesel/80 percent petrodiesel) typically and has poor soils.
require no action beyond that necessary for
Ninety percent of the biodiesel virgin oil
ordinary petrodiesel. (5)
feedstock in the United States in 2001 was
The United States produces approximately from soybeans. There are many reasons why
3 to 5 billion gallons of waste vegetable oil soybean draws most of the market share
every year in restaurants. (7, 8) Much of as a biodiesel feedstock. Soy is a versatile,
this product goes to landfi lls; some is used nitrogen-fixing crop that yields oil and food
in the soap and cosmetics industry. Waste for humans and livestock. Soybean meal is
cooking oil could contribute only a small of higher market value than soy oil. Conse-
percentage of total U.S. diesel demand. Con- quently, soy oil is a low-priced byproduct
verting this waste into a relatively low-cost available in relatively large volumes. Cur-
Transesterification is the term used to the glycerin molecule, resulting in the further processed to make soap.
describe the transformation of veg- byproduct glycerin. The esters then
Free fatty acids are present in vegeta-
etable oil into biodiesel. Vegetable oil attach to alcohol molecules (either
ble oil when it has been used in cook-
is made up of three esters attached to methanol or ethanol) to form biodie-
ing. When free fatty acids are present,
a glycerin molecule—a triglyceride. sel. In order to prompt the esters to as in waste vegetable oil, more base
An ester is a hydrocarbon chain avail- break from the glycerin and bond with catalyst is required to neutralize the
able to bond with another molecule. the alcohol, a catalyst (sodium hydrox- FFAs, which renders the biodiesel fit
During transesterification, the esters ide or potassium hydroxide) must be for use. (Adapted from From the Fryer
in vegetable oil are separated from used. The glycerin byproduct can be to the Fuel Tank by Joshua Tickell)
Sunflower 98 Catch crop for nutrients, breaks up hardpan and compacted soil, Susceptible to sclero-
may reduce fusarium when used in rotation with grain crops, tinia and should be
can serve as a windbreak. Row-cropping provides opportunity grown once very five
for mechanical weed control during growing season. years. Should not be
raised in short rotations
with crucifers.
Safflower 80 Breaks up hardpan and compacted soil with its deep roots.
Camelina 60 Cool season crop—a crucifer like canola, rape, mustard, and
crambe. Has allelopathic effects and it is somewhat drought
resistant. It fairly weed competitive when winter or very early
spring seeded.
Mustard 59 Primarily a cool season crop. Nutrient catch crop. Has nemati- Sclerotinia-susceptible.
cidal properties that reduce soil-borne pathogens. Can smother Should not be grown
weeds and has allelopathic effects on weeds. within five years of
sunflower.
Flaxseed/Linseed 49 A good crop for interseeding or to sow following a competitive
crop onto clean field. Not weed competitive on its own. It is a
light feeder.
Soy 46 Fixes nitrogen, although most of the nitrogen is removed with Poor choice for control-
the bean harvest. ling erosion or building
organic matter levels.
Lupine 24 Moderate nitrogen fixer, takes up soil phosphorus—making it
available for subsequent crops, reduces erosion and crop dis-
ease, deep taproots can open and aerate soil.
Oat 22 Erosion control, enhances soil life, and adds organic matter.
Serves as a catch crop and a nurse crop, can be used for weed
control in rotations, crop residue reduces nitrogen leaching.
E
viscous than either petrodiesel or biodie- can result in soil compaction, erosion, or
ntrepreneurs
sel and must be fi ltered to five microns and downstream nutrient loading. Monocultures
also create more insect, pathogen, and weed and scien-
heated to at least 140°F before use in die-
sel engines. It doesn’t burn the same in the management challenges. tists in
engine and many studies have found that Monocultures exhibit an economic dimen- Montana discovered
it can cause lacquering and other kinds of sion as well—at what point does any cash that a biodiesel
engine damage. crop become an undifferentiated bulk com- plant could not pay
If you are tempted to try SVO, a profes- modity raised in such high volumes that it farmers a sustained
sional engine conversion is strongly rec- doesn’t have enough value for growers to fair price for their
ommended. This conversion often includes turn a profit? Many farmers and ranchers
bioenergy crops
installing a second fuel tank, allowing you are raising more diverse, higher-value food
crops and animals because they perceive (canola or industrial
to start and shut down on biodiesel or pet-
rodiesel. The basic idea is to use only pre- that subsidized, bulk commodity production rape) unless the
heated SVO and to clear your fuel lines is economically unsustainable for them. This co-products could
before shutting down the vehicle. is a factor to consider in producing biofuel be manufactured
crops as well.
The economics of producing and using and sold.
biodiesel on a small scale are outlined in Ownership and Design of
ATTRA’s publication Biodiesel - a Primer
(12) and in other sources, such as Maria Biodiesel Production
“Mark” Alovert’s excellent Biodiesel Home- Ownership and design of biodiesel produc-
tion is also related to
feedstock price and a
fair rate of return to
farmers. Farmer own-
ership of at least part
of the production pro-
cess beyond the farm
gate keeps more dol-
lars in farmers’ pock-
ets and in the local
community. This has
been proven time and
Mustard. Photo courtesy of USDA ARS. again, most recently in
the Midwest with etha-
Access to Biodiesel
Biodiesel is currently available in most
states that produce oilseed crops, and
many farmers use biodiesel as a means
of fostering production and raising public
awareness. Nonetheless, farmers’ access
to biodiesel for farm use is another dimen- Photo courtesy of USDA ARS.
sion that requires consideration and raises
potential for a sad irony.
holds great promise as a sustainable energy
Farmers who raise crops for biodiesel in iso- source, if several sustainability principles are
lated rural areas may not have ready access treated seriously:
to the finished fuel. Unless farmers intend to
make biodiesel on location, or a larger scale 1. Capture as much energy efficiency as
local biodiesel production facility is online, possible on and off the farm, to reduce
many farmers find they cannot use the fuel transportation fuel demand, reduce pro-
they are working to create. duction costs, and improve energy bal-
ance.
On its Web site, the National Biodiesel
Board lists about 50 suppliers to contact 2. Convert as much waste as possible into
to have biodiesel shipped across the U.S. a useable resource, such as converting
Almost every state has at least one pump waste vegetable oil into fuel.
station that offers some blend of biodiesel,
3. Put oil-producing crops and high-qual-
though not necessarily within practical dis-
ity agricultural lands to their highest and
tance for most potential customers. The site
posts a map of retail outlets for biodiesel most sustainable use, which will often be
across the country. The board recommends food production instead of energy pro-
asking regional fuel distributors to get more duction.
biodiesel supplied locally. (20) 4. Raise bioenergy crops that enhance soil
and water resources.
Conclusion 5. Create a range of diverse opportunities
Resources are available to help farmers for biodiesel production in terms of the
and consumers determine the best means scale, design, and ownership so farmers
to manage the advantages biodiesel has to and rural communities can share in the
offer. Biodiesel has “tailpipe benefits” and economic benefits.
Notes
Page 12 ATTRA