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From version 2.1.3 onwards Aspen HYSYS calculates CV internally using the
following equation:
2
V V
C P CV T (1)
T P P T
If this method fails then Aspen HYSYS reports the semi-ideal value. A semi-ideal value
will also be calculated when:
Stream has a solid phase
Magnitude of dV/dP < 1 10 12 (because this cannot be distinguished from round
off errors)
CP / CV < 0.1 or CP / CV > 20, since this is outside of the range of applicability
This method is considered to be the best and most rigorous way to calculate CP / CV.
Write
S S U
(A1-1)
T V U V T V
From the First Law and the definitions of work and entropy
dU TdS PdV (A1-3)
Write U U S ,V and use the chain rule
U U
dU dS dV (A1-4)
S V V S
to give
U V U
C P CV P (A2-4)
T P T P T V
U
Now substitute for T in (A2-4)
P
U U V V U
C P CV P
T V V T T P T P T V
U V V
P (A2-8)
V T T P T P
U V
P
V T T P
U
Now V can be rewritten to eliminate the P in the bracket.
T
hence
CV P
dS dT dV (A2-
T T V
10)
From the First Law and the definitions of work and entropy
dU TdS PdV (A2-
11)
and substitute for dS using (A2-10)
P
dU CV dT T P dV (A2-
T V
12)
Comparing to (A2-5) gives
U P
T P (A2-
V T T V
13)
Substitute (A2-13) into (A2-8) to give
P V
C P CV T (A2-
T V T P
14)
Now use the triple product relationship
P V T
1 (A2-
T V P T V P
15)
rearranged to give
V
P
T P
(A2-
T V
V
P T
16)
to substitute into (A2-14) to give
2
V V
C P CV T
T P P T