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CALCULATIONS
This page looks at how to do routine electrolysis calculations.
Coulombs
That means that you can work out how much electricity has
passed in a given time by multiplying the current in amps by the
time in seconds.
That's easy!
The Faraday
= 96320 coulombs
The numbers we are using here are rounded off. The calculation
just shows you how to work it out if you have to, but doesn't give
the normally-used value. For exam purposes, the value of the
Faraday constant is usually taken as 9.65 x 104 C mol-1
(coulombs per mole). This is another number you are unlikely to
have to remember.
Example 1
Note: If your maths is really bad, so that you aren't happy about simple
proportion sums, then think of it like this:
If 96500 coulombs give 108 g, then 1 coulomb would give 108 divided
by 96500 g. 60 coulombs would produce 60 times this amount.
It doesn't matter in the least how you work this out - all that matters for
your chemistry is that you get the answer right!
Example 2
In other words, you are working out 24/(2 x 96500) and then multiplying
by 900. It is a different order from the way it is shown in the simple
proportion sum shown above, but the answer is still exactly the same.
In addition, if you feel happier working out the value of 2 x 96500 before
you do anything else, that's what you should do. As long as you get the
answer right, nobody is interested in the exact way you handle the
sums.
Example 3
This example shows you what to do if the question is reversed.
This time you can't start by working out the number of coulombs,
because you don't know the time. As with any other calculation,
just start from what you know most about. In this case, that's the
copper, so start with the electrode equation.
Note: And again, if you still don't like simple proportion sums:
Now what?
You know how many coulombs you need, and you know what
the current was in amps. You have got all the information you
need to work out the time.
1930 = 0.200 x t
If this is the first set of questions you have done, please read the
introductory page before you start. You will need to use the BACK
BUTTON on your browser to come back here afterwards.
answers
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