Beruflich Dokumente
Kultur Dokumente
Unit Cell
- Most basic and least volume consuming repeating structure of any solid.
- Crystalline lattice is the regular repeating pattern of atoms in a crystal
- Lattice Contribution
Corner: 1/8 of a point
Face: ½ of a whole point
Body: 1 whole point
Characteristics of a crystal structure
Coordination number- the numbers of atoms touching a particular atom, or the
number of nearest neighbors.
Atomic Packing Factor (APF)- the fraction of space occupied by atoms assuming
that atoms are hard spheres
𝑽𝑶𝑳𝑼𝑴𝑬 𝑶𝑭 𝑨𝑻𝑶𝑴𝑺 𝑰𝑵 𝑨 𝑼𝑵𝑰𝑻 𝑪𝑬𝑳𝑳
𝑨𝑷𝑭 =
𝑽𝑶𝑳𝑼𝑴𝑬 𝑶𝑭 𝑻𝑯𝑬 𝑼𝑵𝑰𝑻 𝑪𝑬𝑳𝑳
Basic Cubic Unit Cell
Note: It is important to know and put units to easily determine the end units
𝒈
𝝆 = 𝟏𝟏. 𝟑𝟒𝟕𝟐
𝒄𝒎𝟑
Example 2: Copper had the most essential industrial applications of the three coinage metals
[Group 1B(11)]. Its crystal structure adopts cubic closest packing, and the edge length of the
unit cell is 361.5 pm. What is the atomic radius of copper?
Solution:
𝑎 = √𝟖𝒓
361.5 𝑝𝑚 = √𝟖𝒓
𝒓 = 𝟏𝟐𝟕. 𝟖𝟎𝟗𝟔 𝒑𝒎
Example 3: Tantalum is a rare, hard, blue-gray, lustrous transition metal that is highly corrosion-
resistant. It has a density of 16.4 𝑔/𝑐𝑚3 and a molecular weight of 180.948 g/mol. What is the
atomic radius of Ta if it adopts the body centered cubic unit structure?
Solution:
𝒏𝑨
𝝆=
𝑽𝒄 𝑵 𝑨
𝒈
𝒈 𝟐 𝒂𝒕𝒐𝒎 (𝟏𝟖𝟎. 𝟗𝟒𝟖 )
𝟏𝟔. 𝟒 = 𝒎𝒐𝒍
𝒄𝒎𝟑 𝟑
𝟒 𝒂𝒕𝒐𝒎
( 𝒓) (𝟔. 𝟎𝟐𝟑 × 𝟏𝟎𝟐𝟑 )
√𝟑 𝒎𝒐𝒍
𝒓 = 𝟏. 𝟒𝟑𝟖𝟐 × 𝟏𝟎−𝟖 𝒄𝒎
Bonding in Solids
1. Molecular (formed from molecules) - usually soft with low melting points and poor
conductivity.
- Solids made of molecules held together by van der waals force
- Properties: brittle, low melting point, poor conductors of heat and electricity
- Ex.: Ice, dry ice, sugar, inert gases (O2 , N2 , H2 )
2. Covalent - very hard with very high melting points and poor conductivity.
- 3D collection of atoms held together by covalent bonds
- Properties: high melting point, poor conductors of heat and electricity
- Ex.: Diamond, quartz, graphite
3. Ionic (formed form ions) - hard, brittle, high melting points and poor conductivity.
- Solids held together by ionic bonds
- Properties: brittle, high melting point, poor conductors of electricity
- Ex.: NaCl, Copper(II) Nitrate, ZnS
4. Metallic (formed from metal atoms) - soft or hard, high melting points, good conductivity,
malleable and ductile. A solid with only one type of atom is also called ‘atomic.
