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GeoResJ 14 (2017) 20–35

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GeoResJ
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Late pleistocene polygenetic Andean wetland soils


Juan C. Loaiza a,∗, Jorge Sánchez-Espinosa b, Yolanda Rubiano-Sanabria c, Rosa M. Poch d
a
Geosciences and Environmental School, Mining Faculty, National University of Colombia, Campus Medellín, Colombia
b
National University of Colombia, Campus Bogotá, Geographic Institute Agustín Codazzi (IGAC), Colombia
c
Ph.D program in Agricultural Science at the National University of Colombia, Campus Bogotá, Geographic Institute Agustín Codazzi (IGAC), Colombia
d
Department of Environment and Soil Sciences, University of Lleida, Catalonia, Spain

a r t i c l e i n f o a b s t r a c t

Article history: The Fusagasuga megafan is located in the Sumapaz River catchment (main tributary of the Magdalena
Received 24 January 2017 River) which drains into the Sumapaz moorland. The soils show non consistent hydromorphic palaeofea-
Revised 17 July 2017
tures that may be related to recent tectonics, therefore a study was conducted to gain insight into the pa-
Accepted 24 July 2017
leoenvironment of the area, in particular the paleohydrology. We studied 6 profiles under 4 different geo-
Available online 27 July 2017
morphological positions: structural eroded mountain, axis, length and base of the alluvial megafan (depo-
Keywords: sitional foothills). Medium-textured Lithic Melanudands are located in a steep high mountain (anticline
Paleohydrology structural slope), Silty loam Ultic Melanudands are developed from volcanic ashes over thick medium-
Polygenetic soils grained sandstones in the transition mountain to alluvial megafan, very fine-textured Typic Paleudalfs
Hydromorphic soils with Bt Horizons (42–85% clay) are found around the middle and proximal parts of the megafan, that
Clay illuviation become Typic Haplustalfs at the distal parts of the megafan. Kaolinite is the dominant clay in all soils,
Micromorphology
followed by halloisite, goethite and traces of vermiculite and quartz. Quartz and feldspars dominate the
sand fraction, together with amphiboles and volcanic glass chemically weathered epidote in small quanti-
ties. Soils are mainly acidic, with a high Al saturation and a low base saturation. Clay illuviation is shown
by hypocoatings and microlaminated clay coatings. Different degrees of hydromorphism are observed
with gleyic to stagnic patterns. Some of the redoximorphic features are related to the current pore sys-
tem and others to palaeoenvironmental conditions often associated to old clay coatings. The most clayey
soils show striated, undifferenciated, speckled b-fabrics and frequent coatings, and some others point to
ferrolysis as iron-depleted hypocoatings and low anisotropic clay coatings along pores, an observation
supported by mineralogical data. The morphological and micromorphological redoximorphic features al-
low us to explain the paleoevolution of the alluvial megafan.
© 2017 Elsevier Ltd. All rights reserved.

1. Introduction 1.800 m.a.s.l. It is made by materials which began to be deposited


about 20,0 0 0 years ago, coming from the Pasca region [24,39]. Af-
Quaternary soils in South America have strong relation between ter this sedimentation, active erosion and incision phases started,
palaeoenvironmental conditions and soil environments. There is a due to a tilting to the east following a tectonic adjustment that
huge number of studies in South America to understand the cli- collapsed its western edge [14]. The Eastern cordillera of Colombia
mate and environmental system, as the reconstruction of paleoen- is a double verging mountain system bounded by major inverse
vironments conditions [29]. faults that locally involve crystalline and metamorphic basement
Concretelly in the Andean mountains few studies have been rocks, Precambrian lower Paleozoic in age, as well as upper Paleo-
carried out to find correlations between paleosoils and palaeoen- zoic Cenozoic sedimentary and volcanic sequences [13].
vironmental conditions [22,37,45,46]. In the Central Andes a fluvial The recent deposits are product of huge landslides occurring at
megafan development is due to the huge accumulation rate of sed- the headwaters of the Cuja River caused by tectonic movements
iments correlated with climate variability [31,72], being their maxi- associated to the Pleistocene orogeny [14,36,37,75,78]. These de-
mum extension because of high seasonal discharge variability [40]. posits, product of the glaciaric activity, were transported and sed-
The Fusagasuga megafan (Cundinamarca, Colombia) is a imented into this morphogenetic environment, and then reworked
huge alluvial formation spanning at altitudes between 800 and and moved down the hillside by melting processes [39,78]. In an
Andean paramo (Bogotà) the presence of an erosional surface re-

flecting geomorphic activity in the last glacial phase, separates the
Corresponding author.
E-mail address: jcloaiza@unal.edu.co (J.C. Loaiza).
andolization (during the Holocene) and paleosoils processes (Last

http://dx.doi.org/10.1016/j.grj.2017.07.001
2214-2428/© 2017 Elsevier Ltd. All rights reserved.
J.C. Loaiza et al. / GeoResJ 14 (2017) 20–35 21

