Phase Test-3 JR Q.P-1, 2 & Solutions PDF

FIITJEE INTERNAL TEST
IIT – JEE 2019

PHASE – III_PAPER – I_SET – A
Time: 3 hours Maximum Marks: 210
INSTRUCTIONS:
A. General
1. This booklet is your Question Paper containing 60 questions.
2. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and
electronic gadgets in any form are not allowed to be carried inside the examination hall.
3. Fill in the boxes provided for Name and Enrolment No.
4. The answer sheet, a machine-readable Objective Response (ORS), is provided separately.
5. DO NOT TAMPER WITH / MULTILATE THE ORS OR THE BOOKLET.
B. Filling in the OMR:
6. The instructions for the OMR sheet are given on the OMR itself.
C. Question paper format:
7. The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part
consists of three sections.
8. Section I contains 10 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.
9. Section II contains 5 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE are correct.
10. Section III contains 5 questions. The answer to each question is a single digit integer, ranging
from 0 to 9 (both inclusive).
D. Marking Scheme
11. For each question in Section I, you will be awarded 3 marks if you darken the bubble
corresponding to the correct answer ONLY and zero marks if no bubbles are darkened. In all
other cases, minus one (–1) mark will be awarded in this section.
12. For each question in Section II, you will be awarded 4 marks if you darken ALL the bubble(s)
corresponding to the correct answer(s) ONLY. In all other cases zero (0) marks will be awarded.
No negative marks will be awarded for incorrect answers in this section.
13. For each question in Section III, you will be awarded 4 marks if you darken the bubble corresponding
to the correct answer ONLY. In all other cases zero (0) marks will be awarded. No negative marks
will be awarded for incorrect answers in this section.
Useful data
–1 –1 –2 –1 –1 –1
R = 8.314 JK mol or 8.206  10 L atm K mol ; 1 F = 96500 C mol
–34 –19
h = 6.626  10 Js; 1 eV = 1.602  10 J
–1
c = 3.0  10 ms ; NA = 6.022  10
8 23
(Atomic Masses in amu : H = 1 , He = 4, C = 12, N = 14, O = 16, Na = 23, Mg = 24, P = 31, S = 32, Cl = 35.5, K
= 39, Ca = 40, Fe = 56, Cu = 63.5)
Don’t write / mark your answers in this question booklet.

If you mark the answers in question booklet, you will not be allowed to continue the exam.
NAME:
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PH-III-2019-P(I)–PCM-2
PAPER–I
PART I: PHYSICS
SECTION – I: Single Correct Answer Type
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
1. In the figure, three identical massless springs are kept

horizontal. The left end of the first is tied to a wall. The left
end of the second spring is tied to a block of mass m placed
on rough ground and the left end of the third spring is tied to a
block of mass m placed on frictionless ground. Right end of
each spring is pulled by a force that is increased gradually
from zero to F. Extension in these springs are x1,x 2 and x 2
respectively. Which of the following statements is correct ?
(A) x1  x2  x3 (B) x1  x2  x3
(C) x1  x2  x3 (D) None of these
2. A uniform rope of length 13 m tied to a peg A on a wall and

passes over a frictionless peg B fixed in level with the peg A as
shown in the figure. Length of 8 m of the rope is hanging between
both the pegs and remaining length hangs vertically on the right
side of the peg. The rope is in equilibrium. The angle which the
rope makes with the wall is closest to
(A) 300 (B) 370
0
(C) 45 (D) 530
3. If a block is pulled up an inclined plane with a force of 20 N

along the line of greatest slope, the block slides up with
constant velocity. If the block is pulled down the inclined
plane with a force of 8 N along the line of greatest slope, the
block down with constant speed. The force of kinetic friction
between the block and the plane is
(A) 8 N (B) 12 N
(C) 14 N (D) None of these
Space for rough work
4. Someone is using a scissors to cut a vertical wire of circular

cross section. To reduce required force the wire must be
placed close to the hinge; but if it is placed close to the hinge;
it slides in the direction away from the hinge until the angle
between the scissors blades becomes  . Find the coefficient
of friction between the blades and the wire.
(A) cot  0.5 (B) tan  0.5
(C) 0.5 tan (D) More information is required to decide.
5. A weight of mass m is hanging on an elastic thread. If an additional stretching force were applied and
is gradually increased to a value F0 . The thread would break. What should be the minimal value of an
additional constant force F that will break the thread ?
1 1
(A) F  F0  mg (B) F  F0  mg
2 2
1 1
(C) F  F0  mg (D) F  F0
2 2
6. Suppose two particles A and B of masses m and 2 m rest at the origin of an inertial frame in free
space. They are acted upon by force of equal magnitudes F in the positive x –direction for equal
amount of time t. Momenta PA / C and PB / C of the particles A and B in center of mass frame are
2Ft ˆ 2Ft ˆ 2Ft ˆ 2Ft ˆ
(A) pA / C  i and pB / C   i (B) pA / C   i and pB / C   i
3 3 3 3
Ft Ft Ft Ft
(C) pA / C  î and pB / C   î (D) pA / C   î and pB / C  î
3 3 3 3
7. Two streams of water flow through the tube assembly

made by joining two U – shaped tubes. The tube on the left
has uniform cross –sectional area. A, and the speed of the
water flowing through it is u; the tube on the right has
uniform cross – sectional area A/2. If the net force on the
tube assembly due to water flow is zero, what must be the
speed of the water flow through the tube on the right ?
neglect effect of gravity.
(A) u/2 (B) u 2
(C) 2 u (D) 4 u
8. A small block of mass m rests on a plank of mass M,

which rests on a frictionless horizontal plane as shown in
the figure. The block is given a sharp impulse, so that it
starts sliding on the plank with initial velocity u. Due to
friction between the block and the plank, the block slows
down and finally stops sliding on the plank. find the total
work performed by the frictional force in this process.
m2M 2 mM2
(A) u (B) u2
2  m  M 2  m  M
2 2
mM  2m  M mM
(C) u2 (D) u2
2  m  M
2
2  m  M
9. Top surface of a large block A of mass M = 4

kg consists of a frictionless slop of height h =
40 cm which smoothly merges into a rough
horizontal portion. The block rests on a
frictionless horizontal floor. When a small
block B of mass m = 1.0 kg is released from
the top of the slope, it slides down the slop
and then stops after sliding a distance
 1.0 m on the horizontal portion of top of
block A. Find coefficient of friction between
the block B and horizontal portion of top of
block A.
(A) 0.1 (B) 0.2
(C) 0.3 (D) 0.4
10. A spherical object of mass 60kg is

dropped from a very large height. Its
speed at every 1.0 s interval is recorded
and is represented in the velocity – time
graph, but the experimenter forgot
marking velocities. Line AB is the
tangent to the graph at the instant t = 5.0
s . Assume acceleration due to gravity g
2
= 10 m/s and find power of air
resistance at the instant t = 5.0 s
(A) 0.6 kW
(B) 15.0 kW
(C) 24.0 kW
(D) Insufficient information
SECTION – II: Multi Correct Answer(s) Type

of which ONE or MORE may be is correct.
11. In the figure, two blocks of equal mass m are connected by an

ideal string that passes over an ideal pulley. The blocks are
connected by spring of force constants k1 and k 2 k1  k 2  .
Initially, both springs are relaxed. Then the left block is slowly
pulled down a distance x and released. Magnitudes of
accelerations of the left and the right blocks immediately after
release are a1 and a2 respectively. Mark the correct option /
options.
(A) a1  a2 (B) a1  a2 if k1  k 2  2mg/ x
(C) a1  a2 if k1  k 2  2mg/ x
(D) Relation between a1 and a2 also depends on magnitude of x.
12. A car moves with constant speed on a turn of suitable banking. Its speed when no friction is required
is known as optimum speed v 0 . In presence of friction it can achieve a maximum safe speed v max
and a minimum safe speed v min . Angle of banking is more than the angle of repose. Which of the
following is correct ?
v  v max v  v max
(A) v 0  min (B) v 0  min
2 2
v min  vmax
(C) v 0  (D) It depends on coefficient of static friction
2
13. A semicircular cylindrical tube is place on the horizontal

ground. Two identical balls that loosely fit inside the tube
are simultaneously released from the top inside the
tube. Each ball moves down the tube on either side.
Which of the following statements best describe or
describe the total normal reaction by the ground on the
rube ?
(A) It decrease continually
(B) It increase continually
(C) It first decreases, acquires a minimum value
then increases
(D) The tube may leave the ground.
14. A dumbbell is constructed by fixing small identical balls at the ends of

a light rod of length . The dumbbell stands vertically in the corner
formed by a frictionless wall and frictionless floor. After the bottom
end is slightly pushed to the right, the dumbbell begins to slide. Value
of which of the following quantities vanishes, when the upper ball is
leaving the wall
(A) Tension in the rod
(B) Acceleration of the upper ball
(C) Acceleration of the lower ball
(D) Normal reaction from floor on the lower ball
15. A box of mass m = 4 kg rests on a rough horizontal surface where

coefficient of static and kinetic frictions are s  s  0.25 . The
box is acted upon by a horizontal force F, which varies as shown.
Which of the following statements correctly describe the motion of
the box ?
(A) The box starts moving at the instant t= 2.0 s
(B) The maximum velocity acquired by the box is 5.0 m/s
(C) The box stops at the instant t =9.0 s
(D) Heat lost during the process is 6125 J.
SECTION – III: Integer Answer Type

