Tip Top Coropur Zinc M: Print Date: 21.10.2015 Page 1 of 10

Safety Data Sheet according to Regulation (EC) No 1907/2006
TIP TOP Oberflaechenschutz Elbe GmbH

TIP TOP COROPUR ZINC M
Revision date: 21.10.2015 Revision No: 1,2
Product code: 00359-1176
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier

Art.-No.
580 0016, 580 0023, 580 0030
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Coating component
1.3. Details of the supplier of the safety data sheet
Company name: TIP TOP Oberflaechenschutz Elbe GmbH
Street: Heuweg 4
Place: D-06886 Wittenberg
Telephone: +49(0)3491/635-50
Telefax: +49(0)3491/635-552
Responsible Department: Responsible for the safety data sheet: sds@gbk-ingelheim.de
1.4. Emergency telephone INTERNATIONAL: +49 - (0) 6132 - 84463, GBK GmbH (24h - 7d/w - 365d/a)
number: England and Wales: NHS Direct - 0845 4647; Scotland: NHS 24 - 08454 24 24
24
SECTION 2: Hazards identification

2.1. Classification of the substance or mixture according to 1272/2008/EC
Hazard categories:
Flammable liquid: Flam. Liq. 3
Respiratory or skin sensitisation: Skin Sens. 1
Hazardous to the aquatic environment: Aquatic Acute 1
Hazardous to the aquatic environment: Aquatic Chronic 1
Hazard Statements:
Flammable liquid and vapour.
May cause an allergic skin reaction.
Very toxic to aquatic life with long lasting effects.
2.2. Label elements
Hazardous components which must be listed on the label
Aromatic polyisocyanate
4-isocyanatosulphonyltoluene
Polyaminoamide salt
Aromatic polyisocyanate prepolymer
Signal word: Warning
Pictograms:
Hazard statements
H226 Flammable liquid and vapour.
H317 May cause an allergic skin reaction.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P243 Take precautionary measures against static discharge .
P260 Do not breathe vapour.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Print date: 21.10.2015 GB - EN Page 1 of 10

P302+P352 IF ON SKIN: Wash with plenty of water.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse .
P391 Collect spillage.
P501 Dispose of contents/container to in accordance with local and national regulations.
Special labelling of certain mixtures
EUH204 Contains isocyanates. May produce an allergic reaction.
2.3. Other hazards
Vapours may form explosive mixture with air.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
Chemical characterization
Aromatic polyisocyanate
Hazardous components
CAS No Chemical name Quantity
EC No Index No REACH No
Classification according to Regulation (EC) No. 1272/2008 [CLP]
7440-66-6 zinc powder - zinc dust (stabilized) 50 - 100 %
231-175-3 030-001-01-9 01-2119467174-37
Aquatic Acute 1, Aquatic Chronic 1; H400 H410
64742-95-6 Solvent naphta (petroleum) 5 - 10 %
918-668-5 649-356-00-4 01-2119455851-35
Flam. Liq. 3, STOT SE 3, STOT SE 3, Asp. Tox. 1, Aquatic Chronic 2; H226 H335 H336 H304
H411 EUH066
53317-61-6 Aromatic polyisocyanate 2,5 - 5 %
Eye Irrit. 2, Skin Sens. 1; H319 H317

103051-64-5 Aromatic polyisocyanate 2,5 - 5 %
Skin Sens. 1; H317

108-65-6 2-Methoxy-1-methylethyl acetate 2,5 - 5 %
203-603-9 607-195-00-7 01-2119475791-29
Flam. Liq. 3; H226
1330-20-7 Xylene (mixed isomers) 1 - 2,5 %
215-535-7 601-022-00-9 01-2119488216-32
Flam. Liq. 3, Acute Tox. 4, Acute Tox. 4, Skin Irrit. 2, Eye Irrit. 2, STOT SE 3, STOT RE 2, Asp.
Tox. 1; H226 H312 H332 H315 H319 H335 H373 H304
127821-00-5 Aromatic polyisocyanate prepolymer 1 - 2,5 %
Eye Irrit. 2, Skin Sens. 1; H319 H317

4083-64-1 4-isocyanatosulphonyltoluene 0,5 - 1 %
223-810-8 615-012-00-7 01-2119980050-47
Skin Irrit. 2, Eye Irrit. 2, Resp. Sens. 1, STOT SE 3; H315 H319 H334 H335 EUH014
Polyaminoamide salt < 0,5 %
Skin Sens. 1; H317

Full text of H and EUH statements: see section 16.
Further Information
According to note P to the regulation (EC) no. 1272/2008, "Solvent naphta (petroleum)" is not to be
classified as "carcinogenic" or "mutagen" ingredient because a benzene content (EINECS No.
200-753-7) is below 0.1 % by weight.
SECTION 4: First aid measures
4.1. Description of first aid measures