- Solids composed of metals
- Properties: variable melting and boiling points, good conductor of heat and electricity
- Ex.: Copper, Iron, Silver, Gold
MODULE 6: POLYMERS
History of Polymers
- 4.5 Billion years ago, polymers already existed
- The human body is made up of polymers such as nucleic acid and proteins
- 1500s: Mayans used polymers from local rubber trees, for ball games
- 1844: Charles Goodyear discover vulcanization by combining natural rubber with sulfur and
heating it to 270 degrees Fahrenheit. Vulcanized rubber is still used up to this date
- 1910: Oldest recorded synthetic polymer known as Bakelite was fabricated by Leo Bakeland
- 1927: Large Scale Production of vinyl-chloride resins begins. This are widely used today to
make plumbing pipes (PVC) and bottles
- 1930: Polystyrene is invented and used for video cassettes and other packaging. Extended
polystyrene (Styrofoam) is used in cups and thermally insulated containers
- 1938: Wallace Carothers of Dupont Company produced nylon. Nylon is a common material
used in clothes and ropes
- 1971: S. Kwolek develops Kevlar. It is a high strength material that can withstand high
temperature and is used in bullet proof vests and fire proof garments
Polymer
- Greek prefix “poly” which means “many” and suffix “meros” which means “parts”
- is a large molecule made up of chains or rings of linked repeating subunits, which are
called monomers.
- usually have high melting and boiling points
- has high molecular weight, can reach more than 1,000,000 g/mol.
Classifications of Polymers
Homopolymer- a polymer containing only one monomer
Ex. A + A + A + A …. To AAAA….
Copolymer- a polymer containing two or more different monomers.
A + B + A + B …. To ABAB….
Linking of Polymer
- Strong hydrogen bonds occur among polar covalent molecules containing H and one of
the three small, highly electronegative elements: F, N, O
- The attraction between a slightly positive H atom on one water molecule to the slightly
negative O atom of another is known as hydrogen bond
- Each water molecule can form four hydrogen bonds with other molecules
- Because of the hydrogen bond, the water has a boiling point of 100°C higher than if the
bond were not present
Intermolecular forces in Water
Dipole-Dipole attractions: The intermolecular forces arise due to the presence of dipoles
in the molecules. Polar molecules attract each other. “like attracts like”
Ion-Dipole attractions: This involves a charged molecule attracting a polar molecule.
Intermolecular Forces in Solution Formation
- Substances with similar types of intermolecular forces dissolve in each other. “Like
dissolves Like”
- When a solute dissolve in a solvent, the following forces must be comparable in strength
in order for a solution to form.
solute-solute interactions
solvent-solvent interactions
solute-solvent interactions
Effect of Temperature on Solubility of Ionic Compounds
𝟎. 𝟐𝟏𝟕𝟏 𝒎𝒐𝒍
𝒎=
𝟏 𝒌𝒈
𝟗𝟎𝒈 × 𝟏𝟎𝟎𝟎𝒈
𝒎 = 𝟐. 𝟎𝟒 𝒎
Percentage (%)
- Weight % and Volume % do not depend on the units used (the numerator and
denominator must be expressed in the same units)
- Weight % is temperature independent
- To avoid uncertainty, always specify the type of percent composition being used.
- Example: The label on a 0.750-L bottle of Italian chianti indicates “11.5% alcohol by
volume.” How many liters of alcohol does the wine contain?
Solution:
v/v = 11.5%
vsoln= 0.750 mL
𝒗 𝑽𝒂𝒏𝒂𝒍𝒚𝒕𝒆
= × 𝟏𝟎𝟎
𝒗 𝑽𝒔𝒐𝒍𝒖𝒕𝒊𝒐𝒏
𝑽𝒂𝒏𝒂𝒍𝒚𝒕𝒆
𝟏𝟏. 𝟓% = × 𝟏𝟎𝟎
𝟎. 𝟕𝟓𝟎 𝒎𝑳
𝑽𝒂𝒏𝒂𝒍𝒚𝒕𝒆 = 𝟎. 𝟎𝟖𝟔𝟐𝟓 𝑳
- Example: What is the mass percentage of H2O2 in a solution with 1.67 g of H2O2 in a
55.5 g sample?