This section contains 5 questions. The answer to each of the questions is a single–digit integer, ranging
16. Between two frictionless platforms A and B is a

water channel of width b = 17 m .A plank of length
 2.0 rest near the platform A. A block of mass m
= 25 kg sliding on the platform A lands on the plank
and stays on it. Force F of water resistance on the
plank is proportional to velocity of the plank v pr A B
relative to the water and given by the law
F  kvpr N , where k = 15 N – s / m. The minimum
speed umin of the block on platform A so that the
plank reaches the platform B is _________ m /s
17. A small disk of mass M= 2.0 kg is connected with two identical

small disk each of mass m = 1.0 kg with the help of two light
inextensible threads each of length  50cm. Initially the system u
rest on a frictionless horizontal floor with centres of the disks in a
straight line and the thread straight. Now the middle disk is given a m M m
sharp impulse to acquire a horizontal velocity u = 2 m/s per
perpendicular to the threads.
tension in the threads immediately before the end disks collide
is ____ N
18. A block of mass M can slide without friction along a

horizontal table. A small ball of mass m is
suspended by a light inextensible cord of length
from a hanger fixed at the top a vertical pole
mounted on the block so that the ball can swing
freely in the vertical plane. The ball is released from
the horizontal position as shown. The maximum
tension of the string during the subsequent motion is
 m 
   M  mg then    is __
 
19. A small block A of mass m = 2.0 kg sliding

on a friction platform lands on cart B of mass
M = 8.0 kg. Distance between left end of the
cart and the obstruction at the right end is
 1.0m . The horizontal floor below the cart
is frictionless. Coefficient of friction between
the cart and the block is  = 0.5. Collision
between the block and the obstruction is
perfectly elastic.
If the speed with which the block lands
on the cart is so adjusted that block
stops on the cart as at its rear end, then
loss of mechanical energy W during
140
this time is J then  is __

20. A ball of mass m is dropped from height h= 9.0 m and some time after another ball of mass m /2 is
dropped from the same place. If the collision between the balls and the ground is elastic, the
maximum height can one of the balls rise is 5 m then  is ____
PART II: CHEMISTRY

21. 0.020g of selenium vapour at equilibrium occupying a volume of 2.463 mL at 1 atm and 27C. The
selenium is in a state of equilibrium according to reaction
3Se2  g Se6  g
What is the degree of association of selenium ?
(At. Wt. of Se = 79)
(A) 0.205 (B) 0.315 (C) 0.14 (D) None of these
22. One mole of SO3 was placed in a two litre vessel at a certain temperature. The following equilibrium
was established in the vessel
2SO3  g 2SO2  g  O2  g
the equilibrium mixture reacted with 0.2 mole KMnO4 in acidic medium. Hence, KC is :
3
23. The density of vapour of a substance (X) at 1 atm pressure and 500 K is 0.8 kg/m . The vapour
effuses through a small hole at a rate of 4/5 times slower than oxygen under the same condition.
What is the compressibility factor (Z) of the vapour ?
(A) 0.974 (B) 1.35 (C) 1.52 (D) 1.22
28
24. The average speed at temperature TC of CH4 (g) is  103 ms1 . What is the value of T ?
88
(A) 240.55C (B) –32.45C (C) 3000C (D) –24.055C
25. How many 2 and 3 carbon atoms are present in the given compound respectively ?
(A) 9 & 4 (B) 10 & 3 (C) 9 & 3 (D) 6 & 1
26. The IUPAC name of the compound shown below is

Cl
Br
(A) 2–Bromo–6–chlorocyclohex–1–ene (B) 6–Bromo–2–chlorocyclohexene
(C) 3–Bromo–1–chlorocyclohex–1–ene (D) 1–bromo–3–chlorocyclohexene
27. The number of metamers of the compound with molecular formula C5H12O is/are
(A) 1 (B) 3 (C) 8 (D) 6
28. Which of the following pairs of structures do not represent isomers ?
(A) (B)
& &
O O O
OH
O
O O
(C) (D) &
&
O
29. The ‘E’– Isomer i/sare

F H CH 2 CH 3
(A) C C (B) C C
Cl Br H H
H C2H5 D CHO
(C) C C (D) C C
H3C CH(CH 3)2 H COOCH 3
30. The correct order/s for the given pair of isomers is

CH 3 CH 3 CH 3 H
(A) C C > C C (melting point)
H H H CH 3
H H H COOH
(B) C C < C C (Dipole moment)
HOOC COOH HOOC H
H Cl Cl Cl
(C) C C > C C (Boiling point)
Cl H H H
H3C H H3C COOH
(D) C C > C C (water solubility)
H COOH H H

31. Consider the reaction given below. In which cases will the reaction proceed toward right by increasing
the pressure ?
1
(A) 4HCl  g  O2  g  2Cl2  g  2H2O  g (B) Cl2  g  H2O  g  2HCl  g  O2  g
2
(C) CO2  g  4H2  g  CH4  g  2H2O  g (D) N2  g  O2  g  2NO  g
32. If a gas expands at constant temperature :

(A) the pressure decrease
(B) the kinetic energy of the molecules remains the same
(C) the K.E. of the molecules decrease
(D) the number of molecules of the gas increase
33. Which of the following IUPAC name(s) is/are incorrect :

(A) 4–chloro–3–methyl cyclopentanol (B) 1–Amino–3–bromohexan–1–one
(C) 4–chloro–3–methylcyclohexane carboxylic acid
(D) 3–Bromo–1–methylhexane–1–ol
34. Which of the following represent correct pair of homologous ?
(A) OH & CH2-OH (B) Me–OH & MeCH2CH2OH
CH3–CH2–NH2 & CH3–CH2–

(C) H–COO–CH3 & CH3COOCH3 (D)
NH(CH3)
35. Which of the following show geometrical isomerism

(A) 1, 2–Dichloro–1–pentene (B) 1, 3–Dichloro–2–pentene
(C) 1, 1–Dichloro–1–pentene (D) 1, 4–Dichloro–2–pentene

36. A mixture of 3 moles of SO2, 4 moles of NO2, 1 moles of SO3 and 4 moles of NO is placed in a 2.0 L
vessel. SO2  g  NO2  g SO3  g  NO  g .
At equilibrium, the vessel is found to contain 1 mole of SO2. Calculate the value of KC.
37. If an ideal gas at 100 K is heated to 109 K in a rigid container, the pressure increases by X%. What is
the value of X ?
38. The number of possible alkynes (structural only) for the compound having molecular formula C 3FCl
BrI is is
39. How many distinct conformers of 2, 3–dimethyl butane are possible if the bond between C2 & C3 is
rotated by an angle  = n x 60 (n = 1, 2, 3, … )
40. How many tertiary alcohols is/are possible with molecular formula C5H12O ?
PART III: MATHEMATICS

3 3 0  4 1 5 
41. If 2x – y =  and 2y + x =  1 4 4  , then
3 3 2  
3 0 1 2 1 1  1 2 3   1 1 2
(A) x + y =   (B) x =  (C) x – y = 2 1 2 (D) y =
0 3 2 1 2 0   
 1 1 2
 
1 sin  1
42. Let  =  sin  1 sin  ; 0   < 2, then
1  sin  1
(A)  = 0 (B)   (0, ) (C)   [–1, 1] (D)   [2, 4]
t 2  3t t  1 t  3
If At + Bt + Ct + Dt + E = t  1 2  t t  3 , then E equals
4 3 2
43.
t  3 t  4 3t
(A) 33 (B) –39 (C) 27 (D) 24
44. If a, b, c are non-zero numbers and if the equations (a – 1)x = y + z, (b – 1)y = z + x,

(c – 1)z = x + y has a non trivial solution, then ab + bc + ca is equal to
(A) a + b + c (B) abc (C) 1 (D) none of these
45. The equation of the plane which passes through the x-axis and perpendicular to the line
 x  1  y  2  z  3 
  is
cos  sin  0
(A) x tan  + y sec  = 0 (B) x sec  + y tan  = 0
(C) x cos  + y sin  = 0 (D) x sin  – y cos  = 0
x y z
46. The plane   = k, meets the coordinate axes at A, B, C such that the centroid of the triangle
a b c
ABC is the point (a, b, c). Then k is
(A) 3 (B) 2 (C) 1 (D) 5
47. The intercepts made on the axes by the plane which bisects the line joining the points (1, 2, 3) and (–
3, 4, 5) at right angles are
 9  9   9   9 
(A)   ,9,9  (B)  ,9,9  (C)  9,  ,9  (D)  9, ,9 
 2  2   2   2 
48. The equation of the plane passing through the intersection of the planes 2x – 5y + z = 3 and x + y +
4z = 5 and parallel to the plane x + 3y + 6z = 1 is x + 3y + 6z = k, where k is
(A) 5 (B) 3 (C) 7 (D) 2
x  3 y  2 z 1 x  2 y  3 z 1
49. The plane containing the two lines   and   is 11x + my + nz =
1 4 5 1 4 5
28, where
(A) m = –1, n = 3 (B) m = 1, n = –3 (C) m = –1, n = –3 (D) m = 1, n = 3
x 1 y 1 z  3
50. The distance of the point (2, 1, –2) from the line   measured parallel to the plane x
2 1 3
+ 2y + z = 4 is
(A) 10 (B) 20 (C) 5 (D) 30

x2  x x 1 x  2
51. If 2x  3x  1 3x
2
3x  3 = Ax + B, where A and B are constants, then
x  2x  3 2x  1 2x  1
2
2 2
(A) A + B = 12 (B) A – B = 36 (C) A + B = 720 (D) A + 2B = 0
1 a a2
52. cos  xz  yz  cos xz cos  xz  yz  depends on
sin  xz  yz  sin xz sin  xz  yz 
(A) x (B) y (C) z (D) a
 
a2  b2  c 2 cos  ab 1  cos   ac 1  cos  
53.
2 2 2
If a + b + c = 1, then ba 1  cos    
b2  c 2  a2 cos  bc 1  cos   is independent of
ca 1  cos   cb 1  cos    
c 2 a2  b2 cos 
(A) a (B) b (C) c (D) 
3 3 4 
54. If A = 2 3 4  , then
0 1 1 
(A) adj (adj A) = A (B) |adj (adj A)| = 1 (C) |adj A| = 1 (D) none of these
55. The equation of a line 4x – 4y – z + 11 = 0 = x + 2y – z – 1 can be put as

x y 2 z3 x  4 y  4 z  11
(A)   (B)  
2 1 4 2 1 4
x 2 y z3 x2 y2 z
(C)   (D)  
2 1 4 2 1 4