General information
Remove contaminated soaked clothing immediately.
If you feel unwell, seek medical advice.
Take away from danger area and lay down affected person .
In case of the person being unconscious put him/her in a stable side position.
After inhalation
Move to fresh air in case of accidental inhalation of vapours or decomposition products.
Refer for medical treatment.
If patient is not breathing, apply artificial respiration.
After contact with skin
Wash off with soap and plenty of water.
Consult a doctor if skin irritation persists.
Do not use solvents or thinners.
After contact with eyes
Remove contact lens.
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Seek medical treatment by eye specialist.
After ingestion
Do not induce vomiting.
Rinse out mouth and give plenty of water to drink.
Never give anything by mouth to an unconscious person.
Summon a doctor immediately.
Induce vomiting only upon the advice of a physician.
4.2. Most important symptoms and effects, both acute and delayed
May cause an allergic skin reaction.
Attention. Beware, danger of aspiration.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptoms.
SECTION 5: Firefighting measures
5.1. Extinguishing media

Suitable extinguishing media
Alcohol-resistant foam, dry chemical, carbon dioxide (CO2), water-spray.
Unsuitable extinguishing media
Full water jet.
5.2. Special hazards arising from the substance or mixture
Fire may produce:
Carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx).
5.3. Advice for firefighters
Wear self-contained breathing apparatus and protective suit.
Additional information
Cool containers at risk with water spray jet.
The vapour/air mixture is explosive, even in empty, uncleaned receptacles.
Vapours are heavier than air and spread along ground .
Fire residues and contaminated firefighting water must be disposed of in accordance with the local
regulations.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures

In case of vapour formation use respirator.
Use only explosion-proof equipment.
Ensure adequate ventilation.

Use personal protective clothing.

Keep away sources of ignition.
6.2. Environmental precautions
Do not discharge into the drains/surface waters/ground water.
Inform competent authority about release into the sewage, ground or into waters.
6.3. Methods and material for containment and cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder).
Shovel into suitable container for disposal.
Container can be pressurized by carbon dioxide due to reaction with humid air and/or water.
Container should not be gas-tight closed.
6.4. Reference to other sections
Observe protective instructions (see Sections 7 and 8).
Information for disposal see section 13.
SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
Keep container tightly closed.
Keep a good ventilation and air-exhaust at the place of work.
Vapours are heavier than air and spread along ground .
Avoid contact with the skin and the eyes.
When using do not eat, drink or smoke.
Do not empty container under pressure. No pressure tank!
Containers that have been opened must be carefully resealed and kept upright to prevent leakage.
Advice on protection against fire and explosion
Keep away from heat and sources of ignition.
Do not smoke.
Take precautionary measures against static discharges .
Use only explosion-proof equipment.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep container tightly closed in a dry, cool and well-ventilated place.
Pay attention to anti-explosion protection rules.
Protect from heat and direct solar radiation.
Storage temperature between 15°C to 30°C
Advice on storage compatibility
Incompatible with:
Oxidizing agents
Acids and bases.
Further information on storage conditions
Keep away from food, drink and animal feeding stuffs.
7.3. Specific end use(s)
Coating component
SECTION 8: Exposure controls/personal protection
8.1. Control parameters

Exposure limits (EH40)
CAS No Substance ppm mg/m³ fibres/ml Category Origin
108-65-6 1-Methoxypropyl acetate 50 274 TWA (8 h) WEL

100 548 STEL (15 min) WEL
- Isocyanates, all (as -NCO) Except methyl - 0.02 TWA (8 h) WEL
isocyanate
- 0.07 STEL (15 min) WEL
1330-20-7 Xylene: mixed isomers 50 220 TWA (8 h) WEL
100 441 STEL (15 min) WEL
Biological Monitoring Guidance Values (EH40)
CAS No Substance Parameter Value Test material Sampling time
1330-20-7 Xylene, o-, m-, p- or mixed isomers methyl hippuric acid 650 urine Post shift
mmol/mol
8.2. Exposure controls

