Beruflich Dokumente
Kultur Dokumente
Fleur Sofia Josef Dela Cruz, Fatima Beatrice Diaz, Nicole Gea Divinasflores, Ruby Lynne
Duran, Nica Michaela Dy, Elishea Jhaira Ebuen, Margaret Claire Epistola
n-butyl chloride
sec-butyl chloride
Beilstein test
Reaction with 2%
ethanolic AgNO3 Sec-butyl chloride White ppt
(1.5 seconds)
n-butyl chloride White precipitate
Slowest – 3 mins
20 seconds Tert-butyl chloride Black solution
White ppt
Sec-butyl chloride Cloudy solution (1 minute)
White precipitate
2 mins
Chlorobenzene No precipitate
Tert-butyl chloride White precipitate
Fastest - 18 secs
Chlorobenzene No precipitate
SN2
n-butyl chloride was the most
SN2 reactive for it was the first to Alkyl halide and nucleophile was the basis
produce white precipitate of kinetics for SN2 reaction, which requires
because of its nucleophilic strong nucleophile, with polar, aprotic
strength and steric effect. This is solvent, giving inversion of stereochemistry.
then followed by sec-butyl SN2 reaction usually happens faster with
chloride and tert-butyl chloride, primary alkyl halides followed by secondary
consequently. alkyl halides, which is inversely related to
SN1 reaction.
d. Unreactive towards SN1 and
SN2? In the case of chlorobenzene, aromatic ring
blocks nucleophile attack from behind
Chlorobenzene is both unreactive making inversion not possible.
towards SN1 and SN2.
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