Glacial and first part of Holocene) [37,46]. Three main factors have 2. Materials and methods
influenced the evolution of the landscape, sedimentation and veg-
etation development; (i) tectonic uplift of the Andes, (ii) develop- 2.1. Site description
ment of large tectonic sedimentary processes, sedimentation, (iii)
quaternary climatic fluctuations and glaciations [27]. Heretofore, The Fusagasuga alluvial megafan is located in the Sumapaz
there is scarce soil information in the area comes from medium- River basin (main tributary of the Magdalena River) which drains
scale surveys and a general review of soil characteristics [35]. Wet into the Sumapaz moorland. It is next to Fusagasuga village, 64 km
tropical soils, highly weathered and an enrichment of residual el- from Bogotá (Colombia) and covers an area of 52.5 km2 and 400 m
ements were described by Burak et al. [11]. The presence of gibb- thick (Fig. 1). The mean annual precipitation fluctuates 1080–
site concretions and redoximorphic features in the deepest hori- 1840 mm/year, and the mean monthly air temperature 14–26 °C.
zons suggests contrast climatic phases (moist and dry) in the past, Unfortunately, it is not possible to estimate paleoprecipitations in
more pronounced than nowadays [19] which is coincident with En- such tropical latitudes [47], however, frequent climatic changes oc-
gel et al. [18] that reported variation of moister, drier and arid peri- curred during the Quaternary; the perpetual snowline of the Suma-
ods in the Andean region during the last 50 0 0 years. Van der Ham- paz paramo descended to 3200 m.a.s.l. during Riss/Illinoian Glacial
men [73], report a dry tropical climate during the Paleogene and Stage, which led to a glacial cirque at the top (Chisacá lake) [55].
Neogene, with scarce and contrasted precipitation that results in a It was the source of coarse materials that were displaced as ice
sparse vegetation. Some studies by Villota [78] and Favre [19] re- and detritus flow [10,19]. During the glacial environment, the up-
port the presence of different grades of hydromorphism in these per montane forest extended up to 20 0 0 m.a.s.l., while in inter-
soils, not consequent with the present-day landforms where they glacial conditions it reached up to 3.200 m.a.s.l. [23,57]. During the
are located. According to Horton and DeCelles [31] active Andean Plio-Pleistocene, the climate was drier (Pal et al. [53]). Denudative
megafans would be affected by tectonic, climatic and geomorpho- processes, agradational, tectonic, hydrologic and volcanic activities
logic processes, this evidence indicates the presence of past glacia- have modelled the quaternary deposits, which are nowadays trans-
tionsin the paramo regions [26]. formed by anthropic activities.
The dominant pedogenetic processes under aquic conditions are The proximal sections of the megafan are colluvial-alluvial
ferrolysis, organic matter accumulation, clay formation and translo- while the middle and distal parts are alluvial. The megafan apex is
cation [77]. In order to elucidate the degree and type of water- at 1.800 m.a.s.l. (close to Fusagasugá city) and goes till 800 m.a.s.l.
logging, the morphological descriptions must pay attention to re- in Chinautá. The megafan is composed by heterometric materi-
doximorphic features, and should identify where oxidation and als, covered intermittently by Quaternary pyoclastic materials; in
reduction occur in the soil horizon in relation to the pore sys- some plateaus there are pebbles mixed with fine (clay and silt)
tem and the structure, in order to understand how water and air and medium (sand and gravels) alluvium [34]. The volcanic materi-
move through the horizon during both infiltration and drainage als come from the Ruiz-Tolima volcanic complex (Cordillera Central
[77]. In the Eastern cordillera of Colombia, the drainage organi- mountain range), with an age of volcanic deposition 30,0 0 0–10,0 0 0
zation is controlled by tectonic activity as it was found in the years B.P. (which covered the region with a thickness 60–120 cm
studies realized by Struth et al. [67]. Modern drainage network [74,75]. The underlying materials are sedimentary rocks from the
in Andean megafans may be inherited from an ancestral drainage Cretaceous and Tertiary periods of the Oriental Mountain range,
network [31]. Pedogenesis and thus the intensity of redoximor- overlying a Paleozoic rock basement with a low degree of meta-
phic processes can be traced back using several proxies identi- morphism [36]. This part of the mountain range is a section of an
fying pedofeatures from micromorphological studies, e.g. Fe de- uplift of 40 0 0 m.a.s.l. The Cretaceous deposits have a strong rela-
pletions, Fe-Mn impregnated hypocoatings and nodules related tion with the actual land geomorphology, folding and fault pres-
to redox environments in soils [5,41]. Minerals, as goethite, lep- ence. They are the main source of Tertiary and Quaternary sedi-
idocrocite, hematite or Mn oxides evidence alternating phases ments, are the parent material of most of the soils.
of reduction and oxidation [2,25,41]. An abrupt increase of iron
hypocoatings along water conducting voids (such as root channels 2.2. Field description and sampling
and slickenside surfaces) associated to iron depletion zones attests
poor drained conditions [50]. The combination of redox depletions This study was carried out along a EW transect (Fig. 2), where
around large pores (not connected with the pore system), and re- six points were selected considering different relief units ac-
dox concentrations within the peds indicates that reduction pro- cording to Birkeland et al. [4] methodology, mainly geormorpho-
ceeds along pores, reducing the iron that migrates into the aggre- logical position, environmental conditions and parental materi-
gates where it is oxidized [7,77]. The movement of water within als. Fig. 2 shows the location of the soil profiles in the topose-
horizons, at the scale of peds and macropores, could be inferred quence, under different positions and altitudinal ranks (paramo,
from the relationship between redox depletions and concentra- subparamo, moist climate and temperate climate). Soil profiles
tions, were ringed by Fe hypocoatings surrounded which are con- were described according to Soil Survey Manual [60] and classified
sidered weathering evidence [41,77]. with Soil Taxonomy [62] and IUSS Working Group (2015). Each soil
Soils of wetlands subjected to water seasonality can be studied profile was sampled for chemical, physical and mineralogical anal-
along drainage toposequences, as the intensity of hydromorphism yses, as well as for micromorphology according to Loaiza and Poch
changes from the lower parts to the surrounding rim and upland [42].
geomorphic positions [30]. No detailed investigations of Ultisol, Al-
fisol and Andisol genesis have been conducted in these Andean 2.3. Laboratory analyses
Paleo-hydrologic environments using micromorphology. Therefore,
the aim of this research was to enhance our understanding of Soil samples were analyzed in the national soil laboratory
wetland soil genesis and paleohydrology under tropical climates, of IGAC Bogotá (Colombia). Size distribution of mineral particles
through soils, their mineralogy and physico-chemical information (≤2 mm) was analyzed by Bouyoucos method [15]. Organic carbon
of the soils on the Fusagasuga megafan. was analyzed by moist digestion [79]. Soil reaction was measured
with a potentiometer (827pHLab Metrohm®) on a 1:1 soil-water
ratio. According SSS [61] cation-exchange capacity (CEC) and ex-
tractable bases were measured on a sample percolated with amo-
22 J.C. Loaiza et al. / GeoResJ 14 (2017) 20–35

Fig. 1. Location and geological units of the study area (line in red indicates the longitudinal profile Fusagasuga megafan shown in Fig. 2). (For interpretation of the references
to colour in this figure legend, the reader is referred to the web version of this article.)

nium acetate 1 N at pH 7.0. Exchangeable Al and H were measured interpretation was carried out with an Axio Lab-A1 Zeiss® micro-
by KCl extraction 1 N and extractable acidity by barium chloride scope, and was based on Stoops [65] and Loaiza et al. [43].
and trietanolamine at pH 8.2. Basic cations were measured in an
extract with ammonium oxalate at a pH 3. Active Al and Fe were
3. Results and discussion
extracted by sodium pyrophosphate 0.1 M at pH 10 and dithionite
citrate bicarbonate, and measured with an atomic absorption spec-
3.1. Soil profiles
trophotometer (Perkin Elmer SpectrAA-Pin AAcle 900T®). Available
phosphorus was measured with modified Bray-II method [8].
The main soil types along the studied toposequence are clas-
Soil samples for mineralogical analysis of clay and sand frac-
sified as Lithic Melanudands, Ultic Melanudands, Typic Paleudults,
tion were prepared according to Deng et al. [16]. The sand fraction
Typic Paleudalfs and Typic Haplustalfs [62], see Table 1. Their mor-
was studied with a petrographic microscope (Axio Lab-A1 Zeiss®)
phology (Table 2) shows clear clay accumulation features in B hori-
according to Tauler and Canals [70]. Clay mineralogy was ana-
zons, by clay coatings on aggregate sides and organoargillic coat-
lyzed by X ray diffractometer (X Empyrean PANanlyticcal’s®) ac-
ings filling cracks and root channels with frequent to abundant
cording to Brindley and Brown [9]. Thin sections were prepared
grey spots, which are common on middle and footslope position.
at national soil laboratory of IGAC (Bogotá, Colombia). After drying
Redoximorphic features (nodules of Fe-oxihydroxides, Fe-depletion
for six weeks at room temperature, the undisturbed samples were
hypocoatings, and Fe-oxihydroxides quasicoatings around pores)
impregnated with polyester resin and let harden for another six
occur throughout all studied soils deposits except on the anticline
weeks. Slabs were cut with a diamond knife and polished with a
steep slope mountain soil (top of the sequence) affected by glaciers
polishing machine (Thin Sectioning System Petrothin Buehler Ltd®)
and characterized by a lithic contact (with the fresh rock), and by
to obtain a thickness up to 20 μm. Thin section description and
krotovines mixing the volcanic ashes with the underlying mate-
J.C. Loaiza et al. / GeoResJ 14 (2017) 20–35 23

Fig. 2. Longitudinal profile Fusagasuga megafan with a schematic representation of the toposequence and horizonation of the soil profiles. The vertical scale of the profiles
(at the right) is exaggerated with respect to that of the relief. Profiles 1–2 are Melanudands, profile 3 is a Paleudult, profiles 4 and 5 Paleudalfs and profile 6 is a Haplustalf.

Table 1
Environmental information of the six soil pedons.