Appropriate engineering controls
Ensure adequate ventilation, especially in confined areas.
Protective and hygiene measures
Do not inhale vapours.
Wash hands before breaks and immediately after handling the product .
When using do not eat, drink or smoke.
Treat subsequently with skin cream.
Remove and wash contaminated clothing before re-use.
Eye/face protection
Tightly fitting goggles (EN 166).
Eye wash bottle with pure water (EN 15154).
Hand protection
Protective gloves resistant to chemicals made of nitrile, minimum coat thickness 0.4 mm, permeation
resistance (wear duration) approx. 480 minutes, i.e. protective glove < Camatril Velours 730> made by
www.kcl.de.
This recommendation refers exclusively to the chemical compatibility and the lab test conforming to EN
374 carried out under lab conditions.
Requirements can vary as a function of the use. Therefore it is necessary to adhere additionally to the
recommendations given by the manufacturer of protective gloves.
Skin protection
Long sleeved clothing (EN 368).
Respiratory protection
In case of insufficient ventilation wear suitable respiratory equipment (gas filter type A) (EN 14387).
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties

Physical state: Liquid
Colour: Various
Odour: characteristic
Changes in the physical state

Flash point: 39 °C DIN 53213
Lower explosion limits: 2,7 vol. %
Upper explosion limits: 10,8 vol. %
Ignition temperature: 180 °C
Vapour pressure: 0,56 hPa
(at 20 °C)

Density (at 20 °C): 2,6 g/cm³

Water solubility: Immiscible
(at 20 °C)
Viscosity / dynamic: 500 - 700 mPa·s
Viscosity / kinematic: > 20,5 mm²/s
(at 40 °C)
Solvent content: 15 %
9.2. Other information
No data available.
SECTION 10: Stability and reactivity
10.1. Reactivity
No decomposition if stored and applied as directed.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
Reactions with acids, alkalies and oxidizing agents
10.4. Conditions to avoid
To avoid thermal decomposition, do not overheat.
Heating can release vapours which can be ignited.
Vapour/air-mixtures are explosive at intense warming.
10.5. Incompatible materials
Strong oxidizing agents
Strong acids and strong bases
10.6. Hazardous decomposition products
Carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx).
Hydrogen cyanide gas, Isocyanates
SECTION 11: Toxicological information
11.1. Information on toxicological effects

Acute toxicity
Based on available data, the classification criteria are not met.
No toxicological data available.
Irritation and corrosivity
Sensitising effects
May cause an allergic skin reaction. (Aromatic polyisocyanate), (Aromatic polyisocyanate), (Aromatic
polyisocyanate prepolymer), (Polyaminoamide salt )
STOT-single exposure
Severe effects after repeated or prolonged exposure
Carcinogenic/mutagenic/toxic effects for reproduction
Aspiration hazard
Additional information on tests
Classification in compliance with the assessment procedure specified in the Regulation (EC) no
1272/2008.
Practical experience
Other observations
Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness,
nausea and vomiting.
Inhalation of high concentrations may cause injuries to liver, kidneys and central nervous system.

A longer or repeated contact my lead to irritation of eyes and mucous membranes .

Repeated or prolonged exposure may cause skin irritation and dermatitis, due to degreasing properties
of the product.
With hypersensitive people, reactions as cough or difficulty of breathing may appear even with tiny
concentrations of isocyanates; therefore keep room aerated and ventilated.
SECTION 12: Ecological information

12.1. Toxicity
Ecological data are not available.
Very toxic to aquatic life with long lasting effects.
12.2. Persistence and degradability
No data available.
12.3. Bioaccumulative potential
No data available.
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB assessment
According to Regulation (EC) No 1907/2006 (REACH) none of the substances, contained in this
product are a PBT / vPvB substance.
12.6. Other adverse effects
Hazardous water pollutant.
Further information
Do not flush into surface water or sanitary sewer system.
SECTION 13: Disposal considerations
13.1. Waste treatment methods

Advice on disposal
Can be incinerated, when in compliance with local regulations.
Where possible recycling is preferred to disposal.
Waste disposal number of waste from residues/unused products
080111 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS
(PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS;
wastes from MFSU and removal of paint and varnish; waste paint and varnish containing organic
solvents or other hazardous substances
Classified as hazardous waste.
Contaminated packaging
Empty containers should be taken for local recycling, recovery or waste disposal.
Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be
taken for reuse.
Packaging that cannot be cleaned should be disposed of like the product.
SECTION 14: Transport information
Land transport (ADR/RID)

14.1. UN number: UN 1263
14.2. UN proper shipping name: Paint
14.3. Transport hazard class(es): 3
14.4. Packing group: III
Hazard label: 3
Classification code: F1
Limited quantity: 5 L / 30 kg
Excepted quantity: E1
Transport category: 3
Hazard No: 30
Tunnel restriction code: D/E
Inland waterways transport (ADN)
Hazard label: 3
Classification code: F1
Marine transport (IMDG)
14.2. UN proper shipping name: Paint (Solvent naphtha (petroleum))
Hazard label: 3
Marine pollutant: Yes

EmS: F-E, S-E
Air transport (ICAO)
Hazard label: 3
Limited quantity Passenger: 10 L