56. If the planes x = cy + bz, y = az + cx, z = bx + ay pass through one line then the value of
2 2 2
a + b + c + 2abc must be
 1  5
p 15 8   100   Dp
  p 1
57. If Dp = p2 35 9 , then the value of must be
66
p3 25 10
58. If the system of equations 3x – 2y + z = 0, x – 14y + 15z = 0, x + 2y + 3z = 0 have a non trivial

solution, then the value of  – 840 must be
2
x2  x x 1 x  2
A
59. If 2x  3x  1 3x
2
3x  3 = Ax – 12, then the value of must be
6
x 2  2x  3 2x  1 2x  1
1 3cos  1
maximum value of   minimum value of 
60. If  = sin  1 3cos  , then the is equal to
5
1 sin  1

IIT – JEE 2019
PHASE – III_PAPER – I_SET-A
ANSWERS
PHYSICS
1. A 2. B 3. C 4. B
5. D 6. C 7. B 8. D
9. D 10. B 11. B,C 12. C
13. C,D 14. A,C 15. A,B,C,D 16. 9
17. 2 18. 5 19. 7 20. 5
CHEMISTRY
21. C 22. B 23. C 24. B
25. A 26. C 27. D 28. D
29. D 30. D 31. A, C 32. A, B
33. A, B, D 34. B, C 35. A, B, C 36. 9
37. 9 38. 4 39. 3 40. 1
MATHEMATICS
41. B 42. D 43. B 44. B
45. C 46. A 47. A 48. C
49. BONUS 50. D 51. ABCD 52. BCD
53. BONUS 54. ABC 55. AB 56. 1
57. BONUS 58. 1 59. 4 60. 2

IIT – JEE 2019
PHASE – III_PAPER – I_SET – B
INSTRUCTIONS:
A. General
D. Marking Scheme
Useful data
–1 –1 –2 –1 –1 –1
–34 –19
h = 6.626  10 Js; 1 eV = 1.602  10 J
–1
c = 3.0  10 ms ; NA = 6.022  10
8 23
= 39, Ca = 40, Fe = 56, Cu = 63.5)

NAME:
ENROLLMENT NO.:
PAPER–I
PART I: PHYSICS
1 1
(A) F  F0  mg (B) F  F0
2 2
1 1
(C) F  F0  mg (D) F  F0  mg
2 2
Ft ˆ Ft 2Ft ˆ 2Ft ˆ
(A) pA / C  i and pB / C   î (B) pA / C   i and pB / C   i
3 3 3 3
2Ft ˆ 2Ft ˆ Ft Ft
(C) pA / C  i and pB / C   i (D) pA / C   î and pB / C  î
3 3 3 3

(A) u 2 (B) u/2
(C) 2 u (D) 4 u

(A) x1  x2  x3 (B) x1  x2  x3

(A) 300 (B) 530
0
(C) 45 (D) 370

(A) 8 N (B) 14 N

mM mM2
(A) u2 (B) u2
2  m  M 2  m  M
2
mM  2m  M m2M
(C) u2 (D) u2
2  m  M 2  m  M
2 2

block A.
(A) 0.1 (B) 0.4
(C) 0.3 (D) 0.2

2
(A) 0.6 kW
(B) 24.0 kW
(C) 15.0 kW

(A) tan  0.5 (B) cot  0.5

v  vmax v  v max
(A) v 0  min (B) v 0  min
2 2
v min  v max
(C) v 0  (D) It depends on coefficient of static friction
2

rube ?
(C) The tube may leave the ground.
(D) It first decreases, acquires a minimum value
then increases

leaving the wall
(B) Acceleration of the lower ball
(C) Acceleration of the upper ball

the box ?
(A) The box stops at the instant t =9.0 s
(C) The box starts moving at the instant t= 2.0 s

options.
(A) a1  a2 if k1  k 2  2mg/ x (B) a1  a2
(C) a1  a2 if k1  k 2  2mg/ x



is ____ N

 m 
   M  mg then    is __
 

perfectly elastic.
140

PART II: CHEMISTRY


Cl
Br
(C) 1–bromo–3–chlorocyclohexene (D) 3–Bromo–1–chlorocyclohex–1–ene
(A) 6 (B) 3 (C) 8 (D) 1
3Se2  g Se6  g
2SO3  g 2SO2  g  O2  g
3
(A) 0.974 (B) 1.52 (C) 1.35 (D) 1.22
O O
(A) (B) &
&
O O
O
(C) (D)
& &
OH O
O

D CHO CH 2 CH 3
(A) C C (B) C C
H COOCH 3 H H
H C2H5 F H
(C) C C (D) C C
H3C CH(CH 3)2 Cl Br

H3C H H3C COOH
(A) C C > C C (water solubility)
H COOH H H
H H H COOH
HOOC COOH HOOC H
H Cl Cl Cl
Cl H H H
CH 3 CH 3 CH 3 H
(D) C C > C C (melting point)
H H H CH 3
28
88
(A) 240.55C (B) –24.055C (C) 3000C (D)–32.45C
(A) 9 & 3 (B) 10 & 3 (C) 9 & 4 (D) 6 & 1

the pressure ?
(A) 4HCl  g  O2  g  2Cl2  g  2H2O  g (B) CO2  g  4H2  g  CH4  g  2H2O  g
1
(C) Cl2  g  H2O  g  2HCl  g  O2  g (D) N2  g  O2  g  2NO  g
2

(B) the K.E. of the molecules decrease
(C) the kinetic energy of the molecules remains the same

(C) 3–Bromo–1–methylhexane–1–ol
(D) 4–chloro–3–methylcyclohexane carboxylic acid
OH & CH2-OH
(A) Me–OH & MeCH2CH2OH (B)

NH(CH3)


the value of X ?
BrI is is

x y z
a b c
(A) 1 (B) 2 (C) 3 (D) 5
9   9   9   9 
(A)  ,9,9  (B)   ,9,9  (C)  9,  ,9  (D)  9, ,9 
 2   2   2   2 
3 3 0  4 1 5 
43. If 2x – y =  and 2y + x =  1 4 4  , then
3 3 2  
3 0 1 1 1 2  1 2 3  2 1 1
(A) x + y =   (B) y =   (C) x – y =   (D) x =  
0 3 2  1 1 2 2 1 2 1 2 0
1 sin  1
44. Let  =  sin  1 sin  ; 0   < 2, then
1  sin  1
(A)   [2, 4] (B)   (0, ) (C)   [–1, 1] (D)  = 0
t 2  3t t  1 t  3
4 3 2
45.
t  3 t  4 3t
(A) 33 (B) 24 (C) 27 (D)–39
(A) 5 (B) 3 (C) 2 (D) 7
x  3 y  2 z 1 x  2 y  3 z 1
1 4 5 1 4 5
28, where
(A) m = –1, n = –3 (B) m = 1, n = –3 (C) m = –1, n = 3 (D) m = 1, n = 3
x 1 y 1 z  3
48. The distance of the point (2, 1, –2) from the line   measured parallel to the plane
2 1 3
x + 2y + z = 4 is
(A) 10 (B) 30 (C) 5 (D) 20

(A) a + b + c (B) 1 (C) abc (D) none of these
 x  1  y  2  z  3  is
 
cos  sin  0
(A) x cos  + y sin  = 0 (B) x sec  + y tan  = 0
(C) x tan  + y sec  = 0 (D) x sin  – y cos  = 0

x2  x x 1 x  2
51. If 2x  3x  1 3x
2
x  2x  3 2x  1 2x  1
2
2 2
(A) A + B = 12 (B) A – B = 36 (C) A + B = 720 (D) A + 2B = 0
1 a a2
(A) x (B) y (C) z (D) a
 
53.
2 2 2
If a + b + c = 1, then ba 1  cos    
ca 1  cos   cb 1  cos    
c 2 a2  b2 cos 
(A) a (B) b (C) c (D) 
3 3 4 
54. If A = 2 3 4  , then
0 1 1

x y 2 z3 x 2 y z3
(A)   (B)  
2 1 4 2 1 4
x  4 y  4 z  11 x2 y2 z
(C)   (D)  
2 1 4 2 1 4

2 2 2
 1  5
p 15 8   100   Dp
  p 1
66
p3 25 10

2
x2  x x 1 x  2
A
59. If 2x  3x  1 3x
2
6
x  2x  3 2x  1 2x  1
2
1 3cos  1
5
1 sin  1

IIT – JEE 2019
PHASE – III_PAPER – I_SET-B
ANSWERS
PHYSICS
1. B 2. A 3. A 4. B
5. D 6. B 7. A 8. B
9. C 10. A 11. A 12. C, D
13. A, B 14. A,B,C,D 15. A, C 16. 9
17. 2 18. 5 19. 7 20. 5
CHEMISTRY
21. D 22. A 23. A 24. A
25. B 26. B 27. A 28. A
29. D 30. C 31. A, B 32. A, C
33. A, B, C 34. A, C 35. A, B, D 36. 9
37. 9 38. 4 39. 3 40. 1
MATHEMATICS
41. C 42. B 43. D 44. A
45. D 46. D 47. BONUS 48. B
49. C 50. A 51. ABCD 52. BCD
53. BONUS 54. ABC 55. AC 56. 1
57. BONUS 58. 1 59. 4 60. 2

IIT – JEE 2019
PHASE – III_PAPER – I_SET – C
INSTRUCTIONS:
A. General
D. Marking Scheme
Useful data
–1 –1 –2 –1 –1 –1
–34 –19
h = 6.626  10 Js; 1 eV = 1.602  10 J
–1
c = 3.0  10 ms ; NA = 6.022  10
8 23
= 39, Ca = 40, Fe = 56, Cu = 63.5)