Pedon Geomorphological position Slope Altitude Holdridge life zone Solum Soil classification
(%) (m.a.s.l.) thick-
ness
(cm)

WRB [80] Soil Taxonomy (2014)

JS1 Structural mountain surface 7–12 3940 Lower montane Wet 28 Leptic, Dystric Andosol Lithic Melanudands
forest (Protoandic, Melanic)
JS2 Sloped colluvial-alluvial 12–25 3280 Lower montane Wet 120 Umbric, Dystric Andosol Ultic Melanudands
megafan forest (Protoandic, Melanic)
JS3 Upper middle alluvial 12–25 2140 Premontane Moist 120 Nudiargic Haplic Alisol Typic Paleudults
megafan forest (Cutanic, Profundic)
JS4 Middle high alluvial 0–1 1660 Subtropical Dry forest 110 Nudiargic Haplic Lixisol Typic Paleudalfs
megafan. (Cutanic, Profundic)
JS5 Middle low alluvial 0–1 1348 Subtropical Dry forest 120 Nudiargic Haplic Lixisol Typic Paleudalfs
megafan. (Cutanic, Profundic)
JS6 Low alluvial megafan 0–1 1100 Subtropical Dry forest 100 Nudiargic Haplic Lixisol Typic Haplustalfs
(Cutanic, Hypereutric)

rial. This lithic contact and lithological discontinuities are related the dominant pedogenetic processes which can only be interpreted
to an arid erosion phase followed by humid and warmer periods in terms of changes of the climatic environment. The argillic hori-
at the Holocene, during which humiferous soils were developed zon is indicated by clay coatings and infillings and by the textural
under forest and grass conditions [21,46]. According to Soil Tax- analyses of the Btg (Table 3, a ratio greater than 1.2 for the clay
onomy [62], this soil is a silty loam, has andic properties, an udic concentration in B and A horizons), while the A horizon has clear
soil moisture regime and a dark melanic horizon (colour 10YR2/1), andic properties. On deep horizons the base saturation is less than
thus it was classified as a Lithic Melanudand. 35%. It was classified as Ultic Melanudand.
Huge subangular rock blocks and heterometric colluvia made The soil on the middle megafan position also shows clay
of boulders and pebbles of sandstones and lutites are common in coatings together with gley conditions (Btg) and nodules of Fe-
the soils at all toposequence positions. Weathered rock fragments oxihydroxides and clay (Btv) together with Fe depletions. It is clas-
are present in the lowest part of the soil profiles. The soil on the sified as a Typic Paleudalf. The lower megafan footslope soil has
uppermost megafan position is polygenetic and has few clay coat- clay (kaolinite) fragmented coatings throughout its Bt-horizon. It
ings on ped faces and pores in its Btg-horizons. According to Fol- has an ustic moisture soil regime and keys out as a Typic Hap-
ster et al. [22] soil morphology (redox features) reflects changes in lustalf.
24 J.C. Loaiza et al. / GeoResJ 14 (2017) 20–35

Table 2
Morphology of the studied profiles in Fusagasuga megafan, Colombia.

Horizon Depth (cm) Munsell colour Texture Structure Consistence Coatings, Fe Observations
(moist)

JS1
A 0–28 10YR2/1 SL Sbl, moderate, Fr, slightly Stk, – NaF strong reaction. depth of the horizon, this can
medium and fine slightly Pl fluctuate between 28,36,41 cm thick
tendence to Gr fine

R 28–100 – – – – –
JS2
Ap 0–30 10YR2/1 SLC Sbl, moderate to Fr, slightly Stk, – Strong reaction to NaF and frequent presence
strong, coarse, slightly Pl krotovinas in the first two horizons.
medium and fine

AB 30–49 10YR3/2 SC Sbl, moderate to Fr, Stk, Pl –


strong, medium,
tendence to Gr fine
2Btg1 49–70 10YR6/8 C Sbl, strong, fine and Fr, Stk, Pl –
10YR6/2 medium
2Btg2 70–120 10YR6/1 C Abl, moderate to very firm, very –
10YR6/8 strong, medium and Stk, very Pl
fine
JS3
Ap 0–23 10YR3/3 SC Abl, moderate to Fr, slightly Stk, – No reaction to NaF
strong, medium and slightly Pl
coarse

2Btg1 23–54 10YR5/2 C Abl, moderate to very firm, Stk, Pl Clay coatings
10YR5/8 strong, coarse and
medium
2Btg2 54–70 10YR5/2 C
10YR5/8
Abl, very firm, Stk, Clay coatings
moderate Pl, fine pores
to strong, regular
medium medium
and fine
2Btg3 70–92 7,5YR5/8 C Abl, moderate to very firm, very Clay coatings
7,5YR5/1 strong, medium and Stk, very Pl
fine
2Btg4 92–120x 7,5YR5/8 C Abl, moderate to very firm, very Clay coatings
7,5YR5/1 strong, medium and Stk, very Pl
fine
(continued on next page)
J.C. Loaiza et al. / GeoResJ 14 (2017) 20–35 25

Table 2 (continued)

Horizon Depth (cm) Munsell colour Texture Structure Consistence Coatings, Fe Observations
(moist)

JS4
Ap 0–25 10YR3/1 S Sbl, moderate, Fr, Stk, Pl No reaction to NaF. Between the surface of the Hz A
medium and fine and AB are present rock fragments 2 and 3 cm in
diameter, dark colors and reddish yellow. Presence of
boulders within the profile from the surface to 1 m
(15%).

AB 25–45 10YR3/1 SC Abl, moderate, fine Fr, Stk, Pl Speckled Fe


5YR4/6
2Btg1 45–59 5YR3/1 C Abl, moderate, very firm, Stk, Pl Clay coatings
7,5YR4/6 medium and fine
10YR3/1
2Btg2 59–88 5YR6/2 C Abl, moderate, fine very firm, very Clay coatings
10YR3/1 Stk, very Pl
10YR5/8
2Btg3 88–110 7,5YR6/8 C Massive very firm, very Clay coatings
10YR2/1 Stk, very Pl
JS5
Ap 0–18 10YR5/3 SC Abl, moderate, Fr, slightly Stk, – No reaction to NaF. Migration of organic matter
medium and fine slightly Pl between the cracks up to 70 cm deep. In some sectors
intercalated banded from 66 cm to 120 cm or gray
colors mixed (5YR6/1) are observed; Reddish
(2,5YR4/8) and yellow (7,5YR5/8). Presence of boulders
subrounded of 36 cm in diameter. Weathered presence
of fragments of up to 40 cm in diameter with irregular
coloration 2, 5YR4/8. Cracks in the gray color (5Y6/1)
up to 4 cm deep, gray-yellow up to 4 cm deep, reddish
up to 7 cm deep, reddish-yellow 8 cm deep.

2Btg1 18–56 10YR5/6 C Abl, moderate, extremely firm, Clay coatings


10YR2/1 medium and heavy Stk, Pl
2Btg2 56–79 10YR5/8 SC Abl, moderate, very firm, Stk, Pl –
10YR5/2 medium and coarse
2Btv 79–103 5YR5/6 SC Abl, moderate, fine Firm, Stk, Pl Fe mottles
5YR5/1
2Btg 103–117 5YR6/1 SC Abl, moderate, fine Firm, Stk, Pl Fe mottles
5YR5/6
2Cv 117–120 5YR5/6 C Massive Firm, very Stk, Fe mottles
5YR6/1 very Pl
(continued on next page)

3.2. Physico-chemical properties native Fe coatings, and Fe depletion hypocoatings along pore walls
and aggregate surfaces, some of them associated to the present
All soils in this toposequence have high clay contents except pore system and some with palaeofeatures [2,5,30]. All soils follow
the uppermost one (SJ1), with increasing concentrations of clay the general trend of having the highest organic matter content in A
with depth, which indicates that either translocation of clay inside horizons (8.8–16.9%), associated to the presence of volcanic ashes.
soil profile or transformation of primary minerals to clay minerals According to Nanzyo et al. [49], humus as well as noncrystalline
[12,58,64] has taken place. Absence of lithologic discontinuites was clays, contribute to the unique chemical and physical properties of
confirmed by morphological characterization, sand and clay miner- Andisols.
alogy [56]. Hydromorphic pedofeatures in the gley horizons (Btg) The pH’s of soils on the crest and uppermegafan are very strong
include hard and soft iron oxyhidroxides concretions and impreg- acidic and are uniform with depth. On middle and lower megafan
26 J.C. Loaiza et al. / GeoResJ 14 (2017) 20–35

Table 2 (continued)

Horizon Depth (cm) Munsell colour Texture Structure Consistence Coatings, Fe Observations
(moist)

JS6
Ap 0–26 10YR3/2 SC Sbl, weakly Fr, slightly Stk, – Presence of rock blocks in the profile, 1 m in diameter.
developed, very slightly Pl Moderate reaction to NaF in the Bt2 horizon.
medium and fine

AB 26–33 5YR5/8 C Sbl, moderate to very firm, Stk, Pl Clay coatings


10YR3/2 strong, médium and
10YR2/1 fine
Bt1 33–49 10YR3/2 C Sbl, strong developed, Firm, Stk, Pl Clay coatings
10YR8/1 medium and fine
Bt2 49–59 10YR3/2 SCSa Abl, strong Firm, slightly Stk, Clay coatings
2,5Y7/4 developed, medium slightly Pl
and fine
Bt3 59–82 10YR3/2 C Abl, moderate, very firm, Stk, Pl Clay coatings
2,5Y7/4 médium to fine
Bt4 82–100× 10YR5/6 C Abl, moderate, very firm, Stk, Pl Clay coatings
10YR5/8 médium to fine
Abl: angular blocks, Sbl: subangular blocks, Gr: grain, C = clay, Sa = sand, L = loam, S= Silt, Fr: Friable, Pl: plastic, Stk: sticky.

