CHEMISTRY

JEE ADVANCED SAMPLE PAPER

Chapter 07. Chemical and Ionic Equilibrium

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1. Acetic acid undergoes dimerisation, when dissolved in benzene

O...HO
2CH3—COOH CH3—C C—CH3
O...HO
Molecular mass of acetic acid is found 120. Which among the following relation is correct?
(a)      


(b)      


    

(c)


(d)   


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 JEE Advanced Sample Paper – 07. Chemical and Ionic Equilibrium

2. The equilibrium :
NH4HS(s) NH3(g) + H2S(g),
is followed to set-up at 127°C in a closed vessel. The total pressure at equilibrium was 20 atm. The
Kc for the reaction is :
(a) 0.092 M2
(b) 0.085 M2
(c) 3.045 M2
(d) None of these

3. 20% of N2O4 molecules are dissociated in a simple of gas at 27°C and 760 torr. Mixture has the
density at equilibrium equal to:
(a) 1.48 g/L
(b) 1.84 g/L
(c) 2.25 g/L
(d) 3.12 g/L

4. The equilibrium constants Kp1 and Kp2 for the reactions X 2Y and Z P + Q;
respectively are in the ratio of 1 : 9. If the degree of dissociation of X and Z be equal then the
ratio of total pressures at these equilibria is:
(a) 1 : 9
(b) 1 : 36
(c) 1 : 1
(d) 1 : 3

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 JEE Advanced Sample Paper – 07. Chemical and Ionic Equilibrium

5. Match the reactions of the Column-I with the factors in Column-II:

Column-I Column-II

(a) N2(g) + 3H2(g) 2NH3(g) (p) Formward shift by rise

in pressure
(Exothermic)

(b) 2SO2(g) + O2(g) 2SO3(g) (q) Unaffected by change in

pressure
(Exothermic)

(c) N2(g) + O2(g) 2NO(g) (r) Forward shift by rise in

temperature
(Endothermic)

(d) PCl3(g) + Cl2(g) PCl5(g) (s) Forward shift by

lowering the temperature
(Endothermic)

6. When NaCl is added gradually to the saturated solution of AgCl then which of the following plot
is correct?

(a) (c)

(b) (d)

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 JEE Advanced Sample Paper – 07. Chemical and Ionic Equilibrium

7. The relative strength of two weak bases at same concentration may be given as:

(a) 


 
(b)  
   

(c) 
 


 
(d) 
 

8. Match the Column-I with Column-II:

Column-I Column-II
(a) Strong acid versus strong base (p) Methyl orange (3 – 4.4)
(b) Weak acid versus strong base (q) Methyl red (4.3 – 6.3)
(c) Strong acid versus weak baes (r) Phenolphthalein (8 – 10)
(d) Weak acid versus weak base (s) No suitable indicator

9. In 1 L saturated solution of AgCl [Ksp (AgCl) = 1.6×10–10], 0.1 mol of CuCl [Ksp (CuCl = 1 × 10–6]
is added. The resultant concentration of Ag+ in the solution is 1.6 × 10x. The value of x is:

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 JEE Advanced Sample Paper – 07. Chemical and Ionic Equilibrium

Passage
10. Higher the amount of acid or base used to produce a definite change of pH in a buffer a solution,
higher will be its buffer capacity. Buffer capacity of solution is maximum under the following
conditions:
[Salt] = [Acid] (in acid buffer)
[Salt] = [Base] (in base buffer)
pH of a buffer a solution lies in the range given below:
pH = pKa ≠ 1
In other words, any buffer solution can be used as buffer up to two pH units only, depending upon
the value of pKa or pKb. A buffer is said to be efficient when pH = pKa or pOH = pKb

I. Any buffer can be used as a buffer up to:

(a) 10 pH units
(b) 5 pH units
(c) 2 pH units
(d) 1 pH units

II. Which among the following solutions will be the most efficient buffer?
(a) 0.1 M CH3COONa + 0.01 M CH3COOH
(b) 0.1 M NH3Cl + 0.1 M NH4OH
(c) 0.001 M COOH + 0.002 M HCOONa
(d) All of the above

III. The buffer capacity is equal to :

∆
(a) 
∆

(b) 
∆
(c) ±lpKa
(d) None of these

IV. Buffer capacity is maximum when:

(a) One mole of NH4Cl is added to two moles of NH4OH
(b) One mole of NH4Cl is added to one mole of NH4OH
(c) One mole of NH4Cl is added to one mole of NaOH
(d) One mole of NaCl is added to one mole of NaOH

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 JEE Advanced Sample Paper – 07. Chemical and Ionic Equilibrium

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 JEE Advanced Sample Paper – 07. Chemical and Ionic Equilibrium

Answer Keys

Q1 Q2 Q3 Q4 Q5
(c) (a) (d) (b) (a) - p, s
(b) - p, s
(c) - q, r
(d) - r, p
Q6 Q7 Q8 Q9 Q10
(b) (b), (c), (d) (a) - p, q, r 7 I. (c)
(b) - r II. (b)
(c) - p, q, III. (a)
(d) - s IV. (b)

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