NAME:
ENROLLMENT NO.:
PAPER–I
PART I: PHYSICS

m2M 2 mM2
(A) u (B) u2
2  m  M 2  m  M
2 2
mM  2m  M mM
(C) u2 (D) u2
2  m  M
2
2  m  M

block A.
(A) 0.1 (B) 0.2
(C) 0.3 (D) 0.4

2
(A) 0.6 kW
(B) 15.0 kW
(C) 24.0 kW

(A) cot  0.5 (B) tan  0.5
1 1
(A) F  F0  mg (B) F  F0  mg
2 2
1 1
(C) F  F0  mg (D) F  F0
2 2
2Ft ˆ 2Ft ˆ 2Ft ˆ 2Ft ˆ
(A) pA / C  i and pB / C   i (B) pA / C   i and pB / C   i
3 3 3 3
Ft Ft Ft Ft
(C) pA / C  î and pB / C   î (D) pA / C   î and pB / C  î
3 3 3 3

(A) u/2 (B) u 2
(C) 2 u (D) 4 u

(A) x1  x2  x3 (B) x1  x2  x3

(A) 300 (B) 370
(C) 450 (D) 530

(A) 8 N (B) 12 N


leaving the wall
(B) Acceleration of the upper ball
(C) Acceleration of the lower ball

the box ?
(A) The box starts moving at the instant t= 2.0 s
(C) The box stops at the instant t =9.0 s

options.
(A) a1  a2 (B) a1  a2 if k1  k 2  2mg/ x
(C) a1  a2 if k1  k 2  2mg/ x
v  v max v  v max
(A) v 0  min (B) v 0  min
2 2
v min  vmax
(C) v 0  (D) It depends on coefficient of static friction
2

rube ?
(C) It first decreases, acquires a minimum value
then increases
(D) The tube may leave the ground.


 m 
   M  mg then    is __
 

perfectly elastic.
140



is ____ N
PART II: CHEMISTRY

(A) (B)
& &
O O O
OH
O
O O
(C) (D) &
&
O

F H CH 2 CH 3
(A) C C (B) C C
Cl Br H H
H C2H5 D CHO
(C) C C (D) C C
H3C CH(CH 3)2 H COOCH 3

CH 3 CH 3 CH 3 H
(A) C C > C C (melting point)
H H H CH 3
H H H COOH
HOOC COOH HOOC H
H Cl Cl Cl
Cl H H H
H3C H H3C COOH
(D) C C > C C (water solubility)
H COOH H H
28
88
(A) 240.55C (B) –32.45C (C) 3000C (D) –24.055C
(A) 9 & 4 (B) 10 & 3 (C) 9 & 3 (D) 6 & 1

Cl
Br
(C) 3–Bromo–1–chlorocyclohex–1–ene (D) 1–bromo–3–chlorocyclohexene
(A) 1 (B) 3 (C) 8 (D) 6
3Se2  g Se6  g
2SO3  g 2SO2  g  O2  g
3
(A) 0.974 (B) 1.35 (C) 1.52 (D) 1.22


(C) 4–chloro–3–methylcyclohexane carboxylic acid
(D) 3–Bromo–1–methylhexane–1–ol
(A) OH & CH2-OH (B) Me–OH & MeCH2CH2OH

NH(CH3)

the pressure ?
1
(A) 4HCl  g  O2  g  2Cl2  g  2H2O  g (B) Cl2  g  H2O  g  2HCl  g  O2  g
2
(C) CO2  g  4H2  g  CH4  g  2H2O  g (D) N2  g  O2  g  2NO  g

(B) the kinetic energy of the molecules remains the same
(C) the K.E. of the molecules decrease

BrI is is
the value of X ?

(A) 5 (B) 3 (C) 7 (D) 2
x  3 y  2 z 1 x  2 y  3 z 1
1 4 5 1 4 5
28, where
(A) m = –1, n = 3 (B) m = 1, n = –3 (C) m = –1, n = –3 (D) m = 1, n = 3
x 1 y 1 z  3
43. The distance of the point (2, 1, –2) from the line   measured parallel to the plane x
2 1 3
+ 2y + z = 4 is
(A) 10 (B) 20 (C) 5 (D) 30

(A) a + b + c (B) abc (C) 1 (D) none of these
 x  1  y  2  z  3 
  is
cos  sin  0
(A) x tan  + y sec  = 0 (B) x sec  + y tan  = 0
(C) x cos  + y sin  = 0 (D) x sin  – y cos  = 0
x y z
a b c
(A) 3 (B) 2 (C) 1 (D) 5
 9  9   9   9 
(A)   ,9,9  (B)  ,9,9  (C)  9,  ,9  (D)  9, ,9 
 2  2   2   2 
3 3 0  4 1 5 
48. If 2x – y =  and 2y + x =  1 4 4  , then
3 3 2  
3 0 1 2 1 1  1 2 3   1 1 2
(A) x + y =   (B) x =  (C) x – y = 2 1 2 (D) y =
0 3 2 1 2 0   
 1 1 2
 
1 sin  1
49. Let  =  sin  1 sin  ; 0   < 2, then
1  sin  1
(A)  = 0 (B)   (0, ) (C)   [–1, 1] (D)   [2, 4]
t 2  3t t  1 t  3
4 3 2
50.
t  3 t  4 3t
(A) 33 (B) –39 (C) 27 (D) 24

 
51.
2 2 2
If a + b + c = 1, then ba 1  cos    
ca 1  cos   cb 1  cos    
c 2 a2  b2 cos 
(A) a (B) b (C) c (D) 
3 3 4 
52. If A = 2 3 4  , then
0 1 1

x y 2 z3 x  4 y  4 z  11
(A)   (B)  
2 1 4 2 1 4
x 2 y z3 x2 y2 z
(C)   (D)  
2 1 4 2 1 4
x2  x x 1 x  2
54. If 2x  3x  1 3x
2
x 2  2x  3 2x  1 2x  1
2 2
(A) A + B = 12 (B) A – B = 36 (C) A + B = 720 (D) A + 2B = 0
1 a a2
(A) x (B) y (C) z (D) a


2
x2  x x 1 x  2
A
57. If 2x  3x  1 3x
2
6
x  2x  3 2x  1 2x  1
2
1 3cos  1
5
1 sin  1
2 2 2
 1  5
p 15 8   100   Dp
  p 1
66
p3 25 10

IIT – JEE 2019
PHASE – III_PAPER – I_SET-C
ANSWERS
PHYSICS
1. D 2. D 3. B 4. B
5. D 6. C 7. B 8. A
9. B 10. C 11. A,C 12. A,B,C,D
13. B,C 14. C 15. C,D 16. 5
17. 7 18. 5 19. 9 20. 2
CHEMISTRY
21. D 22. D 23. D 24. B
25. A 26. C 27. D 28. C
29. B 30. C 31. A, B, D 32. B, C
33. A, B, C 34. A, C 35. A, B 36. 4
37. 3 38. 1 39. 9 40. 9
MATHEMATICS
41. C 42. BONUS 43. D 44. B
45. C 46. A 47. A 48. B
49. D 50. B 51. BONUS 52. ABC
53. AB 54. ABCD 55. BCD 56. 1
57. 4 58. 2 59. 1 60. BONUS
IIT – JEE 2019
PHASE – III_PAPER – II_SET – A
INSTRUCTIONS:
A. General
2. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and electronic
gadgets in any form are not allowed to be carried inside the examination hall.
7. The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part consists
of three sections.
8. Section I contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
9. Section II contains 6 multiple choice questions relating to three paragraphs with two questions on
each paragraph. Each question has four choices (A), (B), (C) and (D) out of which ONLY one is
correct.
10. Section III contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE may be is correct.
D. Marking Scheme
11. For each question in Section I and Section II, you will be awarded 3 marks if you darken the bubble
corresponding to the correct answer ONLY and zero (0) marks if no bubbles are darkened. In all
other cases, minus one (–1) mark will be awarded in these sections.
12. For each question in Section Ill, you will be awarded 4 marks if you darken ALL the bubble(s)
corresponding to the correct answer(s) ONLY. In all other cases zero (0) marks will be awarded. No
negative marks will be awarded for incorrect answer(s) in this section.
Useful data
–1 –1 –2 –1 –1 –1
–34 –19
h = 6.626  10 Js; 1 eV = 1.602  10 J
–1
c = 3.0  10 ms ; NA = 6.022  10
8 23
(Atomic Masses in amu : H = 1 , He = 4, C = 12, N = 14, O = 16, Na = 23, Mg = 24, P = 31, S = 32,
Cl = 35.5, K = 39, Ca = 40, Fe = 56, Cu = 63.5)

NAME:
ENROLLMENT NO.:
PH-III-2019-P(II)-SET-A-PCM-2
PAPER–II
PART I: PHYSICS
The section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
1. A block A slides over another block B which is placed over a smooth

inclined plane as shown in figure. The coefficient of friction between the
two blocks A and B is  . Mass of block B is two times the mass of block
A. The acceleration of the centre of mass of two–block system is
gsin   gcos  g sin  2gsin   gcos 
(A) gsin  (B) (C) (D)
3 3 3
2. A solid right circular cone of height H has another cone scooped out as
shown in figure such that the hollow is a right circular cone on the same
base. Find what should be the height (h) of the hollow so that the C.M. of
remaining cone with conical hollow (shaded part) is at a height of H/2 from
the base:
(A) h = H/2 (B) h = H/4
(C) h = H/3 (D) Not possible
3. Figure shows a fixed smooth cylinder of radius R with centre at origin

of co–ordinates. An ideal thread is thrown over it, On two ends of the
thread two identical masses are tied which are initially at rest at co–
ordinates (R, 0) and (–R, –R) respectively. If mass at x–axis is given a
slight upward jerk, it leaves contact with the cylinder at (R cos , R sin