Table 3
Chemical characteristics of the studied profiles.

Horizon Depth (cm) CIC Ca Mg K Na ESP TEB Al BS OC P pH CaCO3 Al-S A-Al A-Fe Al + 1/2 Fe PR Clay
Cmol(+)/kg % % Mg/kg (1:1) % (Oxalate) % %

JS1
A 0–28 66.7 0.48 0.21 0.23 0.17 0.3 1.09 9.3 1.6 16.9 3.3 4.3 – 89.5 1.71 0.54 1.98 84.72 –
R 28–100 – – – – – – – – – – – – – – – – – – –
JS2
Ap 0–30 43.0 0.38 0.08 0.27 0.04 0.1 0.10 5.3 1.79 8.8 20.5 4.8 – 87.3 1.58 0.86 2.01 91.91 42.4
AB 30–49 30.4 0.35 0.06 0.11 0.04 0.1 0.20 4.2 1.84 3.1 3.0 4.7 – 88.2 0.98 0.96 1.46 92.55 47.4
2Btg1 49–70 24.2 0.61 0.25 0.08 0.06 0.2 1.0 11.7 4.13 0.96 ND 4.8 – 92.1 0.44 0.54 0.71 – 47.8
2Btg2 70–120 21.1 0.48 0.37 0.12 0.37 1.8 1.80 14.6 6.32 0.26 ND 4.7 . 91.6 0.29 0.71 0.65 – 51.0
JS3
Ap 0–23 24.5 20.5 2.4 2.0 0.17 0.7 25.07 – 100 2.3 1174 7.5 ++ – 0.25 0.96 0.73 – 45.4
2Btg1 23–54 23.5 3.4 0.81 0.81 0.10 0.4 5.12 15.2 21.79 0.60 31.2 4.6 – 74.8 0.23 0.27 0.37 – 75.3
2Btg2 54–70 21.7 1.8 0.86 0.62 0.06 0.3 3.34 16.8 15.39 0.33 19.5 4.5 – 83.4 0.22 0.20 0.32 – 72.0
2Btg3 70–92 21.9 1.4 0.91 0.52 0.06 0.3 2.89 13.8 13.20 0.36 11.9 4.5 – 82.7 0.24 0.64 0.56 – 70.6
2Btg4 92–120 18.2 0.71 0.77 0.47 0.08 0.4 2.03 14.0 10.80 0.17 15.2 4.5 – 87.3 0.17 0.51 0.43 – 72.7
JS4
Ap 0–25 11.1 6.2 0.59 0.08 0.16 1.4 7.03 – 63.30 1.5 12.1 6.6 – – 0.11 0.04 0.13 – 23.0
AB 25–45 12.3 4.8 0.74 0.08 0.28 2.3 5.9 – 48.0 1.0 0.14 6.5 – – 0.14 0.35 0.32 – 40.4
2Btg1 45–59 10.1 3.9 0.71 0.09 0.31 3.1 5.01 – 49.6 1.1 ND 6.2 – – 0.12 0.35 0.30 – 43.1
2Btg2 59–88 7.4 2.7 0.31 0.08 0.36 4.9 3.45 – 46.6 0.27 ND 5.7 – – 0.11 0.25 0.24 – 40.2
2Btg3 88–110 7.8 3.3 0.22 0.05 0.44 5.6 4.01 – 51.4 0.07 ND 5.7 – – 0.07 0.20 0.17 – 41.6
JS5
Ap 0–18 10.1 4.4 0.65 0.39 0.41 4.1 5.85 – 57.9 1.8 24.5 5.5 – – 0.01 0.28 0.15 – 22.2
2Btg1 18–56 14.4 5.6 2.2 0.23 1.3 9.0 9.33 – 64.8 0.51 ND 6.8 – – 0.16 0.21 0.27 – 60.9
2Btg2 56–79 13.4 5.4 2.7 0.21 3.6 26.9 11.91 – 88.9 0.11 ND 7.1 – – 0.02 0.17 0.11 – 72.9
2Btv 79–103 15.6 5.7 2.9 0.11 3.8 24.4 12.51 – 80.2 0.07 ND 7.1 – – 0.1 0.17 0.19 – 74.0
2Btg 103–117 17.7 10.4 3.7 0.13 4.7 26.6 18.9 – 100 0.11 1.1 7.1 – – 0.1 0.14 0.17 – 88.5
JS6
Ap 0–26 3.1 2.4 0.52 0.36 0.16 5.2 3.44 – 100 0.43 75 6.3 – – – – – – 7.4
AB 26–33 11.9 6.0 3.0 0.23 3.6 30.3 12.83 – 100 0.42 3.2 7.7 – – – – – – 37.1
Bt1 33–49 20.5 17.5 5.1 0.18 6.3 30.7 29.08 – 100 0.2 14.5 8.7 ++ – – – – – 19.8
Bt2 49–59 21.3 12.7 5.4 0.2 7.8 36.6 26.1 – 100 0.24 31.0 8.6 ++ – – – – – 32.8
Bt3 59–82 15.1 6.7 4.0 0.2 7.2 47.7 18.1 – 100 0.04 48.8 8.6 + – – – – – 15.0
Bt4 82–100 24.2 7.8 5.9 0.31 10.2 42.1 24.21 – 100 0.1 10.8 7.9 + – – – – – 76.5

TEB: total exchangeable bases, ESP: Exchangeable Sodium Percentage, BS: base saturation, OC: organic carbon, Al-S: aluminum saturation, A-Al: active aluminum, A-Fe:
active iron, PR: phosphate retention, ++ Common (15–30%); + Presence (5–15%).
J.C. Loaiza et al. / GeoResJ 14 (2017) 20–35 27