Solution:
W H2O2 =1.67 g
Wsample=55.5 g
𝒘 𝑾𝒂𝒏𝒂𝒍𝒚𝒕𝒆
= × 𝟏𝟎𝟎
𝒘 𝑾𝒔𝒐𝒍𝒖𝒕𝒊𝒐𝒏
𝒘 𝟏. 𝟔𝟕𝒈
= × 𝟏𝟎𝟎
𝒘 𝟓𝟓. 𝟓 𝒈
𝒘
= 𝟑. 𝟎𝟏%
𝒘
Parts per thousands (ppth), parts per million (ppm), parts per billion (ppb)
- Often used for very dilute concentrations.
𝒘𝒆𝒊𝒈𝒉𝒕 𝒐𝒇 𝒂𝒏𝒂𝒍𝒚𝒕𝒆 𝒈 𝒈
𝒑𝒑𝒕𝒉 = × 𝟏𝟎𝟑 = ,
𝒘𝒆𝒊𝒈𝒉𝒕 𝒐𝒇 𝒔𝒂𝒎𝒑𝒍𝒆 𝒌𝒈 𝑳
𝒘𝒆𝒊𝒈𝒉𝒕 𝒐𝒇 𝒂𝒏𝒂𝒍𝒚𝒕𝒆 𝒎𝒈 𝒎𝒈
𝒑𝒑𝒎 = × 𝟏𝟎𝟔 = ,
𝒘𝒆𝒊𝒈𝒉𝒕 𝒐𝒇 𝒔𝒂𝒎𝒑𝒍𝒆 𝒌𝒈 𝑳
𝒘𝒆𝒊𝒈𝒉𝒕 𝒐𝒇 𝒂𝒏𝒂𝒍𝒚𝒕𝒆 𝝁𝒈 𝝁𝒈
𝒑𝒑𝒃 = × 𝟏𝟎𝟗 = ,
𝒘𝒆𝒊𝒈𝒉𝒕 𝒐𝒇 𝒔𝒂𝒎𝒑𝒍𝒆 𝒌𝒈 𝑳
- Example: Find the concentration of calcium (in ppm) in a 3.50-g pill that contains 40.5
mg of Ca.
Solution:
𝑤𝑝𝑖𝑙𝑙 = 3.50 𝑔
𝑤𝐶𝑎 = 40.5 𝑚g
𝟒𝟎. 𝟓 𝒎𝒈
𝒑𝒑𝒎 =
𝟏𝟎𝟎𝟎 𝒎𝒈 𝒎𝒈 𝒎𝒈
𝟑. 𝟓𝟎𝒈 × × 𝟏𝟎𝟔 = ,
𝟏𝒈 𝒌𝒈 𝑳
𝒑𝒑𝒎 = 𝟏𝟏, 𝟓𝟕𝟏. 𝟒𝟐𝟖𝟔𝟔 𝒑𝒑𝒎
Water Quality
- Water quality is commonly defined by its physical, chemical, biological and aesthetic
(appearance and smell) characteristics. A healthy environment is one in which the water
quality supports a rich and varied community of organisms and protects public health.
- The presence of contaminants and the characteristics of water are used to indicate the quality of
water.
- These water quality indicators can be categorized as:
Biological: Algae and bacteria
Physical: temperature, turbidity, and clarity, color, salinity suspended solids, dissolved
solids
Chemical: pH, dissolved oxygen, biological oxygen demand, nutrients (including
nitrogen and phosphorus), organic and inorganic compounds (including toxicants)
Aesthetic: odors, taints, color, floating matter.
Radioactive: alpha, beta and gamma radiation emitters.
Water Quality Indicators
Water hardness
- Hard water is water containing high amounts of mineral ions. The most common ions
found in hard water are the metal cations calcium (Ca2+) and magnesium (Mg2+), though
iron, aluminum, and manganese may also be found in certain areas. These mineral ions
can precipitate out and cause problems in water conducting or storing vessels like pipes.
- General Guidelines for classification of water
Degree of Hardness mg/L of CaCo3
Soft water 0-60
Moderately hard water 61-120
Hard water 121-180
Very hard water >180
pH
The pH of water determines if water is alkaline, acidic or neutral. Alkaline water is
drunk for health purposes. Neutral pH water is neither alkaline nor acidic. Pure water has
a neutral pH of 7, but pure water isn’t found in nature, and drinking it is bad for your
health.
