Nama Kelompok : 1.

Nurani Legahati (05161057)

2. Rebeka (05161062)
3. Virginia Sitompul (05161073)
Subject : Operasi Teknik Kimia 3

SOLUTION :
STEP 1 Diketahui :
VN+1 = 450
yAN+1 = 0
yCN+1 = 1

L0 = 150
xA0 = 0.3
xB0 = 0.7
xC0 = 0
xAN = 0.1

STEP 2 Equilibrium data for the system acetic acid - Isoprophyl Ether are from Appendix A.3
A.3.24 Acetic Acid-Isopropyl Ether System, Liquid-Liquid Equilbria
RAFFINATE EXTRACT
Acetic Isoprophyl Acetic Isoprophyl
Acid (XA) Ether (yA) Acid (Xc) Ether (yC)
0 0.012 0 0.994
0.0069 0.012 0.0018 0.993
0.0141 0.015 0.0037 0.989
0.0289 0.016 0.0079 0.984
0.0642 0.019 0.0193 0.971
0.133 0.023 0.0482 0.933
0.255 0.034 0.114 0.847
0.367 0.044 0.216 0.715
0.443 0.106 0.311 0.581
0.464 0.165 0.362 0.487
0.401 0.425
0.443 0.303
Garis Bantu 0.455 0.265
 Garis Bantu
0.463 0.201
0.464 0.166

STEP 3 x y
1 0
0.9 0.1
0.8 0.2
0.7 0.3
0.6 0.4

0.5 0.5
0.4 0.6
0.3 0.7
0.2 0.8
0.1 0.9
0 1
STEP 4 For the mixture point M, substituting into Eq. (12.7-3) and Eq. (12.7-4)

xCM = 0.75

xAM = 0.075
The point M is plotted and V1 is located at the intersection of line LNM with
the phase boundary to give yA1 = 0,072 and yC1 = 0,895

STEP 5 The lines L0V1 and LNVN+1 are drawn and the intersection is the operating point Δ
as shown.
The coordinates of Δ can in kg/h can be calculated from Eq. (12.7-10)

STEP 6 Starting at L0 we draw line L0Δ, which locates V1.

Then a tie line through V1 locates L1 in equilibrium with V1.
Line L1Δ is next drawn locating V2. A tie line through V2 gives L2.
A line L2Δ gives V3. A final tie line gives L3, which has gone beyond the desired LN
Hence, about 2,5 theoritical stages are needed.
STEP 7 EXTRACT RAFFINATE
ETHER LAYER WATER LAYER
yA xA
% wt wt % wt wt
0 0 0 0
0.18 0.0018 0.69 0.0069
0.37 0.0037 1.41 0.0141
0.79 0.0079 2.89 0.0289
1.93 0.0193 6.42 0.0642

4.82 0.0482 13.3 0.133

11.4 0.114 25.5 0.255
21.6 0.216 36.7 0.367
31.1 0.311 44.3 0.443
36.2 0.362 46.4 0.464

450 Line
x y y
0 0 0

0.5 0.5 0.5

ting into Eq. (12.7-3) and Eq. (12.7-4) STEP 8 yA1 yc1 xCN
0.072 0.895 0.017

Calculate ∆
STEP 9
∆
-350.9112

STEP 10
∆
is located at the intersection of line LNM with
0,072 and yC1 = 0,895

rawn and the intersection is the operating point Δ

can be calculated from Eq. (12.7-10)

1 V1
VN+1
0.9

0.8
M
0.7
Mass Fraction C (Xc, yC)

which locates V1. 0.6

L1 in equilibrium with V1.
0.5
V2. A tie line through V2 gives L2.
P
ne gives L3, which has gone beyond the desired LN. 0.4
s are needed.
0.3

0.2

0.1

0
 P

Mass Fracti
0.4

0.3

0.2

0.1

0
0
L3 LN0.1L2 L1
0.2
L0
0.3

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3

STEP 11 From graphic we know t

 M V1 LN
600 500.91116 99.088838

Calculate ∆

∆x
1.2775755

Ploting Line

V1

Tie Line
M

Operating Line

P
 P

3 L2 L1 L0 A 1
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
Mass Fraction A (XA, yA)

45 line

Equlibrium Line

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

From graphic we know that total stage theoritical in extraction = 2,5 stages