position soils, pH changes from strong to medium acidity and de- could be considered new formed in highly weathering environ-
creases with depth. The soils at the lowest megafan position are ments both on ultisols and alfisols [3,54,64]. On the other side,
neutral to moderately basic and the pH increases with depth. quartz is related to selective accumulation due to its relative re-
The low pH values of the soils on the highest positions, due to sistance to weathering and slight increase in the energy of colu-
the variable charge of kaolinite and iron oxides common in tropi- vial deposition, since it occurs in the sand fraction [17,48,54]. Be-
cal soils [38] indicate that acidic weathering and leaching of basic sides, all the profiles show traces of one or several of the follow-
cations are the dominant pedogenic processes; whereas the higher ing minerals: Integrated 2:1–2:2, Metahalloysite, Halloysite, Cristo-
pH values and base saturation of soil on the medium and low- balite and Goethite as it can be seen in Table 5. The lowest part
est megafan positions associated to a drier environment, lead to of the megafan is poorly drained and has a high base saturation. It
the formation of alfisols. Cation exchange capacities are very vari- has important amounts of metalloysite and non crystalline miner-
able (3.1–66.7 cmol(+)/kg), the highest values being found in the A als, increasing in depth. These changes suggest a present-day for-
horizons on Andosols where organic matter is abundant, whereas mation of clays other than kaolinite, since these soils have proba-
soils on the medium and lowest parts of the megafan have the bly been truncated by multiple arid erosional cycles [53].
lowest CEC values, which is coincident with kaolinite abundance. The coarse fraction is dominated by quartz, feldspars and al-
Consequently, total exchangeable bases and base saturation are tered grains (lithic fragments of sandstones, mudstones and clay-
higher in the middle and lower megafan positions. Al and Fe are stones), with some traces of zircon, amphiboles, magnetite, horn-
highest in the A horizons due to the input of volcanic ashes [49]. blende, tourmaline and lithic fragments (see photos of Table 6).
Conversely, low concentrations of Al and Fe in absence of ashes Ashley et al. [1] reported quartz-feldspar composition in the low
and in underlying horizons are a result of periodical reduction and gradient depositional environment under alluvial fan system in a
removal of dissolved iron in laterally seeping ground water [5,69]. dry conditions and paleo lake conditions in Tanzania. According
The chemical properties of these soils can be viewed in Table 3. to Stoops [66], sand fraction in well drained oxic materials con-
All soils on the top and middle of Fusagasuga megafan topose- sist of the least weatherable minerals,-mainly quartz-with zircon
quence have high aluminium and low base saturation in accor- and tourmaline as the most common accessory components. The
dance with the dominance of kaolinite and iron oxide minerals. traces of phytoliths are indicative of materials derived from vol-
The basic cations (Ca, K and Mg) are found in low concentrations canic ashes [63,64]. According to Sedov et al. [58] a notable fea-
in the epipedons in all soils except JS3. This trend is typical for ture of many Andosols and other soils on volcanic ash is the high
evolved soils or highly weathered materials according to Stoops concentration of phytoliths in the silt fraction.
et al. [64] and Thanachit et al. [71]. The higher concentrations of Concentrations of minor minerals (Table 6) in this toposequence
Fe and Al in soils on the upperslope and in some horizons of soils are in the same range as other soils in high weathering environ-
on backslope positions are associated with typic Fe nodules and ments, as reported by Thanachit et al. [71] and Pal et al. [53].
halos with strong impregnation degree (see Fig. 3a-E, a-F, b-I). A Quartz and zircon contents in depth at all soil positions are quite
selective retention of sodium, shown by a higher ESP in the lower uniform (Table 6); these minerals are very resistant minerals ac-
horizons is remarkable, although it does not reach the levels nec- cording to Sudom and Arnaud [68] and Duchaufour [17] his pres-
essary to diagnose sodicity. ence indicates the homogeneity of the underlying material, in op-
Although soil acidity is a common feature in almost all soils, at position to the differences on the topsoil, affected by volcanic
depths below 30–60 cm the values strongly differ among profiles ashes in the mountainous areas, and colluvial material at the dis-
(Table 4). This is probably due to the cation interchange from sea- tal part of the megafan. The presence of the Fe minerals as goethite
sonal water table fluctuation in depth, that tend to enhance leach- and lepidocrocite traces in clay fraction is due to alternating phases
ing of cations linked to the alternation of Fe(II)-Fe(III) due to the of reduction and oxidation [2,5,54,71].
seasonal reduction-oxidation, that may increase acidity at some
depth. Those materials are related to truncated and transported pa- 3.4. Micromorphological features
leosols relicts as a result of the great degradational phase which
reshaped the soil mantle probably between 20,0 0 0 and 10,0 0 0 The soil micromorphological descriptions are summarized in
years B.P [22]. Depending upon the degree of weathering, and/or Table 4. The most important features are discussed below. The top-
the depth of truncation of this origin cover, different types of soils soils of many of the soils are formed on volcanic ashes. The A
may form poor ultisols on the upper slope, clay rich soils in de- horizon of the highest soils of the toposequence corresponds to
pressions and azonal soils than volcanic ashes soils in mountain a Lithic Melanudand and on a steep mountainous relief. The mi-
areas [66]. cromass is isotropic due to the presence of amorphous clays to-
The OM contents are low in depth, except in the SJ4 soil profile. gether with amorphous organic matter (Fig. 3a-A). The nature and
In these soils, some small changes in the OM content will be asso- distribution of organic matter indicates the influence of volcanic
ciated to ancient seasonal conditions that favoured OM deposition ashes and a high pedogenic alteration resulting in an andolization
in a concave microrelief. The Andean tectonic episodes originated process. The presence of noncrystalline materials evidences a rapid
complex isohumic soil profiles in Colombia, on deep lateritic ma- weathering (see Table 5). According to Shoji et al. [59] preferential
terials, not associated to the actual climatic conditions, at altitudes formation of noncrystalline materials such as allophane, imogolite,
close to 30 0 0 m.a.s.l. [19]. laminar opaline silica, ferrihydrite, and Al/Fe humus complexes is
The high base saturation, higher values of Na+ that point to a characteristic feature of the process of andolization. The result-
sodicity at the middle and distal positions, and the relative high ing undifferentiated b fabric is very normal in soils developed on
amounts of Mg2+ compared to Ca2+ in some horizons are remark- volcanic ashes [58]. Besides, the development of a granular mi-
able, but this is not translated into a different clay formation (e.g. crostructure is common in andosols and reflects the abundance
expanding 2:1 clays). of noncrystalline and organic materials, and supports the theory
of biological origin [58,59]. The rest of the topsoils with volcanic
3.3. Soil mineralogy ashes correspond to soils formed on colluvio-alluvial material on
the medium part of the slope, with A/AB/2Btg1/2Btg2 horizons in-
Soil mineralogy is fairly uniform among all the profiles. Kaoli- side soil profile.
nite dominates the clay in all of them, together with quartz The JS2 profile has a subangular blocky microstructure, and a
(Table 5). Kaolinite is a characteristic weathering product that total porosity decreasing in depth. The groundmass of the topsoil
28 J.C. Loaiza et al. / GeoResJ 14 (2017) 20–35

Fig. 3. (a) Thin section of profiles JS1, JS2, JS3. A: Accumulation of humic substances. Profile JS1 horizon Ah (0–28 cm), 2,5× (PPL). B: Fabric of the groundmass stipple
speckled b-fabric. Coarse/fine related distribution is porphyric. Subangular blocks are present separated by channels and flat. Profile JS2 horizon Ap (30–49 cm) (2,5× PPL).
C–D. Dusty clay coating, not directly related to the pore system, and striated b-fabric. Profile JS2 horizon 2Btg2 (70–120 cm), (PPL and XPL). E–F: Microlaminated clay and
Fe-oxide intercalations. Profile JS3 horizon 2Btg2 (54–70 cm)(PPL and XPL). (b) Thin section of profiles JS4, JS5, JS6. G: Rounded disorthic Fe nodule. Profile JS4 horizon
AB (24–36 cm), (PPL). H: Red colours due to Fe-oxides in the groundmass. Aggregates are partially separated by planar pores. Profile JS4 horizon 2Btg1 (38–49 cm), (PPL).
I: Ferruginous hypocoating on a pore (down) and orthic impregnating nodule (up) indicating a stagnic pattern. Profile JS5 horizon Ap (0–18 cm) (PPL). J–K: Coatings of
microlaminated clay and iron hypocoatings of Fe. Profile JS6 horizon Bt (18–60 cm) (PPL and XPL). (For interpretation of the references to colour in this figure legend, the
reader is referred to the web version of this article.)
J.C. Loaiza et al. / GeoResJ 14 (2017) 20–35 29

Table 4
Main micromorphological characteristics and redoximorphic pattern (when clearly expressed).