). Then find .
sin 
(A) 2 (B) 1/2
(C) 2/3 (D) none
4. A frog of mass m sits at one end of a plank of mass 3m. The length of the plank is L meter and its is
kept on a frictionless surface. The frog wants to jump to the opposite end of the plank. Find the
minimum speed of the frog in the ground frame that would enable the frog to perform the task.
3 3 1
(A) gL (B) gL (C) gL (D) gL
2 4 2
5. The force acting on a body along x-axis varies with the position of the
particle as shown in the figure. The body is in stable equilibrium at:
(A) x = (x1) (B) x = x2
(C) x = x3 (D) none x3
6. When a ceiling fan is switched off, its angular velocity falls to half while it makes 36 rotations. How
many more rotations will it make before coming to rest ?
(A) 24 (B) 36 (C) 18 (D) 12
7. For a particle in uniform circular motion, the acceleration a at a point P  R,  on the circle of radius
R is (Here  is measured from the x-axis)
V ˆ V2 ˆ
2
V2 V2
(A) i j (B)  cos  iˆ  sin  ˆj
R R R R
V2 V2 V2 V2
(C)  sin  iˆ  cos  ˆj (D)  cos  iˆ  sin  ˆj
R R R R
8. Three point masses each of mass ‘m’ are joined together using a string to form an equilateral triangle
of side ‘a’. The system is placed on a smooth horizontal surface and rotated with a constant angular
velocity '  ' about a vertical axis passing through the centroid. Then the tension in each string is
ma 2 ma 2
(A) ma 2 (B) 3ma 2 (C) (D)
3 3
SECTION – II: Paragraph Type

This section contains 6 multiple choice questions relating to three paragraphs with two questions on each
paragraph. Each question has four choices (A), (B), (C) and (D) out of which ONLY one is correct.
Paragraph for questions 9 and 10

Two blocks of equal mass m are connected by an unstretched spring and the system is kept at rest on
a frictionless horizontal surface. A constant force F is applied on the first block pulling it away from the
other as shown in figure.
9. Then the displacement of the centre of mass after time t is

Ft 2 Ft 2 Ft 2 Ft 2
(A) (B) (C) (D)
2m 3m 4m m
10. If the extension of the spring is x0 at time t then the displacement of the first block at this instant is
1  Ft 2
 1  Ft 2  1  Ft 2   Ft 2 
(A)   x0  (B)    x0  (C)   x0  (D)   x0 
2  2m  2  2m  2  2m   2m 

A ring of mass 200 gm and radius 10 m is placed on a smooth Y
horizontal surface with centre at the origin. A small particle, of
5 B
same mass as ring, is given velocity m/s from point ‘A’
5
2 V
2
m/s
(very close to inner surface of the ring) towards point B at
t  0 . Initially particle was not in contact with ring. Assume all X
collisions between the ring and the particle as perfectly elastic. A
11. Particle will collide with point ‘A’ for the first time after a time interval of
(A) 8 s (B) 16 s (C) 12 s (D) 24 s
12. Co–ordinates of centre of mass of ring when particle reaches back to point A for the first time
(A) (10, 10) (B) (0, 0) (C) ( 20, 20 ) (D) ( –20, –20 )

A hemispherical bowl of radius R = 0.1m is rotating about its own axis (which is
 . A particle of mass 102 kg on the frictionless
vertical) with an angular velocity
inner surface of the bowl id also rotating with same '  ' . The particle is about a
height ‘h’ from the bottom of the bowl
13. The value of ' ' in terms of ‘R’ and ‘h’ is

 Rh  Rh  Rh  Rh
(A) sin 1   (B) cos 1   (C) tan 1   (D) sec1  
 R   R   R   R 
14. The relation between h and w is

 g   g 
(A) h  R  2  (B) h  R  gw2 (C) R  h 2  (D) R  h  gw2
w  w 
SECTION – III: Multi Correct Answer(s) Type

15. A block of mass m rests on a smooth stationary wedge of mass M. The

wedge can slide freely on a smooth horizontal surface as shown in figure. If
the blocks are released from the initial position of rest:
(A) the position of the center of mass of the system will change
(B) the position of the centre of mass of the system will change along the
vertical but not along the horizontal
© the total mechanical energy of the system will remain constant.
(D) the change in position of center of mass will be equal in horizontal and
vertical directions
16. A cart moves with a constant speed along a horizontal circular path. From the cart, a particle is thrown
up vertically with respect to the cart
(A) the particle will land somewhere on the circular path
(B) the particle will land outside the circular path
(C) the particle will follow an elliptical path
(D) the particle will follow a parabolic path
17. A ball A collides elastically with an another stationary identical ball B with
velocity 10 m/s at an angle of 30 from the line joining their centres C1 and
C2 select the correct alternative(s):
(A) Velocity of ball A after collision is 5 m/s
(B) Velocity of ball B after collision is 5 3 m/s
(C) Both the balls move at right angle after collision
(D) Kinetic energy will not be conserved here, because collision is not head
on.
18. A small spherical ball is suspended through a string of length . The whole arrangement is placed In a
vehicle which is moving with velocity v. Now suddenly the vehicle stops and ball starts moving along a
circular path. If tension in the string at the highest point is twice the weight of the ball then :
(A) v = 5gl
(B) v = 7gl
(C) velocity of the ball at highest point is gl
(D) velocity of the ball at the highest point is 3gl
19. The spring is compressed by a distance 'a' and released. The block b
again comes to rest when the spring is elongated by a distance 'b'.
During this process :
k(a2  b2 )
(A) work done by the spring on the block =
2
k(a  b2 )
2
(B) work done by the spring on the block =
2
k(a  b)
(C) co-efficient of friction = .
2mg
(D) The magnitude of ‘b’ must be less than the magnitude of ‘a’
20. A simple pendulum of length L and mass M is oscillating in a plane about a vertical line between
angular limits -  and +. For an angular displacement  (|| < ) , the tension in the string and the
velocity of the bob are T and V respectively. The following relations hold good under the above
conditions
(A) Tcos = Mg
2
(B) T – Mgcos = MV /L
(C) The magnitude of the tangential acceleration of the bob |aT| = g sin
(D) T = Mg cos
PART II: CHEMISTRY
21. For which of the following compounds the IUPAC name is incorrect?
(A) CH3-CH2-CH2-COO-CH2-CH3  ethyl butanoate
(B) CH3-CH(CH3)-CH2-CHO  3-methyl butanal
(C) CH3-CH(OH)-CH(CH3)-CH3  2-methyl-3-butanol
(D) (CH3)2C-CO-CH2-CH3  2-methyl-3-pentanone
22. Equal masses of SO2 , CH4 and O2 are mixed in empty container at 298K, when total pressure is
2.1 atm. The partial pressure of CH4 in the mixture is
(A) 0.5 atm (B) 0.75 atm (C) 1.2 atm (D) 0.6 atm
23. Which of the following statement is true about a real gases

(I) A real gas follows ideal gas behavior at low temperature and high pressure
(II) The excluded volume corresponding to a gas molecule is four times the volume of one molecule
(III) A real gas molecule moves at a lower speed as compared to a ideal gas molecule at the same
temperature
(IV) An estimation of critical temperature corresponding to a real gas can be done using Andrews
Isotherm
(A) I, II, III (B) II, III, IV (C) II & IV (D) I & III
24. In the E & Z system of nomenclature of geometrical isomers the relative preference of the groups is
decided according to CIP rules. Which of the following arrangement represents groups increasing
order of their preference?
(A) -D < -H < -CN < -CHO (B) -CH3 < -CH2CH3 < -CHO < -CD2OH
(C) -CH=CH2 < -CH2OH < -CHO < -OCH3 (D) -H < -T < -CH2OH < -CN
25. Which of the following statements is true about conformational isomerism?

(A) The isomers cannot be separated by any physical method
(B) The isomers cannot be obtained by simple rotation of C-C bond
(C) All isomers have same energy
(D) Finite number of isomers are possible
26. An iron cylinder contains helium at a pressure of 200 kPa at 300 K. The cylinder can withstand a
pressure of 1000 kPa. If the room in which the cylinder is kept catches fire. Whether the cylinder will
blow up before it melts or not, if the melting point of the cylinder is 1800 K at :
(A) after the cylinder melts (B) before the cylinder melts
(C) at its melting point (D) none of these.
27. For which of the following reaction is product formation favoured by low pressure & high temperature
(A) H2  g  I2  g 2HI  g H0  9.4kJ
(B) CO2  g  C  s  2CO  g H0  172.5kJ
(C) CO  g  2H2  g CH3OH  g H0  21.7kJ
(D) 3O2  g 2O3  g H0  285kJ
28. Among the following the Newman projection of meso-2,3-butanediol are

Me Me Me Me
H OH H OH HO CH 3 H3C H
HO H H OH HO H H OH
Me Me H OH
P Q R S
(A) P, Q (B) P, R (C) R, S (D) Q, S


Le-Chatelier’s Principle: According to this principle, when external factors or conditions (like P, T,
Concentration, inert gas) is applied to the chemical equilibrium, it moves in such a direction so that the effect
of external factors get annulled or minimized. On increasing pressure, the reaction moves on that direction
where volume is reduced and vice-versa. On increasing temperature or, heat, the equilibrium moves on that
direction, in which direction, heat is consumed and vice-versa. The effect of temperature has great
significance on equilibrium constants which are related as under with the equilibrium constants.
Answer the following questions on the basis of the above write up:
29. For a reaction H2(g) + Cl2(g) 2HCl(g) which is at equilibrium, following change in concentration vs
time graph is plotted. Which of the following changes at equilibrium would result in such a graph?
(A) Pressure of the system is increased (B) Catalyst is added to the system
(C) Volume of the system is increased (D) Product is added to the system
30. For an H2O(s) H2O(l) established in a container at a certain temperature, the Pressure is
suddenly increased. Which of the following changes would take place?
(A) Equilibrium shifts in the backward direction and more ice is formed
(B) Equilibrium shifts in the forward direction and ice melts to form water
(C) Equilibrium isn’t affected since  n for the reaction is zero
(D) Equilibrium isn’t affected since substances in solid and liquid phase aren’t affected by change in
pressure
Read the paragraph carefully and answer the following questions:

Conformational isomers are generated due to the free rotation about single bond. Due to torsional strain
eclipsed form in less thermodynamically stable than staggered form. The gauche is specific conformer of
staggered in which bulky groups are oriented closer to one another. Hence, generally gauche form is less
stable than staggered form. But sometimes it is not true when hydrogen bonding is present
31. For which of the following compounds, the conformational energy diagram plotted for relative energy
of conformers vs the dihedral angle, gives an alike plot
I. Ethane – along C1 & C2
II. Propane – along C1 & C2
III. Propane – along C2 & C3
IV. Butane – along C1 & C2
V. Butane – along C2 & C3
VI. Butane – along C3 & C4
VII. Pentane – along C1 & C2
(A) II, III, IV, V, VII (B) I, II, IV, V
(C) I, II, III, IV, VI, VII (D) all of the above
32. The most stable conformer of 2-fluoro ethanol is

F F
H H H OH
(A) (B)
H H H H
OH H
H F H H
H H OH H OH F
H
(C) (D)
HH HH
HH HH
The compressibility factor (Z), also known as the compression factor or the gas deviation factor, is a
correction factor which describes the deviation of a real gas from ideal gas behavior. It is simply defined as
the ratio of the molar volume of a gas to the molar volume of an ideal gas at the same temperature and
pressure. Plots of Z Vs P for 1 mole of four different gases A, B, C & D at a fixed temperature is given below.
D
C
1.5 B
Z
1 A
200 400 600 800 1000

P (atm)
Answer the following questions based on the above plot.
33. At a pressure of 750 atm, the increasing order of ease of liquefaction of the four gases would be:
(A) A < B < C < D (B) D < B < C < A (C) B < D < C < A (D) D < C < B < A
34. Which set of statements among the following are incorrect?

(I) For the gas B, a = 0 & it’s dependence on pressure is linear at all pressures
(II) For the gas A, a = 0 as well as b = 0 & it behaves as an ideal gas at all pressures
(III) For the gas C & D, nether a nor b = 0 & they behave as real gases
(IV) The slope is positive for all the real gases at high pressures
(A) I, II & IV (B) I & III (C) II & III (D) none of the above

35. Which of the following statements regarding the plots concerning a reaction at equilibrium is/are
correct?
(A) If a reaction which is represented as R  P [R: Reactant & P: Product], for which Keq >1,
hypothetically reaches completion, after achieving the stage of equilibrium, then the Concentration vs
Time plot for such a reaction would be represented as
(B) If a reaction which is represented as R  2P + Q [R: Reactant, P & Q: Product] for which Keq < 1,
then the Concentration vs Time plot for such a reaction would be represented as
(C) If a reaction which is represented as R  2P + Q [R: Reactant, P & Q: Product] for which Keq < 1,
then the Rate vs Time plot for such a reaction would be represented as
(D) If a reaction which is represented as R  2P [R: Reactant, P & Q: Product] for which Keq > 1, is
subjected to an increase in amount of reactant, then the Concentration vs Time plot for such a
reaction would be represented as
36. Select the correct statement for an ideal gas

(A) If all gas molecules are assumed to be rigid sphere of negligible volume, the only possible molecular
motion is translational.
(B) When temperature increases at constant pressure, rate of effusion decreases
1
(C) When temperature increases the volume of the gas increases by times the volume of the gas
273
o
at 0 C, for every degree rise in temperature
(D) Kinetic energy decreases by increasing pressure at constant temperature
37. How many of the following molecules can show geometrical isomerism?
H CH3
(A) (B)
H
H3C CH3
CH3
CH3 H
(C) N (D) CH3
H3C OH
CH3
38. Which of the following molecules cannot show tautomerism

O O
D
NH2 CH3 D
NH C
(A) (B)
N O N O
H
NH2
O
CH3
N
(C) (D) O
O
NH
39. How many “cyclic”-structural & geometrical isomers of C5H10 are possible?
(A) 4 (B) 5 (C) 6 (D) 7
40. In the Newman Projection for 2,2-dimethylbutane, X & Y can be

X
H3C CH 3
H H
Y
(A) H & H (B) H & C2H5 (C) C2H5 & H (D) CH3 & CH3

–1
If A = O, such that A  I for 1  n  4, then (I – A) is equal to
5 n
41.
4 3
(A) A (B) A (C) I + A (D) none of these
n
42. If A = diag (d1, d2, d3, ....., dn), then A is equal to
n–1 n–2 n–1 n–1 n n n n
(A) diag (d1 , d2 , d3 , ...... dn ) (B) diag (d1 , d2 , d3 , ...... dn )
2 3 n
(C) diag (d1, d2, d3, ...... dn) (D) diag (d1, d2 , d3 , ...... dn )
If A is a square matrix of order 2  2 such that A = O, then

2
43.
  
 , where , ,  are numbers such that  +  = 0
2
(A) A = 
   
  
(B) A =   with  = 
   
   
 with  +  = 1
2 2
(C) A = 
   
(D) none of these
x 1 y 1
44. The coordinates of a point on the line  = z at a distance 4 14 from the point (1, –1, 0)
2 3
nearer the origin are
(A) (9, –13, 4) 
(B) 8 14, 12, 1  
(C) 8 14,12,1  (D) (–7, 11, –4)
45. The locus of the point, the sum of square of whose distances, from the planes x – z = 0, x – 2y + z = 0
and x + y + z = 0 is 36 is
2 2 2 2 2 2 2 2 2 –2 –2 –2 1
(A) x + y + z = 6 (B) x + y + z = 36 (C) x + y + z = 216 (D) x + y + z =
36
 1 2 2
46. If A =  2 1 2 , then adj A is equal to
 2 2 1 
T T
(A) A (B) A (C) 3A (D) 3A
47. If A is a skew-symmetric matrix, then trace of A is

(A) –5 (B) 0 (C) 24 (D) 9
48. The equations x – y = 2, 2x – 3y = –, 3x – 2y = –1 are consistent for

(A)  = –4 (B)  = –1, 4 (C)  = 1 (D)  = 1, –4

Let two planes P1: 2x – y + z = 2 and P2: x + 2y – z = 3 are given.

49. The equation of the plane through the intersection of P 1 and P2 and the point (3, 2, 1) is
(A) 3x – y + 2z – 9 = 0 (B) x – 3y + 2z + 1 = 0 (C) 2x – 3y + z – 1 = 0 (D) none of these
50. Equation of the plane which passes through the point (–1, 3, 2) and is perpendicular to each of the
plane P1 and P2 is
(A) x + 3y – 5z + 2 = 0 (B) x + 3y + 5z – 18 = 0 (C) x – 3y – 5z + 20 = 0 (D) none of these

 1 3   2 3 2 4
   
Let A and B are two matrices of same order 3  3, where A =  2 4 8 , B = 3 2 5
 3 5 10  2 1 4
   
51. If A is singular matrix, then tr (A + B) is equal to
(A) 6 (B) 12 (C) 24 (D) 17
52. If matrix 2A + 3B is singular, then the value of 2 is

(A) 11 (B) 13 (C) 15 (D) 17
 1 9 7
a b c  8 2 7  0 0 0
7 3 7 
53. If point (a, b, c) is in the plane 2x + y + z = 1, find 7a + b + c
(A) 3 (B) 6 (C) 9 (D) none of these
n

 1 1
54. If b = 6 and ,  are roots of ax + bx + c = 0, then find
2
    .
n0   

55. The system of equations

x – y cos  + z cos 2 = 0,
–x cos  + y – z cos  = 0
x cos 2 – y cos  + z = 0
has non trivial solution for  equals
  2 
(A) (B) (C) (D)
3 6 3 12
a1  b1x a1x  b1 c1
56. If ai, bi, ci  R (i = 1, 2, 3) and x  R and a2  b2 x a2 x  b2 c 2 = 0, then
a3  b3 x a 3 x  b 3 c3
a1 b1 c1
(A) x = 1 (B) x = –1 (C) a2 b2 c2  0 (D) none of these
a3 b3 c3
57. The plane x – 2y + 7z + 21 = 0

x 1 y  3 z  2
(A) contains the line   (B) contains the point (0, 7, –1)
3 2 1
x y z
(C) is perpendicular to the line   (D) is parallel to the plane x – 2y + 7z = 0
1 2 1
x 1 y 1 z 1 x  4 y  0 z 1
58. The lines   and  
3 1 0 2 0 3
(A) do not intersect (B) intersect
(C) intersect at (4, 0, –1) (D) intersect at (1, 1, –1)
If a square matrix of order 3  3, A = [aij], aij = i – j is of even order, then

2 2
59.
(A) A is a skew matrix (B) |A| is a perfect square
(C) A is a symmetric and |A| = 0 (D) A is neither symmetric nor skew-symmetric
60. Let A, B and C be 2  2 matrices with entries from the set of real numbers. Define o as follows
1
AoB = (AB + BA), then
2
(A) AoB = BoA (B) AoI = A, I is an identity matrix of order 2
2
(C) AoA = A (D) Ao(B + C) = AoB + AoC

IIT – JEE 2019
PHASE – III_PAPER – II_SET - A
ANSWERS
PHYSICS
1. A 2. D 3. A 4. B
5. B 6. D 7. D 8. C
9. C 10. A 11. B 12. C
13. B 14. A 15. A,B,C 16. B,D
17. A,B,C 18. B,D 19. B,C,D 20. B,C
CHEMISTRY
21. C 22. C 23. C 24. C
25. A 26. B 27. B 28. B
29. C 30. B 31. C 32. B
33. BONUS 34. D 35. A, B, C, D 36. A, B, C
37. A, B, C 38. C, D 39. C 40. B, D
MATHEMATICS
41. D 42. B 43. A 44. D
45. B 46. D 47. B 48. B
49. B 50. C 51. C 52. D
53. B 54. B 55. ABCD 56. ABC
57. ABD 58. BC 59. AB 60. ABCD

