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Response statement(s)
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.
Rinse skin with water/shower.
P304 +P340 IF INHALED: Remove victim to fresh air and keep at a rest position comfortable
for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or a doctor/physician.
P321 Specific treatment is advised – see first aid instructions.
P363 Wash contaminated clothing before re-use.
P390 Absorb spillage to prevent material damage.
Storage statement(s)
P405 Store locked up.
P406 Store in corrosive resistant container with a resistant inner liner.
Disposal statement(s)
P501 Dispose of contents/container in accordance with relevant regulations.
Other hazards
No information provided.
FIRST AID PROCEDURES FOR DEALING WITH THIS PRODUCT AND EXPOSURE TO IT
1. Personal Protection By First Aid Personnel
First aid personnel providing first aid treatment to a patient exposed to nitric acid should observe the
following precautions for their own personal protection:
Avoid contact with contaminated skin, clothing and equipment by wearing protective gloves to
prevent contact of nitric acid with skin;
Wear chemical goggles as a minimum level of eye protection to prevent splashes of nitric acid
entering eyes;
Avoid inhalation of nitric acid fumes or mist during rescue in contaminate areas by wearing suitable
respiratory protection;
Respiratory protection suggested is: an air supplied breathing apparatus, or positive pressure self-
contained breathing apparatus.
2. Swallowed
Do not give anything by mouth if victim is losing consciousness, or is unconscious, or convulsing. If victim is
conscious, rinse mouth thoroughly with water immediately and give water or milk to drink.
DO NOT induce vomiting.
Seek urgent medical assistance.
3. Eyes
Persons with potential eye exposure should not wear contact lenses. Immediately irrigate with copious
quantities of water, while holding eyelids open, for at least 15 minutes.
Seek urgent medical assistance.
4. Skin
First aid personnel must avoid contact with this chemical. Wear protective gloves when assisting patient. DO
NOT USE HOT WATER. Immediately wash affected areas with copious amounts of water. Remove all
contaminated clothing and launder before re-use.
Seek medial assistance if irritation persists.
5. Inhalation
Rescuer should wear appropriate personal protection to avoid skin contamination skin and breathing nitric
acid fumes or mist. Remove affected persons from exposure. Allow affected person to assume most
comfortable position and keep warm. Keep at rest until fully recovered. If breathing is laboured, or affected
person is cyanotic (blue), ensure airways are clear and have a qualified person give oxygen through a face-
mask. If breathing has stopped apply expired air resuscitation immediately. If the affected person suffers
cardiac arrest commence cardio-pulmonary resuscitation immediately. Seek urgent medical attention.
ADVICE TO DOCTOR.
Treatment for nitric acid burns to the eyes:
Retract eyelids to ensure thorough irrigation of the conjunctival cul-de-sacs;
Irrigate eyes with several litres of saline for at least 20 minutes;
DO NOT use neutralising agents or any other additives;
Cycloplegic drops, antibiotic drops, steroid drops, vasoconstrictive agents, or artificial tears should
only be administered with the approval of a consulting ophthalmologist.
Treatment for nitric acid fume, or mist, inhalation:
Pulmonary oedema may arise – symptoms may be delayed for several hours. Affected persons
should not be left unattended during this period;
Airway problems may arise from laryngeal oedema – symptoms may be delayed for several hours;
Treat with 100% oxygen initially;
Respiratory distress may require cricothyroidotomy if endotracheal intubation is constrained by
excessive swelling;
Intravenous lines should be established immediately in all cases where there is evidence of
circulatory compromise;
Nitric acid may produce a coagulation necrosis characterised by formation of a coagulum (eschar),
which is the result of the desiccating action of the acid on proteins in specific tissues.
For the management of nitric acid emergencies during transport by road or rail, SAA/SNZ HB76: Dangerous
Goods-Initial Response Guide, Guide 40 should be consulted. This Guide should be carried at all times when
nitric acid is being transported.
Clean up personnel will need personal protection equipment and respiratory protection. Portable safety shower
and eyewash facilities may also be needed for clean up personnel. Bags of neutralising agent or chemical
absorbent and substantial amounts of water will be required for large spill. A front-end loader may be required
to scoop up neutralised acid/lime/soda ash residue. Protein foam blanket may be required for large spills.
NO2Level in Duration in
Resulting Conditions on Humans
ppm minutes
25 60 Respiratory irritation and chest pain.
50 15
100 15 Pulmonary oedema with possible sub-acute or chronic lung lesions.
200 5
100 60 Pulmonary oedema and death.
400 5
Skin:
Highly corrosive to skin. Causes severe burns leading to necrosis and scarring. Nitric acid chars the tissue
with a characteristic yellow colouration. The severity of injury depends on the concentration of nitric acid and
the duration of exposure.
Eye:
Corrosive to eyes. Contact may cause corneal burns. Permanent eye damage including loss of sight may
occur. Nitric acid mists and aerosols are expected to be very irritating.
Swallowed:
Can kill if swallowed. Will cause severe damage to the mucous membranes. May cause nausea, vomiting,
abdominal pain and severe burns to the mouth, throat, stomach and gastrointestinal tract. LD50 (Oral, human)
= 430 mg/kg
Chronic:
Chronic exposure to nitric acid may lead to teeth disorders (yellow discolouration and erosion of the
dental enamel) which are, however, not as severe as with sulfuric, or hydrochloric acids. At low levels,
chronic exposure can lead to nose bleeds and sinus problems, and changes in pulmonary function and
chronic bronchitis.
Kirk-Othmer Encyclopaedia of Chemical Technology, 4th Edition, Wiley InterScience, New York, 1997.
Ullmann's Encyclopaedia of Industrial Chemistry, F. Ulmann, 6 th Edition, Wiley Interscience, New York,
2001.
Standard for the Uniform Scheduling of Drugs and Poisons, National Health and Medical Research Council,
Australian Government Publishing Service, Canberra, 1992.
Poisons Act 1964, State Law Publisher, Western Australia, Reprinted 22 January 1999.
Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environmant,
[NHSC:1003(1991)].
Hazardous Materials Handbook for Emergency Responders, Onguard Training for Life, J. Varela (Editor),
Van Nostrand Reinhold, New York, 1996.
Chemwatch www.chemwatch.net
Guidance for the Compilation of Safety Data Sheets for Fertilizer Materials, European Fertilizer
Manufacturers Association, online at www.efma.org/Publications/Guidance/Index.asp
Sources for data
No data available.
Important Notes
1. To the best of our knowledge this document complies with the Code of Practice for the Preparation
of Safety Data Sheets for Hazardous Chemicals, Safe Work Australia, December 2011.
2. This safety data sheet summarises our best knowledge of the health and safety hazard information of
the product and how to safely handle and use the product in the workplace. Each user should read
this safety data sheet and consider the information in the context of how the product will be handled
and used in the workplace, including in conjunction with other products.
3. If clarification or further information is needed to ensure that an appropriate risk assessment can be
made, the user should contact the Safety Department, CSBP Limited on (08) 9411 8777 (Australia), +61
8 9411 8777 (Overseas).
4. Our responsibility for products sold, is subject to our terms and conditions, a copy of which is sent to
our customers, and is also available on request.
5. CSBP reserves the right to make change to l safety data sheets without notice.