Profile Horizon Micromass/b-fabric Pedofeatures/Redoximorphic pattern

JS1 A Organic matter and clay, black/undifferenciated Passage features by faunal activity.
JS2 Ap Yellowish-red, clay, fine silt and organic (1) Faunal passages, very frequent, mixing materials of the underlying horizons; (2)
pigment/undifferenciated Nodules of Fe-oxihydroxides, anorthic, impregnative, rounded, equant.
AB Yellow, fine silt and clay/cross-striated and (1) Faunal passages, very frequent, mixing materials of the underlying horizons; (2)
stipple speckled Nodules of Fe-oxihydroxides, anorthic, impregnative, rounded, equant; (3) Loose
discontinuous infillings of excrements in channels.
Btg1 Yellowish-red, fine clay and silt/cross-, (1) Clay intercalations, coatings and infillings, mottled, 2nd order interference colours
granostriated and mosaic speckled due to Fe impregnation; (2) some fragmented and deformed Fe-depletion
hypocoatings, and Fe-oxihydroxides quasicoatings around pores; (3) Nodules of
Fe-oxihydrox., moderately impregnated, orthic; (4) Faunal passages and mixing of
materials from other horizons./STAGNIC
Btg2 Grey, fine clay and silt/cross striated and mosaic (1) Clay coatings and infillings, mottled, 1st order interference colours; (2)
speckled Intercalations, hypo- and quasicoatings of Fe-oxihydroxides; (3) Nodules of
Fe-oxihydroxides, moderately to strongly impregnated, orthic; (4) Faunal passages and
mixing of materials from other horizons./GLEYIC
JS3 Ap Dark brown, clay, fine silt and organic (1) Faunal passages, very frequent, mixing materials of the underlying horizons; (2)
pigment/undifferenciated Nodules of Fe-oxihydroxides, anorthic, impregnative, rounded, equant.
Btg1 Greyish brown, clay, fine silt/cross-, granostriated (1) Clay infillings, mottled, oriented; (2) Nodules of Fe-oxihydroxides, moderately to
and mosaic speckled strongly impregnated, orthic; (3) Hypocoatings of Fe-oxihydroxides; (4) Pseudomorphs
of Fe-oxihydroxides after root residues.
2Btg2 Reddish brown, clay and fine silt/stipple specked, (1) Faunal passages, very frequent, mixing materials of the underlying horizons; (2)
slightly granostriated Hypocoatings of Fe-oxihydroxides; (3) Nodules of Fe-oxihydroxides, strongly
impregnated, orthic and disorthic./STAGNIC
2Btg3 Greyish, clay, fine silt/cross- and granostriated Nodules and intercalations of Fe-oxihydroxides, slight to strongly impregnated,
orthic./GLEYIC
JS4 Ap Dark brown, clay, fine silt and organic (1) Nodules of Fe-oxihydroxides, strongly impregnated, disorthic and anorthic; (2)
pigment/undifferentiated Hypocoatings of Fe-oxihydroxides; (3) Pseudomorphs of Fe-oxihydroxides after root
residues.
AB Dark brown, clay, fine silt and organic (1) Nodules of Fe-oxihydroxides, strongly impregnated, disorthic and anorthic; (2)
pigment/undifferenciated Hypocoatings of Fe-oxihydroxides; (3) Pseudomorphs of Fe-oxihydroxides after root
residues.
2Btg1 Dark brown, clay, fine silt and organic (1) Nodules of Fe-oxihydroxides, strongly impregnated, disorthic and anorthic; (2)
pigment/undifferenciated Hypocoatings of Fe-oxihydroxides; (3) Pseudomorphs of Fe-oxihydroxides after root
residues; (4) Intercalations and infillings of kaolinite, limpid, microlaminated.
2Btg2 Irregular mixture of patches of dark brown, clay, (1) Nodules of Fe-oxihydroxides, strongly impregnated, disorthic and anorthic; (2)
fine silt and organic pigment and iron-rich Hypocoatings of Fe-oxihydroxides; (3) Pseudomorphs of Fe-oxihydroxides after root
micromass/undifferenciated residues (4) Intercalations and infillings of kaolinite, limpid, microlaminated (more
abundant than overlying 2Btg1); (5) Faunal passages.
C/2Btg3 Irregular mixture of patches of dark brown, clay, (1) Nodules of Fe-oxihydroxides, moderately impregnated, orthic inside the aggregates;
fine silt and organic pigment and iron-rich (2) Hypocoatings of Fe-oxihydroxides; (3) Intercalations and infillings of kaolinite,
micromass/undifferenciated limpid, microlaminated (more abundant than overlying 2Btg2); (4) mottled coatings of
clay, silt and organic punctuations; (5) Faunal passages.
JS5 Ap Yellowish brown, clay, fine silt and organic (1) Nodules of Fe-oxihydroxides, strongly impregnated, anorthic; (2) Hypocoatings of
pigment/stipple speckled Fe-oxihydroxides around root channels; (3) Pseudomorphs of Fe-oxihydroxides after
root residues; (4) Fragments of kaolinite coatings; (5) Clay hypocoatings around
channels, between sand particles
A Yellowish brown, clay, fine silt/stipple speckled (1) Nodules of Fe-oxihydroxides, strongly impregnated, orthic and disorthic; (2)
Fe-depletion hypocoatings of around root channels; (3) Coatings and infillings of
kaolinite, around pores, mottled due to organic punctuations, very thick (2–3 mm),
distorted and fragmented; (4) Fragments of kaolinite and iron coatings in the
groundmass/STAGNIC, Fe-depletion and dirty clay coatings around voids
2Btg1 Yellowish brown, clay, fine silt/mosaic speckled, (1) Nodules of Fe-oxihydroxides, strongly impregnated, orthic; (2) Fe-depletion areas,
slight cross striation roughly around pores, vertical and horizontal; (3) Coatings and infillings of kaolinite,
around pores, the horizontal ones mottled due to organic punctuations, very thick
(2 mm), distorted (irregular extinction patterns); (4) Fragments of kaolinite and iron
coatings in the groundmass/STAGNIC
2Btg1 Yellowish brown, clay, fine silt/mosaic speckled (1) Nodules of Fe-oxihydroxides, strongly impregnated, orthic; (2) Hypocoatings of
Fe-oxihydroxides around root channels; (3) Coatings and infillings of kaolinite, around
pores, mottled due to organic punctuations, very thick (2 mm), distorted (irregular
extinction patterns); (4) Fragments of kaolinite and iron coatings in the groundmass;
(5) Faunal passages/STAGNIC-GLEYIC
2Btg2 Greyish clay, fine silt/mosaic speckled, cross-, (1) Aggregate nodules of Fe-oxihydroxides and clay, strongly impregnated, orthic,
poro- and grano-striation fragmented by faunal activity; (2) Hypocoatings of Fe-oxihydroxides around root
channels; (3) Coatings and infillings of kaolinite, around pores, some microlaminated,
some mottled due to organic punctuations, very thick (2 mm), distorted (irregular
extinction patterns); (4) Faunal passages/GLEYIC
2Btv Greyish clay, fine silt/mosaic speckled, cross-, (1) Aggregate and typic nodules of Fe-oxihydroxides and clay, strongly impregnated,
poro- and grano-striation orthic, fragmented by faunal activity; (2) Fe-depletion areas, roughly around some
pores; (3) Coatings, intercalations and infillings of kaolinite, around pores, some
microlaminated, some mottled due to organic punctuations, very thick (2 mm),
distorted (irregular extinction patterns), occupying about 40% of the section; (4) Clay
rich areas with vesicular microstructure and strongly impregnated with purple iron
oxi-hydroxides following a reticular pattern; (5) Faunal passages /STAGNIC, more clayed
JS6 Ap Dark grey clay, fine silt and organic Nodules of Fe-oxihydroxides, strongly impregnated, anorthic. STAGNIC
pigment/undifferenciated
(continued on next page)
30 J.C. Loaiza et al. / GeoResJ 14 (2017) 20–35

Table 4 (continued)

Profile Horizon Micromass/b-fabric Pedofeatures/Redoximorphic pattern

AB Grey clay and fine silt/stipple speckled (1) Few kaolinite coatings, microlaminated to irregular extinction pattern, around
channels; (2) Faunal pasajes.
Bt1 Grey clay and fine silt/stipple to mosaic speckled (1) Kaolinite-rich nodules, and intercalations, probably fragmented clay coatings, with
parallel- and cross striated b-fabric,; (2) Few microlaminated kaolinite infillings; (3)
Faunal passages.
Bt2 Grey clay and fine silt/cross-, grano- and (1) Kaolinite-rich nodules, and intercalations, probably fragmented clay coatings, with
porostriated parallel- and cross striated b-fabric; (2) Kaolinite coatings, microlaminated to irregular
extinction pattern, around channels; (3) Disorthic nodules of Fe-oxihydroxides, strongly
impregnated./GLEYIC

Table 5
Mineral composition of the clay fraction in the studied soils and associated difractograms.