IIT – JEE 2019
PHASE – III_PAPER – II_SET – B
INSTRUCTIONS:
A. General
of three sections.
correct.
D. Marking Scheme
Useful data
–1 –1 –2 –1 –1 –1
–34 –19
h = 6.626  10 Js; 1 eV = 1.602  10 J
–1
c = 3.0  10 ms ; NA = 6.022  10
8 23
Cl = 35.5, K = 39, Ca = 40, Fe = 56, Cu = 63.5)

NAME:
ENROLLMENT NO.:
PAPER–II
PART I: PHYSICS
(A) x = (x1) (B) x = x3

2gsin   gcos  gsin   gcos  g sin 
(A) (B) (C) (D) gsin 
3 3 3
the base:
(A) h = H/2 (B) h = H/4


). Then find .
sin 
(A) 1/2 (B) 2
(C) 2/3 (D) none
(A) 12 (B) 36 (C) 18 (D) 24
2 2
V ˆ V ˆ V2 ˆ V2
(A) i j (B)  cos  i  sin  ˆj
R R R R
V2 V2 V2 V2
(C)  sin  iˆ  cos  ˆj (D)  cos  iˆ  sin  ˆj
R R R R
ma 2 ma 2
(A) ma (B) 3ma
2 2
(C) (D)
3 3
3 1 3
2 2 4


5 B
5
2 V
2
m/s
(A) 8 s (B) 12 s (C) 16 s (D) 24 s
(A) (10, 10) (B) (0, 0) (C) (–20, –20) (D) (20, 20 )

 Rh  Rh  Rh  Rh
(A) sin 1   (B) sec1   (C) tan 1   (D) cos 1  
 R   R   R   R 

 g   g 
(A) R  h 2  (B) h  R  gw2 (C) h  R  2  (D) R  h  gw2
w  w 

Ft 2 Ft 2 Ft 2 Ft 2
(A) (B) (C) (D)
2m 3m m 4m
 Ft 2  1  Ft 2  1  Ft 2  1  Ft 2 
(A)   x0  (B)    x0  (C)   x0  (D)   x0 
 2m  2  2m  2  2m  2  2m 

(C) the particle will follow a parabolic path
(D) the particle will follow an elliptical path
velocity 10 m/s at an angle of 30 from the line joining their centres C1 and C2
select the correct alternative(s):
(D) Kinetic energy will not be conserved here, because collision is not head on.
(A) v = 5gl
(B) v = 7gl
(C) velocity of the ball at the highest point is 3gl
(D) velocity of the ball at highest point is gl
k(a2  b2 )
2
k(a  b2 )
2
2
k(a  b)
2mg
conditions
2
(A) T – Mgcos = MV /L
(B) Tcos = Mg
(D) T = Mg cos

(C) the total mechanical energy of the system will remain constant.
vertical directions
PART II: CHEMISTRY


(A) The isomers cannot be obtained by simple rotation of C-C bond
(B) The isomers cannot be separated by any physical method
(C) (CH3)2C-CO-CH2-CH3  2-methyl-3-pentanone
(D) CH3-CH(OH)-CH(CH3)-CH3  2-methyl-3-butanol

temperature
Isotherm
(A) I, II, III (B) II, III, IV (C) I & III (D) II & IV
(A) before the cylinder melts (B) after the cylinder melts
(A) H2  g  I2  g 2HI  g H0  9.4kJ
(B) CO  g  2H2  g CH3OH  g H0  21.7kJ
(C) CO2  g  C  s  2CO  g H0  172.5kJ
(D) 3O2  g 2O3  g H0  285kJ

Me Me Me Me
HO H H OH HO H H OH
Me Me H OH
P Q R S
(A) P, Q (B) Q, S (C) R, S (D) P, R



F F
H OH H H
(A) (B)
H H H H
H OH
H F H H
H H OH H OH F
H
(C) (D)
HH HH
HH HH
D
C
1.5 B
Z
1 A
200 400 600 800 1000

P (atm)

(A) Volume of the system is increased (B) Catalyst is added to the system
(C) Pressure of the system is increased (D) Product is added to the system
(A) Equilibrium shifts in the forward direction and ice melts to form water
(B) Equilibrium shifts in the backward direction and more ice is formed
pressure


1
273
o
H CH3
(A) (B)
H H3C CH3
CH3
H CH3
(C) CH3 (D) N
H3C OH
CH3

O O
NH2
NH
(A) (B) O
N O
H
NH2
O
CH3 D
CH3 D
N
C
(C) (D)
O N O
NH
(A) 4 (B) 5 (C) 6 (D) 7

X
H3C CH 3
H H
Y
(A) H & H (B) H & C2H5 (C) CH3 & CH3 (D) C2H5 & H
correct?
(A) If a reaction which is represented as R  P [R: Reactant & P: Product], for which K eq >1,
(B) If a reaction which is represented as R  2P + Q [R: Reactant, P & Q: Product] for which K eq < 1,

and x + y + z = 0 is 36 is
2 2 2 2 2 2 2 2 2 –2 –2 –2 1
36
–1
5 n
42.
4 3
n
n–1 n–2 n–1 n–1 n n n n
2 3 n

2
44.
  
(A) A =   with  = 
   
  
2
(B) A = 
   
   
 with  +  = 1
2 2
(C) A = 
   
(D) none of these
 1 2 2
45. If A =  2 1 2 , then adj A is equal to
 2 2 1 
T T
(A) A (B) A (C) 3A (D) 3A

(A) –5 (B) 0 (C) 24 (D) 9

(A)  = –4 (B)  = 1, –4 (C)  = 1 (D)  = –1, 4
x 1 y 1
2 3
(A) (9, –13, 4) 
(B) 8 14, 12, 1  (C) (–7, 11, –4) 
(D) 8 14,12,1 
 1 3   2 3 2 4
   
 3 5 10  2 1 4
   
(A) 6 (B) 12 (C) 24 (D) 17

(A) 11 (B) 13 (C) 17 (D) 15
 1 9 7
a b c  8 2 7  0 0 0
7 3 7 
n
 1 1 
If b = 6 and ,  are roots of ax + bx + c = 0, then find     .
2
52.
n0   

53. The equation of the plane through the intersection of P 1 and P2 and the point (3, 2, 1) is
(A) 3x – y + 2z – 9 = 0 (B) 2x – 3y + z – 1 = 0 (C) x – 3y + 2z + 1 = 0 (D) none of these
plane P1 and P2 is
(A) x + 3y – 5z + 2 = 0 (B) x – 3y – 5z + 20 = 0 (C) x + 3y + 5z – 18 = 0 (D) none of these

a1  b1x a1x  b1 c1
a3  b3 x a 3 x  b 3 c3
a1 b1 c1
a3 b3 c3
56. The plane x – 2y + 7z + 21 = 0

x 1 y  3 z  2
(A) contains the line   (B) is parallel to the plane x – 2y + 7z = 0
3 2 1
x y z
(C) is perpendicular to the line   (D) contains the point (0, 7, –1)
1 2 1
x 1 y 1 z 1 x  4 y  0 z 1
3 1 0 2 0 3

2 2
58.
(A) A is a skew matrix (B) A is neither symmetric nor skew-symmetric
(C) A is a symmetric and |A| = 0 (D) |A| is a perfect square
1
2
2
(A) AoA = A (B) AoI = A, I is an identity matrix of order 2
(C) AoB = BoA (D) Ao(B + C) = AoB + AoC

x – y cos  + z cos 2 = 0,
–x cos  + y – z cos  = 0
x cos 2 – y cos  + z = 0
  2 
(A) (B) (C) (D)
3 6 3 12

IIT – JEE 2019
PHASE – III_PAPER – II_SET - B
ANSWERS
PHYSICS
1. C 2. D 3. D 4. B
5. A 6. B 7. D 8. D
9. C 10. D 11. D 12. C
13. D 14. D 15. B, C 16. A,B,C
17. B, C 18. B,C,D 19. A,C 20. A,B,C
CHEMISTRY
21. B 22. C 23. C 24. D
25. A 26. C 27. D 28. C
29. C 30. B 31. BONUS 32. D
33. A 34. A 35. A, B, C 36. A, B, C
37. C, D 38. C 39. B, C 40. A, B, C, D
MATHEMATICS
41. A 42. D 43. B 44. B
45. D 46. B 47. D 48. C
49. C 50. C 51. C 52. C
53. C 54. B 55. ABC 56. ABD
57. BD 58. AD 59. ABCD 60. ABCD

IIT – JEE 2019
PHASE – III_PAPER – II_SET – C
INSTRUCTIONS:
A. General
of three sections.
correct.
D. Marking Scheme
Useful data
–1 –1 –2 –1 –1 –1
–34 –19
h = 6.626  10 Js; 1 eV = 1.602  10 J
–1
c = 3.0  10 ms ; NA = 6.022  10
8 23
Cl = 35.5, K = 39, Ca = 40, Fe = 56, Cu = 63.5)

NAME:
ENROLLMENT NO.:
PAPER–II
PART I: PHYSICS
(A) 24 (B) 36 (C) 18 (D) 12
2 2
V ˆ V ˆ V2 V2
(A) i j (B)  cos  iˆ  sin  ˆj
R R R R
V2 V2 V2 V2
(C)  sin  iˆ  cos  ˆj (D)  cos  iˆ  sin  ˆj
R R R R
ma 2 ma 2
(A) ma (B) 3ma
2 2
(C) (D)
3 3
3 3 1
2 4 2
(A) x = (x1) (B) x = x2

gsin   gcos  g sin  2gsin   gcos 
(A) gsin  (B) (C) (D)
3 3 3
the base:
(A) h = H/2 (B) h = H/4