Alkaline pH water: pH>7 Drink for good health and healing
Acidic pH water: pH<7 Use as hair rinse, it makes hair
manageable and shiny
A natural astringent so it can help your
skin look young and healthy
Strong acidic water is used for sanitation
Neutral pH water: pH=7 Safe to drink
Pure water: pH=7 Never drink pure water; it can actually
steal nutrients from your body!
pH of Natural Water
Coastal dune streams (pH<5)- Coastal sand dunes form a natural barrier against
wind and waves, protecting inland areas from damage due to storms. They also
provide habitat for plants and animals, including rare and endangered species.
Fresh water (6.5<pH<8.5)
Seawater (pH=8)
Estuary (pH=8.5)- An estuary is a partially enclosed coastal body of brackish
water with one or more rivers or streams flowing into it, and with a free
connection to the open sea.
Phospates (PO43-)
- Natural unpolluted water contains less than 0.1 mg/L of all the PO4 (higher
concentrations are caused by human pollution). An increase in phosphates and other
nutrients that increase the rate of plant growth eventually results in dead plant matter
building up in water.
Increasing phosphate concentration in water increases turbidity
Increasing phosphate reduces pH making water more acidic
Increasing phosphate reduces DO content
Total Phospate Effects on aquatic plant growth
0.025-0.1 mg/L Adequate stimulation of plant
growth
0.1 mg/L Maximum acceptable limit to
prevent accelerated eutrophication
>0.1 mg/L Accelerated growth and consequent
problems
Nitrites and Nitrates (NO2- , NO3- )
- Nitrites can react directly with hemoglobin in human blood which causes the blood cells
not to be able to carry oxygen to your cells. This causes a problem known as “blue baby
disease” in infants.
- Nitrates are found in fertilizers and help plants to grow. When it rains, nitrates wash or
runoff. When they find a water source to run into, it results in plants growing out of
control and reducing the amount of dissolved oxygen.
- Nitrates (NO3-) are the major polluters of ground water and also of many effluent and
influent waters. Can lead to: eutrophication of natural water systems (overproduction of
vegetation)
- Sources of Nitrates
Agricultural Sources
Nitrogen-based fertilizers
Natural/atmospheric
Sewage/septic waste
Animal manure
Ammonium (NH4+)
- The presence of ammonium in water shows that the water was in contact with rotting
organic materials, fecals, food wastes, etc. Ammonia is toxic to fish and other aquatic
organisms, even in very low amounts. The danger that ammonia presents for fish is
dependent upon the temperature of the water, the pH, and dissolved oxygen levels. The
higher the pH, the warmer the temperature, and the lower the DO, the more toxic the
ammonia is to fish.
Dissolved Oxygen
- DO is the measurement of oxygen dissolved in water and available for fish and other
aquatic life.
- Indicates health of an aquatic system.
- Can range from 0-18 ppm.
- Most natural water systems require 5-6 ppm to support a diverse population.
Water Pollution
- Water pollution occurs when harmful substances are released into the water in large
quantities which cause damage to people, wildlife, or habitat or indirectly into water
bodies without proper treatment to remove harmful compounds.
Contaminants of Water
Inorganic water pollutants include:
1. Acidity- caused by industrial discharges (especially sulfur dioxide from power plants)
2. Ammonia - from food processing waste
3. Chemical waste as industrial by-products
4. Fertilizers containing nutrients--nitrates and phosphates--which are found in storm water
run-off from agriculture, as well as commercial and residential use
5. Heavy metals from motor vehicles (via urban storm water runoff) and acid mine
drainage
6. Silt (sediment) in runoff from construction sites, logging, slash and burn practices or
land clearing sites.
Consequences of Water Pollution
- Eutrophication is characterized by excessive plant and algal growth due to the
increased availability of one or more limiting growth factors needed for photosynthesis
such as sunlight, carbon dioxide, and nutrient fertilizers.
- Bioaccumulation- increase in concentration of a pollutant in an organism
- Biomagnification (Bioconcentration)- Toxic substances become increasingly
concentrated within living organisms as they move up each of the food chain