Hz Depth Vermiculite Smectite Kaolinite In Ig Ih Metahalloisite Halloisite Mica Cristobalite Quartz Lepidocrocite Goethite Non
(cm) crystalline

JS1
A 0–28 – – – – – – – – – +++ +++ – – +
R 28–100 – – – – – – – – – – – – – –
JS2
Ap 0–30 – – +++ – tr tr – tr – tr ++++ – – –
AB 30–49 – – +++ – ++ tr – tr – – +++ – – –
2Btg1 49–70 tr – +++ – + tr – tr tr – ++++ – tr –
2Btg2 70–120 + – +++ – tr tr – – + – +++ tr tr –
JS3
Ap 0–23 – – ++++ tr – tr – – + tr ++ tr tr –
2Btg1 23–54 – – ++++ + – + – – tr – ++ tr + –
2Btg2 54–70 – – ++++ ++ – tr – tr tr – ++ tr tr –
2Btg3 70–92 – – ++++ + – tr – tr + – ++ + + –
2Btg4 92–120 – – ++++ ++ – tr – tr + – ++ – tr –
JS4
Ap 0–25 – – +++ – – – ++ – – + +++ – – –
AB 25–45 – – ++ – – – ++ – – + +++ tr tr –
2Btg1 45–59 – – +++ – – – tr – – + +++ – + –
2Btg2 59–88 – – +++ – tr – – – – – +++ tr + –
2Btg3 88–110 – – +++ – – – tr – – tr ++ – tr –
JS5
Ap 0–18 – – ++++ – – – – – – + +++ – – –
2Btg1 18–56 – – ++++ – tr – – – – tr tr – tr –
2Btg2 56–79 – – ++++ tr tr – – – – – tr – tr –
2Btv 79–103 – – ++++ – – – tr – – – ++ – tr –
2Btg 103– – – ++++ – – – – – – – tr – – –
117
JS6
Ap 0–26 – – ++ – – – ++ – – + ++++ – – +
AB 26–33 – ++ ++ tr – – ++ – – – + – – ++
Bt1 33–49 – – +++ – tr – – – – tr ++ – – +
Bt2 49–59 – tr +++ + tr – +++ – – tr ++ – – ++
Bt3 59–82 – – +++ tr + – +++ – – tr ++ – – +
Bt4 82–100 – – ++++ tr tr – – – – tr +++ – – +

In: Interbedded, Ig: Integrated 2:1–2:2, Ih: Interbedded hidrobiotite∗ Metahalloysite, ++++ Dominant (> 50%); +++ Abundant (30–50%); ++ Common (15–
30%); + Presence (5–15%); trTraces (< 5%).

contains rests of weathering minerals (e.g. weathering hornblende) canic ashes; and it becomes grano- and cross-striated below. The
in the coarse fraction, and the micromass has an undifferenciated redoximorphic features are iron nodules (anorthic and disorthic in
b-fabric (typical on amorphous clays) which would indicate the the Ap horizon, orthic and disorthic below), weakly to strongly im-
volcanic origin. The rest of the profile is cross-striated and mosaic pregnated. Microlaminated clay coatings are only evident in the
striated, according to the soil micromorphology analysis method of upper Bt horizon, (Fig. 3a-E and a-F) being not evident below. This
Stoops [65]. could be due to the masking effect of coatings and hypocoatings of
Pedofeatures in the Btg horizons are textural and consist of iron oxides on the clay coatings. Again, the redoximorphic pattern
microlaminated and speckled clay coatings probably of kaolinite is stagnic in the upper horizons and gleyic in the lowermost one,
(Fig. 3a-B). The redoximorphic pedofeatures are common in the indicating that the severity of (paleo) redox conditions increase in
whole profile. They are mainly orthic nodules of Fe-oxihydroxides, depth (bottom horizon with a Fe-depleted groundmass).
with different degrees of impregnation, and in the 2Btg horizons The main characteristic of the JS4 profile is its undifferenciated
hypo- and quasicoatings of iron oxides appear (Fig 3a-C and a-D), b-fabric throughout all the horizons, probably due to the mask-
indicating an increasing severity of redox conditions, from stagnic ing effect of the high amount of amorphous iron in the ground-
to gleying in depth. mass (Fig. 3b-G). Pedofeatures are either related to redoximor-
The JS3 profile has also a subangular blocky structure and a phic features, mainly stagnic pattern, although not completely ex-
fairly high porosity throughout. The b-fabric of the topsoil is undif- pressed) or textural, as microlaminated intercalations and infillings
ferenciated, probably due to amorphous clays derived from the vol-
J.C. Loaiza et al. / GeoResJ 14 (2017) 20–35 31

Table 6
Mineral composition in the coarse silt fraction of the studied soils. The minerals, cristals or grains were identified by their features, and counted as they cross the
intersection of horizontal and vertical lines on the microscope’s eyepiece. 300 grains were counted and according this the percentage of each mineral was determined.

Horizon Depth (cm) Qz A Zr Ma Hr Hs P Phy Fp LFg Op He Vg AGr L T E B M Mi

JS1
A 0–28 20 – – – – – – – 40 5 – – 35 – – – – – – –
R 28–100 – – – – – – – – – – – – – – – – – – – –

JS1 (0–22 cm. depth) 10×. N. crossed. Qz-Fp


JS2
Ap 0–30 35 12 – – – – 5 tr 27 – 4 – 5 9 – – 3 – – –
AB 30–49 37 8 – – – – 4 tr 31 – 2 – 5 10 – – 3 tr – –
2Btg1 49–70 43 2 – – – – tr tr 30 – tr – tr 22 – – tr tr tr –
2Btg2 70–120 40 tr tr – – – – – 24 – tr – tr 34 – – – – tr –

JS2 (30–49 cm depth). N. crossed 10×. Qz, A, Vg


JS3
Ap 0–23 45 2 – – – – tr 3 37 – tr – tr 11 – – tr – – –
2Btg1 23–54 55 tr tr – – – – tr 38 – tr – – 5 – – – – – –
2Btg2 54–70 75 tr – – – – – tr 16 – tr – – 7 – tr – – – –
2Btg3 70–92 76 – – – – – – – 15 – tr – – 8 – tr – – – –
2Btg4 92–120 70 tr – – – – – – 7 – tr – – 9 – – – – – –

JS3 (23–54 cm depth) N. crossed 10×. Qz


JS4
Ap 0–25 100 – tr tr tr tr – tr tr tr – tr tr tr – – – – – –
AB 25–45 97 – tr 1 1 tr – 1 tr tr – tr tr tr tr tr – – – –
2Btg1 45–59 100 – tr tr tr tr – – tr tr – tr – – – tr – – – –
2Btg2 59–88 99 – tr tr tr tr – – – 1 – tr – – – tr – – – –
2Btg3 88–110 99 – tr tr tr tr – tr – 1 – tr – – – – – – – –

JS4 (25–45 cm. depth). N. crossed. 10×. Qz

JS5
Ap 0–18 96 1 tr tr – 1 – tr 2 tr – tr – – tr tr – – – –
2Btg1 18–56 97 tr tr 1 – tr – tr 1 tr – tr – – tr 1 – – – –
2Btg2 56–79 98 tr tr tr – tr – – tr 2 – tr – – – tr – – – –
2Btv 79–103 99 – tr tr – – – tr tr – 1 – – – – – – –
2Btg 103–117 97 – tr tr – tr – – tr 3 – tr – – – tr – – – –

JS5 (56–79 cm depth) N. parallel. Qz.