Passenger LQ: Y344
IATA-packing instructions - Passenger: 355
IATA-max. quantity - Passenger: 60 L
IATA-packing instructions - Cargo: 366
IATA-max. quantity - Cargo: 220 L
14.5. Environmental hazards
ENVIRONMENTALLY HAZARDOUS: yes
14.6. Special precautions for user

Handle in accordance with good industrial hygiene and safety practice.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
The transport takes place only in approved and appropriate packaging.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
2004/42/EC (VOC): < 20 %
398 g/l
National regulatory information
Employment restrictions: Observe employment restrictions for young people. Observe employment
restrictions for child bearing mothers and nursing.
Water contaminating class (D): 2 - water contaminating
Additional information
Consider Chemical prohibition regulation.
SECTION 16: Other information

Abbreviations and acronyms
ADR = Accord européen relatif au transport international des marchandises Dangereuses par Route
RID = Règlement concernant le transport international ferroviaire de marchandises dangereuses
ADN = Accord européen relatif au transport international des marchandises dangereuses par voie de navigation intérieure
IMDG = International Maritime Code for Dangerous Goods
IATA/ICAO = International Air Transport Association / International Civil Aviation Organization
MARPOL = International Convention for the Prevention of Pollution from Ships
IBC-Code = International Code for the Construction and Equipment of Ships Carrying Dangerous Chemicals in Bulk
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
REACH = Registration, Evaluation, Authorization and Restriction of Chemicals
CAS = Chemical Abstract Service
EN = European norm
ISO = International Organization for Standardization
DIN = Deutsche Industrie Norm
PBT = Persistent Bioaccumulative and Toxic
vPvB = Very Persistent and very Bio-accumulative
LD = Lethal dose
LC = Lethal concentration
EC = Effect concentration
IC = Median immobilisation concentration or median inhibitory concentration
Relevant H and EUH statements (number and full text)

H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled .
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
EUH014 Reacts violently with water.
EUH066 Repeated exposure may cause skin dryness or cracking.
EUH204 Contains isocyanates. May produce an allergic reaction.
Further Information
Data of items 4 to 8, as well as 10 to 12, do partly not refer to the use and the regular employing of the

product (in this sense consult information on use and on product), but to liberation of major amounts in
case of accidents and irregularities.
The information describes exclusively the safety requirements for the product(s) and is based on the
present level of our knowledge.
The delivery specifications are contained in the corresponding product sheet.
This data does not constitute a guarantee for the characteristics of the product(s) as defined by the
legal warranty regulations.
(n.a. = not applicable; n.d. = not determined)
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)

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Safety Data Sheet according to Regulation (EC) No 1907/2006

TIP TOP Oberflaechenschutz Elbe GmbH

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

SECTION 2: Hazards identification

Print date: 21.10.2015 GB - EN Page 1 of 10

P302+P352 IF ON SKIN: Wash with plenty of water.

SECTION 3: Composition/information on ingredients

Eye Irrit. 2, Skin Sens. 1; H319 H317

Skin Sens. 1; H317

Eye Irrit. 2, Skin Sens. 1; H319 H317

Skin Sens. 1; H317

SECTION 4: First aid measures

4.1. Description of first aid measures

SECTION 5: Firefighting measures

5.1. Extinguishing media

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Print date: 21.10.2015 GB - EN Page 3 of 10

Use personal protective clothing.

SECTION 7: Handling and storage

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Print date: 21.10.2015 GB - EN Page 4 of 10

Exposure limits (EH40)

CAS No Substance ppm mg/m³ fibres/ml Category Origin

108-65-6 1-Methoxypropyl acetate 50 274 TWA (8 h) WEL

Biological Monitoring Guidance Values (EH40)

CAS No Substance Parameter Value Test material Sampling time

8.2. Exposure controls

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Changes in the physical state

Print date: 21.10.2015 GB - EN Page 5 of 10

Density (at 20 °C): 2,6 g/cm³

SECTION 10: Stability and reactivity

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Print date: 21.10.2015 GB - EN Page 6 of 10

A longer or repeated contact my lead to irritation of eyes and mucous membranes .

SECTION 12: Ecological information

SECTION 13: Disposal considerations

13.1. Waste treatment methods

SECTION 14: Transport information

Land transport (ADR/RID)

Marine pollutant: Yes

Limited quantity Passenger: 10 L

14.6. Special precautions for user

Print date: 21.10.2015 GB - EN Page 8 of 10

SECTION 15: Regulatory information

SECTION 16: Other information

Relevant H and EUH statements (number and full text)

Print date: 21.10.2015 GB - EN Page 9 of 10

Print date: 21.10.2015 GB - EN Page 10 of 10

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