). Then find .
sin 
(A) 2 (B) 1/2
(C) 2/3 (D) none



 Rh  Rh  Rh  Rh
(A) sin 1   (B) cos 1   (C) tan 1   (D) sec1  
 R   R   R   R 

 g   g 
(A) h  R  2  (B) h  R  gw2 (C) R  h 2  (D) R  h  gw2
w  w 

Ft 2 Ft 2 Ft 2 Ft 2
(A) (B) (C) (D)
2m 3m 4m m
1  Ft 2  1  Ft 2  1  Ft 2   Ft 2 
(A)   x0  (B)    x0  (C)   x0  (D)   x0 
2  2m  2  2m  2  2m   2m 

5 B
5
2 V
2
m/s
(A) 8 s (B) 16 s (C) 12 s (D) 24 s
(A) (10, 10) (B) (0, 0) (C) ( 20, 20 ) (D) ( –20, –20 )

(A) v = 5gl
(B) v = 7gl
(C) velocity of the ball at highest point is gl
(D) velocity of the ball at the highest point is 3gl
k(a2  b2 )
2
k(a  b2 )
2
2
k(a  b)
2mg
conditions
(A) Tcos = Mg
2
(B) T – Mgcos = MV /L
(D) T = Mg cos

(C) the total mechanical energy of the system will remain constant.
vertical directions
(C) the particle will follow an elliptical path
(D) the particle will follow a parabolic path
velocity 10 m/s at an angle of 30 from the line joining their centres C1 and
C2 select the correct alternative(s):
(D) Kinetic energy will not be conserved here, because collision is not head
on.
PART II: CHEMISTRY

(A) after the cylinder melts (B) before the cylinder melts
(A) H2  g  I2  g 2HI  g H0  9.4kJ
(B) CO2  g  C  s  2CO  g H0  172.5kJ
(C) CO  g  2H2  g CH3OH  g H0  21.7kJ
(D) 3O2  g 2O3  g H0  285kJ

Me Me Me Me
HO H H OH HO H H OH
Me Me H OH
P Q R S
(A) P, Q (B) P, R (C) R, S (D) Q, S

(A) The isomers cannot be separated by any physical method
(B) The isomers cannot be obtained by simple rotation of C-C bond
(C) CH3-CH(OH)-CH(CH3)-CH3  2-methyl-3-butanol
(D) (CH3)2C-CO-CH2-CH3  2-methyl-3-pentanone

temperature
Isotherm
(A) I, II, III (B) II, III, IV (C) II & IV (D) I & III


D
C
1.5 B
Z
1 A
200 400 600 800 1000

P (atm)

(A) Pressure of the system is increased (B) Catalyst is added to the system
(C) Volume of the system is increased (D) Product is added to the system
(A) Equilibrium shifts in the backward direction and more ice is formed
(B) Equilibrium shifts in the forward direction and ice melts to form water
pressure


F F
H H H OH
(A) (B)
H H H H
OH H
H F H H
H H OH H OH F
H
(C) (D)
HH HH
HH HH


O O
D
NH2 CH3 D
NH C
(A) (B)
N O N O
H
NH2
O
CH3
N
(C) (D) O
O
NH
(A) 4 (B) 5 (C) 6 (D) 7

X
H3C CH 3
H H
Y
(A) H & H (B) H & C2H5 (C) C2H5 & H (D) CH3 & CH3
correct?
(A) If a reaction which is represented as R  P [R: Reactant & P: Product], for which K eq >1,
(B) If a reaction which is represented as R  2P + Q [R: Reactant, P & Q: Product] for which K eq < 1,

1
273
o
H CH3
(A) (B)
H
H3C CH3
CH3
CH3 H
(C) N (D) CH3
H3C OH
CH3

 1 2 2
 
41. If A =  2 1 2 , then adj A is equal to
 2 2 1 
T T
(A) A (B) A (C) 3A (D) 3A

(A) –5 (B) 0 (C) 24 (D) 9

(A)  = –4 (B)  = –1, 4 (C)  = 1 (D)  = 1, –4
x 1 y 1
2 3
(A) (9, –13, 4) 
(B) 8 14, 12, 1  
(C) 8 14,12,1  (D) (–7, 11, –4)
and x + y + z = 0 is 36 is
2 2 2 2 2 2 2 2 2 –2 –2 –2 1
36
–1
5 n
46.
4 3
n
n–1 n–2 n–1 n–1 n n n n
2 3 n

2
48.
  
2
(A) A = 
   
  
(B) A =   with  = 
   
   
 with  +  = 1
2 2
(C) A = 
   
(D) none of these

 1 9 7
 a b c  8 2 7  0 0 0
7 3 7 
n

 1 1
50. If b = 6 and ,  are roots of ax + bx + c = 0, then find
2
    .
n0   

51. The equation of the plane through the intersection of P1 and P2 and the point (3, 2, 1) is
(A) 3x – y + 2z – 9 = 0 (B) x – 3y + 2z + 1 = 0 (C) 2x – 3y + z – 1 = 0 (D) none of these
plane P1 and P2 is
(A) x + 3y – 5z + 2 = 0 (B) x + 3y + 5z – 18 = 0 (C) x – 3y – 5z + 20 = 0 (D) none of these

 1 3   2 3 2 4
   
 3 5 10  2 1 4
   
(A) 6 (B) 12 (C) 24 (D) 17

(A) 11 (B) 13 (C) 15 (D) 17

x 1 y 1 z 1 x  4 y  0 z 1
3 1 0 2 0 3

2 2
56.
(A) A is a skew matrix (B) |A| is a perfect square
(C) A is a symmetric and |A| = 0 (D) A is neither symmetric nor skew-symmetric
1
2
(A) AoB = BoA (B) AoI = A, I is an identity matrix of order 2
2
(C) AoA = A (D) Ao(B + C) = AoB + AoC

x – y cos  + z cos 2 = 0,
–x cos  + y – z cos  = 0
x cos 2 – y cos  + z = 0
  2 
(A) (B) (C) (D)
3 6 3 12
a1  b1x a1x  b1 c1
a3  b3 x a 3 x  b 3 c3
a1 b1 c1
a3 b3 c3
60. The plane x – 2y + 7z + 21 = 0

x 1 y  3 z  2
(A) contains the line   (B) contains the point (0, 7, –1)
3 2 1
x y z
(C) is perpendicular to the line   (D) is parallel to the plane x – 2y + 7z = 0
1 2 1

IIT – JEE 2019
PHASE – III_PAPER – II_SET - C
ANSWERS
PHYSICS
1. D 2. D 3. C 4. B
5. B 6. A 7. D 8. A
9. B 10. A 11. C 12. A
13. B 14. C 15. B,D 16. B,C,D
17. B,C 18. A,B,C 19. B,D 20. A,B,C
CHEMISTRY
21. B 22. B 23. B 24. C
25. A 26. C 27. C 28. C
29. BONUS 30. D 31. C 32. B
33. C 34. B 35. C, D 36. C
37. B, D 38. A, B, C, D 39. A, B, C 40. A, B, C
MATHEMATICS
41. D 42. B 43. B 44. D
45. B 46. D 47. B 48. A
49. B 50. B 51. B 52. C
53. C 54. D 55. BC 56. AB
58. ABCD 58. ABCD 59. ABC 60. ABD

Phase Test-3 JR Q.P-1, 2 & Solutions PDF

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FIITJEE INTERNAL TEST

IIT – JEE 2019

Don’t write / mark your answers in this question booklet.

1. In the figure, three identical massless springs are kept

2. A uniform rope of length 13 m tied to a peg A on a wall and

3. If a block is pulled up an inclined plane with a force of 20 N

Space for rough work

4. Someone is using a scissors to cut a vertical wire of circular

7. Two streams of water flow through the tube assembly

Space for rough work

8. A small block of mass m rests on a plank of mass M,

9. Top surface of a large block A of mass M = 4

Space for rough work

10. A spherical object of mass 60kg is

SECTION – II: Multi Correct Answer(s) Type

11. In the figure, two blocks of equal mass m are connected by an

Space for rough work

13. A semicircular cylindrical tube is place on the horizontal

14. A dumbbell is constructed by fixing small identical balls at the ends of

Space for rough work

15. A box of mass m = 4 kg rests on a rough horizontal surface where

SECTION – III: Integer Answer Type

16. Between two frictionless platforms A and B is a

17. A small disk of mass M= 2.0 kg is connected with two identical

Space for rough work

18. A block of mass M can slide without friction along a

19. A small block A of mass m = 2.0 kg sliding

Space for rough work

PART II: CHEMISTRY

(A) 9 & 4 (B) 10 & 3 (C) 9 & 3 (D) 6 & 1

Space for rough work

26. The IUPAC name of the compound shown below is

28. Which of the following pairs of structures do not represent isomers ?

29. The ‘E’– Isomer i/sare

Space for rough work

30. The correct order/s for the given pair of isomers is

SECTION – II: Multi Correct Answer(s) Type

32. If a gas expands at constant temperature :

33. Which of the following IUPAC name(s) is/are incorrect :

Space for rough work

34. Which of the following represent correct pair of homologous ?

(A) OH & CH2-OH (B) Me–OH & MeCH2CH2OH

CH3–CH2–NH2 & CH3–CH2–

35. Which of the following show geometrical isomerism

SECTION – III: Integer Answer Type

Space for rough work

PART III: MATHEMATICS

44. If a, b, c are non-zero numbers and if the equations (a – 1)x = y + z, (b – 1)y = z + x,

Space for rough work

Space for rough work

SECTION – II: Multi Correct Answer(s) Type

55. The equation of a line 4x – 4y – z + 11 = 0 = x + 2y – z – 1 can be put as

Space for rough work

SECTION – III: Integer Answer Type

58. If the system of equations 3x – 2y + z = 0, x – 14y + 15z = 0, x + 2y + 3z = 0 have a non trivial

Space for rough work

FIITJEE INTERNAL TEST

FIITJEE INTERNAL TEST

Don’t write / mark your answers in this question booklet.

3. Two streams of water flow through the tube assembly

Space for rough work

4. In the figure, three identical massless springs are kept

5. A uniform rope of length 13 m tied to a peg A on a wall and