(continued on next page)

of kaolinite, but also mottled coatings in the lowermost horizon clayey, and shows patches with vesicular microstructure stained
(Fig. 3b-H). with a network of purple iron oxi-hydroxides, which suggests a
Profiles JS5 and JS6 are characterized by a stipple specked b- lithological discontinuity. According to Jungerius [37], loss of clay
fabric at the surface that becomes mosaic- and stipple speckled is related to alternating dry and wet conditions during Holocene.
in depth. The type of amorphous pedofeatures, together with the Again, the two types of kaolinite coatings and intercalations (some
colour of the groundmass (yellow at the surface, greyish in depth) microlaminated, some mottled) coexist in the JS5 profile, while
correspond again to stagnic patterns at the topsoil (Fig. 3b-I) and only microlaminated coatings are seen in JS6 (Fig. 3b-J and b-K).
gleyic at the bottom of the profile. The lowermost horizon is more
32 J.C. Loaiza et al. / GeoResJ 14 (2017) 20–35

Table 6 (continued)

Horizon Depth (cm) Qz A Zr Ma Hr Hs P Phy Fp LFg Op He Vg AGr L T E B M Mi

JS6
Ap 0–26 89 – – – – – – – 11 – tr – – – – – – – – –
AB 26–33 75 tr tr – – – tr – 17 – 6 – – – – tr – – – –
Bt1 33–49 71 tr tr – – – tr – 19 – 8 – – – – tr tr – – –
Bt2 49–59 77 tr tr – – – – – 17 – 5 – – – – – – – – tr
Bt3 59–82 82 – tr – – – – tr 8 – 9 – – – – – – – – tr
Bt4 82–100 86 – tr – – – – – 6 – 7 – – – – – tr – – tr

JS6 (18–60 cm. depth). N. parallel. Qz-Fp

Qz, quartz; A, amphibole; Zr, zircon; Ma, magnetite; Hr, hornblende; Hs, hyperstene; P, pyroxene; Phy, phytolites; Fp, feldspar; LFg, lithic fragments; Op, opaque; He,
hematite; Vg, volcanic glass; Agr, altered grains; L, lamprobolite; T, turmaline; E, epidote; B, biotite; M, muscovite; Mi, other micas; tr, traces (<1%).

In summary, the micromorphology shows dominant stagnic re- conditions, as they are found in periglacial environments [6] or to
doximorphic patterns in topsoils and gleyic in depth (except at a high ESP [20,52]. In our case, the mottled coatings are found at
the bottom of profile JS5, where a more clayey horizon could be depth in the non-sodic, proximal profiles; related to paleofeatures
responsible of a perched watertable), these results are coincident of a periglacial environment. High sodium concentration along the
with Folster et al. [22]. This pattern confirms the existence of a re- soil profile in the distal part of the fan is associated to actual
gional waterlogging from the underlying horizons that could be a climatic (dry seasonal) conditions. Regarding the microlaminated
paleofeature. coatings in the distal profiles, they are neither typical of Na-high
Mottled kaolinite coatings, due to silty organic punctuations soils. Since sodification is a present-day process, we could rather
coexist with microlaminated kaolinite coatings, sometimes in the attribute this feature to the higher leaching of the megafan just af-
same horizon. This suggests two generations of coatings, i.e. a first ter the tilting, that was afterwards progressively being sodified by
one (paleofeature) from lacustrine organic layers and a second one the leaching of weathering products of Na-rich parent materials at
(a present-day soil formation process) from clean illuviated clay the source areas of the fan and their accumulation at the distal,
from upper horizons. more arid areas [36,51,56,81].
Another striking feature is the well expressed striated fabrics, The striated fabrics of the groundmass, typical of soils with
common in all profiles except in JS1 (high organic matter content) swelling clays, do not correspond to the kaolinitic mineralogy of
and JS4 (high Fe content); while the clay mineralogy is kaolinitic the soils. Despite of this, soil surveys of the area report frequent
(only traces of swelling clays), and therefore no argilloturbation cracking of the soils in dry periods, which may be due just to the
should be expected. Under lacustrine paleoenvironments, the de- high clay content [32,33]. In any case, part of the striation may
position of kaolinitic clays originates (uni)strial fabrics which un- be due to kaolinite sedimentation in a swampy environment, that
der better drainage conditions and the effect of fauna could evolve was later drained (disturbed) and bioturbated, giving rise to the
to the observed striated fabrics [41]. striation we observe today, due to the seasonal regime (dry-wet).
The current hydromorphic conditions will be influenced by geo-
3.5. Paleohydrological and paleopedological implications morphological position of the water table, which varies with the
topography and if its position is relevant to the formation of soil
Hydromorphic processes are evident in all profiles, both in the [1,64]. The poorer drainage conditions together with water oversat-
field and through the microscope. The micromorphological study urated with silica would have prevented p. ex imperflectly drained
shows different degrees of hydromorphism, some of them asso- soils on the valley bottom [44]. These results are a contribution to
ciated to the present pore system and some to a palaeo char- studies of paleoenvironmental conditions in an Andean megafan,
acter (broken and disturbed redoximorphic pedofeatures). In par- during the Late Pleistocene and Holocene.
ticular, a clear gleyic pattern is observed at the base of profiles
JS2, JS3 and JS6, which does not correspond with the present- 4. Conclusions
day drainage class according to Jungerius [37] and Folster et al.
[22], because of the lack of a water table and the soil surveys of The studied soils of the Fusagasuga megafan are polygenetic
the area [35,56,81]. This paleocharacter corresponds thus to the and characterized by ancient processes as clay formation and il-
poorly-drained conditions previous to the tilting of the megafan. luviation, and redox processes in moist periods. The parent mate-
These evidences are less visible in the topsoils, which nowadays rials, formed by colluvial fluxes between the last interglacial and
have good drainage conditions. Soil profiles reveal the existence glacial periods underwent a high degree of weathering (kaolinite
of two distinct episodes of weathering corresponding to modern formation). After that, the megafan was affected by a poor drainage
soils (Andisols) and paleosols formed on volcano colluvial deposits (marsh-like conditions), that formed a strial b-fabric in the par-
[46] and glaciofluvial deposits in the intermontane environments ent material and gleyic redoximorphic patterns. In the middle and
[28]. A chronostratigraphy and climatic evolution in relation to soil early pleistocene, Andean tectonic phenomena (tilting) changed
forming processes are proposed in Table 7 according Van der Ham- the drainage conditions to more oxidized ones, which originated
men [75] results. more complex soil profiles with a stable organic matter accumula-
The micromorphological study reveals the presence of two tion. This organic matter was associated to rejuvenation phenom-
types of clay coatings, some of them kaolinitic and microlaminated ena (Andean volcanic period- late pleistocene) by wind deposited
(profiles JS4 and JS6), whilst other coatings are mottled, made of volcanic ashes on the upperfan positions in the mountainous area.
silt, clay and organic punctuations (profiles JS2, JS3 and base of Halloysite and Metahalloysite evidence the presence of no crys-
JS6). The latter should therefore correspond to higher dispersive talline minerals, as allophane.
J.C. Loaiza et al. / GeoResJ 14 (2017) 20–35 33

Table 7
Chronostratigraphy and climatic evolution in relation to soil forming processes, based on the dating results of Van Der Hammen [75,76].

Years Geotectonic Soil forming Micromorphological Climatic


Chronostratigraphy dynamics Morphogenetic process characteristics evolution
environ-
ment

Holocene >20 0 0 Recent Structural- Organic matter Faunal passages, Wet climate
neotectonics Denudative accumulation, mixing materials of
clay illuviation. the underlying
horizons,
redeposited
nodules of
Fe-oxihydroxides.
Organic matter
accumulation
(undifferenciated
b-fabrics), limpid
clay coatings.
10,0 0 0 Erosion and
anthropic
influence, clay
illuviation.
Late 30,0 0 0 Tectonism- Andolization, Dusty clay coatings, Cold and more
Pleistocene vulcanism Depositional: clay and silt infillings and dry than
Fusagasugá illuviation intercalations (not present climate
megafan related to present with
pore system). temperature
and moisture
fluctuations
Middle and 70,0 0 0 Fluvioglacial Redox Strial fabrics due to Glacial climatic
Early deposition Sedimentary processes and the sedimentation changes (dry)
Pleistocene (gravels and megabasin- clay deposition of kaolinite, to interglacial
angular rock Fusagasugá Redoximorphic (humit)
fragments) patterns (Stagnic
and gleyic).
Miocene- 7–6 My Tectonic uplift Vulcanism Erosion and Tropical climate
Pliocene of the Oriental sedimentation (wet and
mountain range warm)

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